• Bulletin of the Korean Chemical Society
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• v.6 no.6
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• pp.362-366
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• 1985

The hydrogen atom transfer reaction between substituted methane, $CH_3X,$ and its radical, $CH_2X(X=H,F,CH_3,CN,OH\;and\;NH_2$ was studied by MINDO/3 method. The transition state(TS) structure and energy barriers were determined and variation of the transition state and of the reactivity due to the change of X were analyzed based on the potential energy surface characteristics. It was found that the greater the radical stabilization energy. the looser the TS becomes; the TS occurs at about 15% stretch of the C-H bond, which becomes longer as the radical stabilization energy of $CH_2X$ increasers. The intrinsic barrier, ${\Delta}E*_{x.x},$ of the reaction with X was found to increase in the order $H The degree of bond stretch of the C-H bond stretch of the C-H bond at the TS also had the same order indicating that the homolytic bond cleavage of the C-H bond is rate-determining. Orbital interactions at the TS between LUMO of the fragment $C{\ldots}H{\ldots}C$ and the symmetry adapted pair of nonbonding, $n{\pm}(=n_1{\pm}n_2),$ or pi orbitals of the two X atoms were shown to be the dominant contribution in determining tightness or looseness of the TS. The Marcus equation was shown to apply to the MINDO/3 barriers and energy changes of the reaction.

• Journal of Korean Association for Spatial Structures
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• v.22 no.4
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• pp.99-107
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• 2022

Existing reinforced concrete building structures constructed before 1988 have seismically-deficient reinforcing details, which can lead to the premature failure of the columns and beam-column joints. The premature failure was resulted from the inadequate bonding performance between the reinforcing bars and surrounding concrete on the main structural elements. This paper aims to quantify the bond-slip effect on the dynamic responses of reinforced concrete frame models using finite element analyses. The bond-slip behavior was modeled using an one-dimensional slide line model in LS-DYNA. The bond-slip models were varied with the bonding conditions and failure modes, and implemented to the well-validated finite element models. The dynamic responses of the frame models with the several bonding conditions were compared to the validated models reproducing the actual behavior. It verifies that the bond-slip effects significantly affected the dynamic responses of the reinforced concrete building structures.

• Restorative Dentistry and Endodontics
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• v.21 no.2
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• pp.652-663
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• 1996

The purpose of this study was to evaluate the tensile bond strength to tooth structure of composite resin and glass ionomer cement according to filling methods and light curing units. In this study, two class V cavities were prepared on the buccal surface of each tooth of 140 extracted human molars, and they were randomly assigned into 3 experimental groups with 40 teeth and control group with 20 teeth. And then, each experimental groups subdivided into 2 groups(A,B) according to light curing units. The cavities of each group were filled with the CLEARFIL FII self curing resin(Control Group), Z-100 light curing resin(Group 1), Vitremer$^{TM}$ light curing glass ionomer cement(Group 2) and Z-100 light curing resin over the Vitrebond$^{TM}$ liner(Group 3). And subdivided A Group used Argon Laser(SPECTRUM$^{TM}$, U.S.A.), B Group used XL 1,000 curing light (3M, U.S.A.). The specimens underwent temperature changed from $5^{\circ}C$ to $55^{\circ}C$ five hundred times. After thermocycling, specimens were stored in 100% relative humidity at $37^{\circ}C$ for 24 hours. And then, the tensile bond strength of specimens were calculated with Universal Testing Machine(AGS-100A, Japan). The results were as follows : 1. Among the experimental groups, the group 2-B showed the highest tensile bond strength ($18.89{\pm}7.80$) and the group 1-A showed the lowest tensile bond strength ($11.68{\pm}2.28$). There was significant difference between group 2-B and group 1-A(p<0.01). 2. Between the light curing units, the XL 1,000 unit showed higher tensile bond strength ($16.63{\pm}3.20$) than that of the Argon Laser unit ($13.73{\pm}2.30$). There was significant difference between XL 1,000 and Argon Laser(p<0.01). 3. About filling methods and materials, the group 2 showed the highest tensile bond strength ($17.56{\pm}1.89$) and the group 1 showed the lowest tensile bond strength($13.03{\pm}1.90$). There was significant difference between group 2 and group 1,3(p<0.01). In conclusion, the results showed that the glass-ionomer cement that cured by XL 1,000 light curing unit demonstrated significantly higher tensile bond strength than other curing unit and filling methods.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.10a
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• pp.537-542
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• 2002

The social trouble to the durability of concrete rises recently because the embedded rebar corrosion influences concrete structures to deteriorate structural capacity. And also, the rebar corrosion causes crack of concrete, decrease of steel section and separation of covering concrete. In the result, the bond strength of concrete and embedded rebar decreases, which causes deterioration of the structure behavior in reinforced concrete. In this study, the relation of bond strength and bond-slip was understood to evaluate capacity deterioration of reinforced concrete, and experiments were carried out by compressive strength and embedded rebar condition in the rebar corrosion rate.

