• Proceedings of the Korean Vacuum Society Conference
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• 2010.08a
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• pp.78-78
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• 2010

The Adsorption structures of phenylalanine on Ge(100) surface have been investigated as a function of coverage using high-resolution photoemission spectroscopy (HRPES) and density functional (DFT) calculation. To converge these experimental and theoretical conclusion, we systematically performed HRCLPES measurements and DFT calculation for various coverage in the adsorption structures of phenylalanine molecules on the Ge(100) surface. In this study, we found two different adsorption structure as a function of coverage in phenylalanine on Ge(100), monitoring three core level spectra (Ge 3d, C 1s, N 1s, and O 1s) using HRPES Through analysis of the binding energies, we confirmed that O-H dissociated and N dative-bonded structure emerges at low coverage (0.10 ML), which is the same to the result of glycine and alanine on Ge(100) system, whereas O-H dissociation structure also appears at higher coverage. Moreover, we observed the shape of phenyl group being included in phenylalanine is changed from flat to tilting structure at final state using DFT calculation. Through the spectral analysis for phenylalanine, we will demonstrate variation of coverage dependent structural change for phenylalanine on Ge(100) surface using experimental (HRPES) and theoretical studies (DFT calculation).

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.16 no.6
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• pp.484-489
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• 2003

In this paper, a single phase driven piezoelectric motor design was presented for linear motion Two metal/ceramic composite actuators, a piezoelectric ring which was bonded to a metal endcap from one side, were used as the active elements of this motor. The motor was composed of a piezoelectric ceramic, a metal ring which has 4 arms, and a guider. Motors with 30 [mm] and 35 [mm] diameter were studied by finite element analysis and experiments. As results, the maximum speed of motor was obtained at resonance frequency. When the applied voltage of the motor increased, the speed was increased. Also, bidirectional motion of the motor was achieved by combining two motors which have different resonance frequency. But the characteristics of bidirectional motion were not equaled, because of the problem of reproduction on the fabrication and the experiment. If present motor is used at the auto-zoom device of a camera, it will have much advantage. Because the direct linear motion can be achieved with a simple structure of motor and no gearbox of total system.

• Journal of the Korea institute for structural maintenance and inspection
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• v.12 no.1
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• pp.65-72
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• 2008

The use of hybrid FRP-concrete structures with a dual purpose of both permanent formwork and reinforcement, has been considered in some studies recently. For the FRP plank and the concrete to act as a composite structural member a satisfactory bond at the interface between the smooth surface of the pultruded plank and the cast-in-place concrete must be developed. Sand was bonded to the pultruded FRP plank using a commercially available epoxy system. In applying general analysis techniques to evaluate the performance of composite structures with FRP stay-in-place forming, it is essential that characteristics of the bond stress-slip relation be identified. In this study I would like to propose a simplified bilinear bond stress-slip model for FRP composite structures.

• Journal of KSNVE
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• v.10 no.6
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• pp.1048-1058
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• 2000

Thipaper presents a methodology to suppress the vibration of thin rectangular plate clamped all edges using piezo-ceramic material as actuators and sensors. Dynamic characteristics of the structure bonded with distributed actuators/sensors are identified by the Multi-Input Multi-Output (MIMO) frequency domain modeling technique based on the experimental data. Hybrid control scheme is adopted and feedback controller is designed by LQG(Linear Quadratic Gaussian). Feedforward controller is adapted by multiple filtered -$x$ LMS(least mean square) algorithm. Experiment result demonstrates the effective reduction of the vibration label for both the transient and persistent external disturbances.

• Applied Chemistry for Engineering
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• v.4 no.2
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• pp.409-415
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• 1993

A potential function is applied to a hydrogen bonded system such as O-H---O and is slightly modified to provide a good understanding of a range of data. The use of this model requires a knowledge of terms describing the Van der Waals repulsion and the electrostatic interaction and the determination of these terms form the equilibrium conditions is described. Using this simple model, it will be shown that the relationship between the frequency shift and enthalpy of hydrogen bond formation is predicted to be linear and this is in reasonable agreement with experimental results in the literature.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 1997.04a
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• pp.428-433
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• 1997

