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Enhanced Light Harvesting by Fast Charge Collection Using the ITO Nanowire Arrays in Solid State Dye-sensitized Solar Cells

  • Han, Gill Sang;Yu, Jin Sun;Jung, Hyun Suk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.463-463
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    • 2014
  • Dye-sensitized solar cells (DSSCs) have generated a strong interest in the development of solid-state devices owing to their low cost and simple preparation procedures. Effort has been devoted to the study of electrolytes that allow light-to-electrical power conversion for DSSC applications. Several attempts have been made to substitute the liquid electrolyte in the original solar cells by using (2,2',7,7'-tetrakis (N,N-di-p-methoxyphenylamine)-9-9'-spirobi-fluorene (spiro-OMeTAD) that act as hole conductor [1]. Although efficiencies above 3% have been reached by several groups, here the major challenging is limited photoelectrode thickness ($2{\mu}m$), which is very low due to electron diffusion length (Ln) for spiro-OMeTAD ($4.4{\mu}m$) [2]. In principle, the $TiO_2$ layer can be thicker than had been thought previously. This has important implications for the design of high-efficiency solid-state DSSCs. In the present study, we have fabricated 3-D Transparent Conducting Oxide (TCO) by growing tin-doped indium oxide (ITO) nanowire (NWs) arrays via a vapor transport method [3] and mesoporous $TiO_2$ nanoparticle (NP)-based photoelectrodes were prepared using doctor blade method. Finally optimized light-harvesting solid-state DSSCs is made using 3-D TCO where electron life time is controlled the recombination rate through fast charge collection and also ITO NWs length can be controlled in the range of over $2{\mu}m$ and has been characterized using field emission scanning electron microscopy (FE-SEM). Structural analyses by high-resolution transmission electron microscopy (HRTEM) and X-Ray diffraction (XRD) results reveal that the ITO NWs formed single crystal oriented [100] direction. Also to compare the charge collection properties of conventional NPs based solid-state DSSCs with ITO NWs based solid-state DSSCs, we have studied intensity modulated photovoltage spectroscopy (IMVS), intensity modulated photocurrent spectroscopy (IMPS) and transient open circuit voltages. As a result, above $4{\mu}m$ thick ITO NWs based photoelectrodes with Z907 dye shown the best performing device, exhibiting a short-circuit current density of 7.21 mA cm-2 under simulated solar emission of 100 mW cm-2 associated with an overall power conversion efficiency of 2.80 %. Finally, we achieved the efficiency of 7.5% by applying a CH3NH3PbI3 perovskite sensitizer.

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Parametric Numerical Study on the Performance of Helical Tidal Stream Turbines (헬리컬 터빈의 설계인자에 따른 성능 연구)

  • Han, Jun-Sun;Choi, Da-Hye;Hyun, Beom-Soo;Kim, Moon-Chan;Rhee, Shin-Hyung;Song, Mu-Seok
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.14 no.2
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    • pp.114-120
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    • 2011
  • The characteristics of a helical turbine to be used for tidal stream energy conversion have been numerically studied with varying a few design parameters. The helical turbines were proposed aiming at mitgating the well known poor cut-in characteristics and the structural vibration caused by the fluctuating torque, and the basic concept is introducing some twisting angle of the vertical blade along the rotation axis of the turbine. Among many potential controling parameters, we focused, in this paper, on the twisting angle and the height to diameter ratio of the turbine, and, based on the numerical experiment, We tried to propose a configuration of such turbine for which better performance can be expected. The three-dimensional unsteady RANS equations were solved by using the commercial CFD software, FLUENT with k-${\omega}$ SST turbulence model, and the grid was generated by GAMBIT. It is shown that there are a range of the twisting angle producing better efficiency with less vibration and the minimum height to diameter ratio above which the efficiency does not improve considerably.

Effects of Particle Size and Structure of Fillers on the Friction and Wear Behavior of Filled Elastomer (충전제의 입자크기 및 구조에 따른 고무 배합물의 마찰 마모특성)

  • Kaang, Shin-Young;Ryu, Chang-Seok;Hong, Chang-Kook;Moon, Chae-Woo
    • Elastomers and Composites
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    • v.41 no.3
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    • pp.194-204
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    • 2006
  • The effects of the particle size and the structure of carbon blacks on the friction and the wear behavior of filled natural rubber were investigated in this study. The particle size and the structure of carbon black had a significant effect on the wear rates and the worn surface pattern, and the effect of them on abrasion resistance should be considered for the optimum design of desired wear properties. Ten carbon blacks with various sizes and structures are mixed with natural rubber in order to investigate the effects on the wear rate ($W_R$). The friction and the wear behavior were examined by self-made blade type friction-wear abrader, and the ,elation with characteristic parameter (${\psi}=\sqrt{{N_2^2}+{DBP^2}}$), obtained from the particle size and the structure, was studied. The wear rate ($W_R$) had a Power Law relation with the frictional work ($W_f$) and it was inversely proportional to the characteristic parameter of carbon black. It means that smaller particle size and better structure development of carbon black resulted in improved abrasion resistance.

