• Journal of the Mineralogical Society of Korea
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• v.23 no.2
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• pp.151-159
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• 2010

The effect of calcite and gypsum on the hydration of Portland cement was investigated using GEM-PSI, a geochemical model. Addition of calcite and gypsum up to 5 wt% of total cement clinker into Portland cement was found to influence the hydrate assemblage of the hydrated cement in different ways. The results of geochemical modelling showed that the fraction of calcium monocarbonate increased by the hydration of cement with the increase of calcite addition. The results of modelling also indicated that gypsum increased the fraction of ettringite in the assemblage of hydrated cement as the amount of gypsum added increases. This study showed that porosity generated by the hydration of cement had a significant relation with the amount of calcite and gypsum added. The porosity of hydrated cement was lower when calcite added up to 3 wt% of cement clinker compared to the hydrated cement with the same amount of gypsum addition. However, when calcite added more than 3% of cement clinker, the porosity of hydrated cement were higher than that of hydrated cement with the same amount of gypsum addition.

• Resources Recycling
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• v.5 no.4
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• pp.32-41
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• 1996

The objective of this study was to investigate the facton affecting the property of CaCO, farmed from CaClz-Na,CO,-HiOsystem. The effcct of the concentmtlon of reaclants, impurity, the pH of reaction, the addition of sccd crystal, and injectingvelocity af reaclant solution an thc yield oI CaCO; polymorphs. parlide size and whiteness of CaCO, were investigated. Thcmqor resulls are ;o fallows; I The optimum concentratinn of reildilnts for forming vaterlte and aragonite is the range of 0.1-1.0 mol/l, when the yicld of vittcrite and araga~nles howed 7542% and XU-90%. respedively. 2. Among thc composition of impunticscontained h limestone, Fe' decrease the wh~tcness nf CaCO;. md Mg" increase the yield of aragonite. 3. The pHrange of vaterite and aragonite are formed with high yield is 8-11, and Calcite is famed in pH 6-8 with big particle size of 1over and in pH 11-13 with small particle size of I under. 4. The yicld of calcite and aragonite was increased by addingthc seed cryst.al nf itself.d cryst.al nf itself.

• Economic and Environmental Geology
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• v.40 no.4
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• pp.461-471
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• 2007

A temperature of deformation and the state and direction of paleostress at that time when twins in calcite grains had been produced were observed, using analysis of calcite twins as indicators of paleostress history. The study was performed with the target of carbonate rocks distributed randomly small size in the southern area of south Korea. Considering the appearance of twins (thin or thick straight twins with one or two twin sets), average twin strain (1.235-7.453%), thickness ($0.77-1.94{\mu}m$) and intensity (25.26-41.99 twins/mm) from the results of calculated calcite twins, it is estimated that calcite twins were produced under temperatures lower than approximately $150-200^{\circ}C$. In the magnitudes and directions of principal strains, the maximum shortening strain axis ($e_3\leftrightarrow{\sigma}_1$) is approximately N-S direction in the GS-1 area in the southern Gyeongsang Basin as well as in the BS-1 area in the southern Yongnam Massif, whereas E-W direction in the NR-1 area in the southwestern Ogcheon Fold Belt. In case of the maximum extension strain axis ($e_1\leftrightarrow{\sigma}_3$), it is oriented in NW-SE and NE-SW directions in the GS-1 and BS-1 area, respectively, and in N-S direction in the NR-1 area. That is, it is suggested that the paleostress which produced the calcite twins may be applied at least more than two times in the study area.

