• Title/Summary/Keyword: barrier performance

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Analysis of Thermal Oxide Behavior with Isothermal Degradation of TBC Systems Applied to Single Crystal Superalloy (단결정 초내열합금에 적용된 열차폐코팅의 등온열화에 따른 산화물 거동분석)

  • Kim, K.;Wee, S.;Choi, J.;Kim, D.;Song, H.;Lee, J.;Seok, C.S.;Chung, E.S.;Kwon, S.H.
    • Journal of the Korean Society of Safety
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    • v.34 no.4
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    • pp.1-5
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    • 2019
  • In the field of combined cycle power generation, thermal barrier coating(TBC) protects the super-heat-resistant alloy, which forms the core component of the gas turbine, from high temperature exposure. As the turbine inlet temperature(TIT) increases, TBC is more important and durability performance is also important when considering maintenance cost and safety. Therefore, studies have been made on the fabrication method of TBC and super-heat-resistant alloy in order to improve the performance of the TBC. In recent years, due to excellent properties such as high temperature creep resistance and high temperature strength, turbine blade material have been replaced by a single crystal superalloy, however there is a lack of research on TBC applied to single crystal superalloy. In this study, to understand the isothermal degradation performance of the TBC applied to the single crystal superalloy, isothermal exposure test was conducted at various temperature to derive the delamination life. The growth curve of thermally grown oxide(TGO) layer was predicted to evaluate the isothermal degradation performance. Also, microstructural analysis was performed by scanning electron microscope(SEM) and energy dispersive X-ray spectroscopy (EDS) to determine the effect of mixed oxide formation on the delamination life.

Vehicle Collision Simulation for Roadblocks in Nuclear Power Plants Using LS-DYNA (LS-DYNA를 이용한 원자력발전소의 로드블록에 대한 차량 충돌 시뮬레이션)

  • SeungGyu Lee;Dongwook Kim;Phill-Seung Lee
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.36 no.2
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    • pp.113-120
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    • 2023
  • This paper introduces a simulation method for the collision between roadblocks and vehicles using LS-DYNA. The need to evaluate the performance of anti-ram barriers to prepare for vehicle impact has increased since vehicle impact threats have been included as a design criterion for nuclear power plants. Anti-ram barriers are typically certified for their performance through collision experiments. However, because Koreas has no performance testing facilities for anti-ram barriers, their performance can only be verified through simulations. LS-DYNA is a specialized program for collision simulation. Various organizations, including NCAC, distributes numerical models that have been validated for their accuracy with collision tests. In this study, we constructed a finite element model of the most critical vehicle barrier module and simulated collision between roadblocks and vehicles. The calculated results were verified by applying the validation criteria for vehicle safety facility collision simulations of NCHRP 179.

Geological Factor Analysis for Evaluating the Long-term Safety Performance of Natural Barriers in Deep Geological Repository System of High-level Radioactive Waste (지질학적 심지층 처분지 내 천연방벽의 고준위 방사성 폐기물 장기 처분 안전성 평가를 위한 지질학적 인자 분석)

  • Hyeongmok Lee;Jiho Jeong;Jaesung Park;Subi Lee;Suwan So;Jina Jeong
    • Economic and Environmental Geology
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    • v.56 no.5
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    • pp.533-545
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    • 2023
  • In this study, an investigation was conducted on the features, events, and processes (FEP) that could impact the long-term safety of the natural barriers constituting high-level radioactive waste geological repositories. The FEP list was developed utilizing the IFEP list 3.0 provided by the Nuclear Energy Agency (NEA) as foundational data, supplemented by geological investigations and research findings from leading countries in this field. A total of 49 FEPs related to the performance of the natural barrier were identified. For each FEP, detailed definitions, classifications, impacts on long-term safety, significance in domestic conditions, and feasibility of quantification were provided. Moreover, based on the compiled FEP list, three scenarios that could affect the long-term safety of the disposal facility were developed. Geological factors affecting the performance of the natural barrier in each scenario were selected and their relationships were visualized. The constructed FEP list and the visualization of interrelated factors in various scenarios are anticipated to provide essential information for selecting and organizing factors that must be considered in the development of mathematical models for quantitatively evaluating the long-term safety of deep geological repositories. In addition, these findings could be effectively utilized in establishing criteria related to the key performance of natural barriers for the confirmation of repository sites.

