• Title/Summary/Keyword: bed temperature

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Chlorination Kinetics of Synthetic Rutile with Cl2+CO Gas (Cl2+CO 혼합가스에 의한 합성루타일 염화반응의 속도론적 연구)

  • Hong, Sung-Min;Lee, So-Yeong;Sohn, Ho-Sang
    • Resources Recycling
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    • v.29 no.3
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    • pp.3-10
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    • 2020
  • The chlorination kinetics of synthetic rutile prepared by selective chlorination of ilmenite with Cl2 and CO gas mixture were studied in a fluidized bed. Th e effects of reaction temperature, reaction time, and the ratio of Cl2 and CO partial pressure ($p_{Cl_2}/p_{CO}$) on the conversion rate of TiCl4 were investigated. The conversion rate of TiC4 was low under the high $p_{Cl_2}/p_{CO}$ conditions. Moreover, it was considered that the partial pressure of CO gas was more effective than that of Cl2 gas when comparing the stoichiometric conversion rate and experimental results of high CO partial pressure. Considering the porous structure of particles, the rate controlling step of the chlorination of synthetic rutile was determined to be chemical reaction and the activation energy was calculated as 53.77 kJ/mol.

Combustion Characteristics and Design of Fiber Mat Catalytic Burners (매트 형태 연소촉매를 사용하는 촉매버너의 구조와 연소특성)

  • Song, Kwang-Sup;Jung, Nam-Jo;Kim, Hee-Yeon
    • Journal of Energy Engineering
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    • v.17 no.2
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    • pp.100-106
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    • 2008
  • Flameless fiber mat catalytic burners have been known as an effective heat source in industrial drying processes since heat obtained from combustion can be transferred to absorptive body by far-infrared radiation. In order to extend the application of fiber mat catalytic burner, novel fiber mat catalytic burners were manufactured and combustion characteristics of them were investigated. For diffusive catalytic burners, the efficiency of combustion was significantly affected by the installation direction and the temperature of catalytic bed perimeter influenced on the diffusion rate of oxygen which determined the combustion efficiency of catalytic burner. It was seen in premixed catalytic combustion that air content in premixed fuel gas was optimized at slightly higher than theoretical amount of air. Combustion heat released higher than 70% by radiant heat in premixed catalytic combustion likewise diffusive catalytic combustion.

Experimental Study on Effect on Prey Survival by Juvenile Fish Shelter (JFS) under Pressure by Piscivorous Fishes (포식압력 하에 치어 보호 구조물이 피식자의 생존율에 미치는 영향에 관한 실험적 연구)

  • Ahn, Chang Hyuk;Joo, Jin Chul;Lee, Saeromi;Ahn, Hosang;Park, Jae-Roh;Song, Ho Myeon
    • Journal of Korean Society on Water Environment
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    • v.29 no.6
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    • pp.746-753
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    • 2013
  • The aim of this study was to evaluate artificial fish shelter, which was known to increase prey survival and expand habitat space to improve species diversity and fish communities in a freshwater ecosystem. The experiment was performed at an outdoor test-bed for three months from 2011 by comparing the responses to adjustments in the volume of the artificial patch (juvenile fish shelter, JFS) in the control and experimental groups. Analysis of the environmental conditions over two periods (Period1 ~ 2) showed minor differences in the physichemical characteristics of water quality, phytoplankton, and zooplankton biomass, thus, allowing comparative analysis of feeding ecology. However, high water temperature conditions in Period1 ($25.6{\pm}2.0^{\circ}C$), affected the predation activity of the piscivorous fishes, Coreoperca herzi (C. herzi, size $89{\pm}4mm$). Survival rates of the prey fishes, Rhynchocypris oxycephalus (R. oxycephalus, size $29{\pm}1mm$), improved as the patch volume increased and were higher than those of the control group by 35.9 ~ 46.7%. Analysis showed that JFS reduced the chances of predator-prey encounter, and thereby minimized prey vulnerability.

