• Title/Summary/Keyword: blue carbon

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Involvement of Cytochrome P450 in (-)-(4R)-Isopiperitenone Oxidation by Cell Suspension Cultures of Mentha piperita

  • Park, Si-Hyung;Chang, Yung-Jin;Kim, Kyung-Hyun;Kim, Soo-Un
    • Journal of Microbiology and Biotechnology
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    • v.9 no.2
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    • pp.147-149
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    • 1999
  • Biotransformation of exogenous (-)-(4R)-isopiperitenone in cell suspension cultures of Mentha piperita resulted in oxidized products, with (-)-7-hydroxyisopiperitenone being the major compound. The mass of products obtained $unde^{18}O_2$, atmosphere was two units higher than that under normal atmosphere. The biotransformation was inhibited by several cytochrome P450-specific inhibitors as well as by carbon monoxide. Carbon monooxide inhibition was substantially overcome by irradiation of cells with blue light including light at 450nm wavelength. These results suggested that a cytochrome P450-type monooxygenase was involved in the biotransformation.

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The Synthesis and Photocatalytic activity of Carbon Nanotube-mixed TiO2 Nanotubes

  • Park, Chun Woong;Kim, Young Do;Sekino, Tohru;Kim, Se Hoon
    • Journal of Powder Materials
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    • v.24 no.4
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    • pp.279-284
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    • 2017
  • The formation mechanism and photocatalytic properties of a multiwalled carbon nanotube (MWCNT)/$TiO_2$-based nanotube (TNTs) composite are investigated. The CNT/TNT composite is synthesized via a solution chemical route. It is confirmed that this 1-D nanotube composite has a core-shell nanotubular structure, where the TNT surrounds the CNT core. The photocatalytic activity investigated based on the methylene blue degradation test is superior to that of with pure TNT. The CNTs play two important roles in enhancing the photocatalytic activity. One is to act as a template to form the core-shell structure while titanate nanosheets are converted into nanotubes. The other is to act as an electron reservoir that facilitates charge separation and electron transfer from the TNT, thus decreasing the electron-hole recombination efficiency.

Removal of Dyes by Biosorption on Biomass Ash

  • Rattan, V.K.;Singh, Harminder;Purai, Abhiti
    • Carbon letters
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    • v.8 no.1
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    • pp.1-5
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    • 2007
  • The use of low cost and ecofriendly adsorbent has been investigated as an alternative to the current expensive method of removing dyes from wastewater. Cow dung cakes were collected from the nearby village which was burnt in a muffle furnace at $500^{\circ}C$ to obtain the required ash. This paper deals with the removal of Reactive Blue 221, Acidoll Yellow 2GNL and Olive BGL which are mainly used in textile industry, from aqueous solution by cow dung ash without any pretreatment. The adsorption was achieved under different pH, adsorbate concentration and the applicability of Langmuir and Freundlich isotherms were examined.

Adsorption of Dyes from Aqueous Solution by Cow Dung Ash

  • Rattan, V.K.;Purai, Abhiti;Singh, Harminder;Manoochehri, Mahboobeh
    • Carbon letters
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    • v.9 no.1
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    • pp.1-7
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    • 2008
  • The ability of cow dung ash without any pretreatment to remove color from textile dyes N Blue RGB, Green B and EOSIN YWS from aqueous solution has been investigated in this work. Cow dung ash, an ecofriendly and low cost adsorbent was prepared by burning cow dung cakes in the muffle furnace at $500^{\circ}C$. The adsorption was achieved under different pH and adsorbate concentration. The data was fitted to simple polynomial and the isotherms similar to Langmuir and Freundlich isotherms.

TiO2 Combining Spherical Activated Carbon Photocatalysts and Their Physicochemical and Photocatalytic Activity

