• Title/Summary/Keyword: black slate

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Dispersion and Enrichment of Potentially Toxic Elements in Chubu Area Covered with Black Shales and Slates in Korea (추부지역 흑색셰일 및 점판암 분포지역에서의 잠재적 독성원소들의 분산과 부화)

  • Kim, Jong Shin;Chon, Hyo Taek
    • Economic and Environmental Geology
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    • v.30 no.2
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    • pp.89-103
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    • 1997
  • The purpose of this research is to investigate the enrichment and distribution patterns of naturally occurring potentially toxic elements in soils derived from black shales and slates. Soil samples were collected from the Chubu area covered with uranium-enriched black shales and slates of the Changri Formation of the Okchon Super Group, and analysed for multiple-elements using INAA, ICP-AES and AAS. Soil pH and loss-an-ignition were also measured. Trace element contents in black shale and slate of the Chubu area are relatively lower than those in black shales, and higher than those in black slates reported elsewhere (Chon, Jung, 1991; Chon et al., 1996). Soil pH values range from 3.5 to 6.5, and loss-an-ignition values are in the range from 3 to 10%. Potentially toxic elements including As, Ba, Cr, Cu, Mo and U are highly enriched in residual soils with maximum content of $540{\mu}g/g$, $35,000{\mu}g/g$, $280{\mu}g/g$, $300{\mu}g/g$, $240{\mu}g/g$ and $860{\mu}g/g$, respectively. Significant concentrations of those elements were found in soils taken from the Tojangkol, the Chubu tunnel and the Meokti areas. Soils derived from black shales and slates, calcareous and phyllitic rocks, and intrusions were discriminated in terms of As, Ba, Co, Cr, Cu, Mo, Sc and U contents. Enrichment index was calculated using the concentrations of As, Ba, Cr and Mo, and enrichment index map shows very similar trend with U distribution in soils.

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Radon Concentrations in Groundwater of the Goesan Area, Korea (괴산지역 지하수의 라돈 함량)

  • Cho, Byong-Wook
    • Journal of Soil and Groundwater Environment
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    • v.22 no.5
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    • pp.63-70
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    • 2017
  • Radon concentrations were measured in 250 groundwater samples collected from the Goesan area where uraniferous black slate and granites abundantly occur in the formations. The measured radon levels ranged from 0.90 to 7,218.7 Bq/L with the median value of 54.3 Bq/L, similar to the value measured in the nationwide survey in 4,853 wells (52.1 Bq/L). The median value was highest in the Cretaceous granite area (390.0 Bq/L) while it was as low as 20.0~58.8 Bq/L in the Ogcheon meta-sedimentary rock areas. About 23.6% of the total samples exceeded the WHO guideline value of 100 Bq/L established in 2011. The exceeding rate was 69.0, 39.4, and 7.0~13.7% in the Cretaceous granite area, Jurassic granite area, and Ogcheon meta-sedimentary rock areas, respectively.

Polymetamorphism of Metapelites in the Sunchang Shear Zone, Southwestern part of the Korea peninsula (한반도 남서부의 순창전단대 내에 분포하는 변성퇴적암류의 다변성 작용)

  • 안건상
    • Economic and Environmental Geology
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    • v.32 no.5
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    • pp.519-535
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    • 1999
  • Precambrian metasedimetay rocks in the Sunchang Shear Zone (so-called Seologri and Yongamsan Formation) consist of black slate, phylite, mica schistm quartzite and rarely calc schist. The metamorphic rocks in the area have undergone at least three stages of metamorphism, which are two prograde (M1 and M2) and one contact metamorphism (M3). The metamorphism which made the most prevailing mineral assemblages in the area, is M2 stage metamorphism. The metamorphic grade of M2 methamorphism in metapelites increases from the Chlorite zone through Biotituzone, Garnet zone to Staurolite zone. The M1 stage metamorphism is recognized by kyanite and sillimanite pressure type regional metamorphism. The M3 stage methamorphism is represented in the contact boundary, which area is the chlorite zone and biotite zone near the Sunchang foliated granite and the namwon granite. The M3 stage methamorphism is characterized by andalusite bearing mineral assemblages. The peak temperature condition of M2 metamorphism estimated from coexising garnet and biotite (Kretz, 1990) is 518~598$^{\circ}C$.