• The Journal of the Petrological Society of Korea
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• v.2 no.2
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• pp.95-103
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• 1993

The geology of the talc ore deposits in the Chungju area consists of the Kyemyeongsan Formation, the Munjuri Formation, the Daehyangsan Quartzite, the Hyangsanni Dolomite, and the basic rocks of the Ogcheon belt. The talc ore occurs in the Hyangsanni Dolomite near the Daehyangsan Quartzite The mineral assemblages in the Hyangsanni Dolomite are \circled1calcite-tremolite-talc-quartz, \circled2calcite-talc-quartz, \circled3tremolite-calcite-dolomite, and \circled4calcite-dolomite-phlogopite-chlorite. Talc has almost the ideal composition($X_{Mg}$=Mg/(Fe+Mg)=0.98). Talc was formed in siliceous dolomite by the medium-pressure type regional metamorphism. The evidences for contact metamorphism and/or hydrothermal reaction are not clear. The metamorphic grade of the Hyangsanni Dolomite and its adjacent pelitic or basic rocks near the deposits corresponds to epidote-amphibolite facies or greenschist facies based on the, mineral assemblages of \circled1hornblendebiotite-muscovite-epidote-quartz \circled2biotite-chlorite-quartz, and \circled3hornblende-actinolite-plagioclasequartz. The formation of the talc deposits were caused by the following reactions due to greenschist facies metamorphism of siliceous-dolomitic rocks in the Hyansanni Dolomite. (I) 3 dolomite+4 quartz+$H_2O$= talc+ 3 calcite +3 $CO_2$; (11) 3 tremolite+ 2 $H_2O$+ 6 $CO_2$= 5 talc+ 6 calcite + 4 quartz. The minimum temperature of the talc-tremolite-quartz assemblage is about $434^{\circ}C$ from calcite thermometry and the carbon dioxide mole fraction in metamorphic fulid($X_{$CO_2$}$) is about 0.1 at assumed pressure, 3 kbar.

• Economic and Environmental Geology
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• v.43 no.1
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• pp.21-31
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• 2010

Mine and leachate waters were collected from the Okdong mine for study on reaction with oxidizing agents such as NaOCl and $H_2O_2$. The pH and EC of the mine and leachate waters are 5.77, 831 uS/cm, and 6.38, 1920 uS/cm, respectively. The concentrations of Mg, Mn, and Zn are 23.25 mg/l, 14.90 mg/l, and 22.99 mg/l for the mine water and 98.75 mg/l, 3.38 mg/l, and 6.16 mg/l for the leachate water. The concentrations of Mg, Mn and Zn decreased after the reaction with the oxidizing agents and mine water. The concentrations of Mg, Mn and Zn rapidly decreased when oxidizing agents increased. The saturation indices that were computed by visual MINTEQ for initial mine and leachate water were undersaturated with Mg, Zn and Mn compounds. The precipitates after the reaction with the oxidizing agents are composed mainly of mangano-calcite[(Mn, Ca)$CO_3$] with small amount of calcite-magnesian and calcite.

• The Journal of Engineering Geology
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• v.8 no.1
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• pp.75-86
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• 1998

Eighteen oriented samples from the Jeongsun limestone of the Joseon Supergroup are collected. The orientations of C-axis of calcite and e twin plane, the average thickness, numbers of twins and the widths of calcite grains in 10 samples are measured. Then, the twin strain, mean width, intensity of twin and relative magnitude and orientations of principal stresses are calculated using Calcite Strain Gauge program. Twin strain, mean width and intensitv rainge between 0.801%~10.927%, $0.43{\mu\textrm{m}}~2.03{\mu\textrm{m}}$, and 33.5~113.4twim/mm, respectively. Metamorphic temperatures calculated from twin show below $70^{\circ}C$, indicating that twins were developed within 2.3km depth. In five samples, two events with different orientations of principal stress produced calcite twins, while only one event produced calcite twins in five samples. The direction of the maximum stress is almost horizontal and the minimum is almost vertical, indicating that the stress regirne is identical with thrust fault. E-W and NW-SE are the most dominant directions of comressive stress and N-S and NE-SW directions are also shown. Comparision between paleostress orientations measured in the study and others indicates that the maximum horizontal stress oriented to E-W may represent the paleostress of period either from the Silurian to the Triassic or from the Silulian to the Permian. Paleostress oriented to NW-SE may be the major direction of stress during the Daeho orogeny.