  • Oh, Won-Chun;Kim, Jong-Gyu;Kim, Hyuk;Chen, Ming-Liang;Zhang, Feng-Jun;Zhang, Kan;Choi, Jong-Geun;Meng, Ze-Da
    • Korean Journal of Materials Research
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    • v.20 no.10
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    • pp.535-542
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    • 2010
  • In this study, we used coal-based activated carbons and charcoal as startingmaterials, phenolic resin (PR) as a binder, and TOS as a titanium source to prepare $TiO_2$ combining spherical shaped activated carbon photocatalysts. The textural properties of the activated carbon photocatalysts (SACP) were characterized by specific surface area (BET), energy dispersive X-ray spectroscopy (XRD), scanning electron microscopy (SEM), iodine adsorption, strength intensity, and pressure drop. The photocatalytic activities of the SACPs were characterized by degradation of the organic dyes Methylene Blue (MB), Methylene Orange (MO), and Rhodamine B (Rh. B) and a chemical oxygen demand (COD) experiment. The surface properties are shown by SEM. The XRD patterns of the composites showed that the SACP composite contained a typical single, clear anatase phase. The EDX spectro for the elemental indentification showed the presence of C and O with Ti peaks. According to the results, the spherical activated carbon photocatalysts sample of AOP prepared with activated carbon formed the best spherical shape, a high BET surface area, iodine adsorption capability and strength value, and the lowest pressure drop, and the photocatalytic activity was better than samples prepared with charcoal. We compared the degradation effects among three kinds of dyes. MB solution degraded with the SACP is better than any other dye solutions.

A Study on the Removal of Taste and Odor Compounds by Activated Carbon Adsorption (활성탄(活性炭) 흡착(吸着)에 의한 취기유발물질(臭氣誘發物質) 제거(除去)에 관(關)한 연구(硏究) -GEOSMIN, 2-MIB를 중심으로-)

  • Kim, Han Seung;Kwon, Bong Kee;Park, Chung Hyun
    • Journal of Korean Society of Water and Wastewater
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    • v.8 no.2
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    • pp.12-24
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    • 1994
  • The occurrence of objectionable tastes and odors in drinking water is a common and widespread problem. The most troublesome odors are usually those described as muddy or earthy-musty. Two organic compounds which have been implicated as the cause of earthy-musty odor problems in water are geosmin and 2-Methylisoborneol. These earthy-musty organics have been shown to be metabolites of actinomycetes and blue green algae. The purpose of this paper is to describe adsorbability in removing these two oder causing compounds(geosmin and 2-MIB) upon various conditions like pH variation, adding humic acid and different activated carbon. The conclusion of this study are as followings. In batch test, carbon dosage is 10mg/100ml for geosmin and 15mg/100ml for 2-MIB. Both were in equilibrium state after 60 hours. In model simulation, F-P model described experiment data and modelling data appropriately in geosmin but F-S model not. In case of 2-MIB, models didn't describe relation between experiment and modelling data well. Two causative agents of earthy-musty odor compounds, geosmin and 2-MIB, are strongly adsorbed by activated carbon either coconut or brown. There appears to be no effect of pH (3,7,9) on adsorption of these two organics. Activated carbon proved to be more effective for removing geosmin than for removing 2-MIB. When activated carbon is. used in removing these two organics, the removal of these appeared to be adversely affected by back ground organic compounds, such as humic substances, due to competitive adsorption.

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Classification of Carbon-Based Global Marine Eco-Provinces Using Remote Sensing Data and K-Means Clustering (K-Means Clustering 기법과 원격탐사 자료를 활용한 탄소기반 글로벌 해양 생태구역 분류)

  • Young Jun Kim;Dukwon Bae;Jungho Im ;Sihun Jung;Minki Choo;Daehyeon Han
    • Korean Journal of Remote Sensing
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    • v.39 no.5_3
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    • pp.1043-1060
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    • 2023
  • An acceleration of climate change in recent years has led to increased attention towards 'blue carbon' which refers to the carbon captured by the ocean. However, our comprehension of marine ecosystems is still incomplete. This study classified and analyzed global marine eco-provinces using k-means clustering considering carbon cycling. We utilized five input variables during the past 20 years (2001-2020): Carbon-based Productivity Model (CbPM) Net Primary Production (NPP), particulate inorganic and organic carbon (PIC and POC), sea surface salinity (SSS), and sea surface temperature (SST). A total of nine eco-provinces were classified through an optimization process, and the spatial distribution and environmental characteristics of each province were analyzed. Among them, five provinces showed characteristics of open oceans, while four provinces reflected characteristics of coastal and high-latitude regions. Furthermore, a qualitative comparison was conducted with previous studies regarding marine ecological zones to provide a detailed analysis of the features of nine eco-provinces considering carbon cycling. Finally, we examined the changes in nine eco-provinces for four periods in the past (2001-2005, 2006-2010, 2011-2015, and 2016-2020). Rapid changes in coastal ecosystems were observed, and especially, significant decreases in the eco-provinces having higher productivity by large freshwater inflow were identified. Our findings can serve as valuable reference material for marine ecosystem classification and coastal management, with consideration of carbon cycling and ongoing climate changes. The findings can also be employed in the development of guidelines for the systematic management of vulnerable coastal regions to climate change.

