• 제목/요약/키워드: bulky property

검색결과 26건 처리시간 0.025초

Reversible Addition-Fragmentation Chain Transfer (RAFT) Bulk Polymerization of Styrene: Effect of R-Group Structures of Carboxyl Acid Group Functionalized RAFT Agents

  • Lee Jung Min;Kim Ok Hyung;Shim Sang Eun;Lee Byung H.;Choe Soonja
    • Macromolecular Research
    • /
    • 제13권3호
    • /
    • pp.236-242
    • /
    • 2005
  • Three dithioester-derived carboxyl acid functionalized RAFT(reversible addition-fragmentation chain transfer) agents, viz. acetic acid dithiobenzoate, butanoic acid dithiobenzoate and 4-toluic acid dithiobenzoate, were used in the RAFT bulk polymerization of styrene, in order to study the effects of the R-group structure on the living nature of the polymerization. By conducting the polymerization with various concentrations of the RAFT agents and at different temperatures, it was found that the R-group structure of the RAFT agents plays an important role in the RAFT polymerization; the bulky structure and radical stabilizing property of the R-group enhances the living nature of the polymerization and allows the polymerization characteristics to be well controlled.

릴레이 제어법을 이용한 유연 판상체의 정전부상에 관한 연구 (Electrostatic Suspension System of Flexible Objects using Relay Feedback Control)

  • 전종업;김선민
    • 한국정밀공학회지
    • /
    • 제23권6호
    • /
    • pp.104-110
    • /
    • 2006
  • A design and control of electrostatic suspension system for flexible objects is presented. A number of electrode pairs of which the number depends on the object flexibility are positioned above the object and the voltages applied to each electrode pair are controlled, independently on the others, on the basis of the gap length. To implement the system with low cost and compactness, switched-voltage control scheme that is based on the relay feedback control is utilized. Relay feedback control method deploys only a single high-voltage power supply that can deliver a DC voltage of positive and/or negative polarity and thus high voltage amplifiers that are costly and bulky are not needed any more. It is shown that despite the inherent limit cycle property of the relay feedback based control, an excellent performance in vibration suppression is attained due to the presence of a relatively large squeeze film damping originating from the electrodes and levitated object. Employing fourteen electrode pairs, a thin aluminum plate with a thickness of 0.1 mm has been suspended at a gap length of 0.75mm.

Swelling agent를 이용한 근적외선 흡수 유기색소의 polyester 흡착 (A Study on PET Adsorption Property of NIR Dye Using Swelling Agents)

  • 권수현;최재홍
    • 한국염색가공학회지
    • /
    • 제30권1호
    • /
    • pp.20-28
    • /
    • 2018
  • The near infrared ray camouflage fabric has a near infrared ray reluctance similar to the surrounding environment and has a camouflage effect on the surrounding environment. Synthetic fibers used in military uniforms are difficult to have gastrointestinal function as general commercial dyes, unlike cellulose fibers, which use some commercial vat dyes to impart infrared gastrointestinal function. In this study, we optimized the adsorption pH, temperature and time for NIR dye application for polyester fabrics, and established the optimum concentration for the evaluation of adsorption build-up characteristics. In addition, it is difficult to adsorb it since the polyester material has a dense crystal structure and the NIR dye is bulky. Therefore, a swelling agent used for dyeing meta-aramid fibers with high Tg and high crystallinity was introduced as a separate preparation to increase the affinity to polyester, which is a hydrophobic fiber, to thereby obtain an excellent adsorption rate. As a result of comparing before and after using swelling agent, the adsorption rate difference was 10 times or more when compared with before.

Advanced Indentation Studies on the Effects of Hydrogen Attack on Tensile Property Degradation of Heat-Resistant Steel Heat-Affected Zones

  • Choi, Yeol;Jang, Jae-il;Lee, Yun-Hee;Kwon, Dongil;Kim, Jeong-Tae
    • Corrosion Science and Technology
    • /
    • 제2권6호
    • /
    • pp.266-271
    • /
    • 2003
  • Safety diagnosis of various structural components and facilities is indispensable for preventing catastrophic failure of material by time-dependent and environment accelerating degradation. Also, this diagnosis of operating components should be done periodically for safe maintenance and economical repair. However, conventional standard methods for mechanical properties have the problems of bulky specimen, destructive procedure and complex procedure of specimen sampling. So, a non-destructive and simple mechanical testing method using small specimen is needed. Therefore, an advanced indentation technique was developed as a potential method for non-destructive testing of in-field structures. This technique measures indentation load-depth curve during indentation and analyzes the mechanical properties related to deformation such as yield strength, tensile strength and work-hardening index. In this paper, we characterized the tensile properties including yield and tensile strengths of the V-modified Cr-Mo steels in petro-chemical and thermo-electrical plants. And also, the effects of hydrogen-assisted degradation of the V-modified Cr-Mo steels were analyzed in terms of work-hardening index and yield ratio.

