• 한국주조공학회지
• /
• 제38권1호
• /
• pp.16-26
• /
• 2018

In this study, the effects of the pouring temperature, preheating temperature, surface condition and fraction of the wear resistant part on the production of duo-castings were investigated using a high Cr white cast iron with excellent abrasion resistance and a low Cr alloy steel with good toughness. The constituent materials of the duo-castings were designed to have high hardness, fracture toughness and abrasive wear resistance for the replacement of high Mn alloy steels with low abrasive wear resistance. In particular, the amount of abrasive wear of 17% Cr white cast iron was about 1/20 of that of high Mn alloy steel. There was an intermediate area of about 3mm due to local melting at the bonding interface of the duo-castings. These intermediate regions were different from those of the constituent materials in chemical composition and microstructure. This region led to fracture within the wear resistant part rather than at the bonding interface in the bending strength test. The bending fracture strengths were 516-824 MPa, which were equivalent to the bending proof strength of high Mn steel. The effects of various casting conditions on the duo-cast behavior were studied by simple pouring of low Cr alloy steel melt, but the results proved practically impossible to manufacture duo-castings with a sound bonding interface. However, the external heating method was suitable for the production of duo-castings with a sound bonding interface.

• 콘크리트학회지
• /
• 제11권1호
• /
• pp.129-139
• /
• 1999

본 연구는 콘크리트 구조물의 보강공법으로 널리 쓰이고 있는 강판에 의한 부착식 보강공법의 단점인 단부에서의 강판분리 현상에 대한 보완실험으로 실시되었다. 실험결과 노치가 적용된 강판부착식 공법이 항복하중 이후 최대하중까지의 증가율이 기존의 공법보다 증가되어 구조물의 보강 성능의 개선 및 안전성의 확보 측면에서 크게 개선되었을 뿐만 아니라 균열이나 처짐의 조절측면에서도 우수한 것으로 판명되었다. 이는 강판에 대한 약간의 변형만으로도 구조물의 수명을 연장시킬 수 있다는 장점과 함께 경제적으로도 보강된 구조물에 대한 추가적인 제반 비용의 절감도 기대할 수 있을 것이다.

• 한국재료학회지
• /
• 제20권12호
• /
• pp.681-685
• /
• 2010

The application of flip chip technology has been growing with the trend of miniaturization of electronic packages, especially in mobile electronics. Currently, several types of adhesive are used for flip chip bonding and these adhesives require some special properties; they must be solvent-free and fast curing and must ensure joint reliability against thermal fatigue and humidity. In this study, imidazole and its derivatives were added as curing catalysts to epoxy resin and their effects on the adhesive properties were investigated. Non-isothermal DSC analyses showed that the curing temperatures and the heat of reaction were dependent primarily on the type of catalyst. Isothermal dielectric analyses showed that the curing time was dependent on the amount of catalysts added as well as their type. The die shear strength increased with the increase of catalyst content while the Tg decreased. From this study, imidazole catalysts with low molecular weight are expected to be beneficial for snap curing and high adhesion strength for flip chip bonding applications.

• 한국재료학회지
• /
• 제11권3호
• /
• pp.159-163
• /
• 2001

실리콘 웨이퍼 직접 접합을 성공하기 위해서는 양호한 접합면을 구성하여야 하며, 이를 위해 접합면에서 발생하는 주요 결함 중 하나인 기포형 접합 결함을 억제하여야 한다. 본 연구에서는 접합면에서 발생하는 기포형 결함의 상온 접합 및 열처리 과정에서의 거동을 관찰하여 내부의 압력이 증가함을 직접 관찰할 수 있었다. 또한, 대기압 하의 열처리에서 결함이 발생하지 않는 $SiO_2$-$SiO_2$ 접합 웨이퍼가 진공에서의 열처리에서 결함이 발생하는 현상을 통해 기포형 결함의 내부 압력과 성장과의 관계를 실험을 통하여 증명할 수 있었다.

