• Title/Summary/Keyword: blue-light

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Efficient Blue Light Emitting Diode by Using Anthracene Derivative with 3,5-Diphenylphenyl Wings at 9- and 10-Position

  • Kim, Yun-Hi;Lee, Sung-Joong;Jung, Sang-Yun;Byeon, Ki-Nam;Kim, Jeong-Sik;Shin, Sung-Chul;Kwon, Soon-Ki
    • Bulletin of the Korean Chemical Society
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    • v.28 no.3
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    • pp.443-446
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    • 2007
  • The novel blue light emitting material, 9,10-bis(3',5'-diphenylphenyl)anthracene (BDA) was synthesized by Suzuki coupling reaction and characterized by the measurements of 1H NMR, 13C NMR and FT-IR. The new anthracene derivative, which contains anthracene as a main core unit and 3',5'-diphenylphenyl group derivative as wings, has high fluorescence yield, good thermal stability, and high glass transition temperature at 188 oC. With the newly non-doped blue emitting material in the multilayer device structure, it was possible to achieve the current efficiency of 3.0 cd/A. The EL spectrum of the ITO/CuPc/α-NPD/BDA/Alq3/LiF/Al device showed a maximum wavelength (λmax) at 440 nm. The emitting color of device showed the blue emission (x,y) = (0.18,0.19) at 10 mA/cm2 in CIE (Commission Internationale de l'Eclairage) chromaticity coordinates.

Highly Efficient Blue Organic Light-emitting Devices Based on Copper Phthalocyanine/Aromatic Diamine Composite Hole Transport Layer

  • Liao, Chi Hung;Tsai, Chih Hung;Chen, Chin H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.724-726
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    • 2004
  • Highly efficient blue organic light-emitting devices (OLEDs) utilizing the idea of copper phthalocyanine (CuPc)/N,N'-bis-(1-naphthyl)-N,N'-diphenyl,1,1'-biphenyl- 4,4'-diamine (NPB) composite hole transport layer (CPHTL) have been fabricated. The effect of inserting CPHTL upon the performance of blue OLEDs with 2-methyl-9,10-di(2-naphthyl)anthracene (MADN) as the blue emitter has been investigated. Compared with the luminous efficiency of the standard blue device without CPHTL (1.33 cd/A), that of the device with 40:60 CuPc/NPB CPHTL has been increased by more than twice up to 2.96 cd/A with a Commission Internationale d'Eclairage (CIE) coordinates of(x = 0.15, y = 0.10) and a power efficiency of 1.46 lm/W (20 mA/$cm^2$) at 6.39 V. The increased device efficiency is attributed to an improved balance between hole and electron currents arriving at the recombination zone.

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Development of ZnSSe:Te/ZnMgSSe DH structure Blue~Green tight Emitting Diodes (ZnSSe:Te/ZnMgSSe DH 구조 청색~녹색발광다이오드의 개발)

  • 이홍찬
    • Journal of Advanced Marine Engineering and Technology
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    • v.27 no.1
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    • pp.33-41
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    • 2003
  • The optical properties of $ZnS_ySe_{1-\chi-y}:Te_{\chi}(\chi<0.08,y~0.11)$ alloys grown by molecular beam epitaxy (MBE) have been investigated by photoluminescence (PL) and PL-excitation (PLE) spectroscopy. Good optical properties and high crystal quality were established with lattice match condition to GaAs substrate. At room temperature, emission in the visible spectrum region from blue to green was obtained by varying the Te content of the ZnSSe:Te alloy. The efficient blue and green emission were assigned to $Te_1 and Te_n(n\geq2)$cluster bound excitons, respectively. Bright green (535 nm) and blue (462 nm) light emitting diodes (LEDs) have been developed using ZnSSe:Te system as an active layer. The turn-on voltage of 2.1 V in current-voltage characteristics is very small compared to that of commercial InGaN-based LEDs (>3.4 V), indicating the formation of a good ohmic contact due to the optimized p-ZnSe/p-ZnTe multi-quantum well (MQW) superlattice electrode layers.

Molecular Engineering of Blue Organic Light Emitting Materials Based on Diarylamino-fluorene

  • Lee, Kum-Hee;Kwon, Young-Soo;Kang, Lee-Kyung;Kim, Gu-Young;Seo, Ji-Hoon;Kim, Young-Kwan;Yoon, Seung-Soo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.435-438
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    • 2008
  • We demonstrated the efficient blue organic light-emitting diodes (OLEDs) by employing diarylamino-fluorene derived blue fluorescent molecules as dopants. Among those, a device exhibited blue emission with the luminous efficiency of 11.2 cd/A at $20\;mA/cm^2$, the external quantum efficiency of 9.7% at $20\;mA/cm^2$, and the $CIE_{x,y}$ coordinates of (x=0.163, y=0.259) at 8V.

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Characteristics of blue phosphorescent OLED with PVK host layer. (PVK Host를 이용한 청색인광 OLED의 특성)

  • Lee, Sun-Hee;Jo, Min-Ji;Moon, Dae-Gyu
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.153-153
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    • 2010
  • We have developed blue phosphorescent organic light emitting diode using spin-coated poly(9-vinylcarbazole) (PVK) host layer doped with blue phosphorescent material, Iridium(III) bis(4,6-difluorophenyl)-pyridinato-N,C2) picolinate (FIrpic). the concentration of FIrpic dopants was varied from 2% to 10%. The electrical and optical characteristics of the blue phosphorescent OLED with PVK:FIrpic layer were investigated.

