• 한국생물공학회:학술대회논문집
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• 한국생물공학회 2005년도 생물공학의 동향(XVI)
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• pp.287-292
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• 2005

Hybrid시스템의 운전결과 황화수소의 removal efficiency는 황화수소의 inlet load가 $200g/m^{3}/h$에서 removal efficiency가 급격히 감소하여 약 60%의 수준을 유지하였다. 또한 톨루엔에 대한 removal efficiency는 거의 100%를 유지하다가 톨루엔의 inlet load가 $644g/m^{3}/h$로 증가할 때에는 약 60%로 감소하였다. 이와 같은 Hybrid시스템 운전결과로 부터 바이오필터만을 이용하여 황화수소와 톨루엔을 동시처리할 때보다 removal efficiency가 제고되었음이 관찰되었다.

• Journal of Microbiology and Biotechnology
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• 제15권6호
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• pp.1207-1213
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• 2005

In a search for bacteria capable of degrading styrene better than previously isolated strains, bacterium IS-3 was isolated from activated sludge and found to be most closely related to Pseudomonas sp. Styrene degradation by this strain was tested in liquid cultures and polyurethane-packed biofilters. In liquid cultures, the rate of styrene degradation by this bacterium increased from 24.93 to $76.53\;{\mu}mol\;g^{-1}\;DCW\;H^{-1}$ for an initial mass range from 8.7 to $34.8{\mu}mol$. The maximum styrene elimination capacity was 580-635 $g/m^{3}\cdot$h at a space velocity (SV) of 50-200/h. The critical elimination capacities guaranteeing $95\%$ removal of the input styrene were determined to be 635, 170, and 38 $g/m^{3}\cdot$h, respectively, at SVs of 50, 100, and 200/h. Kinetic analysis revealed that the maximum styrene elimination velocity ($V_{m}$) for this biofilter was 1,000 g/m$\cdot$h, and the saturation constant ($K_{m}$) was 454 ppmv. Together, these results suggest that a polyurethane biofilter containing Pseudomonas sp. IS-3 could have potential practical applications for the effective removal of styrene gas.

• 한국농공학회논문집
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• 제47권3호
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• pp.69-76
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• 2005

An Absorbent Biofilter System (ABS) combined with the recirculation process was investigated for the feasible application in additional removing of organics (BOD, SS) as well as nutrients (TN, TP) from small Community wastewater in Korea. Polyurethane biofilter media with high porosity and large surface area were /used for the aerobic system. A part of treated wastewater was recirculated into the anoxic septic tank to promote removal of nutrients. The concentrations of BOD and SS of treated wastewater satisfied the regulations for small on-site wastewater treatment facility (10 mg/L) during the overall experimental period. The effluent concentrations of BOD and SS were decreased with enhancement of removal efficiencies of 95.7 and $96.7\%$. The nitrogen and phosphorus removal efficiencies by the recirculation increased to $52.9\%\;and\;43.2\%$ in average during the overall experimental period, respectively. With the improvement, these values were increased as much as additional 42 and $18\%$ compared with those of non-recirculation. The rates of nitrification and denitrification were enhanced showing $65\~77\%\;and\;42\~92\%$, respectively. The described process modification is a low cost and effective method of enhancing nitrogen and phosphorus removal, especially on existing systems without changing major design components of a treatment facility.

• 상하수도학회지
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• 제8권1호
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• pp.44-52
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• 1994

The purpose of this experimental research was focused to improve the quality of the effluent and the yielded sludge when the papermill wastewater was treated by the indirect aerated submerged biofilter as a second treatment method of papermill wastewater. Changing the various experimental factors(Nutrient additions or not, HRT, F/M ratio, recirculation ratio, etc) with indirect aerated biofilter, the results obtained are as follows. 1. Because of the microbes concentration could be sustained to $9,000mg/l$ in submerged biofilter and then the volumetric organic loads could be increased to $2.7kg-BOD/m^3/day$(that of activated sludge is $0.8kg-BOD/m^3/day$), the reactor volume can be reduced to one third of the activated sludge treatment. 2. Because of the yield coefficient(Y) and the endogenous decay coefficient(kd) were revealed 0.4 and 0.07/d, the yielded sludge volume was reduced by for compared with that of the activated sludgg process. 3. The concentration of the sloughed sludge in the reactor was 2.62~4.01%, so the thickener could be omitted in the papermill wastewater sludge treatment process. 4. When the operating was conducted at HRT of 4hrs, the treatment efficiencies of BOD and COD were obtained 80% and 70%, Therefore operating time can be reduced to one half of the activated sludge treatment.

• 한국환경과학회지
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• 제13권1호
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• pp.47-53
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• 2004

A biofiltration system using activated carbon/polyurethane composite as solid support inoculated with Bacillus sp. was developed for treating a gaseous stream containing high concentrations of H$_2$S. The effects of operating condition such as the influent H$_2$S concentration and the empty bed contact time (EBCT) on the removal efficiency of H$_2$S were investigated. The biofilter showed the stable removal efficiencies of over 99 ％ under the EBCT range from 15 to 60 sec at the 300 ppmv of H$_2$S inlet concentration. When the inlet concentration of H$_2$S was increased, the removal efficiencies decreased, reaching 95 and 74％, at EBCTs of 10 and 7.5 sec, respectively. The maximum elimination capacity in the biofilter packed with activated carbon/polyurethane composite media was 157 g/m$^3$/hr.

