• Journal of the Korea institute for structural maintenance and inspection
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• v.17 no.2
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• pp.135-141
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• 2013

In this study, to improve the early-age compressive strength of mortar, the compressive strength tests of mortar mixed smart BFS powder added powder of rapid setting additives milled by processing, using functional grinding aid, the power-typed rapid setting cement clinker developed by sintering industrial waste and by-products with much CaO-$SiO_2-Al_2O_3$ to cement were performed. From the tests, the followings are found that (1) for BFS early-age strength improvement test (Series I): early-age strength improvement of BFS mixed rapid setting additive milled after adding functional grinding aid, when the clinker is milled, is superior and (2) for OPC early-age strength improvement test (Series II): case of additive mixed rapid setting powder typed activator milled after adding functional grinding aid to Clinker-C showed the higher compressive strength.

• Journal of the Korean Recycled Construction Resources Institute
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• v.4 no.4
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• pp.425-430
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• 2016

Both rapid industrial development and society has achieved more comfortable life. But, behind this facts of this industrial development have current pictures that occur global warming and much more by-products by environmental pollution. Therefore, this study used BFS and CFA as by-products to reduce cement usage emitted at a high rate of $CO_2$ gas, to examine sludge recycling strategy more than 200,000ton emitted at local dyeing complex, we suggest basic data research about non-cement matrix properties of utilizing dyeing sludge carbide. As a result, the more dyeing sludge carbide replacement ratio gets higher, the more air content and flow rise. Also, as the dyeing sludge carbide replacement ratio increase more, flexural strength and compressive strength go down.

• Korean Journal of Materials Research
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• v.25 no.2
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• pp.75-80
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• 2015

The carbon dioxide($CO_2$) released while producing building materials is substantial and has been targeted as a leading contributor to global climate change. One of the most typical method to reducing $CO_2$ for building materials is the addition of slag and fly ash, like pozzolan material, while another method is reducing $CO_2$ production by carbon negative cement development. The MgO-based cement was from the low-temperature calcination of magnesite required less energy and emitted less $CO_2$ than the manufacturing of Portland cements. It is also believed that adding reactive MgO to Portland-pozzolan cements could improve their performance and also increase their capacity to absorb atmospheric $CO_2$. In this study, the basic research for magnesia cement using $MgCO_3$ and magnesium silicate ore (serpentine) as main starting materials, as well as silica fume, fly ash and blast furnace slag for the mineral admixture, were carried out for industrial waste material recycling. In order to increase the hydration activity, $MgCl_2$ was also added. To improve hydration activity, $MgCO_3$ and serpentinite were fired at $700^{\circ}C$ and autoclave treatment was conducted. In the case of $MgCO_3$ as starting material, hydration activity was the highest at firing temperature of $700^{\circ}C$. This $MgCO_3$ was completely transferred to MgO after firing. This occurred after the hydration reaction with water MgO was transferred completely to $Mg(OH)_2$ as a hydration product. In the case of using only $MgCO_3$, the compressive strength was 3.5MPa at 28 days. The addition of silica fume enhanced compressive strength to 5.5 MPa. In the composition of $MgCO_3$-serpentine, the addition of pozzolanic materials such as silica fume increased the compression strength. In particular, the addition of $MgCl_2$ compressive strength was increased to 80 MPa.

• Journal of the Korea institute for structural maintenance and inspection
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• v.17 no.6
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• pp.88-94
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• 2013

The hexavalent chromium (Cr(VI)) is well known as a hazardous ion, presumably inducing dermatic diseases and if serious cancer. The present study concerns the binding capacity of Cr(VI) ions in the cement powder and matrix for a quantitative technique of Cr(VI) ions in cement to influence human health. Both the water-soluble and acid-soluble Cr(VI) ions present in 3 types of ordinary Portland cement (OPC), pulverised fuel ash (PFA), ground granulated blast furnace slag (GGBS), and silica fume (SF) were measured using the spectrophotometer. As a result, it was found that the concentration of water-soluble Cr(VI) ion in cement ranged from 10.5 to 18.9mg/kg-cement, and in the additional materials a very low value of Cr(VI) ion was measured. Acid-soluble Cr(VI) ion was even higher than water-soluble Cr(VI) ion, ranging from 172.4 to 318.2mg/kg-cement. Nevertheless, the concentration of acid-soluble Cr(VI) ion is not proportional to addition of acid. It depends rather the variable pH of solvent involving cement paste. As enough cement hydration occurs, the binding capacity of Cr(VI) ion increases, inhibiting this ions from leaching out in the presence of hydration products such as ettringite or tri-calcium aluminate which bind Cr(VI) ion by ion-exchange.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.4
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• pp.523-530
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• 2022

The problem in the construction of seawall reinforcing the seawall where there is seawater flow is the outflow of materials. Gravity-type pouring of concrete is difficult to fill the voids smoothly, and the cement of concrete that has not hardened is likely to be dispersed in seawater. This phenomenon not only reduces the reliability of quality after concrete hardening, but can also adversely affect the surrounding environment. Therefore, there is a need for a gel-like injection material that can be injected, In this study, the initial strength and durability improvement effect of seawater immersion were evaluated by using electrofurnace reduction slag and blast furnace slag with acute properties. As a result of the experiment, it was possible to prepare a gel-like injection material having flowability through reaction with silica-based chemical liquid. The flowability of the gel is 105~143 mm depending on the formulation, and the on-site simulation test can fill the voids without external leakage, confirming its on-site applicability.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.1
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• pp.22-28
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• 2019

Cement is a basic material for the construction industry and it requires high temperature sintering when manufacturing cement. $CO_2$ emissions from raw materials and fuels are recognized as new environmental problems and efforts are underway to reduce them. Techniques for reducing $CO_2$ in concrete are also recommended to use blended cement such as blast furnace slag or fly ash. In addition, the construction waste generated in the dismantling of concrete structures is recognized as another environmental problem. Thus, various methods are being implemented to increase the recycling rate. The purpose of this study is to utilize the inorganic raw materials generated during the dismantling of the structure as a raw material for the low carbon type cement binder. Such as, waste concrete powder, waste cement block, waste clay brick and waste textile as raw materials for low carbon type cement binder. From the research results, low carbon type cement binder was manufactured from the raw material composition of waste concrete powder, waste cement block, waste clay brick and waste textile.