릴레이 제어법을 이용한 유리패널의 정전부상에 관한 연구 (Electrostatic Suspension System of Glass Panels using Relay Feedback Control)

  • 전종업
    • 한국정밀공학회지
    • /
    • 제25권6호
    • /
    • pp.71-79
    • /
    • 2008
  • In the manufacture of flat panel display devices, there is a strong demand for contactless glass panel handling devices that can manipulate a glass panel without contaminating or damaging it. To fulfill this requirement, an electrostatic suspension device far glass panels where the glass panel is supported by electrostatic forces without any mechanical contact is proposed. To implement the system with low cost and compactness, switched-voltage control scheme that is based on the relay feedback control is utilized. Relay feedback control method deploys only a single high-voltage power supply that can deliver a DC voltage of positive and/or negative polarity and thus high voltage amplifiers that are costly and bulky are not needed any more. It is shown that despite the inherent limit cycle property of the relay feedback based control, an excellent performance in vibration suppression is attained due to the presence of a relatively large squeeze film damping originating from the electrodes and levitated object. Using this scheme, a $100{\times}100mm^2$ glass panel was levitated stably with airgap variation decreasing down to $1\;{\mu}m$ at an airgap of $100\;{\mu}m$.

나노사이즈 탄산칼슘이 종이의 물리·광학적 특성에 미치는 영향 (Effects of Nano-sized Calcium Carbonate on Physical and Optical Properties of Paper)

  • 박정윤;이태주;김형진
    • 펄프종이기술
    • /
    • 제46권4호
    • /
    • pp.1-10
    • /
    • 2014
  • In papermaking industry, inorganic fillers are widely used for the purpose of improving opacity, brightness, printability, uniformity and dimensional stability. They are also useful for production costs and energy savings. In the past, inorganic fillers in papermaking industry only focused on micro-scale but recently, new trials on nano-powdered technology are applying. Even nano-powdered fillers are rapidly utilized for improving the optical and surface properties in coating and surface sizing, there still have some problems in wet-end process due to poor dispersibility and retention. In this study, nano-particled calcium carbonate was produced by milling the PCC and its applicability between micro sized and nano sized calcium carbonated was compared in wet-end process, and finally the sheet properties were evaluated. Nano-PCC was not retained in sheet structure without applying retention system, but with retention system nano-powdered PCC was absorbed on fiber surface with expanding the fiber networks. The application of PAM-bentonite system has resulted in high ash retention and bulky structure for copier paper, and good optical properties in brightness and opacity. However, it required to solve the weakness of low tensile property due to interruption of hydrogen bonding by nano fillers.

DGEBF/방향족아민 경화계의 벤젠링 사이에 위치한 Methyl기와 Sulfone기가 유발하는 물성변화에 대한 연구 (Chemo-Mechanical Analysis of Bifunctional linear DGEBF/Aromatic Amino Resin Casting Systems)

  • 이재락;명인호
    • Composites Research
    • /
    • 제18권4호
    • /
    • pp.14-20
    • /
    • 2005
  • 방향족아민 경화제의 벤젠링 사이의 관능기 변화가 반응특성, 기계적특성 및 열적특성에 미치는 영향을 고찰하기 위하여 범용 에폭시수지인 DGEBF와 방향족아민 경화제 DDM, DDS 각각을 1:1의 당량비로 혼합하여 동일한 조건으로 경화하였다. 그 결과 에폭시수지 경화물의 특성은 경화제의 벤젠링 사이의 관능기 구조에 따라 매우 큰 영향을 받았다. 즉, 벤젠링 사이에 길이가 길고 bulky한 술폰기를 포함한 DDS는 반응성, 열안정성, 밀도, shrinkage($\%$), 선팽창계수, 인장탄성율. 인장강도, 굴곡탄성율, 굴곡강도의 값이 벤젠링 사이에 메틸기를 가지는 DDM 경화물계 보다 높게 나타났지만, epoxide기의 전환율, 유리전이온도의 값은 낮게 나타냈다. 이것은 술폰기의 강한 전기음성도와 메틸기의 전기 양성적인 repulsive한 성질의 차이에 의한 영향인 것으로 판단된다. 굴곡 파단면의 관찰 결과는 DDS 경화물계의 각개 grain이 불규칙적으로 분포되어 있음을 확연하게 보여준다.

