• Title/Summary/Keyword: bound rubber

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Optimal design of Base Isolation System considering uncertain bounded system parameters

  • Roy, Bijan Kumar;Chakraborty, Subrata
    • Structural Engineering and Mechanics
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    • v.46 no.1
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    • pp.19-37
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    • 2013
  • The optimum design of base isolation system considering model parameter uncertainty is usually performed by using the unconditional response of structure obtained by the total probability theory, as the performance index. Though, the probabilistic approach is powerful, it cannot be applied when the maximum possible ranges of variations are known and can be only modelled as uncertain but bounded type. In such cases, the interval analysis method is a viable alternative. The present study focuses on the bounded optimization of base isolation system to mitigate the seismic vibration effect of structures characterized by bounded type system parameters. With this intention in view, the conditional stochastic response quantities are obtained in random vibration framework using the state space formulation. Subsequently, with the aid of matrix perturbation theory using first order Taylor series expansion of dynamic response function and its interval extension, the vibration control problem is transformed to appropriate deterministic optimization problems correspond to a lower bound and upper bound optimum solutions. A lead rubber bearing isolating a multi-storeyed building frame is considered for numerical study to elucidate the proposed bounded optimization procedure and the optimum performance of the isolation system.

Fabrication and Characterization of Modified Poly(2-hydroxyethyl methacrylate)(PHEMA) Hydrogels by Thermal/Photo Polymerization

  • Lee, Minsu;Lee, Junghyun;Jang, Jihye;Nah, Changwoon;Huh, Yang-il
    • Elastomers and Composites
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    • v.54 no.4
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    • pp.359-367
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    • 2019
  • Poly(2-hydroxyethyl methacrylate) (PHEMA) hydrogels modified with various co-monomers, such as N-vinyl pyrrolidone (NVP), glycidyl methacrylate (GMA), and glycerol monomethacrylate (GMMA), were prepared to investigate the effect of adding a co-monomer on the water contents, surface wettability, and tensile modulus. These polymers were synthesized by thermal- and photo-polymerization in the presence of azobisisobutyronitrile (AIBN) and diphenyl(2,4,6-trimethylbenzoyl)-phosphineoxide (TPO) as the initiators. The characteristics of the hydrogels were analyzed via FTIR and UV/Vis spectroscopies, contact angle measurements, and tensile modulus measurements with UTM. Regarding the properties of water in the hydrogels, the ratio between free to bound water was investigated using differential scanning calorimetry (DSC). The effects of adding the co-monomers on the water content, surface wettability, and tensile modulus for soft contact lenses were also investigated. In the case of p(HEMA-co-NVP) hydrogels, the increase in the equilibrium water content (EWC) was primarily due to the increase in the bound water content. For p(HEMA-co-GMMA) hydrogels, an increase in free water content was the main reason for the increased EWC. In contrast, in the case of p(HEMA-co-GMA) hydrogels, a decrease in bound water content was observed to be the main factor that reduced the EWC. Photo-polymerized PHEMA hydrogels showed enhanced surface wettability and tensile modulus as compared to those produced via thermal polymerization.

Properties of Polymer-Modified Mortar with Styrene-Butyl Acrylate and Styrene Butadiene Rubber (S/BA와 SBR을 혼입한 폴리머 시멘트 모르타르의 특성)

  • Mun, Kyung-Ju;Song, Hae-Ryong;Hyung, Won-Gil
    • Polymer(Korea)
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    • v.32 no.6
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    • pp.555-560
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    • 2008
  • Polymer-modified mortars have been largely used as paving materials, flooring, waterproofing material, adhesives, anticorrosive linings, deck coverings, and other various materials. The various types and properties of the mixed polymer largely affect the characteristics of polymer-modified mortar that has been mixed with polymer latexes. Consequently, its application purposes are varied according to these properties. This paper investigates the typical properties of polymer-modified mortars that contain styrene and butyl acrylate latexes and styrene butadiene rubber. They are then tested to obtain air contents, water-cement ratios, flexural and compressive strengths, water absorption, and chloride-ion penetration. From the test results, the superior flexural strength of polymer-modified mortars is obtained at a S/BA-2 and a polymer-cement ratio of 20%. And, the water absorption and chloride ion penetration depth are greatly affected by the polymer-cement ratio rather than the types of polymer. In the polymer-modified mortar and concrete structures, aggregates are bound by such a co-matrix phase, resulting in the superior properties of polymer-modified mortar and concrete compared to conventional mortar and concrete.