Characteristics and Physical Property of Tungsten(W) Related Diffusion Barrier Added Impurities (불순물을 주입한 텅스텐(W) 박막의 확산방지 특성과 박막의 물성 특성연구)

  • Kim, Soo-In;Lee, Chang-Woo
    • Journal of the Korean Vacuum Society
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    • v.17 no.6
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    • pp.518-522
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    • 2008
  • The miniaturization of device size and multilevel interlayers have been developed by ULSI circuit devices. These submicron processes cause serious problems in conventional metallization due to the solubility of silicon and metal at the interface, such as an increasing contact resistance in the contact hole and interdiffusion between metal and silicon. Therefore it is necessary to implement a barrier layer between Si and metal. Thus, the size of multilevel interconnection of ULSI devices is critical metallization schemes, and it is necessary reduce the RC time delay for device speed performance. So it is tendency to study the Cu metallization for interconnect of semiconductor processes. However, at the submicron process the interaction between Si and Cu is so strong and detrimental to the electrical performance of Si even at temperatures below $200^{\circ}C$. Thus, we suggest the tungsten-carbon-nitrogen (W-C-N) thin film for Cu diffusion barrier characterized by nano scale indentation system. Nano-indentation system was proposed as an in-situ and nanometer-order local stress analysis technique.

Operational Properties and Microbial Inactivation Performance of Dielectric Barrier Discharge Plasma Treatment System (유전체장벽방전 플라즈마 장치의 조작특성과 살균력)

  • Mok, Chulkyoon;Lee, Taehoon
    • Food Engineering Progress
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    • v.15 no.4
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    • pp.398-403
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    • 2011
  • A dielectric barrier discharge plasma (DBDP) treatment system was fabricated and the optimum operating conditions for the plasma generation were determined in order to explore the potential of cold plasma as a non-thermal proessing technology. The microbial inactivation performance of the system was also evaluated against Staphyloocus aureus. The system consisted of power supply, transformer, electrode assembly and sample treatment plate. The input power was 220 V single phase AC and amplified to 10.0-50.0 kV on a transformer. A pulsed sine wave of frequency 10.0-50.0 kHz was introduced to the electrode embedded in ceramic as a dielectric barrier material in order to generate plasma at atmospheric pressure. Higher currents and consequently greater power were required for the plasma generation as the frequencies increased. A homogeneous and stable plasma was generated at currents of 1.0-2.0, and frequencies of 32.0-35.3 kHz. The optimum electrode-gaps for the plasma generation were 1.85 mm without loaded samples. More power was consumed as the electrode-gaps increased. The practically optimum electrode- gap was, however, 2.65 mm when samples were treated on slide-glasses for microbial inactivation. The maximum temperature increase after 10 min treatment was less than 20$^{\circ}C$, indicating no microbial inactivation effect by heat and thereby insuring a non-thermal method. The DBDP inactivation effect against Staphyloocus aureus increased linearly with treatment time up to 5 min, but plateaued afterward. More than 5 log reduction was achieved by 10 min treatment at 1.25 A.

New Approaches for Overcoming Current Issues of Plasma Sputtering Process During Organic-electronics Device Fabrication: Plasma Damage Free and Room Temperature Process for High Quality Metal Oxide Thin Film

