• Journal of the Korean Chemical Society
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• v.31 no.6
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• pp.481-485
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• 1987

Various partial miscibilities of binary liquid mixtures predicted by the extended Flory-Huggins lattice theory are shown in this article, and the mathematical conditions for each partial miscibility are obtained. And in terms of the theory it is shown that the unusual partial miscibility of water-2-butanol system can occur.

• Journal of the Korean Chemical Society
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• v.14 no.2
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• pp.193-199
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• 1970

Further validity of the significant structure theory has been tested by calculating the viscosities of binary mixtures-three pairs of $C_6H_6(1)+C_6H_{12}\;(2),\;CCI_4\;(1)+C_6H_6{2}and\l;CCI_4(1)+C_6H_{12}(2)$-and also by calculating the viscosities of n-$C_5H_{12}\;and\;n-C_6H_{14}$ in the pressure range of 1 bar to 4000 bars. The results are quite satisfactory for both cases and provide another evidence for the validity of the significan structure theory.

• Journal of Energy Engineering
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• v.25 no.4
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• pp.190-197
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• 2016

Flash point is the one of the important properties for the safe handling of inflammable liquid solution. In this paper, flash points of binary liquid solutions, water+1-propanol and water+2-propanol, were been measured by using Seta flash closed cup aparatus. Flash point was estimated using regression analysis method. Flash points were also estimated by the method based on Raoul's law and the method optimizing the binary parameters of van Laar equation. Experimental results were compared with the calculated results. The regression analysis method is able to estimate the flash point fairly well for water+1-propanol and water+2-propanol mixture.

• Journal of the Korean Society of Safety
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• v.32 no.6
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• pp.34-39
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• 2017

Vapor-liquid equilibrium calculation is required to properly design and operation of distillation process. The general calculation method is to use binary interaction parameter. Lower flash points of cyclohexanol+aniline and cyclohexanol+cyclohexanone were measured by using Seta-flash closed cup apparatus. The measured flash points were compared with those calculated by the method based on Raoult's law and the optimization method using Wilson equation. The absolute average errors(A.A.E.) of the results calculated by Raout's law are $0.25^{\circ}C$ and $1.07^{\circ}C$ for cyclohexanol+aniline and cyclohexanol+cyclohexanone, respectively. The absolute average errors of the results calculated by the optimization method are $0.22^{\circ}C$ and $0.65^{\circ}C$ for cyclohexanol+aniline and cyclohexanol+cyclohexanone, respectively. As can be seen from A.A.E., the calculated values based on the optimization method were found to be better than those based on the Raoult's law. The binary interaction parameters calculated by the optimization method are used to predict the dew points of cyclohexanol+aniline and cyclohexanol+cyclohexanone. The A.A.E. for these mixtures show that there is an acceptable agreement between experimental and calculated dew poins.

• Journal of the Korean Applied Science and Technology
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• v.17 no.2
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• pp.132-138
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• 2000

Excess enthalpies ($H^{E}$) were measured by isothermal flow calorimetry for the nonionic amphiphile 2-butoxyethanol/water mixtures at 10 different temperatures (48.5 to $70^{\circ}C$) around and above the lower consolute solution temperature, $T_{lc}$. $H^{E}$ exhibits U-shape for the binary mixtures, and is large and negative which reflects substantial interaction between two chemical species. When the commonly used, semi-empirical Redlich-Kister (RK) polynomials were fitted to the measured $H^{E}$, plots of $H^{E}$ vs. weight fraction provided more accurate fitting with fewer parameters than conventionally drawn $H^{E}$ vs. mole fraction plots. This was due to the enhanced symmetry of $H^{E}$ vs. weight fraction plots. Using the fitted Redlich-Kister polynomials and the Gibbs-Helmholtz relation, temperature dependence of the activity coefficients were found and compared to the values determined from vapor-liquid equilibria. The activity coefficients were in the range of one to three, indicating that the binary system deviates from ideality but not substantially. They slightly depended on temperature and the temperature effect was equivalent to 10 % change in the activity coefficients.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.22 no.4
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• pp.440-451
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• 1998

An experimental study has been conducted to investigate solidification of NH$_{4}$CI-H$_{2}$0 mixtures inside a vertical rectangular enclosure. Solidification process is visualized by the shadowgraph method. Emphasis is placed on the effect of solidification parameters such as the aspect ratio, cooling wall temperature and initial composition. The aspect ratio shows a dominant effect on the number and developing time of the double diffusive layers which reveals the relative strength of solutal convection to thermal convection. Similar flow pattern is observed when the concentration difference between interdendritic liquid and the pure liquid which drives solutal convection is the same regardless of the different cooling wall temperature and initial concentration.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.2
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• pp.906-918
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• 2012