Influence of Silane Coupling Agent on Retraction Behaviors of NR Vulcanizates Reinforced with Carbon Black and Clay (실란 커플링제가 카본블랙과 점토로 보강된 천연 고무 가황물의 회복 특성에 미치는 영향)

  • Choi, Sung-Seen;Park, Byung-Ho;Kim, Wan-Soo;Kim, Wan-Doo
    • Elastomers and Composites
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    • v.40 no.2
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    • pp.112-118
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    • 2005
  • Influence of a silane coupling agent on the reatraction behaviors of NR vulcanizates reinforced with carbon black and c lay was studied. Bis-(3-(triethoxysilyl)-propyl )-tetrasulfide (TESPT) was used as a silane coupling agent. The vulcanizates containing the silane coupling agent were, on the whole, recovered faster than those without the silane coupling agent. However, for the vulcanizate with the higher clay content at low temperature region (below $-12^{\circ}C$), the vulcanizate containing the silane coupling agent was recovered slower than that without the silane coupling agent. The recovery difference of the vulcanizates with and without silane coupling agent decreased with increase of clay content. The experimental results were explained with crosslink density, modulus, and bound rubber content.

Electrochemical Properties of Tobacco Peroxidase Incorporated Enzyme Electrode Bound with CSM Rubber (CSM 고무로 결합된 담배 과산화효소 고정 효소전극의 전기화학적 특성)

  • Yoon, Kil Joong
    • Applied Chemistry for Engineering
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    • v.25 no.5
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    • pp.538-543
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    • 2014
  • In order to substitute for the marketed horseradish peroxidase, a hydrogen peroxide sensor embedded with tobacco leaf in carbon pastes was constructed and its sensing ability was electrochemically evaluated. Ten and more electrode parameters obtained implied that the enzyme electrode exerts its remarkable specificity quantitatively in the experimental range of potential. Especially the small symmetry factor (${\alpha}$, 0.21) showed that the electrode kinetics is very sensitive to the change of electrode potential. The experimental facts above suggested that our enzyme electrode functions as a hydrogen peroxide sensor normally and tobacco peroxidase can be used in the place of the marketed one as an alternative to marketed ones.

Improvement of Interfacial Performances on Insulating and Semi-conducting Silicone Polymer Joint by Plasma-treatment

  • Lee, Ki-Taek;Huh, Chang-Su
    • Transactions on Electrical and Electronic Materials
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    • v.7 no.1
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    • pp.16-20
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    • 2006
  • In this paper, we investigated the effects of short-term oxygen plasma treatment of semiconducting silicone layer to improve interfacial performances in joints prepared with a insulating silicone materials. Surface characterizations were assessed using contact angle measurement and x-ray photoelectron spectroscopy (XPS), and then adhesion level and electrical performance were evaluated through T-peel tests and electrical breakdown voltage tests of treated semi-conductive and insulating joints. Plasma exposure mainly increased the polar component of surface energy from $0.21\;dyne/cm^2$ to $47\;dyne/cm^2$ with increasing plasma treatment time and then leveled off. Based on XPS analysis, the surface modification can be mainly ascribed to the creation of chemically active functional groups such as C-O, C=O and COH on semi-conductive silicone surface. This oxidized rubber layer is inorganic silica-like structure of Si bound with three to four oxygen atoms ($SiO_x,\;x=3{\sim}4$). The oxygen plasma treatment produces an increase in joint strength that is maximum for 10 min treatment. However, due to brittle property of this oxidized layer, the highly oxidized layer from too much extended treatment could be act as a weak point, decreasing the adhesion strength. In addition, electrical breakdown level of joints with adequate plasma treatment was increased by about $10\;\%$ with model samples of joints prepared with a semi-conducting/ insulating silicone polymer after applied to interface.

A Study on the Flame Retardance and Electrical Properties of Silicone Composites (실리콘 복합체의 내화 및 전기 특성에 관한 연구)