Design and Safety Performance Evaluation of the Riding Three-Wheeled Two-Row Soybean Reaper

  • Jun, Hyeon-Jong;Choi, Il-Su;Kang, Tae-Gyoung;Kim, Young-Keun;Lee, Sang-Hee;Kim, Sung-Woo;Choi, Yong;Choi, Duck-Kyu;Lee, Choung-Keun
    • Journal of Biosystems Engineering
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    • v.41 no.4
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    • pp.288-293
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    • 2016
  • Purpose: The purpose of this study was to investigate the key factors in designing a three-wheeled two-row soybean reaper (riding type) that is suitable for soybean production, and ensure worker safety by proposing optimal work conditions for the prototype of the designed machine in relation to the slope of the road. Methods: A three-wheeled two-row soybean reaper (riding type) was designed and its prototype was fabricated based on the local soybean-production approach. This approach was considered to be closely related to the prototype-designing of the cutter and the wheel driving system of the reaper. Load distribution on the wheels of the prototype, its minimum turning radius, static lateral overturning angle, tilt angle during driving, and The working and rear overturning (back flip) angle were measured. Based on the gathered information, investigations were conducted regarding optimal work conditions for the prototype. The investigations took into account driving stability and worker safety. Results: The minimum ground clearance of the prototype was 0.5 m. The blade height of the prototype was adjusted such that the cutter was operated in line with the height of the ridges. The load distribution on the prototype's wheels was found to be 1 (front wheel: F): 1.35 (rear-left wheel: RL): 1.43 (rear-right wheel: RR). With the ratio of load distribution between the RL and RR wheels being 1: 1.05, the left-to-right lateral loads were found to be well-balanced. The minimum turning radius of the prototype was 2.0 m. Such a small turning radius was considered to be beneficial for cutting work on small-scale fields. The sliding of the prototype started at $25^{\circ}$, and its lateral overturning started at $39.3^{\circ}$. Further, the critical slope angle for the worker to drive the prototype in the direction of the contour line on an incline was found to be $12.8^{\circ}$, and the safe angle of slope for the cutting was measured to be less than $6^{\circ}$. The critical angle of slope that allowed for work was found to be $10^{\circ}$, at which point the prototype would overturn backward when given impact forces of 1,060 N on its front wheel. Conclusions: It was determined that farmers using the prototype would be able to work safely in most soybean production areas, provided that they complied with safe working conditions during driving and cutting.

Development of a Belt Pick-up Type Two-row Sesame Reaper

  • Jun, Hyeon-Jong;Choi, Il-su;Kang, Tae-Gyoung;Kim, Young-Keun;Lee, Sang-Hee;Kim, Sung-Woo;Choi, Yong;Choi, Duck-Kyu;Lee, Choung-Keun
    • Journal of Biosystems Engineering
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    • v.41 no.4
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    • pp.281-287
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    • 2016
  • Purpose: The purpose of this study is to develop a walking-type two-row sesame reaper, which can simultaneously perform the cutting and collecting of sesame plants and other crops like perilla and soybean. Methods: The factors involved in reaping sesame were determined experimentally in order to design a prototype of the sesame reaper. The prototype is made up of four parts for cutting, conveying, collecting, and running. The height of two disc-plate saw blades on the cutting part is adjusted by an adjusting wheel, and peripheral speed is adjusted in accordance with the running speed. The conveying belt of the conveying part can be tilted from $0^{\circ}$ to $90^{\circ}$. The collecting part extracts a predetermined amount of transferred sesame plants. The prototype was used to evaluate the performance at different working speeds, so that the work efficiency can be calculated. Results: The center of gravity of the sesame plants was 900 mm, measured from the end of the cut stem. The diameter of the disc-plate saw blade was determined to be 355 mm, peripheral speed was 20.4-32.7 m/s, and the picking height of the conveying belt for sesame was 130 mm. The performance of transfer and collection of the sesame, when the insertion angles were $60^{\circ}$ and $90^{\circ}$, proved to be excellent. However, when the angle was over $120^{\circ}$, the performance was only 75-80%. The performance was at 100% efficiency when the ratio between running speed and conveying belt speed of the prototype was 1:2, which seems to be the ideal ratio for the sesame reaper. Conclusions: A sesame reaper was developed, which can integrate the processes of cutting, conveying, and collecting, by investigating and considering various factors involved in the reaping process. The sesame reaper can reduce the costs for yielding and producing sesame due to its highly efficient performance.

