• Title/Summary/Keyword: behavior of pollutants

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Interaction of industrial effluents and bentonite: a comparative study of their physico-chemical and geotechnical characteristics

  • Murugaiyan, V.;Saravanane, R.;Sundararajan, T.
    • Geomechanics and Engineering
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    • v.1 no.4
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    • pp.291-306
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    • 2009
  • One-dimensional soil-column studies were carried out to understand the interaction of three industrial effluents namely amino acid ('highly acidic'), surfactant ('highly organic') and pharmaceutical ('organic and toxic') on the physicochemical behavior, index properties and shear strength of bentonite due to artificial contamination extending to nearly 300 days. Changes in inorganic and organic pollutants present in the effluents due to the interaction of the above effluents and soil were assessed to understand the physico-chemical behaviour. Batch and continuous modes of operation, 8 hrs and 16 hrs Hydraulic Retention Time [HRT] and 25%, 50% concentrations of effluents, were the parameters considered. Amino acid, surfactant and pharmaceutical effluents have shown a high variation in pH (7 to 8) after artificial contamination on bentonite that is their original characteristics of the above effluents have been completely reversed. Further, it is found that the shear strength of bentonite has reduced by about 20%, and with respect to liquid limit and plastic limit shows an increasing trend with time within the period of contamination.

Sorption behavior of slightly reduced, three-dimensionally macroporous graphene oxides for physical loading of oils and organic solvents

  • Park, Ho Seok;Kang, Sung Oong
    • Carbon letters
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    • v.18
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    • pp.24-29
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    • 2016
  • High pollutant-loading capacities (up to 319 times its own weight) are achieved by three-dimensional (3D) macroporous, slightly reduced graphene oxide (srGO) sorbents, which are prepared through ice-templating and consecutive thermal reduction. The reduction of the srGO is readily controlled by heating time under a mild condition (at 1 10−2 Torr and 200℃). The saturated sorption capacity of the hydrophilic srGO sorbent (thermally reduced for 1 h) could not be improved further even though the samples were reduced for 10 h to achieve the hydrophobic surface. The large meso- and macroporosity of the srGO sorbent, which is achieved by removing the residual water and the hydroxyl groups, is crucial for achieving the enhanced capacity. In particular, a systematic study on absorption parameters indicates that the open porosity of the 3D srGO sorbents significantly contributes to the physical loading of oils and organic solvents on the hydrophilic surface. Therefore, this study provides insight into the absorption behavior of highly macroporous graphene-based macrostructures and hence paves the way to development of promising next-generation sorbents for removal of oils and organic solvent pollutants.

The Concept of Microplastics and their Occurrence, Transport, Biological Effects, and Management Methods in the Ocean (미세플라스틱의 개념과 해양에서의 발생, 이동, 생물영향 및 관리대책)

  • Han, Sun-Kee
    • Journal of Environmental Health Sciences
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    • v.46 no.5
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    • pp.610-626
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    • 2020
  • Objectives: This study aims to investigate the concept of microplastics and their occurrence, transport, biological effects, and management methods in the ocean. Methods: I reviewed articles on microplastics in the ocean by using the Google Scholar database. Results: Plastic litter has been reported as a ubiquitous pollutant in the ocean due to the extensive consumption of plastics and the mismanagement of plastic wastes. Microplastics are generally defined as synthetic polymer particles <5 mm in size. Microplastics generated from the degradation of plastic litter are currently a serious global concern since they spread easily all over the ocean, transfer to different tissues inside contaminated animals, and even across different trophic levels inside the food web. An additional concern is the ability of microplastics to adsorb organic and inorganic pollutants and subsequently release them into the ocean. Thus, alternatives to reduce microplastics in the ocean are discussed. Conclusions: This paper summarizes the concept of microplastics and their behavior in the ocean and suggests management methods for microplastics in support of a cleaner ocean.