• 상하수도학회지
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• 제25권5호
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• pp.741-750
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• 2011

A pilot-scale biofilter was constructed to discover degradation characteristics of the complex odor discharged from Ansan wastewater treatment plant. Candida tropicalis for volatile organic compounds, sulfur oxidizing bacteria(SOB) for hydrogen sulfide, and bacteria extracted from feces soil were immobilized on a polymer gel media. According to this study, the EBCT was varied from 36 sec to 18 sec. Toluene was removed as 80% along the variations, but it was recovered as 100% within 1 week. All benzene and xylene were removed during the operation while the efficiency of hydrogen sulfur was temporary decreased at 18 sec of EBCT, thereafter it was recovered to 100% within a week. The maximum elimination capacities of the benzene, toluene, xylene, and hydrogen sulfur were 6.6 g/$m^{3}$/hr, 31.7 g/$m^{3}$/hr, 7.8 g/$m^{3}$/hr, and 133.6 g/$m^{3}$/hr, respectively. There were merits on removal both organic and inorganic complex odor using the pilot-scale biofilter embedded with microorganisms immobilized on polymer gel media.

• Journal of Korean Society for Atmospheric Environment
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• 제18권E3호
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• pp.165-174
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• 2002

A dual -column biofilter system with two different composts was used to investigate the macro-kinetics of dim-ethyl disulfide (DMDS) degradation. The biofilter columns were filled with compost mixtures up to one meter, The gas How rate and DMDS concentration to the biofilters were varied to study their effect on the removal characteris-tics of DMDS. It was found that the biodegradation of DMDS was governed by zero-order reaction -limited macro-kinetics for inlet DMDS concentrations between 10 and 55 ppmv. The overall average zero-order kinetic coeffi-cient for DMDS removal by compost was 0.50 ($\pm$0.1) ppm/sec for both compost mixtures studied. Variations in individual kinetic coefficients were observed due to varying environmental conditions, such as pH and temperature. The kinetic coefficients determined are specific to the system discussed in this work. During high acidity conditions in the filter beds, methyl mercaptan (MM) was observed in the gas samples collected. Appearance of MM was pro-bably due to decreased microbial activity in the lower portions of the biofilter. Considering the neutral pH range required and the presence of methyl mercaptan, it is likely that the microorganisms present in the biofilters used in this research are similar to the T. thioparus (strain E6) species.

• Journal of Korean Society for Atmospheric Environment
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• 제18권E3호
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• pp.153-163
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• 2002

A laboratory- scale dual-column biofilter system was used to study the biofiltration of dimethyl disulfide (DMDS). The gas flow rate and DMDS concentration to the biofilter were varied to study their effect on the remov-al of dimethyl disulfide. Operating parameters such as pH, temperature, and water content were monitored during the biofilter operation and necessary precautions were taken to keep these parameters within the acceptable limits. It was observed that the removal efficiency of DMDS was optimal at neutral pH values. After five month op-eration, the neutralization of the filter beds with sodium carbonate became necessary for the optimum operation of the biofilters. The microbial population already present in the compost mixtures was found to be adequate in treat-ing DMDS. The compost mixtures were found to be similar in terms of biofiltration efficiency of DMDS. However, pressure drops observed in the first column compost mixture (compost/ peat mulch) was extremely high, making this compost economically not feasible. The second mixture (compost/bark) provided pressure drops within accept-able limits. A minimum residence time of 30 seconds at the optimal operating conditions appeared to be adequate for achieving high removal efficiencies (>90%).

• Korean Chemical Engineering Research
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• 제45권4호
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• pp.372-377
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• 2007

본 연구에서는 생물학적 공정을 사용하여 황화수소를 제거하는데 있어 망상구조의 폴리우레탄 담체의 바이오필터 충진물로서의 특성을 유입가스농도와 유입가스량의 두 변수를 대상으로 조사하였다. 실험결과 망상구조의 폴리우레탄 담체를 적용한 바이오필터의 황화수소 최대제거용량은 $488.3g-H_2S/m^3{\cdot}h$이었으며, 추정된 임계부하속도는 $330.1g-H_2S/m^3{\cdot}h$이었다. 본 연구의 결과 망상구조의 폴리우레탄 담체를 황화수소의 생물학적 처리를 위한 바이오필터의 담체로서 적용가능성을 확인하였다.

• 한국지반환경공학회 논문집
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• 제8권4호
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• pp.41-45
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• 2007

바이오필터의 운전에 있어 큰 표면적, 높은 한계 역압력을 가지고 있는 충진 담체의 선택은 매우 중요하다. 본 연구의 목적은 황산화 세균을 분리하고 분리된 황산화 세균과 바이오필터를 이용해 담체 종류에 따른 황화수소의 제거특성을 조사하는 것이며 연구결과는 다음과 같다. 1) 전남 화순의 폐탄광 폐수에서 Thiobacillus sp. IW.를 분리하였다. 2) 다양한 담체를 이용해 유입농도, 공간속도에 따른 바이오필터의 황화수소 제거특성 및 압력손실 변화 살펴본 결과 무기성 담체가 유기성 담체에 비해 우수한 성능을 나타내었다. 3) 무기성 담체 중에서는 섬유상, PU 담체가 다른 담체에 비해 우수한 성능을 나타내었다.