• Bulletin of the Korean Chemical Society
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• v.14 no.6
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• pp.740-743
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• 1993

By considering both electron-electron and electron-lattice interactions, the effect of charge transfer on the bond structure and electronic states of $C_{60}$ is studied without configuration limitation. The results show that the electron-electron interaction does not eliminate the layer structure of the bond distortion and the self-trapping of transferred electrons. For charged ${C_{60}}^{2-}$, there exist two localized electronic states, which possess laminar wave functions, and four nonequivalent groups of carbon atoms, which induce a fine-structure in the NMR spectrum line.

• Computers and Concrete
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• v.26 no.6
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• pp.515-531
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• 2020

Due to the construction difficulties of steel reinforced concrete (SRC), a new composite structure of steel and steel fiber reinforced concrete (SSFRC) is proposed for solving construction problems of SRC. This paper aims to investigate the bond properties and composition of interfacial bond stress between steel and steel fiber reinforced concrete. Considering the design parameters of section type, steel fiber ratio, interface embedded length and concrete cover thickness, a total of 36 specimens were fabricated. The bond properties of specimens were studied, and three different methods of calculating interfacial bond stress were analyzed. The results show: relative slip first occurs at the free end; Bearing capacity of specimens increases with the increase of interface embedded length. While the larger interface embedded length is, the smaller the average bond strength is. The average bond strength increases with the increase of concrete cover thickness and steel fiber ratio. And calculation method 3 proposed in this paper can not only reasonably explain the hardening stage after the loading end curve yielding, but also can be applied to steel reinforced high-strength concrete (SRHC) and steel reinforced recycled coarse aggregate concrete (SRRAC).

• Proceedings of the Korea Concrete Institute Conference
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• 2001.05a
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• pp.443-448
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• 2001

This paper presents a bond characteristics of high strength steel reinforced concrete members. High strength steel is what yield strength is higher than that of normal strength steel. So, the amount of flexural steel needed in R.C. members can be decreased. In result, it is expected that the workability and structure quality can improve and man power can minimize. For this purpose, specimens were made and tested with experimental parameters, such as concrete strength, steel diameter and yield strength. The result showed that under same tensile force of steel, in case of substituting normal strength steel with high strength steel, maximum bond stress increased and development length didn't almost change. In addition, the governing equation of bond and bond stress verse slip relationship were derived and compared with test values such as maximum bond stress, slip and bond stiffness.

• Bulletin of the Korean Chemical Society
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• v.7 no.3
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• pp.186-190
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• 1986

Effects of substituents in the nucleophile(X), the substrate(Y) and the leaving group(Z) on the structure of $S_N2$ transition states have been analyzed by considering effects of four components, electrostatic($E_{es}$), exchange repulsion ($E_{ex}$), polarization($E)_{pl}$) and charge transfer($E_{ct}$) terms, of interaction between the reactants on the degree of bond making and bond breaking. Prediction of net effects of all substituents(X, Y and Z) on the degree of bond making were found to be clearcut whereas the effect of an electron withdrawing group on the substrate (Y = EWG) on the degree of bond breaking was complex; the substituent(Y = EWG) is normally carbon-leaving group($C^{\ast}$-L) bond tightening($E_{pl}$ dominance) but becomes $C^{\ast}$-L bond loosening when the bond is strongly antibonding ($E_{ct}$ dominance). Our model calculations on the reaction of $CH_2XNH_2$ with $YCH_2COOCH_2Z$ using energy decomposition scheme have confirmed that predictions based on our analysis are correct.

• Bulletin of the Korean Chemical Society
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• v.15 no.2
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• pp.150-153
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• 1994

By treating mer, trans-Re(${\equiv}NC_6H_5)(PPh_3)_2Cl_3$, Ⅰ, with 5 atm of CO at room temperature for 52 h, fac-Re(${\equiv}NC_6H_5)(CO)(PPh_3)Cl_3$, Ⅱ, was obtained as dark green precipitates in 81% yield. The crystal structure of Ⅱ was determined through X-ray diffraction. Ⅱ crystallizes in the monoclinic system, space group $P2_1/n$ with cell parameters a=9.740 (2) ${\AA}$, b=16.210 (5) ${\AA}$, c=16.192 (6) ${\AA}$, ${\beta}$=97.50 $(2)^{\circ}$, and Z=4. Least-squares refinement of the structure led to a R$(R_w)$ factor of 0.030 (0.036) for 2878 unique reflections of I>3${\sigma}(I)$ and for 241 variables. In comparison to the starting material Ⅰ, the bond distance of Re-N became longer from 1.726 (6) to 1.736 (5) ${\AA}$ and the bond angle of Re-N-C(Ph) became smaller from 172.6 (6) to 167.0 $(2)^{\circ}$, indicating that the Re-N bond in Ⅱ is weakened and has a less triple-bond character than that in Ⅰ.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.3
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• pp.2279-2286
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• 2015

Recently it has been actively studied that the use of hybrid GFRP-concrete structure with dual purpose of both a permanent forwork and main tensile reinforcement of GFRP plank. In applying general analysis and design technique to evaluate the performance of hybrid structures with cast-in-place high strength concrete and GFRP plank, it is essential that the characteristics of the bond slip model is identified. In this study a simplified bilinear bond slip model for hybrid structure with GFRP plank and cast-in-place high strength concrete is proposed. Maximum average bond stress of simple bond slip relationship that has been proposed in this study is 3.29MPa, initial slope is 35.66MPa/mm, the total slip is 0.23mm and interfacial fracture energy is 0.37kN/m.

