• Journal of the Korea Concrete Institute
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• v.12 no.5
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• pp.141-151
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• 2000

Compressive strength, sulfate deterioration factor(SDF) and length change of 5 types of mortars immersed in sodium sulfate solution were observed. As the results of tests, it was found that the sulfate resistance of blended cement mortars were superior to that of portland cement mortars. Pore volume with diameter larger than 0.1 $\mu\textrm{m}$ of 5 types of pastes indicated that the micro-structures of blended cement pastes were denser, due to pozzolan reaction and latent hydraulic properties, than those of portland cement pastes. The XRD, ESEM, EDS and TG analyses demonstrated that the reactants such as ettringite and gypsum were significantly formed in portland cement pastes. Besides, compared with the $Ca(OH)_2$ content of ordinary portland cement pastes immersed in water and sodium sulfate solution, the $Ca(OH)_2$ contents of fly ash blended cement and ground granulated blast-furnace slag cement paste were about 58% and 28% in water, and 55% and 20% in sodium sulfate solution, respectively.

• International Journal of Concrete Structures and Materials
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• v.9 no.3
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• pp.381-390
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• 2015

Investigating the microstructure of hardened cement mixtures with the aid of advanced technology will help the concrete industry to develop appropriate binders for durable building materials. In this paper, morphological, mineralogical and thermogravimetric analyses of autoclave-cured mixtures incorporating ground dune sand and ground granulated blast furnace slag as partial cementing materials were investigated. The microstructure analyses of hydrated products were conducted using scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), differential thermal analysis (DTA), thermo-graphic analysis (TGA) and X-ray diffraction (XRD). The SEM and EDX results demonstrated the formation of thin plate-like calcium silicate hydrate plates and a compacted microstructure. The DTA and TGA analyses revealed that the calcium hydroxide generated from the hydration binder materials was consumed during the secondary pozzolanic reaction. Residual crystalline silica was observed from the XRD analysis of all of the blended mixtures, indicating the presence of excess silica. A good correlation was observed between the compressive strength of the blended mixtures and the CaO/$SiO_2$ ratio of the binder materials.

• Proceedings of the Korea Concrete Institute Conference
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• 1998.04a
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• pp.161-166
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• 1998

The main object of this study is to examine the basic properties of fresh concrete as well as hardened concrete using several types of cement such as ordinary portland cement, sulphate resisting portland cement, blast furnace slag cement, ternary blended cement. In addition, effects of each cement on the durability including drying shrinkage, freeze-thawing resistance, resistance of chloride ion penetration, carbonation of concrete were investigated. As the results of this study, it was proved that most of the properties of concrete using each cement were similar, but there were some differences in bleeding, setting time, resistance of chloride ion penetration and carbonation.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.05a
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• pp.929-934
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• 2001

This study aimed to examine the cause of latent hydraulic property manifestation of ground granulated blast-furnace slag(GGBFS) using different alkali activators in pH, type and quantity. According to the experimental result, the higher pH value accelerated lastly latent hydraulic property and the early stage strength of GCBFS was ranked as activators with the higher pH, in an order of NaOH, $Ca(OH)_{2}$ and $Na_{2}$$Co_{3}$. Also, NaOH had accelerated latent hydraulic property of GGBFS, which had 40~50% of the 3 and 7 days compressive strength of base mortar in case of using 10% of powder-weight. In the case of 30% of GGBFS substitution with annexing 2.5% $Ca(OH)_{2}$, the compressive strength on the 3 and 7 days of the early-age, was increased to 5~10% than that of the same admixture with no activator. With annexing 5.0% $Ca(OH)_{2}$, the strength was increased to 10~20%. Although activator NaOH was effective on the manifestation of latent hydraulic property, it caused cement mortar compressive strength decrease by enlarging pore diameter.

• International Journal of Concrete Structures and Materials
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• v.18 no.2E
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• pp.125-132
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• 2006

Waste glass has been increasingly used in industrial applications. One shortcoming in the utilization of waste glass for concrete production is that it can cause the concrete to be weakened and cracked due to its expansion by alkali-silica reaction(ASR). This study analyzed the ASR expansion and strength properties of concrete in terms of waste glass color(amber and emerald-green), and industrial by-products(ground granulated blast-furnace slag, fly ash). Specifically, the role of industrial by-products content in reducing the ASR expansion caused by waste glass was analyzed in detail. In addition, the feasibility of using ground glass for its pozzolanic property was also analyzed. The research result revealed that the pessimum size for waste glass was $2.5{\sim}1.2mm$ regardless of the color of waste glass. Moreover, it was found that the smaller the waste glass is than the size of $2.5{\sim}1.2mm$, the less expansion of ASR was. Additionally, the use of waste glass in combination with industrial by-products had an effect of reducing the expansion and strength loss caused by ASR between the alkali in the cement paste and the silica in the waste glass. Finally, ground glass less than 0.075 mm was deemed to be applicable as a pozzolanic material.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2011.11a
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• pp.49-50
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• 2011

This study tried to utilize basic data for developing the cement substitute material through ternary system inorganic composite properties of flowing and strength. W/B and addition ratio of Na2SiO3 have been changed in ternary system inorganic composite combined blast furnace slag, red mud and fly ash. As to the experimental result inorganic composite, the flowing and intensity improvement effect was showed to be bigger than W/B according to the addition ratio change of the Na2SiO3. When particularly the Na2SiO3 addition ratio was 6%, the rapid flowing and strength improvement effect was confirmed.