This paper presents a new control strategy for the position and force control of flexible manipulators. The governing equation of motion of a two-link flexible manipulator which features piezoceramic actuators bonded on each flexible beam is derived via Hamilton's principle. The control torque of the motor to command desired position and force is determined by a sliding mode controller on the basis of the rigid-mode dynamics. In the controller formulation, the sliding mode controller with perturbation estimation(SMCPE) is adopted to determine appropriate control gains. The SMCPE is then incorporated with the fuzzy technique to mitigate inherent chattering problem while maintaining the stability of the system. A set of fuzzy parameters and control rules are obtained from a relation between estimated perturbation and actual perturbation. During the commanded motion, undesirable oscillation is actively suppressed by applying feedback control voltages to the piezoceramic actuators. These feedback voltages are also determined by the SMCPE. Consequently, accurate force and position control of a two-link flexible manipulator are achieved. Computer simulations are undertaken in order to demonstrate the effectiveness of the proposed control methodology.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.38-38
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• 2011

Covalently bonded halogen ligands possess unusual charge distributions, attracting both electrophilic and nucleophilic molecular ligands to form halogen bonds. In many biochemical systems, halogen bonds and hydrogen bonds coexist. The interplay between halogen and hydrogen bonds has been actively studied in various three-dimensional bulk molecular co-crystals. It was found that halogen bonds could be complementary to hydrogen bonds due to their similar bond strength and dissimilar directionality. In those ensemble-averaging approaches, however, it was not possible to extract local information such as individual bond configurations and nano-level domain structures, which is a crucial part of supramolecular studies. In this study, we directly visualize the individual molecular configuration of a brominated molecule and the role of halogen bonds on Au(111) using scanning tunneling microscopy. The precise arrangement of observed molecular structures was reproduced by first-principle studies and explained in the context of halogen and hydrogen bonds. We discuss the distances and the strengths of the observed halogen bonds and hydrogen bonds, which are consistent with previous bulk data.

• Transactions of the Korean Society of Automotive Engineers
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• v.7 no.5
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• pp.154-161
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• 1999

An elastomeric bushing is a device used in automotive suspension systems to cushion the force transmitted from the wheel to the frame of the vehicle. A bushing is an elastomeric hollow cylinder which is bonded to a solid metal shaft at its inner surface and a metal sleeve at its outer suface. The relation between the force applied to the shaft or sleeve and their relative deformation is nolinear and exhibits features of viscoelasticity. Numerical solutions of the boundary value problem represent the exact bushing response for use in the method for determining the force relaxation function of the bushing. The new nonlinear viscoelastic bushing model, which is called Pipkin-Rogers model, is proposed and it is shown that the predictions of the proposed force-displacement relation are in very good agreement with the exact results. This new bushing model is thus very suitable for use in multi-body dynamics codes. The success of the present study for axial mode response suggests that the same approach be applied to other modes, such as torsional or radial modes.

• Journal of Korea Foundry Society
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• v.28 no.6
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• pp.282-287
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• 2008

The effect of CaO mold on the formation of reaction layer was investigated. CaO mold was prepared by mixing of Colloidal silica($NALCO^{(R)}$ 1130) and an $ZrO_2$, CaO at room temperature. The dried at $20{\pm}3^{\circ}C$, 75% humidity for 12hrs. Sample was prepared from the Cp-Ti(grade-2) and melted by high frequence induction melting system in the vacuum condition. The react ion layer of Ti was confirmed by optical microscopy, microhardness(Hv) and X-ray diffraction. Thickness of reaction layer using the CaO stabilized ZrO2 was thinner than the CaO added ZrO2. And thickness of reaction layer were decreased with decreasing pH of slurry. CaO addition in the slurry could not controlled reaction between molten Ti and investment mold. On the other hand, the CaO chemical bonded ZrO2 by stabilization treatment could controlled reaction between molten Ti and investment mold.

• Journal of the Korean Vacuum Society
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• v.7 no.s1
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• pp.140-148
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• 1998

We prepared $C_3N_4$ films by rf plasma enhanced chemical vapor deposition(PCVD) and alternating $C_3N_4$/TiN composite films by dc magnetron sputtering. X-ray diffraction (XRD) and transmission electron diffraction (TED) revealed that the structure of the films is amorphous or polycrystalline, depending on deposition conditions and heat treatment. X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FTIR) spectroscopy confirmed the presence of $sp_3\; and sp _2$ hybridized C atoms bonded with N atoms in the tetrahedral and hexagonal configurations, respectively. Graphite-free $C_3N_4$ films were obtained by PCVD under optimal conditions. To prepare well crystallized $C_3N_4$ films by magnetron sputtering, we introduced negatively biased gratings in the sputtering system. CN films deposited at grating voltages (Vg) lower than 400V are amorphous. Crystallites of cubic and $\beta$-$C_3N_4$ were formed at increased voltages.