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Geochemical Correlations Between Uranium and Other Components in U-bearing Formations of Ogcheon Belt (옥천대(沃川帶) 함(含)우라늄지층중(地層中)의 우라늄과 타성분(他成分)과의 상관관계(相關關係))

  • Lee, Min Sung;Chon, Hyo Taek
    • Economic and Environmental Geology
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    • v.13 no.4
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    • pp.241-246
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    • 1980
  • Some components in uranium-bearing formations which consist mainly of black shale, slate. and low grade coal-bearing formation of Ogcheon Belt were processed statistically in order to find out the geochemical correlations with uranium. Geochemical enrichment of uranium, vanadium and molybdenum in low grade coal-bearing formations and surrounding rocks is remarkable in the studied area. Geochemical correlation coefficient of uranium and molybdenum in the rocks displays about 0.6, and that of uranium and fixed carbon about 0.4. Uranium and vanadium in uranium-bearing low grade coals denote very high correlation with fixed carbon, which is considered to be responsible for enrichment of metallic elements, especially molybdenum. Close geochemical correlation of uranium-molybdenum couple in the rocks can be applied as a competent exploration guide to low grade uranium deposits of this area.

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A Study on the Building Stone Resources in Korea (국내석재자원(國內石材資源)에 관(關)한 연구(硏究))

  • Shin, Byung Woo;Hyun, Jeon Ki
    • Economic and Environmental Geology
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    • v.18 no.3
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    • pp.263-276
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    • 1985
  • Building stones can be divided into two groups: raw stone and stone product. In Korea, they consist of granite, diorite, gabbro, andesite, tuff, slate and marble, of which granite is main product. The disribution area is approximately $31,753km^2$. The enterprises of building stone are about 1,500 at present. The granites for building stone are biotite granite, hornblende granite. granodiorite and porphyritic granite, of different colors (white, pink, grey, green and black). The compressive strength of granite ranges from 813 to $1,338kg/cm^2$, hardness from 78 to 101 and water absorption ratio from 0.09 to 0.40%. The weight reduction ratio of granite for 14 hours in aqua regia+$KMnO_4$solution is 0.3~4.5wt.%. There are eighty granite quarries in Korea. Marbles can also be extensively used for building but only a few mines are operated at present.

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촉매제에 의한 연탄깨스 제거에 관한 연구

  • Heo, Jin
    • Journal of the Korean Professional Engineers Association
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    • v.5 no.19
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    • pp.3-16
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    • 1972
  • 1. Purposes and importances of the study. In gaining heating resources by combustion of briquette, which is the necessaries of every day's life, victims occur from poisonous affection of combustion gas (carbon mono-oxide) in every year and this gas attributable to increase death rate proportion to the high demand of briquette usage. It arise great problem ill point of national sanitation. Therefore, the study has a big aim to accomplish depressing CO gas or stimulating comlete combustion by both the methods of physical improvement of present combustion devices and chemical improvement by using V$_2$O$\sub$5/ catalyst to depress CO gas or fasten complete combustion Progress. Sucessful result of this study will not only to decrease the death rate but also to contribute fearless handling of briquette combustion so as to perform improving public Welfare. 2. Contents and scope of study. A. comparison of present and improved fuel hole device. B. Examination of effectness of improved elements. C. Effectness of miffed usage of catalyst. D. Comparison of Catalyst effectness. E. Examination of effectness of black slate containing V$_2$O$\sub$5/. 3. Results and recommendations of the study A. Absolute necessity of supplying secondary air by improved combustion device. B. Oxide Vanadium (V$_2$O$\sub$5/) has the greatest effectness to eliminate CO gas. C. Most effective catalyst of V$_2$O$\sub$5/ containing slate comes from "Samgoe" coal mine. D. By plastering catalyst on the cover plate of fire hole, it stimulate chemical reaction of re-combustion and preserving heat. E. Recommend to continute further precise study to practice with low-cost and handy devices to be applied the study results.