• 비파괴검사학회지
• /
• 제30권3호
• /
• pp.236-243
• /
• 2010

Fiber Bragg grating(FBG) sensor arrays can be used to monitor the mechanical behavior of the large composite structures such as wind turbine rotor blades and aircrafts. However, brittle FBG sensors, especially multiplexed FBG sensors are easily damaged when they are installed in the flexible structures. As a protection of brittle FBG sensors, epoxy packaged FBG sensors have been presented in this paper. Finite element analysis and experiments were performed to evaluate the effects of adhesives, packaging materials and the bonding layer thickness on the strain transmission. Two types of epoxy were used for packaging FBG sensors and the sensor probes were attached with various bonding layer thickness. It was observed that thin bonding layer with high elastic modulus ratio of the adhesive to packaging provided good strain transmission. However, the strain transmission was significantly decreased when elastic modulus of the adhesive was much lower than the packaged FBG sensor probe's one.

• 한국근적외분광분석학회:학술대회논문집
• /
• 한국근적외분광분석학회 2001년도 NIR-2001
• /
• pp.1181-1181
• /
• 2001

Robinson with ${coworkers}^{1}$ have introduced two-state outer-neighbor bonding model to explain the anomalies of water. The studies on the properties of water as a function of temperature and pressure revealed that, unlike other ideas, all $H_2O$ molecules in liquid are tetrabonded. On the average they are forming two different bonding types. One type is the regular tetrahedral water-water bonding similar to that found in the ordinary ice Ih, whereas the other is a more dense nonregular tetrahedral bonding similar to that appearing in the ice II. The transformation between these two bonding forms is evidenced by FT-NIR experiment. The FT-NIR measurements were done for liquid water in the temperature range from $20^{\circ}C$ up to $80^{\circ}C$ in a wide extent of frequencies: 12 000 - 4000 $cm^{-1}$ /. Temperature dependent variations in the volume fraction of these two structures are directly related to the spectral changes. The absorbance variations are explored by means of the two-dimensional correlation spectroscopy (2DCOS), principal component analysis (PCA), curve fitting and second derivatives. The presence of the isosbestic points in a range of the combination and overtone transitions indicates that the experimental spectra are a superposition of two temperature independent components. One component of diminishing intensity with temperature increase, is assigned to a stronger hydrogen bonds occurred in the Ih type, whereas the second component showing an opposite behavior, one can attribute to a weaker H-bonds characteristic for the II type. The understanding of the hydrogen bonding network in the liquid water is very important in interpretation of the interaction between water and protein chain. The two-state model of water surrounding the protein surface could advance an understanding of the hydration process.

• Corrosion Science and Technology
• /
• 제7권1호
• /
• pp.50-60
• /
• 2008

The majority of the described experimental results deal with relatively pure aluminium. Variations were made in the pretreatment of the aluminum substrates and an investigation was performed on the resulting changes in oxide layer composition and chemistry. Subsequently, the bonding behavior of the surfaces was investigated by using model adhesion molecules. These molecules were chosen to represent the bonding functionality of an organic polymer. They were applied onto the pretreated surfaces as a monolayer and the bonding behavior was studied using infrared reflection absorption spectroscopy. A direct and clear relation was found between the hydroxyl fraction on the oxide surfaces and the amount of molecules that subsequently bonded to the surface. Moreover, it was found that most bonds between the oxide surface and organic functional groups are not stable in the presence of water. The best performance was obtained using molecules, which are capable of chemisorption with the oxide surface. Finally, it was found that freshly prepared relatively pure aluminum substrates, which are left in air, rapidly lose their bonding capacity towards organic functional groups. This can be attributed to the adsorption of contamination and water to the oxide surface. In addition the adhesion of a typical epoxy-coated aluminum system was investigated during exposure to water at different temperatures. The coating was found to quite rapidly lose its adhesion upon exposure to water. This rapid loss of adhesion corresponds well with the data where it was demonstrated that the studied epoxy coating only bonds through physisorptive hydrogen bonding, these bonds not being stable in the presence of water. After the initial loss the adhesion of the coating was however found to recover again and even exceeded the adhesion prior to exposure. The improvement could be ascribed to the growth of a thin oxyhydroxide layer on the aluminum substrate, which forms a new, water-stable and stronger bond with the epoxy coating. Two routes for improvement of adhesion are finally decribed including an interphasial polymeric thin layer and a treatment in boiling water of the substrate before coating takes place. The adhesion properties were finely also studied as a function of the Mg content of the alloys. It was shown that an enrichment of Mg in the oxide could take place when Mg containing alloys are heat-treated. It is expected that for these alloys the (hydr)oxide fraction also depends on the pre-treatment and on the distribution of magnesium as compared to the aluminium hydroxides, with a direct impact on adhesive properties.

