• Journal of the Optical Society of Korea
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• v.10 no.1
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• pp.1-10
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• 2006

Optical transparency and high diffraction efficiency are two essential factors for high performance of the photopolymer. Optical transparency mainly depends on the miscibility between polymer binder and photopolymerized polymer, while diffraction efficiency depends on the refractive index modulation between polymer binder and photopolymerized polymer. For most of organic materials, the large refractive index difference between two polymers accompanies large structural difference that leads to the poor miscibility and thus poor optical quality via light scattering. Therefore, it is difficult to design a high-performance photopolymer satisfying both requirements. In this work, first, we prepared a new phase-stable photopolymer (PMMA) with large refractive index modulation and investigated the optical properties. Our photopolymer is based on modified poly (methyl methacrylate) as a polymer binder, acryl amide as a photopolymerizable monomer, triethanolamine as initiator, and yellow eosin as a photosensitizer at 532 nm. Diffraction efficiency over 85% and optical transmittance over 90% were obtained for the photopolymer. Second, Organic-inorganic nanocomposite films were prepared by dispersing an aromatic methacrylic monomer and a photo- initiator in organic-inorganic hybrid sol-gel matrices. The film properties could be controlled by optimizing the content of an organically modified silica precursor (TSPEG) in the sol-gel matrices. The photopolymer film modified with the organic chain (TSPEG) showed high diffraction efficiency (> 90%) under an optimized condition. High diffraction efficiency could be ascribed to the fast diffusion and efficient polymerization of monomers under interference light to generate refractive index modulation. The TSPEG modified photopolymer film could be successfully used for holographic memory.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2013.11a
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• pp.194-195
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• 2013

Recently, it is the tendency that the CO₂ gas generated in the manufacturing process is increased every year in case of the portland cement used in the most of constructions and civil engineering field. The method that uses the mineral admixtures as the cement substitute material in order to be more serious and as much as it occupies 7% of the global CO₂ gas outlet amount such as 1 ton produces the cement and it ejects the CO₂ gas of 0.4~1.0 ton, etc conclude this problem is examined. Therefore, PVA fiber was mixed into the inorganic binder recycling the blast furnace slag, which is the industrial byproduct with the purpose studying the Geo polymer which doesn't use the cement at all silica fume, red mud, and etc. In addition, the water curing temperature was differentiated and the strength characteristic of the curing body tried to be examined.

• Proceedings of the Korea Concrete Institute Conference
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• 1998.04a
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• pp.69-74
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• 1998

Concrete has a many problems to apply high rise building of its low strength to weight and low ductility, compared to steel products. Therefore, it is necessary to make high strength concrete for applying to night rise building. In the experiment, the high strength concrete was made in variable of unit weight of binder, water to binder ratio(W/B), and sand to aggregate ratio(S/a) using batcher plant. As a result, it was possible to make high strength concrete using only materials for ordinary concrete without admixtures such like silica fume in batcher plant.

• Proceedings of the Korea Concrete Institute Conference
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• 1996.04a
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• pp.192-197
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• 1996

An experimental study was performed to examine the feasibility of using silicic wastes as construction materials for civil structures, and investigate its utility as a replacement for the favored nature resource to prevent the economic loss. In order to achieve this objective, mechnical properties of concrete containing silicic wastes is tested by investigating the strength development through parameters of water-binder ratios replacement 10 percent ratio with respect to curting conditions. The effect of stringth development is investigated for curing conditions when silicic wastes of 10 percent of cement-binder ratios is containde. Comparision on compressive strength of normal concrete and concrete containing silicic wastes at 28 day is conducted. The concrete with silicic wastes have larger compressive strength than of normal concrete by about 20 percent, when cured at 80 degree. The wastes concrete using silica sand shows increased strength, fracture toughness, elastic modulus and strain than the normal concrete, although the silicic wastes concrete could be able to satisfy the generally required strength for conventional concrete structures.

• Environmental Engineering Research
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• v.10 no.2
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• pp.54-61
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• 2005

Liquid-phase catalytic degradation of waste high-density polyethylene (HDPE) over ZSM-5 (powder type (PW)) and ZSM-5+binder (granule type (GR)) has been investigated with a stirred semi-batch operation at 400°C. Two ZSM-5 catalysts with a different crystal size were synthesized and also each ZSM-5 (25%) Catalyst was mixed with a same binder (kaolin: silica sol: alumina = 55%:10%:10%). The performance of prepared catalysts that has different physicochemical properties was discussed with the cumulative amount distribution, molecular weight distribution and also paraffin, olefin, naphthene and aromatic (PONA) distribution in liquid product. These liquid product quality and distributions were changed depending on the physicochemical properties of the catalyst. Moreover, the characteristic of ZSM-5 in the catalyst was strongly influenced on the activity and PONA distribution in liquid product.

• Computers and Concrete
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• v.10 no.1
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• pp.49-57
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• 2012

Nano-particle-reinforced cement mortars have been the basis of research in recent years and a significant growth is expected in the future. Therefore, optimization and quantification of the effect of processing parameters and mixture ingredients on the performance of cement mortars are quite important. In this work, the effects of nano-silica, water/binder ratio, sand/binder ratio and aging (curing) time on the compressive strength of cement mortars were modeled by means of artificial neural network (ANN). The developed model can be conveniently used as a rough estimate at the stage of mix design in order to produce high quality and economical cement mortars.