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Study on The Contact Metamorphism of Weolagsan Granite (월악산화강암(月岳山花崗岩)의 접촉변성(接觸變成)에 관(關)하여)

  • Lee, Dai Sung;Kang, Jun Nam
    • Economic and Environmental Geology
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    • v.11 no.4
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    • pp.169-182
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    • 1978
  • The Weolagsan area consists of four units; (1) Low grade meta-sediments of the upper members of Ogcheon age unknown group such as Changri (mainly black slate and phyllitic rock), Majeonri (mainly alternation of slate, limestone and chert) and Hwanggangri Formation (pebble bearing phyllitic sediments); (2) Samtaesan Formation of Chosun System of Ordovician; (3) So called meta-volcanics and (4) Weolagsan Granite and its associations which intruded above mentioned meta-sediments and meta-volcanics. This study was focused to know the Woelagsan granite and its metasomatic effects to the country rocks petrographically and petrochemically. According to the field survey, microscopic work and some chemical analysis, the granite is a "normal granite" based on the Streckeisen's classification and belongs to a mass of the Central-zone younger group in Ogcheon geosynclinal belt. The granite metasomatized the country rocks along its northern contact zone. Zone of calcareous and cherty rocks (Majeonri formation) was silicified partly and skarned locally at the contact with the granite. The chemical analysis of the zone show no difinite variations in contents of $SiO_2$ and CaO with the distance from the granite. It seems to be indicated that the silicification of this part was not so metasomatized by the granite body, but thermally affected as much as to be partially remelted in the specific parts of the formations. Meta-volcanic rock zone was slightly chloritized near contact with the granite. Limestone of Samtaesan Formation was silicified and skarned along the contact zone by the granite body. The chemical analysis of the zone show some noticiable changes in compositions of $SiO_2$ and CaO with distance from the granite boundary. It can be imagined that the silicification of this zone was metasomatically originated by Woelagsan Granite. According to chemical analysis on several trace elements, the ratio of Zn/Cr and Ni/Cr are relatively higher than that of Cu/Cr in the above mentioned silicified zones. Generally the variation of these metal elements in the zones tend to be regular with distance from the granite body.

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Cultural, Morphological and Pathological Variation in Indian Isolates of Ascochyta rabiei, the Chickpea Blight Pathogen

  • Basandrai, A.K.;Pande, S.;Kishore, G. Krishna;Crouch, J.H.;Basandrai, D.
    • The Plant Pathology Journal
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    • v.21 no.3
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    • pp.207-213
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    • 2005
  • Cultural, morphological and pathogenic variation in Indian isolates of Ascochyta rabiei, the causal agent of blight of chickpea, was investigated. Fungal isolates representative of seven agroclimatic regions in north western plain zones (NWPZ) of India showed variation in colony colour as mouse gray with green hue, light mouse gray with slate gray centre and gray with dark brown centre, when grown on chickpea dextrose agar (CDA). Conidiomatal color of the isolates varied from brown to slate gray and black. The number of conidiomata and conidia formed on CDA ranged from 49.7 to 90.7 and $5.5\times10^4\;to\;3\times10^5cm^{-2}$, respectively. The size of conidiomata and conidia of A. rabiei isolates varied from $274\times232{\mu}m\;to\;156\times116{\mu}m$, and from $14.0\times6.2{\mu}m\;to\;10.7\times4.6{\mu}m$, respectively. Fourteen A. rabiei isolates from the seven agroclimatic regions of NWPZ were evaluated for their virulence on 180 chickpea genotypes in controlled environment. Cluster analysis based on the disease rating on a 1-9 scale indicated higher similarity coefficient (> 0.65) between isolates from different agroecological regions, while few isolates from the same region had less similarity. The 14 isolates were grouped into eight pathotypes at > 0.5 similarity coefficient. Sixteen genotypes were identified as probable differentials to distinguish A. rabiei isolates.