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Effects of Electron Transport Layers on Electrical and Optical Characteristics of Blue Phosphorescent Organic Light Emitting Diodes (전자수송층이 청색 인광 OLED의 전기 및 광학적 특성에 미치는 영향)

  • Suh, Won-Gyu;Moon, Dae-Gyu
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.4
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    • pp.323-326
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    • 2009
  • We have developed blue-emitting phosphorescent organic light emitting diodes (OLEDs) using 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (BCP) and tris (8-quinolinolato)aluminum ($Alq_3$) electron transport layers. As blue dopant and host materials, bis[(4,6-di-fluorophenyl)-pyridinate-N,C2']picolinate (FIrpic) and N,N'-dicarbazolyl-3,5-benzene (mCP) were used, respectively. The driving voltage, current efficiency and emission characteristics of devices were investigated. While the driving voltage was about $1{\sim}2$ V lower in the device with an $Alq_3$ layer, the current efficiency was about 66 % higher in the device with BCP electron transport layer. the blue phosphorescent OLED with BCP layer exhibited higher purity of color, resulting from a relatively weak electroluminescence intensity at 500 nm.

Development of $Blue{\sim}Green$ LEDs by Controlling Te Cluster (Te Cluster 제어에 의한 청${\sim}$녹색 발광다이오드의 개발)

  • Lee, Hong-Chan;Lee, Sang-Tae;Kim, Yoon-Sik
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2005.11a
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    • pp.51-52
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    • 2005
  • Optical characteristics of excitonic blue and green emission of Te-doped ZnSSe:Te epitaxial layers, grown by molecular beam epitaxy, were investigated by photoluminescence (PL) measurements. The Te-doped ternary specimen shows strong blue or green emission (at 300K) which is assigned to $Te_1$ or $Te_n$ $(n{\geq}2)$ cluster cluster bound exciton, respectively. Bright green and blue light emitting diodes (LEDs) have been developed using ZnSSe:Te system as an active layer. The green LEDs exhibit a fairly long device lifetime (>2000 h) when operated at 3 $A/cm^2$ under CW condition at room temperature.

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The relation between optical diffraction pattern and domain size in blue phase

  • Lee, Ho-Hyun;Kim, Jong-Hyun;Kikuchi, H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.942-944
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    • 2009
  • Blue phase shows several different reflection colors from the randomly oriented domains and crystal direction. Also there are variations in the size of domains. The domain size is dependent on the temperature gradient. With smaller cooling rate of temperature, the domain size was increased compared with rapid cooling. With injection of light of specific wavelength, we find that the diffraction patterns were occurred around the light spot in the cell of blue phase. It was supposed to be from the matching of the phase retardation and domain size. However, actually the diffraction pattern is reflecting the lattice structure in double twist of the blue phase. The lattice constant from the radius of diffraction patterns shows very similar one from the reflection spectrum, which indicates the internal lattice constant in double twist of the blues phase.

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Wide bandgap III-nitride semiconductors: opportunities for future optoelectronics

  • Park, Yoon-Soo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.12 no.1
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    • pp.11-20
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    • 2002
  • The world at the end of the $20^{th}$ Century has become "blue" Indeed, this past decade has witnessed a "blue rush" towards the development of violet-blue-green light emitting diodes (LEDs) and laser diodes (LDs) based on wide bandgap III-Nitride semiconductors. And the hard work has culminated with, first, the demonstration of commercial high brightness blue and green LEDs and of commercial violet LDs, at the very end of this decade. Thanks to their extraordinary properties, these semiconductor materials have generated a plethora of activity in semiconductor science and technology. Novel approaches are explored daily to improve the current optoelectronics state-of-the-art. Such improvements will extend the usage and the efficiency of new light sources (e.g. white LEDs), support the rising information technology age (e.g. high density optical data storage), and enhance the environmental awareness capabilities of humans (ultraviolet and visible photon detectors and sensors). Such opportunities and many others will be reviewed in this presentation.

Simplified Bilayer White Phosphorescent Organic Light-Emitting Diodes

  • Lee, Jonghee;Sung, Woo Jin;Joo, Chul Woong;Cho, Hyunsu;Cho, Namsung;Lee, Ga-Won;Hwang, Do-Hoon;Lee, Jeong-Ik
    • ETRI Journal
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    • v.38 no.2
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    • pp.260-264
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    • 2016
  • We report on highly efficient blue, orange, and white phosphorescent organic light-emitting diodes consisting only two organic layers. Hole transporting 4, 4,' 4"-tris (N-carbazolyl)triphenylamine (TcTa) and electron transporting 2-(diphenylphosphoryl) spirofluorene (SPPO1) are used as an emitting host for orange light-emitting bis(3-benzothiazol-2-yl-9-ethyl-9H-carbazolato) (acetoacetonate) iridium ((btc)2(acac)Ir) and blue light-emitting iridium(III)bis(4,6-difluorophenyl-pyridinato-N,C2') picolinate (FIrpic) dopant, respectively. Combining these two orange and blue light-emitting layers, we successfully demonstrate highly efficient white PHOLEDs while maintaining Commission internationale de l'eclairage coordinates of (x = 0.373, y = 0.443). Accordingly, we achieve a maximum external quantum, current, and power efficiencies of 12.9%, 30.3 cd/A, and 30.0 lm/W without out-coupling enhancement.