• Title/Summary/Keyword: branched

Search Result 887, Processing Time 0.028 seconds

Flow and Mechanical Properties of Linear and Branched Polycarbonates Blends (선형 및 분지화된 폴리카보네이트 블렌드의 기계적 성질과 유동특성)

  • 류민영;이재식;배유리
    • Polymer(Korea)
    • /
    • v.24 no.1
    • /
    • pp.38-47
    • /
    • 2000
  • A study of linear and branched polycarbonates blend system is presented. Flow and mechanical properties, and miscibility were studied for the blends of various compositions. No phase separations were observed in the blend systems. The mechanical properties of blends were examined through tensile strength, tensile modulus, flexural strength, flexural modulus and impact strength. Melt viscosity, storage and loss moduli of the blends with various compositions were examined at various temperatures. The dependence of viscosity on molecular weight was also presented. Flow properties of the blends showed significant variations however, mechanical properties were relatively independent of the compositions. As the content of branched polycarbonate increased, the dependence of viscosity on molecular weight and shear thinning behavior became more marked. Therefore the blend systems which have same mechanical properties but different flow properties can be obtained.

  • PDF

Electrical Noise Reduction and Stiffness Increase with Self Force-Balancing Effect in a High-Resolution Capacitive Microaccelerometer using Branched Finger Electrodes with High-Amplitude Sense Voltage (고감지전압 및 가지전극을 이용한 고정도 정전용량형 미소가속도계의 전기적 잡음 감소 및 자율 균형력 발생에 의한 강성 증가)

  • Han, Gi-Ho;Jo, Yeong-Ho
    • The Transactions of the Korean Institute of Electrical Engineers C
    • /
    • v.51 no.4
    • /
    • pp.169-174
    • /
    • 2002
  • This paper presents a high-resolution capactive microaccelerometer using branched finger electrodes with high-amplitude sense voltage. From the fabricated microacceleromcter, the total noise is obtained as 9 $\mu\textrm{g}$/√Hz at the sense voltage of 16.5V, while the conventional microaccelerometers have shown the noire level of 25~800 $\mu\textrm{g}$/√Hz. We reduce the mechanical noise level of the microaccelerometer by increasing the proof-class based on deep RIE process of an SOI wafer. We reduce the electrical noise level by increasing the amplitude of AC sense voltage. The nonlinearity problem caused by the high-amplitude sense volage has been solved by a new electrode design of branched finger type, resulting in self force-balancing effects for the enhanced linearity and bandwidth. The fabricated microaccelerometer shows the electrical noise of 2.4 $\mu\textrm{g}$/√Hz at the sense voltage of 16.5V, which is an order of magnitude reduction of the electrical noise of 24.3 $\mu\textrm{g}$/√Hz measured at 0.9V. For the sense voltage higher than 2V, the electrical noise of the microaccelerometer is lower than the voltage-independent mechanical noise of 11 $\mu\textrm{g}$/√Hz. Total noise, composed of the electrical noise and the mechanical noire, has been measured as 9 $\mu\textrm{g}$/√Hz at the sense voltage of 16.5V, which is 31% of the total noise of 28.6 $\mu\textrm{g}$/√Hz at the sense voltage 0.9V. The self force-balancing effect in the blanched finger electrodes increases the stiffness of the microaccelerometer from 1.1N/m to 1.61N/m as the sense voltage increases from 0V to 17.8V, thereby generating additional stiffness at the rate of 0.0016$\pm$0.0008 N/m/V$^2$.

A Study on the Rheological Properties of Branched Polycarbonates by Melt Polymerization (용융중합에 의한 분지형 폴리카보네이트의 유변학적 특성 연구)

  • Choi, Su-Jung;Yoon, Kyung-Hwa;Kim, Hee-Seung;Yoo, Seung-Yoon;Kim, Youn-Cheol
    • Polymer(Korea)
    • /
    • v.35 no.4
    • /
    • pp.356-362
    • /
    • 2011
  • The branched polycarbonates (B-PCs) with two different branching agents were synthesized from melt polymerization. The contents of branching agent were in the range of 0.001~0.005 mol%. The chemical structure of the synthesized PC was determined by FTIR, $^1H$ NMR, and $^{13}C$ NMR, spectroscopy. The molecular weight, glass transition and degradation temperatures were determined by GPC, DSC, and TGA. The molecular weight of the phloro type B-PC had a lower value than the other one, and the glass transition temperature increased with molecular weight. Compared with linear PC, the rheological properties of the B-PC indicated an increase of complex viscosity in the low frequency region and shear thinning tendency. Power law index(n) representing shear thinning was calculated by linear regression and the values were in the range of 0.483~0.996. The rheological properties of the B-PCs were measured by a dynamic rheometer.

