• 접착 및 계면
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• 제3권4호
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• pp.1-9
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• 2002

본 연구의 목적은 목분과 폴리프로필렌으로 제조한 목질-고분자 복합재료의 점탄성적 성질에 미치는 결합제, 기핵제의 영향에 대해 고찰하는데 있으며, 목분과 결합제간의 esterification 반응이 목질-고분자 복합재의 기계적 성질에 미치는 영향 또는 고찰하고자 한다. 복합재는 목분 60%와 폴리프로필렌 40%를 혼합하여 제조하였으며, DMTA (Dynamic mechanical thermal analysis)를 사용하여 damping peaks (than ${\delta}$), storage modulus (E'), loss modulus (E")를 측정하였다. 또한 XPS (X-ray Photolectron Spectroscopy)를 사용하여 목분에 MAPP를 처리하기 전과 후의 상태를 고찰하였다. DMA 시험은 온도범위 $-20{\sim}100^{\circ}C$에서 여러가지 주파수 (1, 5, 10, 25 HZ) 조건과, 승온속도 $5^{\circ}C/min$으로 실시하였다. 이 시험결과를 토대로 복합재의 활성화에너지를 구하여 결합제와 기핵제가 목분과 고분자물질간 계면의 성질에 미치는 영향을 고찰하였다.

• The Journal of the Acoustical Society of Korea
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• 제14권2E호
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• pp.91-97
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• 1995

본 논문은 저비트율을 갖는 고품질의 HDTV용 멀티채녈 오디오 코덱을 구현에 대해 기술한다. 이 코덱은 저주파수 효과 채널을 포함한 최대 3/2 스테레오 채널 구성, 최대 채널 구성보다 낮은 채널 구성과의 호환성, 기존 2채널 스테레오 시스템과의 호환성(MPEG-1 오디오), 그리고 다중 대화 채널 등을 제공하는 특징을 갖는다. 구현한 멀티채널 오디오 코덱의 인코더는 3개의 DSP(TI의 TMS320C40)로 구성되었고, 최대 48KHz 샘플링율과 16비트의 부호화를 갖는 5.1 채널의 아날로그 및 AES/EBU, IEC 958등의 포맷을 갖는 스테레오 2채널의 디지털 오디오를 이력으로 받아 지각 심리음향 모델을 사용하여 압축한후 384Kbps의 빛 스트림으로 전송하는 특징을 가지며, 디코더는 2개의 DSP로 구성되어 있고, 384Kbps로 입력되는 비트 스트림을 받아 최대 5.1 채널의 아날로그 및 2개의 2채널 스테레오의 디지털 오디오 신호로 출력시키는 특징을 갖는다. DSP를 이용한 다중처리는 DMA를 통한 통신포트를 이용한 DSP들간의 고속 데이터 전송에 의해 이루어진다. 끝으로, 멀티 채널 오디오 코덱의 구현을 통하여 나타난 실시간 처리는 위해 고려해야할 기술적 사항을 제안한다.

• Macromolecular Research
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• 제11권6호
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• pp.418-424
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• 2003

Exfoliated poly(methyl methacrylate-co-styrene) [P(MMA-co-ST)]/silicate nanocomposites were synthesized through a multistep emulsion polymerization. The methyl methacrylate monomers were polymerized first and then the styrene monomers were polymerized. The nanocomposites had core-shell structures consisting of PMMA (core) and PS (shell); these structures were confirmed by $^1$H NMR spectroscopy and TEM, respectively. P(MMA-co-ST) copolymers showed two molecular weight profiles and two glass transition temperatures (T$_{g}$) in GPC and DMA measurements. At 30 $^{\circ}C$, the nanocomposites exhibited 83 and 91 % increases in their storage moduli relative to the neat copolymer because the silicate layers were dispersed uniformly in the polymer matrix.x.

• 전기학회논문지
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• 제62권5호
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• pp.649-656
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• 2013

A conventional epoxy-microsilica composite (EMC) and an epoxy-microsilica-nanosilicate composite (EMNC) were prepared in order to apply them to mold-type transformers, current transformers (CT) and potential transformers (PT). Nanosilicate was exfoliated in a epoxy resin using our electric field dispersion process and AC insulation breakdown strength at $30{\sim}150^{\circ}C$, glass transition temperature and viscoelasticity were studied. AC insulation breakdown strength of EMNC was higher than that of EMC and that value of EMNC was far higher at high temperature. Glass transition temperature and viscoelasticity property of EMNC was higher than those of EMC at high temperature. These results was due to the even dispersion of nanosilicates among the nanosilicas, which could be observed using transmission electron microscopy (TEM). That is, the nanosilicates interrupt the electron transfer and restrict the mobility of the epoxy chains.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 1998년도 하계종합학술대회논문집
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• pp.835-838
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• 1998