Study on EPB TBM performance by conducting lab-scaled excavation tests with different foam injection for artificial sand (실내 굴진 시험을 통한 폼 주입 조건에 따른 인공 사질토 지반에서 EPB TBM 굴진성능에 대한 고찰)

  • Lee, Hyobum;Shin, Dahan;Kim, Dae-Young;Shin, Young Jin;Choi, Hangseok
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.21 no.4
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    • pp.545-560
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    • 2019
  • During EPB TBM tunnelling, an appropriate application of additives such as foam and polymer is an essential factor to secure the stability of TBM as well as tunnelling performance. From the '90s, there have been many studies on the optimal injection of additives worldwidely contrary to the domestic situation. Therefore, in this paper, the foam, which is widely adopted for soil conditioning, was selected as an additive in order to investigate the effect of foam injection on TBM performance through a series of laboratory excavation tests. The excavation experiments were carried out on artificial sandy soil specimens with consideration of the variance of FIR (Foam Injection Ratio), FER (Foam Expansion Ratio) and $C_f$ (Surfactant Concentration), which indicate the amount and quality of the foam. During the tests, torque values were measured, and the workability of conditioned soil was evaluated by comparing the slump values of muck after each experiment. In addition, a weight loss of the replaceable aluminum cutter bits installed on the blade was measured to estimate the degree of abrasion. Finally, the foam injection ratio for the optimal TBM excavation for the typical soil specimen was determined by comparing the measured torque, slump value and abrasion. Note that the foam injection conditions satisfying the appropriate level of machine load, mechanical wear and workability are essential in the EPB TBM operational design.

Thrust and torque prediction of multicopter propeller in hovering based on BET method (BET 기법을 이용한 멀티콥터 프로펠러의 정지비행시 추력 및 토크 계산)

  • Lee, Bumsik;Woo, Heeseung;Lee, Dogyeong;Chang, Kyoungsik;Lee, Dongjin;Kim, Minwoo
    • Journal of Aerospace System Engineering
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    • v.12 no.6
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    • pp.23-31
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    • 2018
  • In the present work, the thrust and torque of multicopter propellers in hovering are predicted based on BET method. The geometry information of the propellers is obtained using a three dimensional scanner and the airfoil section is extracted using CATIA. EDISON CFD is adopted to calculate the drag and lift of airfoil at a given geometry and flow conditions and then thrust is calculated with respect to a given RPMs based on BET. Two simulations with laminar and turbulent flows are considered. The predicted value is compared with the performance data from the Product Company and results from JavaProp software, which is used in the design and prediction of propellers. In the case of a 9-inch propeller, the thrust from the product company is corresponding to the results between the laminar and turbulent flow conditions. In the 16-inch case, the predicted thrust at turbulent flow conditions conformed well with reference one. The predicted torque shows a big difference with the reference data.

Optimization of impeller blade shape for high-performance and low-noise centrifugal pump (고성능 저소음 원심펌프 개발을 위한 임펠러 익형 최적설계)

  • Younguk Song;Seo-Yoon Ryu;Cheolung Cheong;Tae-hoon Kim;Junhyo Koo
    • The Journal of the Acoustical Society of Korea
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    • v.42 no.6
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    • pp.519-528
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    • 2023
  • The aim of this study was to enhance the flow rate and noise performance of a centrifugal pump in dishwashers by designing an optimized impeller shape through numerical and experimental investigations. To evaluate the performance of the target centrifugal pump, experiment was conducted using a pump performance tester and noise experiment was carried out in a semi-anechoic chamber with microphones and a reflecting wall behind the dishwasher. Through the use of advanced computational fluid dynamics techniques, numerical simulations were performed to analyze the flow and aeroacoustics performance of our target centrifugal pump impeller. To achieve this, numerical simulations were carried out using the Reynolds-Average Navier-Stokes equations and Ffowcs-Willliams and Hawkings equations as governing equations. In order to ensure the validity of numerical methods, a thorough comparison of numerical results with experimental results. After having confirmed the reliability of the current numerical method of this study, the optimization of the target centrifugal pump impeller was conducted. An improvement in flow rate was confirmed numerically, and a manufactured proto-type of the optimized model was used for experimental investigation. Furthermore, it was observed that by applying the fan law, we could effectively reduce noise levels without reducing the flow rate.