• Advances in materials Research
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• v.9 no.3
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• pp.203-218
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• 2020

This research paper presents the outcomes in terms of mechanical and microstructural characteristics of binary and ternary concrete when exposed to elevated temperature. Three parameter were taken into account, (a) elevated temperature (i.e., 200, 400, 600 and 800℃) (b) binary concrete with cementitious material sugarcane bagasse ash (SCBA) and ground granulated blast furnace slag (GGBFS) replacement percentage (i.e., 0, 15, 20, 25 and 30%) and (c) ternary concrete with cementitious material SCBA and GGBFS replacement percentage (i.e., 0, 15, 20, 25 and 30%). A total of 285 standard cube specimens (150 mm × 150 mm × 150 mm) containing Ordinary Portland Cement (OPC), SCBA, and GGBFS were made. These specimens then exposed to several elevated temperatures for 2 h, afterword is allowed to cool at room temperature. The following basic physical, mechanical, and microstructural characteristics were then determined and discussed. (a) mass loss ratio, (b) ultrasonic pulse velocity (UPV) (c) physical behavior, (d) compressive strength, and (e) field emission scanning electron microscope (FESEM). It was found that compressive strength increases up to 400℃; beyond this temperature, it decreases. UPV value and massloss decrease with increase in temperature as well as the change in color and crack were observed at a higher temperature.

• Korean Journal of Materials Research
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• v.21 no.9
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• pp.502-508
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• 2011

The goal of the present work was to investigate the development of a geopolymeric ceramic material from a mixture of mine residue, coal fly ash, blast furnace slag, and alkali activator solution by the geopolymer technique. The results showed that the higher compressive strength of geopolymeric ceramic material increased with an increase in active filler (blast furnace slag + coal fly ash) contents and with a reduction of mine residue contents. The geopolymeric ceramic had very high early age strength. The compressive strength of the geopolymeric ceramic depended on the added active filler content. The maximum compressive strength of the geopolymeric ceramic containing 20 wt.% mine residue was 141.2 MPa. The compressive strength of geopolymeric ceramic manufactured by adding mine residue was higher than that of portland cement mortar, which is 60 MPa, when cured for 28 days. SEM observation showed the possibility of having amorphous aluminosilicate gel within geopolymeric ceramic. XRD patterns indicate that the geopolymeric ceramic was composed of amorphous aluminosilicate, calcite, quartz, and muscovite. The Korea Standard Leaching Test (KSLT) was used to determine the leaching potential of the geopolymeric ceramic. The amounts of heavy metals were noticeably reduced after the solidification of mine residue with active filler.

• Proceedings of the KSR Conference
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• 2005.11a
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• pp.1184-1189
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• 2005

Durability of concrete has been currently issued in the engineering societies and a large number of studies on the concrete corrosion in salty environment have been performed. The reinforcement corrosion, which is the primary reason of deterioration of the concrete structure exposed to chloride environment. is caused by the chloride ions infiltration owing to underground water seeping into the concrete. In this study. the endurance periods using the diffusion equation of the concrete specification have been evaluated on the concrete structures with different addictives for the brand new R/C subway structure exposed to seashore underground water. Furthermore. the guidance for proper use of the addictives and the reasonable thickness of concrete cover are derived for concrete mixing. From the result of the evaluation corresponding to salt damage for Inchon subway line I, the endurance periods of the ordinary Portlandcement concretes are represented as $42\~75$ years and fail to achieve the objective period of 100 years. However, the lower water-cement ratio expands the endurance periods and the blast furnace slag concrete with small quantity of the silica fume, which shows the best performance of corrosion resistance in this study, represents more than 170 years of the endurance period. Moreover, the case of use of blast furnace slag and fly ash together shows the endurance period of $134\~171$ years and it means that the result very satisfies the objective endurance period.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2011.05a
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• pp.61-62
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• 2011

This study reviewed the effect of W/B, WO and curing method on the quality properties of RA using the BS brick under the zero cement condition. compressive strength was found to show an increasing trend as W/B increased, but to show a improvement in case steam curing was conducted, showing a higher increase at 1 day age in comparison with 7 day age. In addition, the compressive strength on the mixing of WO didn't show any specific trend. The absorption tended to decrease as W/B increased and met the less than 10% regulation value at 30~35% W/B in case WO was used, there appeared a decrease attributable to capillary pore filling effect due to saponification. On the other hand, compressive strength increases, th absorption showed a gradually decreasing tendency.