MULTISPECTRAL REMOTE SENSING ALGORITHMS FOR PARTICULATE ORGANIC CARBON (POC) AND ITS TEMPORAL AND SPATIAL VARIATION

  • Son, Young-Baek;Wang, Meng-Hua;Gardner, Wilford D.
    • Proceedings of the KSRS Conference
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    • v.1
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    • pp.450-453
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    • 2006
  • Hydrographic data including particulate organic carbon (POC) from the Northeastern Gulf of Mexico (NEGOM) study were used along with remotely sensed data obtained from NASA's Sea-viewing Wide Field-of-view Sensor (SeaWiFS) to develop POC algorithms to estimate POC concentration based on empirical and model-based principal component analysis (PCA) methods. In Case I and II waters empirical maximized simple ratio (MSR) and model-based PCA algorithms using full wavebands (blue, green and red wavelengths) provide more robust estimates of POC. The predicted POC concentrations matched well the spatial and seasonal distributions of POC measured in situ in the Gulf of Mexico. The ease in calculating the MSR algorithm compared to PCA analysis makes MSR the preferred algorithm for routine use. In order to determine the inter-annual variations of POC, MSR algorithms applied to calculate 100 monthly mean values of POC concentrations (September 1997-December 2005). The spatial and temporal variations of POC and sea surface temperature (SST) were analyzed with the empirical orthogonal function (EOF) method. POC estimates showed inter-annual variation in three different locations and may be affected by El $Ni{\tilde{n}}o/Southern$ Oscillation (ENSO) events.

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Analysis of Charcoal from Quercus phillyraeoides (졸가시나무 탄화물 분석)

  • Shin, Soo-Jeong;Kim, Byung-Ro
    • Journal of the Korean Wood Science and Technology
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    • v.41 no.3
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    • pp.181-186
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    • 2013
  • In this work, charcoal making characteristics of Quercus phyllyaeoides (which has been known as one of best raw materials for charcoals) was investigated. Charcoal from Quercus phyllyaeoides had more than 85% of fixed carbon, which is 5~25% higher fixed carbon content than other charcoals. Also specific gravity of this charcoal was more than 1.0, which is quite higher than other black charcoals (average of commercial products: 0.52) or white charcoals (average of commercial products: 0.73). Methylene blue adsorption, pH, and adsorption of water vapour was lower than other commercial charcoals. Carolic value of this charcoal was similar to other commercial products. Far infrared ray's emission from this charcoal was higher than others. Application of charcoal from Quercus phyllyaeoides should be consider the characteristics of this product.

Semiconductor coupled solar photo-Fenton's treatment of dyes and textile effluent

  • Raji, Jeevitha R.;Palanivelu, Kandasamy
    • Advances in environmental research
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    • v.5 no.1
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    • pp.61-77
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    • 2016
  • $NanoTiO_2$ was synthesized by ultrasonication assisted sol-gel process and subjected to iron doping and carbon-iron codoping. The synthesized catalysts were characterized by XRD, HR-SEM, EDX, UV-Vis absorption spectroscopy and BET specific surface area analysis. The average crystallite size of pure $TiO_2$ was in the range of 30 - 33 nm, and that of Fe-$TiO_2$ and C-Fe $TiO_2$ was in the range of 7 - 13 nm respectively. The specific surface area of the iron doped and carbon-iron codoped nanoparticles was around $105m^2/g$ and $91m^2/g$ respectively. The coupled semiconductor photo-Fenton's activity of the synthesized catalysts was evaluated by the degradation of a cationic dye (C.I. Basic blue 9) and an anionic dye (C.I. Acid orange 52) with concurrent investigation on the operating variables such as pH, catalyst dosage, oxidant concentration and initial pollutant concentration. The most efficient C-Fe codoped catalyst was found to effectively destruct synthetic dyes and potentially treat real textile effluent achieving 93.4% of COD removal under minimal solar intensity (35-40 kiloLUX). This reveals the practical applicability of the process for the treatment of real wastewater in both high and low insolation regimes.