In this study, we compared with results simulated by EOS(Equation of State) using Peng-Robinson model and GERG-2004 model for estimating vapor pressure, latent heat of vaporation, liquid density, and binary isotherm vapor-liquid equilibrium on pure components composing natural gases. We obtained the simulated results that while EOS using GERG-2004 model is more accurate than EOS using Peng-Robinson model for estimating liquid density, but rather it is less accurate for estimating binary isotherm vapor-liquid equilibrium. On the other hand, the use of Costald model in EOS using Peng-Robinson model for increasing more accuracy to calculate liquid density is almost same as EOS using GERG-2004 model within the error of 1 % compared with experimental data. Also, we confirmed that on the estimation of binary isotherm vapor-liquid equilibrium, EOS using GERG-2004 model is more accurate than EOS using Peng-Robinson model, but they are almost same.

• Macromolecular Research
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• v.12 no.2
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• pp.246-250
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• 2004

We have classified a number of aqueous ternary systems containing two different polymers into three types by focusing on the deviation of the Huggins constant k'from the additivity line. Systems of type I have negative deviations of k'; the repulsive interaction between the two different polymers dominates. In systems of type II, k' almost follows the additivity relation; the repulsive and attractive interactions between the two different polymers are balancing. Type III systems have positive deviations of k'; the attractive interactions are relatively dominant. This classification of systems is supported by the fact that the positive and negative deviations of k' from the additivity line also correspond to the sign of interaction parameter between polymer 2 and 3, Δb$\_$23/. Furthermore, we have verified the relatively high compatibility between dextran and poly(vinyl alcohol) by determining the binodal concentration of a liquid-liquid phase separation for a water/dextran/poly(vinyl alcohol) system, which is classified as type III. Thus, we found that the compositional dependence of k' closely relates to the compatibility of binary polymer mixtures in aqueous ternary systems.

• Clean Technology
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• v.25 no.2
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• pp.140-146
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• 2019

Flammable substances, such as organic solvents, are commonly used in laboratories and industrial processes. The flash point of flammable liquid mixtures is a very important parameter for characterizing the ignition and explosion hazards, and the flash points of mixtures of $C_2{\sim}C_3$ alcohols and 2,2,4-trimethylpentane were measured in the present study. The 2,2,4-trimethylpentane is an important component of gasoline and is frequently used in the petroleum industry as a solvent. Lower flash point data were measured for the binary systems {ethanol + 2,2,4-trimethylpentane}, {1-propanol + 2,2,4-trimethylpentane}, and {2-propanol + 2,2,4-trimethylpentane}. The flash point measurements were carried out according to the standard test method (ASTM D3278) using a Stanhope-Seta closed cup flash point tester. The measured flash points were compared with the predicted values calculated using Raoult's law and also following $G^E$ models: Wilson, Non-Random Two Liquid (NRTL) and UNIversal QUAsiChemical (UNIQUAC). These models were able to predict the experimental flash points for different compositions of {$C_2{\sim}C_3$ alcohols + 2,2,4-trimethylpentane} mixtures with minimal deviations. The average absolute deviation between the predicted and measured lower flash point was less than 1.28 K. A minimum flash point behaviour was observed in all of the systems as in the many observed cases for the hydrocarbon and alcohol mixtures.

• Journal of Mechanical Science and Technology
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• v.20 no.3
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• pp.399-408
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• 2006

Nucleate pool boiling heat transfer coefficient (HTCs) were measured with one nonazeotropic mixture of propane/isobutane and two azeotropic mixtures of HFC134a/isobutane and propane/HFC 134a. All data were taken at the liquid pool temperature of $7^{\circ}C$ on a horizontal plain tube of 19.0mm outside diameter with heat fluxes of $10\;kW/m^2\;to\;80kW/m^2$ with an interval of $10\;kW/m^2$ in the decreasing order of heat flux. The measurements were made through electrical heating by a cartridge heater. The nonazeotropic mixture of propane/isobutane showed a reduction of HTCs as much as 41% from the ideal values. The azeotropic mixtures of HFC134a/isobutane and propane/HFC134a showed a reduction of HTCs as much as 44% from the ideal values at compositions other than azeotropic compositions. At azeotropic compositions, however, the HTCs were even higher than the ideal values due to the increase in the vapor pressure. For all mixtures, the reduction in heat transfer was greater with larger gliding temperature difference. Stephan and Korner's and lung et al's correlations predicted the HTCs of mixtures with a mean deviation of 11%. The largest mean deviation occurred at the azeotropic compositions of HFC134a/isobutane and propane/HFC134a.