• Title/Summary/Keyword: blend

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Effect of In Vitro Degradation on the Weight Loss and Tensile Strength of PLA/PEG Melt Blend Fiber (In Vitro 분해가 PLA/PEG 용융블렌드 섬유의 무게감량률 및 인장강도에 미치는 영향)

  • Yoon, Cheol-Soo;Ji, Dong-Sun
    • Polymer(Korea)
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    • v.33 no.6
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    • pp.581-587
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    • 2009
  • PLA/PEG blend fibers composed of poly (lactic acid) (PLA) and poly (ethylene glycol) (PEG) were prepared via melt blending and spinning for bioabsorbable filament sutures. The blend fibers hydrolyzed with the immersion in a phosphate buffer solution at pH 7.4 and $37\;^{\circ}C$ for 1~8 weeks. The effects of blending time, blend composition, and hydrolysis time on the weight loss and tensile strength of the hydrolyzed blend fibers were investigated. After hydrolysis, the weight loss of the blend fibers increased with increasing PEG content, blending time, and hydrolysis time. The tensile strength and tensile modulus of the blend fibers decreased with increasing PEG content, blending time, and hydrolysis time. Therefore, it can be concluded that the weight loss of the PLA/PEG blend fibers was less than 0.9% even at hydrolysis time of 2 weeks and their strength retentions were over 90%.

Preparation and Properties of Poly(vinyl alcohol)/Chitosan Blend Films (폴리(비닐 알코올)/키토산 블렌드 필름의 제조 및 특성)

  • 정민기;김대선;최용혁;손태원;권오경;임학상
    • Polymer(Korea)
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    • v.28 no.3
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    • pp.253-262
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    • 2004
  • Poly(vinyl alcohol)(PVA)/chitosan blend films with non-toxicity, biodegradability, and biocom-patibility were prepared by solution casting. Variation of the physicochemical properties of the blend films was investigated through to several analysis methods. Examination of antibacterial properties revealed that bacterio-static ratios of all blend samples containing chitosan more than 10 wt% were greater than 99.9%. Moisture regain was increased with increasing chitosan content but the degree of swelling was decreased. Up to chitosan content 15 wt%t, the melting and crystallization temperature of blend films was increased with chitosan content. The blends containing chitosan content 10 and 15 wt% gave melting temperature 229 and 228$^{\circ}C$, respectively. However, the melting temperature was decreased if chitosan content exceeded 20 wt%. The mechanical properties of the blend films were increased with increasing chitosan content in both dry and wet states. The blend film including 15 wt% chitosan exhibited unusually high tensile strength.

Study on the Properties of Antiwashout Underwater Concrete with Variation of Blend Ratio of Crushed Sand (부순모래 혼입률 변화에 따른 수중불분리성 콘크리트의 특성 연구)

  • 박세인;오광영;이환우;김종수;김명식
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.427-432
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    • 2001
  • In this study, crushed sand is blended with river sand and sea sand, to investigate the quality change of antiwashout underwater concrete with variation of blend ratio of crushed sand(0%, 20%, 40%, 60%, 80%, 100%). To see experiment conclusion, the more blend ratio of crushed sand increases, the more unit weight increases. Because the for that specific gravity of crushed sand is higher comparatively than that of river sand and sea sand. Higher compressive strength is measured following the order of river sand, crushed sand, sea sand regardless of age and casting-curing condition. Except for case of using river sand, blend ratio of 40% is appeared on most compressive strength. So the optimum blend ratio of crushed sand is 40% from the view point of compressive strength.

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Reactive Dyeing Properties of Cotton/hemp Blend

  • Lee, Ji-Eun;Kim, Sung-Eun;Kim, Hyung-Sup;Kim, Hyung-Joo;Koh, Joon-Seok
    • Textile Coloration and Finishing
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    • v.21 no.5
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    • pp.10-15
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    • 2009
  • A mixed bi-functional reactive dye has been applied to the cotton and the cotton/hemp blend and their dyeing and fastness properties were compared. The cotton/hemp blend exhibited higher exhaustion values and better build-up property than cotton, presumably due to the lower crystallinity. Hence, the reproducibility of dyeing of hemp is expected to be excellent. Fastness properties of reactive dyes on cotton and cotton/hemp blend are found to be almost identical. The results obtained suggest that hemp in cellulosic fabric could be used as an important alternative to universal cotton in cellulose fabrics.