친환경 효소가공에서 플라즈마 전처리가 염색성과 태에 미치는 영향 (The Study on the Effect of Plasma Pre-treatment on the Dyeing Properties and the Handle in the Environment Friendly Enzyme Finishing)

  • 김지현
    • 한국의상디자인학회지
    • /
    • 제10권3호
    • /
    • pp.173-180
    • /
    • 2008
  • Cotton, wool, cotton/wool blended (80:20) and tencel fabrics were treated with low temperature oxygen plasma, enzymes (cellulase or protease), or oxygen plasma-enzyme and they were examined for dyeing and handling properties for environment friendly finishing. The appropriate conditions for cellulase treatment were enzyme concentration of 3g/l, pH of 5, and $60^{\circ}C$ for one hour, and for protease treatment were enzyme concentration of 4g/l, pH of 8, and $60^{\circ}C$ for one hour. The equilibrium uptake of a direct dye on cotton changed with plasma treatment and plasma-cellulase treatment, and the rate of dyeing slightly decreased. When wool was dyed with acid dye, the equilibrium dye uptake did not change with plasma, protease treatment nor plasma-protease treatment, however, the rate of dyeing had increased with plasma-protease treatment. From these results, it is assumed that plasma attacks the surface of the fiber, and enzyme mainly affects the inner part of the fiber. Plasma treatment did not affect mechanical properties related to the handling of fabrics. The handling test showed increased extension at maxmum load(EM), tensile energy(WT) with decreased tensile resilience (RT), and the fabrics became softer but resilience decreased slightly with enzyme treatment. The bending recidity(B), hysteresis of bending moment(2HB), and hysteresis of shear force at five degrees(2HG5) decreased, however, shear stiffness(G) increased. I knew the plasma pre-treatment made fabrics softer with lower koshi(stiffness). The handling of plasma pre-treated fabrics was better than that of enzyme-treated fabrics. When we pre-treated fabrics, the handling test showed decreased coefficient of friction(MIU), geometrical roughness(SMD), while the surface of fabrics became smoother and numeri increased. Even though compression resilience(RC) increased, fukurami(bulky property) and compressive elasticity, decreased due to the linearity of compression-thickness curve(LC) and compression energy(WC).

  • PDF

휴대용 의료 초음파 프로브 적용을 위한 압전체 제조 및 특성 (Modified Piezoelectric Ceramics for Portable Ultrasonic Medical Probe Application)

  • 강동헌;채미나;홍세원
    • 한국전기전자재료학회논문지
    • /
    • 제29권8호
    • /
    • pp.483-488
    • /
    • 2016
  • Ultrasound imaging by using piezoelectric materials, such as lead zirconium titanate (PZT) has been one of the most preferred modes of imaging in the medical field due to its simple, low cost and non-ionizing radiation in comparison to other imaging techniques. Recently, the market demand for portable ultrasound is becoming larger with applications in developing countries, disaster area, military, and emergency purposes. However, most of ultrasound probes used is bulky and high power consumable, so unsuitable for such applications. In this study, the 3 layered ceramic specimen consisted of 128 pitches of $420{\mu}m$ in width and $450{\mu}m$ in thickness were prepared by using the Ti-rich PZT compositions co-fired at $1,050^{\circ}C$. Their electrical and ultrasound pulse-echo properties were investigated and compared to the single layer specimen. The 3 layered ultrasound probe showed 1.584 V of Vp-p, which is 3.2 times higher than single layered one, implying that it would allow effectively such a portable ultrasound probe system. The result were discussed in terms of higher capacitance, lower impedance and higher dielectric coefficient of the 3 layered ultrasound probe.

원사의 수축에 따른 다공성 편성물의 형태변화와 열·수분 전달특성 (The appearance change and heat·moisture transfer properties of knitted fabric by yarn shrinkage)

  • 상정선;박주현;이미식;오경화
    • 복식문화연구
    • /
    • 제25권6호
    • /
    • pp.880-892
    • /
    • 2017
  • In this study, the appearance change and the heat moisture transfer properties of knitted fabric by yarn shrinkage were examined to obtain useful data on the development of thermo-sensitive functional materials. Eleven types of knitted fabric were knitted using highly bulky acrylic-blended yarn. After shrinking the specimens using dry heat treatment, the appearance change and thickness were measured. An HEC simulator was adopted for measuring the heat moisture transfer properties of specimens by yarn shrinkage. When holes were arranged vertically in the mesh structure, the specimens with 2,500 and 5,000 holes showed high percent change of hole area, appearance, and thickness. When holes were diagonally arranged in the mesh structure, the percent change of hole area in the specimen with 1,250 holes was larger than the one with 2,500 holes. However, the dimensional stability of the specimen with 2,500 holes was better because of its smaller appearance and thickness change. In the tuck structure, the percent change of hole area in the specimen with 625 and 416 holes was relatively large compared with the appearance and thickness change. Furthermore, the hole size in the tuck structure was smaller than that in the mesh structure but the percent change of hole area was larger. Therefore, it was proved that the tuck structure is more suitable than the mesh structure for developing thermo-sensitive functional materials. Heat moisture transfer property test verified that the change of hole area by yarn shrinkage enabled obtaining the thermal effect due to the distinct temperature difference in the inner layer.