Decomposition of Aromatic Organic Solvents with Catalytic Oxidation in SC-CO2 (초임계 이산화탄소내 촉매산화분해에 의한 방향족 유기용매의 분해특성)

  • Lee, Seung Bum;Hong, In Kwon
    • Applied Chemistry for Engineering
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    • v.9 no.5
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    • pp.624-628
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    • 1998
  • The aromatic organic solvents(BTX) were decomposed in the fixed bed reactor packed with a 0.5% $Pt/{\gamma}-Al_2O_3$ catalyst, then, supercritical carbon dioxide(SC-$CO_2$) was used as the reaction media. And the conversion was dependent on the inlet concentration of BTX and the molar density of SC-$CO_2$. The conversion of BTX was decreased with increasing of inlet concentration, and was increased with temperature and pressure. The maximum conversion of benzene was 98.5% at $300^{\circ}C$ and 204.1 atm, and that of toluene and xylene were 82.0 and 76.5%, respectively, at $350^{\circ}C$ and 204.1 atm. The intermediate products of partial oxidation were identified as benzaldehyde, phenol, benzenemethanol, and so on. The BTX can be effectively converted into harmless $CO_2$ and $H_2O$ at appropriate operating condition. Thus, the nontoxic recovery process was suggested as the removal method of BTX.

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Study of Hydration Reaction Characteristics of Inorganic Salts for Chemical Cold Storage and Method of Enhancement of Heat and Mass Transfer (화학축냉용 무기염들의 수화반응 및 열 및 물질전달 향상방안)

  • 김상욱;한종훈;황용준;이건홍
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1999.05a
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    • pp.185-191
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    • 1999
  • An air-conditioning system based on the chemical heat storage principle was considered. $H_2O$ was chosen as the reaction gas and the working fluid as well. Na$_2$S, CaCl$_2$, MnCl$_2$, BaCl$_2$, MgCl$_2$, Fe$_2$(SO$_4$)$_3$ and MnSO$_4$ were tested as the solid reactants by using Cahn pressure balance. Na$_2$S was superior to other salts in respect of high capability of absorption of water gas, 5 moles of $H_2O$ per unit mole of Na$_2$S, and adequate temperature of adsorption, $65^{\circ}C$ at 7torr, and of desorption, 13$0^{\circ}C$ at 76torr. Clausius-Clapeyron diagram of Na$_2$S was obtained via adsorption experiments at several vapor pressures of water gas. To enhance heat and mass transfer characteristics, usually below 1W/m K, of the reactor bed of general adsorption systems, expanded graphite block was adapted as the support of Na$_2$S salt. Expanded graphite blocks had thermal conductivity values of 20~80W/mK with respect to 100~400kg/㎥ of block bulk density. Permeability values of expanded graphite blocks were 10$^{-13}$ ~ 10$^{-14}$ $m^2$ with respect to 100~300kg/㎥ of block bulk density showing highly decreasing values of permeability, below 10$^{-l4}$$m^2$, in the range of above 150kg/㎥ of block bulk density.y.

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Comparison of Sleep Pattern, Factors of Sleep Disturbance and Sleep Enhancement Behaviors between Sleep Disturbance and Non-Sleep Disturbance Aged Patients (수면장애 노인 환자와 일반 노인 환자의 수면양상, 수면장애요인 및 수면증진행위)

  • Han, Suk-Jung;Lee, Eun-Young;Kim, Kyung-Mi;Park, Sun-Nam
    • Journal of Korean Academy of Fundamentals of Nursing
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    • v.14 no.1
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    • pp.62-71
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    • 2007
  • Purpose: This study was done to compare sleep patterns, factors of sleep disturbance and sleep enhancement behaviors between sleep disturbance and non-sleep disturbance elderly patients. Method: The participants were 117 patients over 65 years old who were hospitalized at 5 general hospitals in Seoul. There were 83 patients in the good sleeper group and 34 in the poor sleeper group. The survey questionnaires included questions on general characteristics, sleep patterns, sleep disturbing factors, and sleep enhancement behaviors of the patients. Results: For sleep patterns and environmental factors of sleep disturbance, the poor sleepers was significantly higher than that of the good sleepers. Significant differences between good sleepers and poor sleepers were also found on the following variables: Environmental factors of sleep disturbance -'Sound of other patient's or care-giver's', 'Discomfort of bed, linen, pillow and patient's gown', 'Light in the room', 'Emergency situations', 'Temperature of patients rooms too hot or too cold'. The significant physical factor of sleep disturbance was 'Hard to breath even without moving' and for sleep enhancement behaviors: 'Use of ear plugs or eye covers' Conclusion: Consequently it is necessary to develop positive and differentiated programs for sleep enhancement for the inactive and poor sleeper among the elderly patients.