Structural control, and Correlation of Uranium Distribution and Mineralogy of Meta-pelites in Ogcheon Terrain, Korea (한반도(韓半島) 옥천대(沃川帶)에 분포(分布)하는 함(含)우라늄층(層)의 지질구조규제(地質構造規制) 및 조성광물(組成鑛物)과 우라늄분포(分布)와의 상관관계연구(相關關係硏究))

  • Park, Bong-Soon;So, Chil-Sup
    • Economic and Environmental Geology
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    • v.13 no.4
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    • pp.215-227
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    • 1980
  • The rock units of Goesan area in the Ogcheon metamor phic terrain established on the basis of field criteria should be redefined into following sequence. Based on shear senses in secondary small structures which are usually observable in the investigated area, the stratigraphy can be lithologically divided into the lower pelite, pebbly mudstone, upper pelite, quartzite and psammite unit in ascending order. This conclusion is in discordance with a previous opinion; Munjuri formation and Guryongsan formation may be equivalent to upper pelite unit, Iwonri formation and Hwanggangri formation to pebbly mudstone. From this, it may be inferred that isoclinal overturned folds repeatly occur in the area. The uranium bearing coaly thin layers in upper pelite unit have relatively broad exposures in Deogpyeongri block of Goesan area along culmination zone in the central part of the investigated area. It is believed that structural feature in the block recognized complexly refolded synform plunging to southwest. Mineralogical and radiometric studies were made on 135 representative samples from the Ogcheon Group of Korea. The mineralogy of all black slate samples is qualitatively similar but quantitatively ·different. The uranium distribution in the studied area show approximately log normal. Uranium in the black slates of the Ogcheon Group was deposited together under same physico-chemical environmental conditions. The chemical and geological factors that controlled the abundance of organic carbon and iron oxides also controlled the uranium content. The relationship of the major components to uranium can be expressed by the following regression equation: $Log(U\times10^4+1)$= 1.70999-0.00367(quartz)0.00512(micas)-0.00930 (other silicates)+0.01911 (iron oxides)-0.03389(other opaques)+0.02062(organic carbon).

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Characteristics of Stone-monuments and Geological Studies on the Rocks for Conservation(III) - Hanam city, Yangpyeong-gun and Yeoju-gun, Gyeonggi-do - (석조문화재의 특징과 암석에 대한 지질학적 연구 (III) -경기도 하남시, 양평군 및 여주군을 중심으로-)

  • Lee, Sang Hun;Park, Kyung Rip
    • Journal of Conservation Science
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    • v.4 no.1 s.4
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    • pp.11-42
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    • 1995
  • Stone-monuments, distributed in this area, have been investigated and studied on the characteristics and the rock phases in the geological and conservational points of view. Most of them may have been built from the end of the Shilla Kingdom to the Koryeo Kingdom, which are based on the typical characteristics of the form. The used rocks in these monuments are mainly biotite granite of the Jurassic age which is widely distributed around the area. Black slate and marbles are also used in some monuments, which may be obtained from other areas. The biotite granite of massive and coarse texture contains often inclusions of biotite aggregates or fragments of dioritic rock phase. However, the biotite granite in the area may be very weak to the chemical weathering so that irregular rock surface shows generally $2\~3mm$ relief. The irregular relief is mainly due to different relative degree on the chemical weathering according to the kind of minerals especially quartz, feldspar and biotite. The chemical weathering is also influenced by organisms. For conservation, they must be scientifically considered based on the characteristics, kind of the rock phase, factors on the weathering process, situation in situ or being transported, and protection.

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