• Title/Summary/Keyword: bituminous

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Bioassay of Marine Animals to the Aquatic Toxicity of Composite Slag and Bituminous Coal (복합슬래그와 석탄에 대한 해산동물의 생물독성 검정)

  • KIM Jin Mee;KIM Kyoung Sun;LEE Jung Ah;SHIN Yun Kyung;PARK Chung Kil;CHIN Pyung
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.38 no.2
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    • pp.100-105
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    • 2005
  • Two species of fish and five species of marine invertebrate showed different tolerances to the toxicity of composite slag and bituminaus coal. Especially, Hemicentrotus pulcherrimus and young Haliotis discus hannai displayed marked differences in tolerance from. H. pulcherrimus and young H. discus hannai showed lethal effects at higher concentrations than those concentrations of the composite slag in the 1.0 and $0.4\%$ range, respectively. H. pulcherrimus showed no lethal effects at a lower concentration of $1.0\%$ composite slag and some differences in the rate of oxygen consumption with this concentration of composite slag. The lethal effects of bituminous coal on marine and fisheries organisms, even with higher concentrations, were not observed. At a higher concentration than that of 500 mg/L (ppm) of bituminous coal, decrease effects appeared in the rate of oxygen consumption of the experimental organisms. Taking into consideration that the experimental concentration of composite slag and bituminous coal were impracticable in the ocean, the results of this experiment suggest that composite slag and bituminous coal pose no real threat to marine or fisheries organisms.

Investigation of Tar/soot Yield of Bituminous and Low Rank Coal Blends (발전용 역청탄과 저열량탄 혼소시 Tar/Soot의 배출 특성 연구)

  • Lee, Byung Hwa;Kim, Jin Ho;Kim, Gyu Bo;Kim, Seng Mo;Jeon, Chung Hwan
    • Journal of Energy Engineering
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    • v.23 no.2
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    • pp.42-48
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    • 2014
  • Soot and tar which were derived from combustion or pyrolysis processes in Puverized Coal(PC) furnace or boiler have been significantly dealing in a radiative heat transfer and an additional source of NOx. Furthermore, the increasing for the use of a coal with low caloric value gives rise to a lot of tar-soot yield and LOI in a recycled ash for using cement materials. So, the ash with higher tar-soot yield and LOI can not recycle due to decreased strength of concrete. In this study, tar-soot yields and flame structures were investigated using the LFR for a blending combustion with bituminous coal and sub-bituminous coal. Also, The investigation were conducted as each single coals and blending ratio. The coals are used in a doestic power plant. In the experimental results, sub-bituminous coal with high volatile contents shows longer soot cloud length than bituminous coal, but overall flame length was shorter than bituminous coal. Tar-soot yields of sub-bituminous coal is lower than those of bituminous coal. Combustion characteristics are different between single coal and blended coal. Therefore, finding an optimal coal blending ratio according to coal rank effects on tar-soot yields.

A Study of Evaluation for Optimum Content and Bond Strength Properties of Bituminous Materials applied for preventing Separation of Asphalt Pavement Layers (아스팔트 포장층 분리억제용 역청재료의 부착성능 및 최적함량 평가에 대한 연구)

  • Kim, Dowan;Lee, Sangyum;Mun, Sungho
    • International Journal of Highway Engineering
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    • v.18 no.6
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    • pp.137-143
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    • 2016
  • OBJECTIVES : Bituminous materials, such as tack coat, are utilized between pavement layers for improving the bond strength in pavement construction sites. The standards regarding the application of bituminous material are not clearly presented in the Korean construction guideline without RS(C)-4. Hence, the objective of this study is to determine the optimum content of bituminous materials by analyzing interlayer shear strength (ISS) from the direct shear tester, which was developed in this research. The shear strength of tack coat was defined with the sort of bituminous materials. METHODS : The mixtures for the shear test were made using marshall mix design. The specimens were vertically and horizontally separated for the direct shear test. The separated specimens were bonded using bituminous material. The objectives of the experiment are to determine the performance of bond and shear properties resulting from slippage, rutting, shovel, and corrugation of asphalt pavements. A machine based on the Louisiana interlayer shear strength tester (LISST) of NCHRP Report-712 was developed to determine the ISS. The applied types of tack coat were RS(C)-4, AP-3, QRS-4, and BD-coat with contents of $0.3{\ell}/m^2$, $0.45{\ell}/m^2$, $0.6{\ell}/m^2$, and $0.8{\ell}/m^2$, respectively. RESULTS : Table 2 gives the results of the direct shear test using the developed shear machine. The BD-coat type indicated the highest average ISS value compared to the others. Between the surface and binder course, optimum tack coat application rates for AP-3, RS(C)-4, QRS-4, and BD-Coat were $0.6{\ell}/m^2$, $0.3{\ell}/m^2$, $0.6{\ell}/m^2$, and $0.45{\ell}/m^2$, respectively. These optimum contents were determined using the ISS value. CONCLUSIONS : The ISS values of AP-3, RS(C)-4, and QRS-4 showed similar tendencies when ISS increased in the range $0.3{\sim}0.6{\ell}/m^2$, while ISS decreased when the applied rate exceeded $0.6{\ell}/m^2$. Similarly, the highest ISS value of the BD-coat was observed when the applied rate was $0.45{\ell}/m^2$. However, shear strength was similar to the maximum value of ISS when the tack-coat application rate of BD-Coat exceeded $0.45{\ell}/m^2$.