• 한국지반신소재학회논문집
• /
• 제10권2호
• /
• pp.1-12
• /
• 2011

조립재료의 입자 결합 및 파쇄 형태가 전단거동 특히 잔류 전단거동 특성에 미치는 영향을 분석하기 위하여, 개별요소법(DEM, discrete element method)에 기초를 둔 프로그램인 PFC(Particle Flow Code)를 이용하여 링 전단시험을 수치해석적으로 모델링하였다. 본 연구에서는 PFC내의 clump 모델 및 cluster 모델을 이용하여 두 개의 비파쇄모델 그리고 두 개의 파쇄모델을 포함한 총 네 개의 모델을 제시하였다. Lobo-Guerrero and Vallejo(2005)가 제안한 Lobo-crushing 모델의 적합성을 검토하였다. 또한 링 전단시험 모델링의 결과 분석을 통하여 직접전단시험 모델링 결과와 비교하였다. 연구 결과, 잔류 전단거동 분석을 위해서는 링 전단시험의 모델링이 필수적임을 알 수 있었다. 또한 잔류 전단강도 분석을 위해서는 Lobo-crushing 모델이 부적합함을 알 수 있었다. 따라서 본 연구에서 제시한 수치해석 모델은 향후 입자 파쇄를 포함한 조립재료의 잔류 전단강도 특성 연구에 다양하게 적용될 수 있다고 판단된다.

• 대한토목학회논문집
• /
• 제30권3A호
• /
• pp.221-228
• /
• 2010

탄소섬유시트 보강공법은 열화 손상된 콘크리트 구조물의 보강에 가장 많이 사용되는 보강공법 중 하나이다. 탄소섬유시트 보강공법은 에폭시접착제를 사용하여 탄소섬유시트를 콘크리트의 외부에 부착하는 보강공법으로 탄소섬유시트에 의한 휨보강이 에폭시 접착 경계면을 통하여 콘크리트로 전달된다. 따라서 사용기간이 경과함에 따라 에폭시 접착 경계면에 발생하는 크리프 등의 시간의존적 거동은 보강효과를 감소시키는 요인이 된다. 본 연구에서는 경계면에서 발생하는 크리프 영향을 해석하기 위하여 콘크리트의 크리프 거동에 대한 기존의 연구들을 고찰하고, 이를 바탕으로 에폭시 접착 경계면의 크리프 영향을 예측할 수 있는 이론적인 연구를 수행하였다. 제안된 유한요소해석기법은 기존의 콘크리트 크리프 거동 분석을 위해 사용되던 유변모델을 에폭시 접착 경계면에 적용한 것으로 기존 실험결과와 비교를 통하여 타당성을 검증하였다. 또한, 제안된 유한요소해석을 통하여 탄소섬유시트로 보강된 콘크리트 구조물의 시간의존적 거동에 경계면 재료의 크리프 영향을 반드시 고려해야 한다는 것을 입증하였다.

• Structural Engineering and Mechanics
• /
• 제44권2호
• /
• pp.257-266
• /
• 2012

Walls are the most important vertical load-carrying elements of masonry structures. Their bond designs are different from one country to another. This paper presents the shear effects of some structural bond designs commonly used for masonry walls. Six different bond designs are considered and modeled using finite element procedures under lateral loading to examine the shear behavior of masonry walls. To obtain accurate results, finite element models are assumed in the inelastic region. Crack development patterns for each wall are illustrated on deformed meshes, and the numerical results are compared.