Detailed Mode of Action of Arabinan-Debranching α-ʟ-Arabinofuranosidase GH51 from Bacillus velezensis

  • Oh, Gyo Won;Kang, Yewon;Choi, Chang-Yun;Kang, So-Yeong;Kang, Jung-Hyun;Lee, Min-Jae;Han, Nam Soo;Kim, Tae-Jip
    • Journal of Microbiology and Biotechnology
    • /
    • v.29 no.1
    • /
    • pp.37-43
    • /
    • 2019
  • The gene encoding an ${\alpha}-{\text\tiny{L}}-arabinofuranosidase$ (BvAF) GH51 from Bacillus velezensis FZB42 was cloned and expressed in Escherichia coli. The corresponding open reading frame consists of 1,491 nucleotides which encode 496 amino acids with the molecular mass of 56.9 kDa. BvAF showed the highest activity against sugar beet (branched) arabinan in 50 mM sodium acetate buffer (pH 6.0) at $45^{\circ}C$. However, it could hardly hydrolyze debranched arabinan and arabinoxylans. The time-course hydrolyses of branched arabinan and arabinooligosaccharides (AOS) revealed that BvAF is a unique exo-hydrolase producing exclusively ${\text\tiny{L}}-arabinose$. BvAF could cleave ${\alpha}-(1,2)-$ and/or ${\alpha}-(1,3)-{\text\tiny{L}}-arabinofuranosidic$ linkages of the branched substrates to produce the debranched forms of arabinan and AOS. Although the excessive amount of BvAF could liberate ${\text\tiny{L}}-arabinose$ from linear AOS, it was extremely lower than that on branched AOS. In conclusion, BvAF is the arabinan-specific exo-acting ${\alpha}-{\text\tiny{L}}-arabinofuranosidase$ possessing high debranching activity towards ${\alpha}-(1,2)-$ and/or ${\alpha}-(1,3)-linked$ branches of arabinan, which can facilitate the successive degradation of arabinan by $endo-{\alpha}-(1,5)-{\text\tiny{L}}-arabinanase$.

Effect of Orally Administered Branched-chain Amino Acids on Protein Synthesis and Degradation in Rat Skeletal Muscle

  • Yoshizawa, Fumiaki;Nagasawa, Takashi;Sugahara, Kunio
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.18 no.1
    • /
    • pp.133-140
    • /
    • 2005
  • Although amino acids are substrates for the synthesis of proteins and nitrogen-containing compounds, it has become more and more clear over the years that these nutrients are also extremely important as regulators of body protein turnover. The branched-chain amino acids (BCAAs) together or simply leucine alone stimulate protein synthesis and inhibit protein breakdown in skeletal muscle. However, it was only recently that the mechanism(s) involved in the regulation of protein turnover by BCAAs has begun to be defined. The acceleration of protein synthesis by these amino acids seems to occur at the level of peptide chain initiation. Oral administration of leucine to food-deprived rats enhances muscle protein synthesis, in part, through activation of the mRNA binding step of translation initiation. Despite our knowledge of the induction of protein synthesis by BCAAs, there are few studies on the suppression of protein degradation. The recent findings that oral administration of leucine rapidly reduced $N^{\tau}$-methylhistidine (3-methylhistidine; MeHis) release from isolated muscle, an index of myofibrillar protein degradation, indicate that leucine suppresses myofiblilar protein degradation. The details of the molecular mechanism by which leucine inhibits proteolysis is just beginning to be elucidated. The purpose of this report was to review the current understanding of how BCAAs act as regulators of protein turnover.

Physicochemical Properties of Corn Starch-derived Branched Dextrin Produced by a Branching Enzyme

  • Song, Eun-Bum;Min, Byoung-Cheol;Hwang, Eun-Sun;Lee, Hyong-Joo
    • Food Science and Biotechnology
    • /
    • v.17 no.2
    • /
    • pp.234-240
    • /
    • 2008
  • The optimal conditions for the production of branched dextrin from com starch (CSBD) using branching enzyme (BE) were established by investigating the degree of retrogradation of the gelatinized starch. The physicochemical properties of CSBD prepared using the established process were evaluated. It was found that physicochemical properties of com starch were greatly modified by BE treatment. CSBD had a higher dextrose-equivalent value and water solubility than the corresponding control. On the other hand, the viscosities in gelatinized solution and amylose contents of CSBD were lower than those of the control. A high-performance size-exclusion chromatography/multiangle laser light scattering/retractive index (HPSEC/MALLS/RI) system showed that the average molecular weight of CSBD was lower than that of the control. The pasting viscosities of CSBD were stable during the entire temperature cycle. In general, the BE treatment resulted in the retrogradation during storage being lower for CSBD than for the control.

Fabrication of branched Ga2O3 nanowires by post annealing with Au seeds

  • Lee, Mi-Seon;Seo, Chang-Su;Gang, Hyeon-Cheol
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2015.08a
    • /
    • pp.203-203
    • /
    • 2015
  • Gallium Oxide (Ga2O3) has been widely investigated for the optoelectronic applications due to its wide bandgap and the optical transparency. Recently, with the development of fabrication techniques in nanometer scale semiconductor materials, there have been an increasing number of extensive reports on the synthesis and characterization of Ga2O3 nano-structures such as nano-wires, nano-belts, and nano-dots. In contrast to typical vapor-liquid-solid growth mode with metal catalysts to synthesis 1-dimensional nano-wires, there are several difficulties in fabricating the nano-structures by using sputtering techniques. This is attributed to the fact that relatively low growth temperatures and higher growth rate compared with chemical vapor deposition method. In this study, Ga2O3 nanowires (NWs) were synthesized by using radio-frequency magnetron sputtering method. The NWs were then coated by Au thin films and annealed under Ar or N2 gas enviroment with no supply of Gallium and Oxygen source. Several samples were prepared with varying the post annealing parameters such as gas environment annealing time, annealing temperature. Samples were characterized by using XRD, SEM, and PL measurements. In this presentation, the details of fabrication process and physical properties of branched Ga2O3 NWs will be reported.