CARBON ISOTOPE ANALYSES OF INDIVIDUAL HYDROCARBON MOLECULES IN BITUMINOUS COAL, OIL SHALE, AND MURCHISON METEORITE

  • Kim, Kyoung-Sook;Yang, Jong-Mann
    • Journal of Astronomy and Space Sciences
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    • v.15 no.1
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    • pp.163-174
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    • 1998
  • To study the origin of organic matter in meteorite, terrestrial rocks which contain or-ganic compounds similar to the ones found in carbonaceous chondrites are studied and compared with Muchison meteorite. Hydrocarbon molecules were extracted by benzene and methanol from bituminous coal and oil shale and the extracts were partitioned into aliphatic, aromatic, and polar fractions by silica gel column chromatography. Carbon isotopic ratios in each fractions were analysed by GC-C-IRMS. Molec-ular compound identifications were carried by GC-MS Engine. Bituminous coal and oil shale show the organic compound composition similar to that of meteorite. Oil shale has a wide range of ${\delta}^{13}C,-20.1%_0~-54.4%_0$ compared to bituminous coal, $-25.2%_0~34.3%_0$. Delta values of several molecular compounds in two terrestrial samples are different. They show several distinct distributions in isotopic ratios compared to those of meteorite; Murchison meteorite has a range of ${\delta}^13C\;from\;-13%_0\;to\;+30%_0$. These results provide interpretation for the source and the formation condition of each rock, in particular alteration and migration processes of organic matter. Especially, they show an important clue whether some hydrocarbon molecules observed in meteorite are indigenous or not.

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An Experimental Study on Slagging/Fouling Characteristics for Various Coals in a 50kWth Pulverized Coal Combustion System (50kWth미분탄 연소 시스템에서 탄종별 슬래깅 및 파울링 특성 연구)

  • Kang, Kieseop;Lee, Jaewook;Chae, Taeyoung;Ryu, Changkook;Yang, Won
    • 한국연소학회:학술대회논문집
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    • 2012.11a
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    • pp.107-109
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    • 2012
  • In Korean coal power plants, rising coal prices have recently led to the rapid utilization of low lank coals such as sub-bituminous coal with low calorific values and low ash fusion temperatures. Using these coals beyond the design range has resulted in important issues including slagging and fouling, which cause negative effects in boiler performances and unstable operations. The purpose of this study is to observe slagging and fouling characteristics resulted from burning various ranks of pulverized coals. We have tested 3 different coals: FLAME(bituminous), KCH(sub-bituminous) and MOOLARBEN(bituminous)coals in the pilot system $50kW_{th}$ scale. A stainless steel tube with preheated air inside was installed in the downstream in order to simulate water wall. Collected ash on the probe and the slag inside the furnace near burner were analyzed by SEM (scanning electron microscopy) to verify the formation degree, surface features and color changes of the pasty ash particles. Induced coupled plasma and energy dispersive X-ray spectroscopy were also performed to figure out the chemical characteristics of collected samples. As a result, KCH was observed that more slag was developed inside the walls of the furnace and on the probe than the other two kinds of coals, as shown in the calculate slagging and fouling indices as well.

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The Use of Bituminous Subballast on Future High-Speed Lines in Spain: Structural Design and Economical Impact

  • Teixeira, P.F.;Ferreira, P.A.;Pita, A. Lopez;Casas, C.;Bachiller, A.
    • International Journal of Railway
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    • v.2 no.1
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    • pp.1-7
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    • 2009
  • The development of structural solutions for high-speed or very high-speed tracks that minimize total life cycle costs of the system is a key issue to improve the operational profitability of new investments. In opposition to conventional ballasted tracks, slab track solutions can be a cost-effective solution, but only in the cases where the benefits due to the increase in track availability and the reduction of track maintenance offsets its much higher construction costs. In the cases where such investment is not feasible, it is worth to evaluate possible structural improvements to ballasted track that allow reducing its maintenance needs without increasing too much its construction costs. This paper evaluates the design requirements and the impact of improving conventional high-speed ballasted tracks by using a bituminous subballast layer. It is divided into two main parts: first the design requirements of the structural solutions with bituminous subballast and its possible benefits on high-speed track deterioration, and secondly the evaluation of the economic impact, in terms of construction costs, of using this structural solution material in future Spanish high-speed lines.