Blend membranes based on sulfonated-fluorinated poly(arylene ether)s and chemically-modified polyvinilydene fluoride for high performance PEMFC (고분자 전해질 막 연료 전지의 고성능을 위한 술폰화된 과불소계 poly(arylene ehter)s와 화학적으로 변형된 polyvinilydene fluoride의 blend 막 연구)

  • Kim, Na-Young;Seo, Min-Seon;Lee, In-Ja
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.426-426
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    • 2008
  • Blend membranes were prepared by solvent casting method from sulfonated fluorinated poly(arylene ether)s (SDFF) and chemically modified polyvinylidene fluoride (mPVdF) in isopropanol and were evaluated as proton exchange membrane electrolytes in PEMFC. $^1H$-NMR, differential scanning calorimeter and thermogravimetric analysis was utilized to characterize the structure of the blend membranes (SDFF/mPVDF) and effects of mPVDF content on the properties of the membrane such as water uptake and proton conductivity were also investigated.

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Characterization and processing of Biodegradable polymer blends of poly(lactic acid) with poly(butylene succinate adipate)

  • Lee, Sang-Mook;Lee, Jae-Wook
    • Korea-Australia Rheology Journal
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    • v.17 no.2
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    • pp.71-77
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    • 2005
  • We investigated thermal, rheological, morphological and mechanical properties of a binary blend of poly(lactic acid) (PLA) and poly(butylene succinate adipate) (PBSA). The blends were extruded and their molded properties were examined. DSC thermograms of blends indicated that the thermal properties of PLA did not change noticeably with the amount of PBSA, but thermogravimetric analysis showed that thermal stability of the blends was lower than that of pure PLA and PBSA. Immiscibility was checked with thermal data. The rheological properties of the blends changed remarkably with composition. The tensile strength and modulus of blends decreased with PBSA content. Interestingly, however, the impact strength of PLA/PBSA (80/20) blend was seriously increased higher than the rule of mixture. Morphology of the blends showed a typical sea and island structure of immiscible blend. The effect of the blend composition on the biodegradation was also investigated. In the early stage of the degradation test, the highest rate was observed for the blend containing $80wt\%$ PBSA.

Preparation and Dyeing of Superfine Down-powder/Viscose Blend Film

  • Wang Xin;Xu Weilin;Ke Guizhen
    • Fibers and Polymers
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    • v.7 no.3
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    • pp.250-254
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    • 2006
  • Superfine down-powder/viscose blend films were prepared and characterized for their dyeing properties. Down-powder with average size of $2.56{\mu}m$ were suspended in viscose dope and blend films were obtained by solution casting. When the blend films were dyed with acid dye, the dye uptake and K/S values increased with the increase in down-powder content. Amino-acid analyses showed that amino acid component of the down were not affected during the film formation, which confirmed the changes of dye uptake and K/S value.

Prediction of Pervaporation Performance Using Solubility Parameter Calculation

  • John R. Dorgan;Nam, Sang-Yong
    • Korean Membrane Journal
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    • v.5 no.1
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    • pp.36-42
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    • 2003
  • A Prediction of pervaporation performance was studied by solubility parameter calculation approach for the benzene/cyclohexane mixture system using rubbery blend membrane with various solubility parameters. The solubility parameter of the rubbery blend membranes were controlled with different blend ratio of the poly(acrylonitrile-co-butadiene), poly(styrene-co-butadiene) and poly(vinyl chloride). Screening of blend formulations was accomplished by simple swelling tests. When the content of NBR is increased, the swelling of both benzene and cyclohexane are decreased. However, the ratio of benzene swelling to swelling by cyclohexane (the swelling selectivity) increases. The same is true for blends in which the PVC content is increased. Adoption of a solubility parameter calculation provides an a priori methodology for seeking the best blend formulation.

Properties of the Dynamically Cured EPDM and HDPE Cure-blend (전단력 하에서 가교된 EPDM과 HDPE블렌드의 물성 ; Cure-blend에 대한 연구)

  • Ha, Chang-Sik;Cho, Won-Jei
    • Elastomers and Composites
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    • v.25 no.2
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    • pp.103-111
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    • 1990
  • The blends of ethylene-propylene-diene terpolymer (EPDM) and high density polyethylene (HDPE) have been studied. Blends were prepared in a laboratory internal mixer, where EPDM was cured under shear with dicumyl peroxide (DCP) in the absence of HDPE and later blended with HDPE (cure-blend). The effect of DCP concentration, shear intensity of the mixing, and rubber/plastic composition were studied on the rheological, thermal and physical properties of the cure-blend. The results obtained were compared with those from blend-cure of Lee and Kim's work and discussed.

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