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Calculation of Bed Change Depth using Temperature Sensors (온도 센서를 활용한 하상 변동고 산정)

  • Ahn, Myeonghui;Ji, Un
    • Proceedings of the Korea Water Resources Association Conference
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    • 2018.05a
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    • pp.274-274
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    • 2018
  • 최근 지표수-지하수 혼합대 흐름은 하천의 지형학적 및 생태학적으로 그 중요성이 인지되고 있으며, 이에 대한 연구가 활발하게 진행되고 있다. 혼합대 흐름 특성에 영향을 미치는 다양한 요소들 중 하상형태 변화는 혼합대 흐름의 체류시간 및 이동경로에 가장 큰 영향을 미친다. 따라서 하상형태는 혼합대 흐름 특성 분석을 위한 수리학적 변수로 활용 될 수 있다. 일반적으로 다양한 지형측량 장비를 활용하여 종횡단으로 하상형태를 확인할 수 있으며, 최근 온도 센서를 활용하여 장기간 하상형태를 모니터링 하는 방법이 제시된 바 있다. 온도 센서를 이용하여 하상변화를 예측하는 방법은 하상변화 측정의 지속성 및 효율성을 고려한 적절한 측정 방법 중 하나이다. 온도 센서를 활용한 하상변화 예측 방법은 하상에 온도 분포 센서를 설치한 후 하상 온도 및 수온을 일정한 간격으로 장기간 측정하여 기존에 제시된 공식을 통해 시간에 따른 하상 변동고를 산정하는 방식이다. 이러한 온도 분포 센싱을 활용한 계측방법은 하천에서 발생하는 침식 및 퇴적의 시간적 변화를 모니터링 하는데 매우 경제적이며 효과적인 것으로 알려져 있다. 따라서, 온도 분포 센서를 활용하여 시간에 따른 하상형태 변화를 계측하고, 측정 결과는 하상형태에 따른 혼합대 흐름체류시간 및 이동성 분석을 할 수 있는 기초자료로 활용할 수 있다. 이에 본 연구에서는 온도 센서를 활용하여 하상형태 예측 및 하상 변동고를 산정하기 위해 한국건설기술연구원 안동하천실험센터 급경사수로에 온도 센서를 설치하여 하상 온도와 수온을 약 72시간 측정하였고 유량을 공급하기 전과 후에 Total Station으로 지형 측량을 수행하였다. 온도센서로부터 측정된 결과로 하상 변동고를 산정하였고 이를 Total Station으로 측량한 결과와 비교분석하였다. 또한, 하상 온도와 수온의 시간에 따른 변화 패턴을 확인하였다.

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Optimal Cutting Conditions for the Production of Cudriania tricuspidata Bureau (꾸지뽕나무 묘목생산을 위한 최적 꺽꽂이 조건)

  • Sung, Gyoo Byung;Kim, Ki Young;Kim, Hyun Bok;Ji, Sang Duk
    • Journal of Sericultural and Entomological Science
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    • v.50 no.2
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    • pp.166-170
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    • 2012
  • Most of Cudriania tricuspidata Bureau saplings in Korea have been produced by crown division. But the production of Cudriania tricuspidata B. saplings by this method is very low in efficiency and in uniformity. Therefore, to develop Cudriania tricuspidata B. saplings production system by cutting method which is suitable for mass production, several conditions on rooting and growth of cuttings were investigated. The rooting ability of cuttings varied according to temperature on the bed, length, thickness of the hard wood cutting and rooting agent application. Of different concentration of rooting agent, the 5,000 ppm of 1-naphthalenacetic acid(NAA) and Indole butyric acid(IBA) were found to be the highest in rooting of hardwood cuttings; other concentration were in order as follows; 2,500, 1,000 and 10,000 ppm in concentration of rooting agents. The shading ratio of polyethylene film showed the highest rooting ratio of the softwood cuttings at 55%.