( Studies on the Grassland Development in the Forest II. Effect of fertilizer ievel on qrowth and dry matter yield of grass-clover mixtures grown under pine trees (임간초지 개발에 관한 연구 II. 임간혼파초지에서 3요소 시비수준이 목초의 생육과 수량에 미치는 영향)

  • Han, Y.C.;Park, M.S.;Seo, S.
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.5 no.2
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    • pp.136-142
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    • 1985
  • For better grassland development in the forest, this field experiment was carried out to investigate the effect of thirteen different fertilizer levels of nitrogen(N), phosphorus ($P_2O_5$) and potassium ($K_2O$) on the botanical composition, growth and dry matter yield of grass-clover mixtures grown under trees with 40-50% of shading level. This experiment was arranged as a randomized block design with replications, and performed on the experimental field in the suburban forest of Suweon in 1984. The results obtained are summarized as follows: 1. Plant height and cover degree of grasses found to be high with 28 and 42kg N fertilizer per 10a, while those were the lowest with zero and N-zero fertilizer levels. The degree of bare land after the fourth cut was also high in the low N level. 2. A significant higher degree of leaf green and chlorophyll content of leaf blade was observed in the plot of 28 and 42 kg N per 10a when compared with low N fertilizer plot. However, leaf decay and plant type of grasses tended to be a little poor as the high N was applied. 3. the regrowth plant length and dry weight of grasses after the first cut increased significantly with 28 and 42 kg N fertilizer. However, those showed slightly increased regrowth in the plot of zero and N-zero fertilizer levels. 4. The dry matter yield of grasses was higher with 28 and 42 kg N than that of low N fertilizer level. Higher yields were obtained in the plot of standard ($N-P_2O_5-K_2O$=28-20-24 kg/10a), 50% increase of $N,P_2O_5K_2O$ and N-50% increase, although there were no significant differences among three fertilizer levels. 5. Growth, botanical composition, regrowth and yield of grasses grown under pine trees were significantly influenced by N fertilizer level, regardless of $P_2O_5\;and\;K_2O$. The fertilizer level of $N-P_2O_5-K_2O$ was 28-20-24 kg per 10a for more forage production in the forest. Considering economic yield in this study, however, the optimum fertilizer level of N, $P_2O_5\;and\;K_2O$ was suppose to be 21-28, 10-15, and 12-18kg per 10a, respectively.

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Research on Mechanized Upland Reclamation Works An Experiment for the Selection of Optimum Teeth Interval and the Analysis of Efficiency of Stumping and Root-Clearing Methods by Rake Dozer. (Report 1) (야산 기계화 개간공법에 관한 연구 -레이크 도저의 적정 이빨 간격의 선택과 발배근작업능률 시험(제1보)-)

  • 류한열;정하우박승우
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.17 no.3
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    • pp.3860-3871
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    • 1975
  • This experiment was carried out to establish the mechanized methods in stumping and root-clearing, which were the most important works in the reclamation of sloping uplands. The determination of optimum teeth interval of rake blades and its operation methods to reduce the quantity of transported topsoil during the works, are the aims of this investigation. A newly designed rake blade, whose net teeth intervals could be regulated by three stages as 15cm, 25cm, and 35cm, was manufactured to attach to the bulldozer of 13ton. The experiments were carried out at Kilsang-Myon, Kwangwha-Gun, from Aug. 9 to Aug. 23, 1975. For each interval, 36 test plots of 50${\times}$10mn in size, which were regulated under three levels of land slopes of 10, 20, and 30% and two different tree stand density of high or medium values, were randomly chosen and arranged by two-replicated split-split plot design. Each stump classified by its diameter was stumped and cleared by the rake dozer to be related between diameter and stumping time. The results obtained in this experiment can be summarized as follows: 1. Stumping times for the diameters ranging from 6 to 18cm of stumps are almost the same and they are not varied by the difference of teeth intervals of rake dozer. 2. By back-ward stumping method, the number of stumps which can be stumped per hour ranges almost from 100 to 170, showing significant difference with respect to the teeth intervals. The working area is sharply varied with not only the stand density of stumps but the teeth intervals. 3. Optimum stumping distance for each teeth interval of rake dozer to minimize the quantity of transported topsoil are varied with such the rates as it is 15m or 20m for 15cm of teeth interval, but 25m for 25cm or 35cm, respectively. The clearing distance could be chosen almost double as long as the operating distance. 4. The working areas per hour of the simultaneous stumping and clearing methods are no significant difference among the various treatments of working conditions, but they are affected by the operating techniques. However, the influencing factors of the working conditions as classified before and the working directions are ranged from 10 to 15 per cent of total working area, respectively. 5. The residual rates of stumps which are not stumped by the rake dozer in each test plot are generally reduced as the teeth interval gets narrower, but there are no significant difference among them. The mean residual rates average to be about 4% for the simultaneous stumping and clearing method. The back-ward stumping method are recommended to be supervised and directed by more than one man, to show the operator where the stumps are located. 6. The results according to the stumping and clearing methods are summarized as Table IV-2. And the selection of working methods is recommended to follow as shown in Fig. IV-9 with respect to the stand density of the field. 7. Generally speaking, the narrower the teeth interval, the better become the working results, but the more the quantity of transported topsoil is increased. Therefore, it is recommended that the teeth interval should be reduced from the present distance of more than 30cm to 25cm or 15cm, by developing suitable working methods through more field works and experiments.

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