• Journal of the Korean Geotechnical Society
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• v.32 no.5
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• pp.5-13
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• 2016

A calcium source is necessary for calcite precipitation within soil particles by microbial decomposition of urea and a calcium chloride is usually used. The harmful environmental impact of calcium chloride on road, ground and plants is severe. In this study, an eggshell with vinegar is investigated for an environmental-friendly calcium source. Urea-decomposing microorganism and eggshell or calcium chloride as a calcium source are mixed with Ottawa sand to precipitate calcite. Then, the cemented sand with calcite is tested for calcite precipitation, permeability and unconfined compressive strength. A specimen is prepared by loose Ottawa sand in a size of 5 cm in diameter and 10 cm in height. A urea solution with Sporosarcina pasteurii and two different calcium sources is injected into the specimen once a day for 30 days. Calcite precipitated at average of 7.2% on the specimen with eggshell as a calcium source, which was 1.2 times more than that with calcium chloride. The permeability of a specimen with eggshell was at average of 3.82E-5 cm/s, which was 7.7 times lower than that with calcium chloride. Unconfined compressive strength of a specimen with eggshell was at average of 387 kPa, which was 1.2 times higher than that with calcium chloride. As more calcite precipitated, the strength increased while the permeability decreased, regardless of calcium sources.

• Korean Chemical Engineering Research
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• v.60 no.4
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• pp.564-573
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• 2022

Calcium carbonate (CaCO₃) exhibits three polymorphs: calcite with arhombohedral, vaterite with a spherical, and aragonite with a needle-like structure. Qualitative and quantitative analyses of the morphology of CaCO₃ are very important to investigate the synthesis of single-crystal vaterite and aragonite. In this work, the polymorphs of calcium carbonate were quantitatively analyzed using XRD. Pure vaterite and pure aragonite were synthesized and the peak distribution of a single phase was analyzed. The vaterite fraction of a mixture of calcite and vaterite was calculated based on the intensity of a specific diffraction peak, and compared to the results based on the peak area. The mean value of f_sV (the correction factor for the peak area of vaterite) was 0.654. The phase analysis of calcite-aragonite mixtures was performed, and the mean value of f_sA (the correction factor for the peak area of aragonite) was obtained as 0.6713. Using these factors, Eq. (24)~Eq. (32) for the quantitative analysis based on the total peak area of XRD were derived to calculate the phase contents of ternary phase CaCO₃. And three-component XRD section was defined considering overlapping sections.

• KSBB Journal
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• v.29 no.3
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• pp.188-192
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• 2014

Calcite forming bacteria (CFB) have been received increasing attention as a novel and environmental friendly strategy for the healing of concrete crack. Among the CFB, spore forming bacteria were proposed to overcome concrete condition (high pH, hydration heat, deicer). In this study, Lysinibaclillus sphaericus WJ-8 (WJ-8) isolated from concrete pavement was characterized. The WJ-8 was able to precipitate calcite at 10 mg/mL. When observed by scanning electron microscopy, WJ-8 showed spore formation and maximum spore yield was approximately 97.9%. Also response of spores against various environment stresses was examined. Approximately 83~97% of spores maintained their survivability at each three conditions ($60^{\circ}C$, 3 M NaCl and pH 12).

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.5 no.2
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• pp.175-180
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• 1995

In order to clarify the part of thermal properties of coal fly ash, the change of mineral compositions of the heated coal fly ash was investigated by XRD, TG - DTA and SEM. It was found that the mineral composition of coal fly ash was quartz, mullite and glassy phase ( a b. 20 ~ 25 wt % ), and had no difference in the range of 105 to $1000^{\circ}C $. Only in the case of Ansan coal fly ash, calcite was detected besides the crystalline of quartz and mullite. And anorthite was produced by the reaction between thermal- decomposed calcite, quartz and $Al_2O_3$component in the glassy phase at $1200^{\circ}C $.