• Textile Coloration and Finishing
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• v.10 no.4
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• pp.53-61
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• 1998

The absorptions of ultraviolet rays of benzophenone derivatives were investigated in terms of the position of substituent, especially hydroxyl group. When the derivatives were added to the aqueous solution of Rhodamin B, which has very low light-fastness, all of them delayed the photofading of Rhodamin B solution. But on the fabrics, only the derivatives with the hydroxyl group at 2-position showed the good ability of ultraviolet rays absorption. The benzophenone derivatives absorb ultraviolet rays to form a hydrogen bond between hydroxyl group and carbonyl group, and return to their original structure by releasing heat energy. In solution, the derivatives can form a intermolecular hydrogen bond, and absorb the ultraviolet rays. But on the fabric, the intermolecular hydrogen bond is impossible, only hydroxyl group of 2-position forms a intramolecular hydrogen bond, and that makes the derivatives on the fabric absorb ultraviolet rays.

• Proceedings of the Korea Concrete Institute Conference
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• 2003.05a
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• pp.579-584
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• 2003

For strengthening deteriorated concrete structures, externally bonded FRP sheets or plates using epoxy resins are widely used. For the external FRP composites to be effective in improving the performance of the structure, bond between FRP composites and concrete is required. In general, the most frequently observed failure mode in FRP strengthened concrete structures is debonding failure at the interfacial section between FRP and concrete. Therefore, it is very important to find out the interfacial behavior properties. This paper presents experimental results of the relationship of concrete and FRP sheet for some conditions including concrete compressive strength, concrete surface preparation to observe the bond behavior between concrete and FRP sheet and various anchorage types to increase the bond capacity of FRP sheet.

• Applied Chemistry for Engineering
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• v.8 no.2
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• pp.262-266
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• 1997

The CNDO/2 calculations have been applied on cluster models for the representative hydroxyls on silica surface to get Wiberg bond orders, total energies, LUMO energies, dipole moments, and formal charge densities. The Br${\ddot{o}}$nsted acidities of suggested models for the hydroxyls were explained in terms of Wiberg bond orders. The calculated bond orders of cluster models have been changed remarkably according to the hydrogen bond. However the Lewis acidities of terminal hydroxyls on silica surface were not related to the structure of hydroxyls.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2006.11a
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• pp.1-4
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• 2006

Because do placing joint after smallest $1{\sim}3$ day about concrete that is placed beforehand in field, it is difficult that remove laitance happening harden concrete. This laitance happens a problem of bond properties, deterioration in strength. In this research got following conclusion as result that do research about bond properties the way of disposal placing joint. Air Jet is loft interior and exterior. Water Jet appeared that laitance Removal Capacity is superior to dimension within 5%. Deterioration in strength is measured 37% by splitting tensile strength test result by laitance. Deterioration in strength by laitance do more than 30% that removal of laitance is predicted must consist necessarily at concrete horizontality placing joint stroke.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.11a
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• pp.321-324
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• 2006

An experimental study on the bond strength of wall-slab joint in SC(steel plate-concrete) structure was performed. Six-full scale specimens were tested. Specimens were constructed with key variables, such as, development length, location of the bar and quantity of the shear bar. The experimental results, show that as the development length and quantity of the shear bar increase, the bond strength increases. As the bars is located on the inside the stud bolt, the bond performance was highly increased compared to the bars located out of plane of the stud bolts.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.20 no.6
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• pp.514-519
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• 2007

The surfaces of $SiO_2$ films were treated by PMMA diluted solutions, and analyzed the chemical shift from Fourier Transform Infrared Spectrometer. The $SiO_2$ film treated by PMMA diluted solution changed the properties of the surface, and showed the blue and red shift according to the concentration of PMMA. The C-H bond elongation effect due to the high electro-negative atom chlorine showed the red shift, and makes the final material with the cross-link structure. The leakage current was efficiently reduced at the sample No 7 with the red shift, witch depends on the electron deficient group.