Perfluorinated Compounds; New Challenge and Problem (과불화 화합물 (PFCs); 새로운 도전과 과제)

  • Son, Hee-Jong;Yoo, Soo-Jeon;Roh, Jae-Soon
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.12
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    • pp.1151-1160
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    • 2009
  • Perfluorinated compounds (PFCs) have been recognized as emerging environmental pollutants and are widely distributed all over the world. These compounds are hardly degradable and cause bioaccumulation and biomagnification during present for a long time in the environment: thereby after adversely biota and human bodies. It is difficult to remove PFCs using conventional water/wastewater treatment because of resistant property to photodecomposition, biodegradation and chemical decomposition. Moreover, domestic literature data on the pollution of PFCs in rivers and lakes are limited. In this paper, species, sources and risk of PFCs as well as behavior properties in drinking water/wastewater and treatment processes are demonstrated to encourage the domestic concern about PFCs.

A Study on the Behavior Change of Zebrafish For Toxicity Evaluation of Residual Psychoactive Medication in Wastewater Treatment Plant Effluent (하수처리시설 방류수 내 잔류 향정신성 의약품의 독성평가를 위한 zebrafish의 행동성 변화 연구)

  • Yoon, Hyojik;Kim, Minjae;Kim, Jongrack;Kim, Sungpyo
    • Journal of Korean Society on Water Environment
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    • v.35 no.6
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    • pp.574-579
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    • 2019
  • As interest in health issues increases, it is imperative to ensure good water quality from wastewater treatment plant effluent to preserve environmental health. In particular, currently there is a lack of water ecosystem risk assessment on pharmaceutical substances remaining in effluent. In this study, antidepressant escitalopram (ESC), antiepileptic carbamazepine (CBZ) and lead, which impact the behavior of aquatic organisms, were used to test their impact on the potential behavior of zebrafish. Zebrafish have been widely used in toxicological assessment studies due to the ease of handlinggenerically and genetically. It was possible to observe changes in the growth of organisms through monitoring the embryos' cognitive and behavior assessment. In this study, the embryo lethal dose test showed that the lethal concentration of ESC and CBZ was at 10 ppb, which is below the water quality criterion (100 ppb), increased by 32.5 % and 40 %, respectively. In the cognitive test, it was found that the cognitive ability function decreased by 22 % and 17% for ESC(500 ppb) and CBZ(1,000 ppb) respectively relative to control. Based on these results, it is necessary to initiate efforts to remove these trace pollutants from sewage treatment facilities to protect the health of aquatic organisms.

Prediction on Safety Time of Water Intake at Paldang Reservior According to Scenarios of Water Pollution (팔당 유역 수질사고 시나리오에 따른 취수 안전시간 예측)

  • Baek, Kyong-Oh
    • Journal of the Korean Society of Safety
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    • v.27 no.5
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    • pp.135-140
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    • 2012
  • In this study, the behavior of pollutant was calculated at Paldang reservior according to several scenarios of the accidental water pollution by means of the numerical models for forecasting water quality. Also managemental plans for situation of the accidental water pollution happening at Paldang watershed were simulated. According to the simulating results, a plan of increase of discharge at Cheongpyeong dam reduced the peak concentration of pollutants, whereas extended the time for stopping water intake. Another plan, drop of water elevation at Paldang dam, decreased seriously the time for stopping water intake although there were a little effect to decrease the peak concentration. Thus it was concluded that appropriate combinations of the plans for the increase discharge and the dropping water elevation should be used to deal with the accidental water pollution at Paldang watershed.