• Applied Chemistry for Engineering
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• v.28 no.3
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• pp.360-368
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• 2017

In order to investigate the durability of high performance polymer concrete composites, polymer concrete specimens were prepared using the ortho-type unsaturated polyester resin (UPR) and iso-type UPR as a polymer binder and the calcium carbonate and silica fine powder as a filler. The durability of polymer concrete specimens was measured by hot water resistance, chemical resistance, pore analysis and SEM observation. The compressive strength of the specimen using the iso-type UPR was higher than that of using the ortho-type UPR, and the compressive strength of the specimen using the silica fine powder was higher than that of using the calcium carbonate filler. From hot water resistance results, it was found that the specimen using the iso-type UPR was superior to that of using the ortho-type UPR and the specimen using the calcium carbonate filler was superior to that of using the silica fine powder. The compressive strength reduction rate was measured after the chemical resistance test and the sodium hydroxide solution showed the highest reduction rate, followed by sulfuric acid, hydrochloric acid and calcium chloride solutions. When using the alkaline solution of sodium hydroxide, the weight reduction rate of the specimen using calcium carbonate was lower than that of using silica fine powder, while for the acidic solutions of sulfuric acid and hydrochloric acid, the weight reduction rate of the specimen using the silica fine powder was lower than that of using calcium carbonate.

• Computers and Concrete
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• v.19 no.4
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• pp.357-363
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• 2017

This paper conveys the effects of fly ash and silica fume incorporated in concrete at various replacement ratios on the durability properties of concretes. It is quite well known that concrete durability is as much important as strength and permeability is the key to durability. Permeability is closely associated with the voids system of concrete. Concrete, with less and disconnected voids, is assumed to be impermeable. The void system in concrete is straightly related to the mix proportions, placing, compaction, and curing procedures of concrete. Reinforced concrete structures, particularly those of subjected to water, are at the risk of various harmful agents such as chlorides and sulfate since the ingress of such agents through concrete becomes easy and accelerates as the permeability of concrete increases. Eventually, both strength and durability of concrete reduce as the time moves on, in turn; the service life of the concrete structures shortens. Mineral additives have been proven to be very effective in reducing permeability. The tests performed to accomplish the aim of the study are the rapid chloride permeability test, pressurized water depth test, capillarity test and compressive strength test. The results derived from these tests indicated that the durability properties of concretes incorporated fly ash and silica fume have improved substantially compared to that of without mineral additives regardless of the binder content used. Overall, the improvement becomes more evident as the replacement ratio of fly ash and silica fume have increased. With regard to permeability, silica fume is found to be superior to fly ash. Moreover, at least a 30% fly ash replacement and/or a replacement ratio of 5% to 10% silica fume have been found to be highly beneficial as far as sustainability is concerned, particularly for concretes subjected to chloride bearing environments.

• Journal of the Korea institute for structural maintenance and inspection
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• v.15 no.1
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• pp.215-225
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• 2011

Metakaolin is a dehydroxylated form of the clay mineral kaolinite. Rocks that are rich in kaolinite are known as china clay or kaolin, traditionally used in the manufacture of porcelain. The particle size of metakaolin is smaller than cement particles, but not as fine as silica fume. This paper investigates the effect of the concrete containing metakaolin as a mineral admixture on the compressive strength and resistance properties to chloride ion penetration. In this study, the experiment was carried out to investigate and analyze the influence of replacement ratio of metakaolin and micro silica fume on the compressive strength and chlorine ion penetration resistance of concrete. All levels were water/binder ratio 30%, replacement ratio of metakaolin and silica fume were 0, 5, 10, 15, 20% respectively. The compressive strength of concrete using metakaolin tends to increase, as the replacement ratio increases but the chlorine ion penetration resistance was not so as lager as silica fume concrete. Therefore, the optimum mixing ratio of metakaoline to satisfy a properties of compressive strength and chlorine ion penetration resistance was was approximately10%.

• Computers and Concrete
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• v.19 no.6
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• pp.667-675
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• 2017

One of the main disadvantages of Ultra High Performance Concrete exists in the large suggested value of UHPC ingredients. The purpose of this study was to find the models mechanical properties which included a 7, 14 and 28-day compressive strength test, a 28-day splitting tensile and modulus of rupture test for Ultra High Performance Concrete, as well as, a study on the interaction and correlation of five variables that includes silica fume amount (SF), cement 42.5 amount, steel fiber amount, superplasticizer amount (SP), and w/c mechanical properties of UHPC. The response surface methodology was analyzed between the variables and responses. The relationships and mathematical models in terms of coded variables were established by ANOVA. The validity of models were checked by experimental values. The offered models are valid for mixes with the fraction proportion of fine aggregate as; 0.70-1.30 cement amount, 0.15-0.30 silica fume, 0.04-0.08 superplasticizer, 0.10-0.20 steel fiber, and 0.18-0.32 water binder ratio.