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Combustion and Emission Characteristics of Utility Boiler burning Anthracite-Bituminous Coal Blends (발전용 보일러에서의 유, 무연탄 혼소시 연소 및 환경특성)

  • Park, Ho-Young;Kim, Young-Joo;Park, Hyun-Joo;Kim, Sung-Chul
    • Journal of Energy Engineering
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    • v.17 no.3
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    • pp.153-160
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    • 2008
  • The combustion behaviors of the blends of Korean anthracite, bituminous coal and their blends were studied with a thermogravimetric analyzer. Concerning the burning profiles of the anthracite-bituminous coal blends in TGA, it has been observed the independent burning of two coals without any interaction between two coals. With the blends of 50% anthracite with 50% bituminous coal in weight basis, the combustion tests in a utility boiler have been carried out for the analysis of the combustion and operational characteristics by increasing the power output from 134 MW to 197 MW. The stable combustion has been observed in a boiler. With the increase of power output, the exhaust gas temperature was exceeded the design value of $430^{\circ}C$, so the combustion air was taken from atmosphere instead of the boiler penthouse.

Combustion Characteristics and Activation Energy From Thermogravimetric Analysis of Bituminous and Anthracite Coal (TGA에 의한 유.무연탄의 연소특성과 활성화에너지 비교)

  • 김성철;최병선;이현동;홍성선
    • Journal of Energy Engineering
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    • v.5 no.2
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    • pp.170-175
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    • 1996
  • This study is to determined the activation energy from TGA experimental data for the bituminous and anthracite coals of three kinds which are being used in the domestic coal-fired power plants. TGA experimental data indicate that the weight loss temperature of bituminous coal is 200$^{\circ}C$ higher than that of anthracite coal. Activation energy of bituminous coal is in the range of 14∼20 Kcal/mole compared with 37∼55 Kcal/mole of anthracite coal. A reduction of particle size of coals results in the decrease of activation energy and activation energy has a good correlation with the weight loss percent of coal in the TGA experiment. Addition of CaCO$_3$ on anthracite coal caused to decrease the activation energy of 1∼23 Kcal/mole while activation energy of bituminous coal do not change significantly.

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Development of Emission Factors for Greenhouse Gas (CO2) from Bituminous coal Fired Power Plants (에너지사용시설의 온실가스 배출 특성 연구 -유연탄 화력발전소의 이산화탄소를 중심으로-)

  • Jeon Eui Chan;Sal Jae Whan;Lee Seong Ho;Jeong Jae Hak;Kim Ki Hyun;Bae Wi Sup
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.1
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    • pp.107-116
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    • 2006
  • The main purpose of this study is to develop the greenhouse gas emission factor for power plant using bituminous coal. The power plant is a major source of greenhouse gases among the sectors of fossil fuel combustion, thus information of its emission factors is very essential to the establishment of control strategies for the greenhouse gas emissions. These emission factors derived in this study were compared with those of U. S. EPA, AGO and CCL. The $CO_{2}$ concentrations in the flue gas were measured using NDIR analyser and the GC-FID with a methanizer. The amount of carbon (C) and hydrogen (H) in fuel was measured using an elemental analyzer. Calorific values of fuel were also measured using a calorimeter. Caloric value of bituminous coal used in the power plants were 5,957 (as received basis), 6,591 (air-dried basis) and 6,960 kcal/kg (dry basis). Our estimates of carbon emission factors were lower than those of IPCC. The CO2 emission factors for the power plants using bituminous coal were estimated to be 0.791 Mg/MWh (by carbon contents and caloric value of the fuel) and 0.771 Mg/MWh (by $CO_{2}$ concentration of the flue gas). The $CO_{2}$ emission factors estimated in this study were $3.4\sim 5.4\%$ and $4.4\sim 6.7\%$ lower than those of CCL (2003) and U. S. EPA (2002).

Analysis of Combustion Characteristics of Bituminous and Anthracite Coal in a Fluidized Bed Combustor (유동층연소로에서 유연탄과 무연탄의 연소특성 해석)

  • Jang, Hyun Tae;Park, Tae Sung;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.10 no.4
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    • pp.586-591
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    • 1999
  • Mixed-firing of a bituminous and an anthracite coal carried out in a batch fluidized bed combustor(0.109 m-I.D., 0.9 m-height). Effect of particle size an mixing fraction of anthracite and bituminous coal combustion characteristics were studied. The temperature profiles and pressure fluctuation properties were measured to interpret the combustion characteristics in a batch fluidized bed combustor. The used domestic anthracite coal has heating value of 2010 kcal/kg and the imported high-calorific bituminous coal has heating value of 6520 kcal/kg. The combustion characteristics in a batch fluidized bed combustor could be interpreted by using pressure fluctuation properties and temperature increasing rates. It was found that the optimum anthracite mixing percentage could be predicted analyzing the combustion rate and fluidization characteristics, The optimum mixing fraction was about 30 %. The different burning region of fluidized bed combustor was measured by temperature increasing rates.

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