본 연구에서는 칼라 CCD 센서를 제어하여, shading과 .gamma. correction 된 데이터를 읽어 들여, 이를 이진레벨 데이터로 바꾼후, 원래의 다치레벨 또는 이진레벨 데이터를 SCSI나 DMA I/F를 통해 전달하는 ASIC을 설계하였다. 본 ASIC에서는 이진화를 위하여 문자 모드에서는 simple threshold와 LAT(local adaptive threshold) 알고리즘을, 그림모드에서는 stucki error diffusion 알고리즘을 적용하였다. 그리고, 구성은 CCD센서 제어블락, 스텝 모타 제어제어블락, 이미지 축소블락, 데이터 이진화 블락, 그리고 DATA I/F 블락 등으로 이루어져 있다. 또한 사용된 technology는 삼성 0.5um CMOS standard cell이며, 크기는 45K gates(내부 메모리 제외)이고, 160QFP package로 구현되었다. ㅎㅁㅅㄷㄴ (soqn apa

• 폴리머
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• 제25권2호
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• pp.226-232
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• 2001

The properties of poly(ethylene terephthalate) (PET)/maleic anhydride-grafted polypropylene (MAgPP)/poly(styrene-co-maleic anhydride)(PScMA) ternary blend were investigated. The ternary blend was immiscible based on the glass transition temperatures measured by dynamic mechanical analyzer (DMA). The degradation of MAgPP during melt mixing for 30 min at 280$^{\circ}C$ did not affect the properties of the ternary blend. The interaction among the components was confirmed from the rheological properties, which was increased with the PSCMA contents. In terms of the mechanical properties, it was observed to satisfy the mixture rule for a multiple system.

• 한국안전학회지
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• 제18권4호
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• pp.57-63
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• 2003

Thermal degradation of Acrylonitrile butadiene rubber(NBR), which is used for O-ring material as elastomeric sealed diaphragm value in the nuclear power plants, is examined. The thermal degradation is accelerated at 130$^{\circ}C$ by Arrhenius exploit method using the activation energy calculated by thermogravimetric analysis. The weight loss temperature and glass transition temperature are verified for thermally aged NBR. The relationship between dynamic mechanical properties and elongation at break are also investigated. The threshold alue of thermally aged NBR is a ten year in the change of elongation at break.

• Bulletin of the Korean Chemical Society
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• 제32권spc8호
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• pp.3074-3080
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• 2011

We synthesized three novel poly(norbornene bisimide)s by ring opening metathesis polymerization (ROMP) and subsequent hydrogenation. Their thermal, mechanical and optical properties were investigated with TGA, DMA, UV-Vis spectrometer, and optical reflectometer. The new polymers showed high glass transition temperatures over $260^{\circ}C$ and good thermal stability with 5% wt-loss temperature higher than $390^{\circ}C$. When solvent casted, they yielded optically transparent and dimensionally stable films with a relatively low coefficient of thermal expansion of about 50 ppm $K^{-1}$. Therefore, the bisimide moieties substantially enhanced thermal and dimensional stabilities, as compared with normal ROMP-prepared polynorbornene films. Though the water uptake was increased to 0.6 wt-%, this water uptake is still considerably lower than that for polyethersulfones (1.4 wt-%) or polyimides (2.0 wt-%). Hence, the new poly(norbornene bisimide)s may become attractive candidates for flexible substrates of optoelectronic devices such as displays and photovoltaic solar cells.

• 한국환경과학회지
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• 제21권11호
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• pp.1339-1348
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• 2012

The versatile aerosol concentration enrichment system (VACES) have proven useful for providing elevated levels of atmospheric aerosol to human and animal exposures. In this study, we describe a VACES and tests conducted to both optimize the enhancement factor (EF) and characterize how it depends on experiment conditions. Particle number concentrations were measured from upstream and downstream of the system by scanning mobility particle sizer (SMPS) with a long differential mobility analyzer (DMA) in combination with a condensation particle counter (CPC). SMPS was used for to determine VACES particle EF. Particle EF tends to increase for higher the saturator temperature ($T_{Sat}$) and lower the condenser temperature ($T_{Con}$). $T_{Con}$ higher than $0^{\circ}C$ and $T_{Sat}$ lower than $50^{\circ}C$ was the best to obtain the most increase in particle concentration. Correlation analysis of EF with factor variables of $T_{Sat}$ and $T_{Con}$ resulted in correlation 0.662 and 0.416, respectively. With all five predictor variables included in a multiple regression model, the EF had a liner correlation with $R^2=0.643$.

• 대한기계학회논문집B
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• 제28권9호
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• pp.1117-1123
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• 2004

The characteristics of soot near the soot inception point for an ethene-air flame was carried out in a WSR (well-stirred reactor). The new sampling tool like the temperature controlled filter system was introduced to minimize the condensation during sampling. The new analysis tools applied include the real time size distribution analysis with the Nano-DMA, particle size by transmission electron microscopy, C/H analysis, g filter analysis, and thermogravimetric analysis using both non-oxidative and oxidative pyrolysis. The WSR can generate young soot particles that can be collected and examined to gain insight into inception. For the current conditions, soot does not form for ${\Phi}$=1.9, inception occurs at or before ${\Phi}$=2.0, and inception combined with soot surface growth and/or coagulation occurs for ${\Phi}$=2.1. The filter samples for ${\Phi}$=1.9 are composed of volatile compounds that evolve at relatively low temperatures when heated in the presence or absence of O$_2$. The samples collected from the WSR at ${\Phi}$=2.0 and ${\Phi}$=2.1 are precursor-like in morphology and size. They have higher C/H ratios and lower organic percentages than precursor particles, but they are clearly not fully carbonized soot. The WSR PAH distribution is similar to that in young soot from inverse flames.