  • PDF

Morphology and Life History of Stylonema cornu-cervi Reinsch (Goniotrichales, Rhodophyta) from Japan

  • Kikuchi, Norio;Shin, Jong-Ahm
    • ALGAE
    • /
    • v.20 no.1
    • /
    • pp.37-42
    • /
    • 2005
  • The morhology and life history of Stylonema cornu-cervi Reinsch from Japan were investigated. The species had multiseriate erect thalli from a basal cell. The thalli usually branched dichotomously, occasionally trichotomously near the base, and non-branched thalli were sometimes observed. A dichotomous branch on the upper portion near the base occurred only one time on each erect branch. Cells contained a stellate chloroplast, which was composed of a central rounded part with an obscure pyrenoid and 5-8 cup-like lobes connected to the central part by a small thin stipe. The biseriate part was observed on the six-celled stage in culture, and the grown thalli were multiseriate except for base and apices. Monospores forming from the immediate transformation of vegetative cells were observed. Thalli grew at 15-25$^{\circ}C$ and died at 10 and 30$^{\circ}C$. The fastest growth and maturation were observed under 25$^{\circ}C$ and 14L:10D. Although S. alsidii (Zanardini) Drew usually had uniseriate thalli, irregularly branched multiseriate thalli had been reported in cultures. It is possible that in the previous report the thalli were confused with S. cornu-cervi. In this report, S. cornu-cervi were distinguished from S. alsidii in that the branches were few, the multiseriate portions were observed on the early stage (six-celled stage), and the grown thalli were multiseriate except at the base and apices.

Miscibility of Branched Polycarbonate Blends with Poly(ethylene-co-1,4-dimethyl cyclohexane terephthalate) Copolyesters

  • Song, Jeong-Oh;Jeon, Mi-Young;Kim, Chang-Keun
    • Macromolecular Research
    • /
    • v.15 no.7
    • /
    • pp.640-645
    • /
    • 2007
  • The phase behavior of branched polycarbonate (BPC) blends with poly(ethylene terephthalate-co-1,4-dimethyl cyclohexane terephthalate) copolyesters (PECT), as well as their rheological properties, were assessed. Even though BPC blends with PECT prepared by solvent casting proved to be immiscible, BPC and PECT copolyesters containing 1,4-dimethyl cyclohexane (CHDM) from 32 to 80 mole% formed homogeneous mixtures upon heating. The homogenization temperatures of the blends decreased with increasing CHDM content in PECT. The interaction energies of the BPC-PECT pairs calculated from the phase boundary in accordance with the lattice-fluid theory were positive and also decreased with increasing CHDM content in PECT. It was shown that the phase homogenization of these blends occurs upon heating when the combinatorial entropy term, which is favorable for miscibility, overcomes unfavorable energetic terms at elevated temperatures. A novel product, which is not limited by the drawbacks of linear polycarbonate (PC) and evidences processability superior to that of the PC/PECT blends, can be developed via the blending of BPC and PECT.

Methyl-Branched Fatty Acids, Inhibitors of Enoyl-ACP Reductase with Antibacterial Activity from Streptomyces sp. A251

  • Zheng, Chang-Ji;Sohn, Mi-Jin;Chi, Seung-Wook;Kim, Won-Gon
    • Journal of Microbiology and Biotechnology
    • /
    • v.20 no.5
    • /
    • pp.875-880
    • /
    • 2010
  • Bacterial enoyl-ACP reductase (FabI) has been demonstrated to be a novel antibacterial target. In the course of our screening for FabI inhibitors, we isolated two methyl-branched fatty acids from Streptomyces sp. A251. They were identified as 14-methyl-9(Z)-pentadecenoic acid and 15-methyl-9(Z)-hexadecenoic acid by MS and NMR spectral data. These compounds inhibited Staphylococcus aureus FabI with $IC_{50}$ values of 16.0 and $16.3\;{\mu}M$, respectively, but did not affect FabK, an enoyl-ACP reductase of Streptococcus pneumonia, at $100\;{\mu}M$. Consistent with their selective inhibition for FabI, they blocked intracellular fatty acid synthesis as well as the growth of S. aureus, but did not inhibit the growth of S. pneumonia. Additionally, these compounds showed reduced antibacterial activity against fabI-overexpressing S. aureus, compared with the wild-type strain. These results demonstrate that the methylbranched fatty acids show antibacterial activity by inhibiting FabI in vivo.