A Study on the Spatial and Environmental Characteristics of Forest Biology using GIS: A Case Study of Baekdudaegan area, Gyeongsangbuk-do and Chungcheongbuk-do (GIS를 이용한 산림 생물의 공간적·환경적 특성 분석 - 백두대간(경북·충북)을 대상으로 -)

  • Park, Jeong-Mook;Seo, Hwan-Seok;Lee, Jung-Soo
    • Journal of Forest and Environmental Science
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    • v.27 no.3
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    • pp.169-181
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    • 2011
  • The purpose of this study was to understand the geographical and environmental distribution of animals and plants in Baekdudaegan region using field survey and GIS data. Crucial factors were selected and analyzed to understand the distributional characteristics of wild animals (16 species in 5 orders) and rare endemic plants (20 species in 12 orders). These crucial factors include stand factor (forest type, DBH class, and crown density), soil factor (bed rock, soil texture, and organic matter), geographical factor (elevation, slope, aspect) and climatic factor (temperature, rain fall, humidity). Finally, ten crucial factors were selected by statistical analysis and categorized for analyzing geographical and environmental features. Three orders such as Rodentia, Carnivora, and Artiodactula in wild animal showed the similar habitat characteristics with the small diameter and the elevation range from 801 to 1,000m. The Hydropotes inermis of Artiodactyla and Rattus norvegicus of Rodentia were different in the type of orders, but they had the similar habitat characteristics with the coniferous forest and loam. On the other hand, four orders such as Tubiflorales, Liliales, Ericales, and Rhamnales in the rare and endemic plants were showed high occurrence rate in the organic matter between 4 and 6%. The Rodgersia podophylla of Rosales and Gastrodia elata Blume of Microspermae were different in the type of orders, but they had the similar habitat characteristics with the stand factor and soil factor.

Characterisation and Co-pyrolytic Degradation of the Sawdust and Waste Tyre Blends to Study the Effect of Temperature on the Yield of the Products

  • Shazali, Erna Rashidah Hj;Morni, Nurul Afiqah Haji;Bakar, Muhammad Saifullah Abu;Ahmed, Ashfaq;Azad, Abul K;Phusunti, Neeranuch;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.32 no.2
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    • pp.205-213
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    • 2021
  • The present study aimed to determine the effect of co-pyrolysis of sawdust biomass and scrap tyre waste employing different blending ratios of sawdust to waste tyre such as 100:0, 75:25, 50:50, 25:75, and 0:100. The thermochemical characterization of feedstocks was carried out by employing the proximate, ultimate analysis, and thermogravimetric (TGA) analyses, calorific values, and scanning electron microscope coupled with energy dispersive x-ray analysis (SEM-EDX) to select the blending ratio having better bioenergy potential amongst the studied ratios. The blending ratio of 25:75 (sawdust to waste tyre) was selected for the co-pyrolysis study in a fixed-bed pyrolysis reactor system based on its solid biofuels properties such as heating value (30.18 MJ/kg), and carbon (71.81 wt%) and volatile matter (63.82 wt%) contents. The pyrolysis temperatures were varied as 500, 600 and 700 ℃ while the other parameters such as heating rate and nitrogen flowrate were maintained at 30 ℃/min and 0.5 L/min respectively. The bio-oil yields as 31.9, 47.1 and 61.2 wt%, bio-char yields as 34.5, 34.2 and 31.4 wt% and gaseous product yields as 33.6, 18.60 and 7.3 wt% at the pyrolysis temperatures of 500, 600 and 700 ℃ respectively were obtained. The blends of sawdust and waste tyres showed the improved energy characteristics which could provide the solution for the beneficial management of sawdust and scrape tyre wastes via co-pyrolysis processing.