  • Hong, Mun-Pyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.100-101
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    • 2012
  • The plasma damage free and room temperature processedthin film deposition technology is essential for realization of various next generation organic microelectronic devices such as flexible AMOLED display, flexible OLED lighting, and organic photovoltaic cells because characteristics of fragile organic materials in the plasma process and low glass transition temperatures (Tg) of polymer substrate. In case of directly deposition of metal oxide thin films (including transparent conductive oxide (TCO) and amorphous oxide semiconductor (AOS)) on the organic layers, plasma damages against to the organic materials is fatal. This damage is believed to be originated mainly from high energy energetic particles during the sputtering process such as negative oxygen ions, reflected neutrals by reflection of plasma background gas at the target surface, sputtered atoms, bulk plasma ions, and secondary electrons. To solve this problem, we developed the NBAS (Neutral Beam Assisted Sputtering) process as a plasma damage free and room temperature processed sputtering technology. As a result, electro-optical properties of NBAS processed ITO thin film showed resistivity of $4.0{\times}10^{-4}{\Omega}{\cdot}m$ and high transmittance (>90% at 550 nm) with nano- crystalline structure at room temperature process. Furthermore, in the experiment result of directly deposition of TCO top anode on the inverted structure OLED cell, it is verified that NBAS TCO deposition process does not damages to the underlying organic layers. In case of deposition of transparent conductive oxide (TCO) thin film on the plastic polymer substrate, the room temperature processed sputtering coating of high quality TCO thin film is required. During the sputtering process with higher density plasma, the energetic particles contribute self supplying of activation & crystallization energy without any additional heating and post-annealing and forminga high quality TCO thin film. However, negative oxygen ions which generated from sputteringtarget surface by electron attachment are accelerated to high energy by induced cathode self-bias. Thus the high energy negative oxygen ions can lead to critical physical bombardment damages to forming oxide thin film and this effect does not recover in room temperature process without post thermal annealing. To salve the inherent limitation of plasma sputtering, we have been developed the Magnetic Field Shielded Sputtering (MFSS) process as the high quality oxide thin film deposition process at room temperature. The MFSS process is effectively eliminate or suppress the negative oxygen ions bombardment damage by the plasma limiter which composed permanent magnet array. As a result, electro-optical properties of MFSS processed ITO thin film (resistivity $3.9{\times}10^{-4}{\Omega}{\cdot}cm$, transmittance 95% at 550 nm) have approachedthose of a high temperature DC magnetron sputtering (DMS) ITO thin film were. Also, AOS (a-IGZO) TFTs fabricated by MFSS process without higher temperature post annealing showed very comparable electrical performance with those by DMS process with $400^{\circ}C$ post annealing. They are important to note that the bombardment of a negative oxygen ion which is accelerated by dc self-bias during rf sputtering could degrade the electrical performance of ITO electrodes and a-IGZO TFTs. Finally, we found that reduction of damage from the high energy negative oxygen ions bombardment drives improvement of crystalline structure in the ITO thin film and suppression of the sub-gab states in a-IGZO semiconductor thin film. For realization of organic flexible electronic devices based on plastic substrates, gas barrier coatings are required to prevent the permeation of water and oxygen because organic materials are highly susceptible to water and oxygen. In particular, high efficiency flexible AMOLEDs needs an extremely low water vapor transition rate (WVTR) of $1{\times}10^{-6}gm^{-2}day^{-1}$. The key factor in high quality inorganic gas barrier formation for achieving the very low WVTR required (under ${\sim}10^{-6}gm^{-2}day^{-1}$) is the suppression of nano-sized defect sites and gas diffusion pathways among the grain boundaries. For formation of high quality single inorganic gas barrier layer, we developed high density nano-structured Al2O3 single gas barrier layer usinga NBAS process. The NBAS process can continuously change crystalline structures from an amorphous phase to a nano- crystalline phase with various grain sizes in a single inorganic thin film. As a result, the water vapor transmission rates (WVTR) of the NBAS processed $Al_2O_3$ gas barrier film have improved order of magnitude compared with that of conventional $Al_2O_3$ layers made by the RF magnetron sputteringprocess under the same sputtering conditions; the WVTR of the NBAS processed $Al_2O_3$ gas barrier film was about $5{\times}10^{-6}g/m^2/day$ by just single layer.

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A Study on Copper hydroxide affecting the Curing and the Corrosion resistance of Electrocoating (수산화구리가 전착도막의 경화성과 내식성에 미치는 영향)

  • Yang, Wonseog;Hwang, Woonsuk
    • Corrosion Science and Technology
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    • v.12 no.5
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    • pp.253-258
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    • 2013
  • Effects of copper hydroxide(II) on the curing and the corrosion resistance of electrocoating were investigated by MEK rubbing test, electrochemical impedance spectroscopy (EIS) and Thermo-gravimetric analysis (TGA). Curing performance of electrocoating was lowered with increasing the content of copper hydroxide(II) as evidenced by the MEK rub performance which decreased with increasing the content of copper hydroxide(II). This indicates copper hydroxide(II) affected the blocked isocyanate reaction in the coatings, by the decomposition of copper hydroxide(II) to CuO and $H_2O$ during reaction of isocyanate with nuclephiles. Corrosion resistance of coatings also decreased with the content of copper hydroxide. This reflects the higher barrier property in coatings with higher curing performance.