• Journal of the Korea institute for structural maintenance and inspection
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• v.20 no.5
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• pp.75-84
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• 2016

This paper presents an investigation of the mechanical properties on non-sintered cement pastes immersed in sea waters at three different temperatures. The non-sintered cement pastes were synthesized using blended binder(Class F fly ash; FA and ground granulated blast furnace slag; GGBFS) and alkali activator(sodium hydroxide and sodium silicate). Binders were prepared by mixing the FA and GGBFS in different blend weight ratios of 6:4, 7:3 and 8:2. The alkali activators were used 5wt% of blended binder, respectively. Calcium carbonate was used as an chemical additive. The compressive strength, bulk density and absorption of alkali-activated FA-GGBFS blends pastes were measured at 3 and 28 days after immersed in sea waters at three different temperatures($5^{\circ}C$, $15^{\circ}C$ and $25^{\circ}C$). The XRD and SEM tests of the pastes were conducted at 28 days. Water-soluble chloride(free chloride) and acid-soluble chloride(total chloride) contents in the pastes were also measured after 28 days immersion in sea water. The experimental results showed that increasing the content of FA in alkali-activated FA-GGBFS blends pastes immersed in sea water increases the absorption, water-soluble chloride content and acid-soluble chloride content, and reduces the compressive strength and bulk density. And it was found that there was a variation of strength change for the alkali-activated FA-GGBFS blends pastes immersed in sea waters at three different temperatures that depends on the blending ratio of FA and GGBFS.

• Korean Journal of Mineralogy and Petrology
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• v.35 no.1
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• pp.25-39
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• 2022

This study was conducted to evaluate the manufacturing process of non-sintered cement for the safe containment of radioactive waste using low level or ultra-low level radioactive waste soil generated from nuclear-decommissioning facilities, clay minerals, and blast furnace slag (BFS) as an industrial by-product recycling and to characterize the products using mineralogical and morphological analyses. A stepwise approach was used: (1) measuring properties of source materials (reactants), such as waste soil, clay minerals, and BFS, (2) manufacturing the non-sintered cement for the containment of radioactive waste using source materials and deducing the optimal mixing ratio of solidifying and adjusting agents, and (3) conducting mineralogical and morphological analyses of products from the hydration reactions of manufactured non-sintered cement solidifier (NSCS) containing waste concrete generated from nuclear-decommissioning facilities. The analytical results of NSCS using waste soil and clay minerals confirmed none of the hydration products, but calcium silicate (CSH) and ettringite were examined as hydration products in the case of using BFS. The compressive strength of NSCS manufactured with the optimum mixing ratio and using waste soil and clay minerals was 3 MPa after the 28-day curing period, and it was not satisfied with the acceptance criteria (3.44 MPa) for being brought in disposal sites. However, the compressive strength of NSCS using BFS was estimated to be satisfied with the acceptance criteria, despite manufacturing conditions, and it was maximized to 27 MPa at the optimal mixing ratio. The results indicate that the most relevant NSCS for the safe containment of radioactive waste can be manufactured using BFS as solidifying agent and using waste soil and clay minerals as adsorbents for radioactive nuclides.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.109-112
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• 2008

In this study, Assessment of bond property of HSC with the rate of Blust-furnace(0, 12, and 25 percent by weight cement) and Evaluation of the relationship of the compressive strength coefficient (${\beta}$) between compressive strength with 40${\sim}$120MPa were performed. Design and Test of Bond specimens were carried out based on the ASTM C-234. Test results are follows, most specimens showed that the splitting failure in all specimens, except for B-40 series which showed that the pull-out failure. For the B-40 Series, the relation of compressive strength versus bond stress has well converged that of the proposed equation with the variation(${\beta}$=2/3) in UCB/E.E.R.C-83. The crack strength of concrete in splitting was proportioned to the compressive strength of concrete, and was the highest on the contents of blast furnace slag to 12 percent by weight of cement in each series, except for B-60 series. In the relation of admixture replacement rate versus maximum bond stress, The maximum bond stress was the highest in 12 percent by weight of cement according to less than 40MPa, and was the highest in 25 percent by weight of cement according to 80MPa.

• Journal of the Korean Recycled Construction Resources Institute
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• v.12 no.1
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• pp.82-93
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• 2024

Since the cement industry generates more than 60 % of CO₂ during the clinker production process, supplementary cementitious materials are used worldwide to reduce CO₂ efficiently. Mainly used supplementary cementitious materials such as blast furnace slag and fly ash, which are used in various industries including the cement industry, concrete admixtures, and ground solidification materials. However, since their availability is expected to decrease in the future according to the carbon neutrality strategy of each industry, new supplementary cementitious materials should be used to achieve the cement industry's goal for increasing the additive content of Portland cement. Limestone is a material that already has a large amount in the cement industry and has the advantage of high grinding efficiency, so overseas developed countries established Portland limestone cement standards and succeeded in commercialization. This study was an experimental study conducted to evaluate the possibility of utilizing domestic PLC, the effect of fineness and replacement ratio on the physical properties of cement was investigated, and the environmental impact of cement was evaluated by analyzing CO₂ emissions.