  • Lee, Sung-Ill;Lee, Hae-Joon
    • Elastomers and Composites
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    • v.38 no.3
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    • pp.227-234
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    • 2003
  • Silicone composites for high voltage insulator (HVI SC) were prepared by adding aluminum trihydrate(ATH) treated by surface treatment agent to base silicone compound at the ratio oi 100:20, 100:40, 100:60, 100:80, and 100:100, respectively And also, ATH was treated by various surface treatment agents, such as stearic arid, acryl silane, and vinyl silane under compounding process. Mechanical properties and electrical properties were investigated for the various contents of ATH and surface-treatment agents. Mechanical properties such as tensile strength, elongation, and tear strength decreased as the load of ATH increased. Volume resistivity, AC break down strength, and tracking resistance for HVI SC containing ATH treated by vinyl silane were better than those for HVI SC containing ATH treated by other surface treatment agents, such as stearic acid and acryl silane. Polymer-filler interaction of silicone composites according to surface treatment agents was studied by measuring bound rubber contend(BR). From the experimental results, BR of silicone composite containing ATH treated with vinyl silane was higher than that of the others. The degree of rule for silicone composite was investigated using Rheometer. Maximum torque of silicone composites contaning ATH treated with vinyl silane was higher than that of silicone composite contaning ATH treated with other surface agents.

The Assesment of Heavy metal Pollution in Sewage Sludeges from Gully Pots Alongside Some Main Roads in Seoul, Korea (서울시 도로변의 빗물받이에서 체취한 하수슬러지의 중금속 오염 평가)

  • 이평구
    • Economic and Environmental Geology
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    • v.32 no.6
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    • pp.633-644
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    • 1999
  • Gully pot is a part of urban darainage system to butter the runoff water fluxes from road to rivers and to minimize environmental pollution by prevending over the surrounding area. A series of studies have been carried out concerning the physicochemical characteristics of the sewage sludge sediments sttling down in such a gully pot in order to over to evaluate the contamination for heavy metals such as pb, Zn, Cu and Cd. The roadside soil and sewage sludge samples from gully pots were characterized by XRD analyses and sequential extraction : Zn 2595.7$\mu$g/g; Cd9.8$\mu$/g; Cu602.5$\mu$g/g; Pb260.0$\mu$g/g),because of a long-term accumulation of vehicle- and industrial-related pollutants. Mean Zn concentration in Yeouido (3873$\mu$g/g) and Junggu(3262$\mu$g/g)areas are 4-5 times higher than those in Dobonggu area, suggesting that Zn may be derived from automobile traffic (including the rubber of automobile tires). The mean concentrations of Cu and Cr are very significantly high in Junggu and Gurogu areas, possibly due to the industrial activities in these areas. The low Pb levels throughtotut the whole study areas in Seoul can be accounted for the use of unleaded gasoline since 1987. Sequential extraction experiments illustrate that a major part of Zn is bound to FII and FIII, representing about 88% of the total Zn concentration. Fraction IV, related to orgnic matter, is mostly significant for Cu accounting for 60% of the total Cu, and FII is next in importance. The main carriers of Pb are the fractions III, II and FIV, and in that order. The behavior of Cd is quite different from other elements (Zn, Cu, Pb), and most of the Cd is associated with FV. Changes in the physicochemical environments (such as acidification) may result in severe environmental pollution of surface water and rivers with respect to heavy metals (especially Zn and Cu).

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Evaluation of Surface Emission and Internal Movement of Water in Japanese Larch Lumber (낙엽송재 내 수분의 내부이동 및 표면방사 평가)

  • Han, Yeongjung;Eom, Changdeuk;Kim, Se Jong;Kang, Wook;Park, Joo Saeng;Park, Moon Jae;Yeo, Hwanmyeong
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.4
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    • pp.1-8
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    • 2007
  • Japanese larch specimens with dimension of 2.5 (radial direction) ${\times}$ 2.5 (tangential direction) ${\times}$ 2.5 cm (longitudinal direction) were prepared to determine 3 different directional internal moisture movement coefficients and surface emission coefficients along the radial-, the tangential-, and the tangential-direction. 4 sides of each cubic specimen were wrapped with paraffin tape and rubber tape, leaving open the 2 opposite surfaces of interest, to provide one dimensional moisture movement during drying. The coefficients were determined at three different temperatures, 70, 50 and $30^{\circ}C$ and at two different relative humidities, 30 and 60%. Internal moisture movement coefficients inclusive of flow of free water and diffusion of bound water and water vapor were increased in the high temperature condition. The internal moisture movement coefficient in the longitudinal direction was about six times of those in transverse directions with radial value being 20% greater than the tangential. Surface emission coefficients were increased with temperature and decreased with surface moisture content. Using this results, moisture content (MC) profile and quantities of moisture evaporating in Japanese larch lumber could be predicted in dynamic drying situations.