Assessment of Three-Phase Actuated Signal Operation at Diamond Interchanges (다이아몬드 인터체인지의 3 현시 신호운영 평가)

  • 이상수
    • Proceedings of the KOR-KST Conference
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    • 2002.02a
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    • pp.143-159
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    • 2002
  • The performance of two single-barrier three-phase actuated control systems at diamond interchanges was evaluated for various traffic conditions. To emulate the actuated signal control, hardware-in-the-loop system combined with CORSIM simulation program was used. Two performance measures, average delay and total stops, were used for the evaluation process. Results showed that the two three-phase systems gave similar performance in terms of average delay, but not stops. The delay performance of each phasing system was generally dependent on the traffic pattern and ramp spacing. The total stops decreased as the spacing increased, and it was the most sensitive variable that can differentiate between the two three-phase systems. It was also shown that the hardware-in-the-loop control could provide a good method to overcome the limitations of current simulation technology.

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Na-Ion Anode Based on Na(Li,Ti)O2 System: Effects of Mg Addition

  • Kim, Soo Hwa;Bae, Dong-Sik;Kim, Chang-Sam;Lee, June Gunn
    • Journal of the Korean Ceramic Society
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    • v.53 no.3
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    • pp.282-287
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    • 2016
  • This study involves enhancing the performance of the $Na(Li,Ti)O_2$ system as an Na-ion battery anode with the addition of Mg, which partially replaces Li ions. We perform both computational and experimental approaches to achieve a higher reversible capacity and a faster transport of Na ions for the devised system. Computational results indicate that the $Na(Li,Mg,Ti)O_2$ system can provide a lower-barrier path for Na-ion diffusion than can a system without the addition of Mg. Experimentally, we synthesize various $Na_z(Li_y,Mg_x,Ti)O_2$ systems and evaluate their electrochemical characteristics. In agreement with the theoretical study, Mg addition to such systems improves general cell performance. For example, the prepared $Na_{0.646}(Li_{0.207}Mg_{0.013}Ti_{0.78})O_2$ system displays an increase in reversible capacity of 8.5% and in rate performance of 13.5%, compared to those characteristics of a system without the addition of Mg. Computational results indicate that these improvements can be attributed to the slight widening of the Na-$O_6$ layer in the presence of Mg in the $(Li,Ti)O_6$ layer.

Health-Promotion Behavior and its correlates of Individuals Seeking Comprehensive Health Check-ups (종합건강 피검진자의 건강증진 행위와 관련요인)

  • Lee, Jin-Hee;Suh, Soon-Rim;Park, Chai-Soon
    • Women's Health Nursing
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    • v.5 no.3
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    • pp.327-336
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    • 1999
  • The purpose of this study was to identify the health promotion behavior and its related factors of persons who wanted a comprehensive health check-up in order to provide a basis for health education to promote health enhancing behavior. Study variables were induced from Pender's Health Promotion Model. The subjects were 160 persons who had a check-up at the health promotion center in a university hospital in Tae-Gu, between September 8 and 22, 1998. The following instruments were used in the study : Lee Tae Wha's Health Promoting Life-style Profile, Park Chai soon's Self-efficacy Instrument and Moon Jeong Soon's Perceived Benefit and Barrier Instrument. Data was collected by self-reporting questionnaire. Analysis of the data was done by SAS program, t-test, ANOVA and Pearson-Correlation Coefficient. The results of this study were as follows. 1. The average score for the health-promotion behavior was 104.64. In the subcategories, self-actualization showed the highest degree of performance and physical exercise showed the lowest degree of performance. 2. In the relation of general characteristics of subjects to the level of health-promoting behavior, the male, the married, the group with several symptoms showed a high level of health-promoting behavior. 3. The relationship between the degree of performance in health-promotion behavior and its correlates were as follows: Self-efficacy was positively correlated to health promotion behavior, while the perceived barrier was correlated negatively. But the perceived benefit did not show a significant correlation with health promotion behavior. Results suggest that the development of programs with strategies to strengthen doing physical exercise and concerning health, increase self-efficacy and exclude the barriers to health promotion is recommended to individuals seeking a comprehensive health check-up.

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