• Restorative Dentistry and Endodontics
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• v.19 no.1
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• pp.64-72
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• 1994

Zinc Phosphate Cement hand been used for about more than 100 years in luting of cast gold inlay. But many scientists had been trying to develop the new form of luting agent because the ZPC hand shown the lack of adhesiveness on the tooth structure and the toxicity to the pulp tissue. Recently many researches about the surface treatment of the cast body are being done to increase the adhesion of cement to it. The conventional Class I gold inlays were fabricated in the 20 permanent molars. After the internal surface of the cast body was sandblasted with $Al_2O_3$ particles and was tin-plated, the inlays were cemented with adhesive cement [G I cement and resin cement(Super-Bond & $Panavia_{EX}$)] and the evaluation on the adhesion pattern, adhesive strength and the fracture pattern of the adhesive cast gold inlay was compared to that of the cast gold inlay cemented conventionally with ZPC. The results were as follows : 1. The surface roughness of the cast body was increased significantly after sandblasting with the $Al_2O_3$ particles and the tin oxide layer, which was consisted of round particles, came into being. 2. The bond strength was in the order of Super-Bond, ZPC, Fuji I, $Panavia_{EX}$ group. The group cemented with Super-Bond showed statistically greater strength than the other groups(p<0.05). 3. The group cemented with ZPC was fallen apart by principal adhesion failure and that with Fuji I was by complete adhesion failure. But the group with Super-Bond showed pricncipal cohesive failure pattern and in the group with $Panavia_{EX}$, complete cohesive fracture pattern was shown and small protion of tooth structure was fractured out with cast body and the fractured surface showed the figure just as the enamel prism. 4. Various gaps were shown at the pulpal side regardless of little gap at the side walls of the cavity in all groups. Only the Super-Bond was attached to the tooth structure and the other cements were detached from both the tooth and the cast body.

• Journal of the Architectural Institute of Korea Structure & Construction
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• v.35 no.1
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• pp.3-10
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• 2019

The purpose of this paper is to find the fire-protection method for keeping on the bond capacity of Near-Surface-Mounted (NSM) FRP under high temperature. Experiments have been carried out to evaluate the bond capacity of NSM FRP by using CFRP-plates and to confirm the heat transfer to the concrete block when the refractory insulation is attached to the surface of NSM FRP. Bond test of NSM FRP under room temperature was conducted to obtain the maximum bond strength. And then a heating tests were carried out with keeping the bond stress of 30% of the maximum bond strength. As a result, the bond capacity of NSM FRP was disappeared when the temperature at epoxy reached to its glass transition temperature (GTT). In order to secure the bond capacity of the NSM FRP, it is necessary to protect the front as well as side by using insulation materials.

• Journal of Technologic Dentistry
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• v.39 no.2
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• pp.101-107
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• 2017

Purpose: The purpose of this study was to compare the shear bond strength of the metal-heat pressed glass ceramic bilayer structure. Methods: Metal framework specimens were prepared and surface is spreaded opaque(IPS InLine system opaque, IvoclarVivadent, Liechtenstein). There were 10 specimens for each bilayer dental ceramic group. The first group was porcelain fused metal, Press on metal IPS Inline press group, and press on metal HASS prototype group. Specimens measured for the shear bond strength on Schwickerath test by Instron universal testing machine(Instron3345, Instron Corp., USA). Mean average bond strength values of each specimen group were analyzed using a one-way ANOVA analysis of variance Saphiro-wilk's test. Statistical analysis were performed using IBM SPSS 23.0(IBM Co., Armonk, USA) Results: $RMS{\pm}SD$ The highest mean average HASS POM showed a bond strength value ($47.55{\pm}12.80Mpa$). The lowest mean average values Porcelain fused metal ($33.30{\pm}2.00Mpa$). Independent t-test was conduct to analysis the significant difference (p<0.05) (Table 3). Conclusion: Three kinds of Metal/ glass bilayer dental ceramics bond strength were clinical acceptability. Especially, as lithium disilicate containing represents higher bond strength.

• KCI Concrete Journal
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• v.13 no.2
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• pp.67-74
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• 2001

In this study, a numerical model for the simulation of reinforced concrete columns subject to cyclic loading is presented. The model consists of three separate models representing concrete, reinforcing steel bars and bond-slip between a reinforcing bar and ambient concrete. The concrete model is represented by the plane stress plastic-damage model and quadrilateral finite elements. The nonlinear steel bar model embedded in truss elements is used for longitudinal and transverse reinforcing bars. Bond-slip mechanism between a reinforcing bar and ambient concrete is discretized using connection elements in which the hysteretic bond-slip link model defines the bond stress and slip displacement relation. The three models are connected in finite element mesh to represent a reinforced concrete structure. From the numerical simulation, it is shown that the proposed model effectively and realistically represents the overall cyclic behavior of a reinforced concrete column. The present plastic-damage concrete model is observed to work appropriately with the steel bar and bond-slip link models in representing the complicated localization behavior.