HIGH ORDER IMPLICIT METHOD FOR ODES STIFF SYSTEMS

  • Vasilyeva, Tatiana;Vasilev, Eugeny
    • Journal of applied mathematics & informatics
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    • v.8 no.1
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    • pp.165-180
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    • 2001
  • This paper presents a new difference scheme for numerical solution of stiff system of ODE’s. The present study is mainly motivated to develop an absolutely stable numerical method with a high order of approximation. In this work a double implicit A-stable difference scheme with the sixth order of approximation is suggested. Another purpose of this study is to introduce automatic choice of the integration step size of the difference scheme which is derived from the proposed scheme and the one step scheme of the fourth order of approximation. The algorithm was tested by means of solving the Kreiss problem and a chemical kinetics problem. The behavior of the gas explosive mixture (H₂+ O₂) in a closed space with a mobile piston is considered in test problem 2. It is our conclusion that a hydrogen-operated engine will permit to decrease the emitted levels of hazardous atmospheric pollutants.

Preparatory Monitoring of Trace Chemicals Load into Nakdong River (낙동강 상수원에 부하되는 미량유해화학물질의 사전 모니터링)

  • Kang, Mee-A;Jo, Soo-Hyun;Jeong, Gyo-Cheol;Lee, Seung-Hwan;Kim, Sun-Il
    • The Journal of Engineering Geology
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    • v.16 no.4 s.50
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    • pp.351-357
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    • 2006
  • Recently there is increasing the flow of hazardous chemical substances caused by industrial waste waters into a main river. It is needed to make the high treatment in drinking water treatment plants for reducing a health risk. Therefore, the monitoring of trace hazardous chemical substances by the industrial waste water inflow is available increasing economical efficiency of river management as well as reduction of risk. In this study, the most important substance among numerical and quantitative trace hazardous chemicals is Hexachlorobutadiene in an effluent of industrial wastes. However all items of GroupII which was included with semiconductor, electricity/electron and metal assemble was not detected. It means that we must consider the characteristics and behavior of load pollutants to water resources to select monitoring items. That was called 'preparatory monitoring'. We can reduce an economical consumption as well as risks from these pollutants using the preparatory monitoring.

BAYQUAL Model for the Water Quality Simulation of a Bay Using Finite Element Method (유한요소법에 의한 하구의 수질모델 BAYQUAL)

  • 류병로;한양수
    • Journal of Environmental Science International
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    • v.8 no.3
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    • pp.355-361
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    • 1999
  • The aim of this study is to develop the water quality simulation model (BAYQUAL) that deal with the physical, chemical and biological aspects of fate/behavior of pollutants in the bay. BAYQUAL is a two dimensional, time-variable finite element water quality model based on the flow simulation model in bay(BAYFLOW). The algorithm is composed of a hydrodynamic module which solves the equations of motion and continuity, a pollutnat dispersion module which solves the dispersion-advection equation. The applicability and feasibility of the model are discussed by applications of the model to the Kwangyang bay of south coastal waters of Korea. Based on the field data, the BAYQUAL model was calibrated and verified. The results were in good agreement with measured value within relative error of 14% for COD, T-N, T-P. Numerical simulations of velocity components and tide amplitude(M2) were agreed closely with the actual data.

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Organic Pollutant Transport in Unsaturated Porous Media by Atmospheric Breathing Processes( I ) - Partition Coefficient -

  • Ja-Kong;Lim, Jae-Shin;Do, Nam-Young
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1996.11a
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    • pp.50-53
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    • 1996
  • This paper reports the experimental results for the determination of the overall partition coefficient of VOCs in unsaturated soil, A chromatographic method was used for the determination of gaseous partition coefficients to natural soil under various water content conditions. The equilibrium vapor pressure of water over saturated salt solution was used to fix the relative humidity of the air and control the water content of the soil systems. The transport behavior was studied for dichloromethane, trichloroethane and dichlorobenzene pollutants, with log octanol-water partition coefficients(log $K_{ow}$ ) which range from 1.25 to 3.39, or water to soil partitioning which varies by 135 times; water solubility constants which vary by 3 times; and vapor pressures which range from 1 to 362 torr. Water content of the soil had a pronounced effect on the effective partition coefficient(between gas and soil + water stationary phase) as well as on the effective dispersion coefficient.

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