A study of the destructive styles from Contemporary Paintings - Focused on distinguishing enmity-destruction and self-destruction - (현대회화에서 드러난 해체의 형식론에 관한 연구 -타의적 해체와 자의적 해체의 성격규정을 중심으로-)

  • Park Ki-Woong
    • Journal of Science of Art and Design
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    • v.7
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    • pp.5-63
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    • 2005
  • Generally, the meanings of destruction are related in the meaning of demolition, breakdown, into fragments ... and so on, and the similar meanings are twist, crush, demolish, split, cut, into pieces , break up ... etc. Further, it has related in the cruelty and destructive heart which are linked with orgy, Sadism, Necrophilia and so on. The meanings are also expressed by the initial , which are deprivation, deface, defame, deform, degrade, delegitimize, denounce , deride, destroy, devalue, as well as debase, debunk, declaim, declassify, decry, delete, denigrate, deprecate, despise or detract ...and so on. Dario Gamboni has discussed the meaning in his book as two categories Iconoclasm and Vandalism. And the similar meanings could be found in the words which has the initial of , like abase, abate, abhor, abjure, abolish, abridge, abuse ...and so on. Even though the distinct meanings of Iconoclasm and Vandalism, it is not easy to distinguish clearly between the differences when the results are accomplished in contemporary paintings because of the similarity of the results. In korean vocabulary there are no similar words to distinguish between the meanings of destruction and deconstruction, and the deconstruction is not recorded in the general dictionaries. However the meaning of is diminishing, separation, contrast and so on. So the unification of the word as do-construction is not construct, minus construction, reverse construction. And Vincent Ditch explained that there are the meaning of destroy the text. From Jacques Derrida, the deconstruction strategy is to criticise the world of traditional metaphysics and logocentrism, and not to reconstruire the philosophical meaning of texts but $d\'{e}construire$ them. And Saussure emphasized that the signifers could have more meaning that there can be more signified in traditional texts in the art. as a result, deconstruction is explained that there are many signified meanings in a signifer. In this thesis , from using the meanings of destruction and deconstruction, to distinguish the expressive skills in contemporary art works are arising. Therefore, special methods which are linked in the destruction styles are selected. As a result, the two different purposes of destruction is arising, one is enmity destruction and the other is self destruction another word, auto destruction or destruction to create The enmity destruction can be distinguished by the two category Iconoclasm and Vandalism. They come from the moment of different historical aspect is arising and want to attack the Icon or masterpiece this concept is from the study of John Philips and especially iconoclasm is linked with religious and artistic heart, but Vandalism is come from the political attack. Sometime, this distinguish is not clearly arising, because the two aspects are co-related in the attack. As a result, firstly, the Iconoclastic controversy had arisen in the methods of Dadaism which has developed by Man Ray, Francis Picabia and Marcel Duchamp. They want to attack the pre-established master-pieces and painting spaces, and they had 'non-artistic attitude' not to be art. Since 1980, the German artist Anselm Kiefer adapted the methods and made them his special skills so he had tried to paint tough brush strokes and draw with hugh pallette image line and fire and water images , they can be the image attack as the Iconoclasm. secondly, the model of vandalism is to be done by hammer, drill, canon and so on. the method is to attack the content of painting. Further, the object of destruction is bound by cords and iron lings to demolish or to declare the authority of pre-statues; it symbolize the pre-authority is gone already. Self-destruction based paintings are clearly different in the purpose of approaching the art work. First of all, they can be auto-destruction, creative destruction and metamorphosis destruction, which is linked with the skill the material aspect and basic stature, and sign destruction or signifier destruction, which is link with the inner meaning destruction that is considered as the Semiotical destruction in post-modern paintings. Since 1960, the auto destruction is based on the method of firing, melting, grinding and similar skills, which is linked with Neo-Dada and reverse-assemblage. Metamorphosis destruction is strongly linked with the basic inner heart price and quality, so it can be resulted in the changedness of expectation and recognition. Tony Cragg has developed the skills to metamorphose the wood as stone or iron as cloth and stone as sponge and rubber and so on. The researcher has developed the same style in the series of since 2003. The other self-destructive methods are found in the skill of sign destruction. In the methods the meaning of the art is not fixed as one or two, but is developed multi-meaning and differ from original starting situation, so Jacques Derrida called the difference meaning in deconstruction. It is the destruction of textes. These methods are accomplished by David Salle, Francesco Clemente, and recently Tracy Emin, who has developed the attacking heart in the spectators' emotion. Sometime in the method of self-destruction, it is based on horror and shock, the method is explored by Demian Hirst and Jakes and Dinos Chapman. Their destructive styles stimulate ambivalent heart and destroy original sign of girl and animals.

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