• Bulletin of the Korean Chemical Society
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• v.16 no.3
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• pp.217-221
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• 1995

Axial coordination of anions or water to the square-planar nickel(Ⅱ) complexes of the hexaaza macrocyclic ligands 1, 2, and 3, which contain two extra uncoordinated tertiary nitrogens, have been investigated in aqueous solutions containing HX (X=Cl-, Br-, NO3-, or ClO4-) and/or NaX. The nickel(Ⅱ) complexes exist in the acidic solutions as equilibrium mixtures of the square-planar [Ni(L)]2+ (L=1, 2, and 3) and octahedral species [Ni(H2L)X2]2+ (H2L=diprotonated form of L). Some octahedral complexes have been isolated and characterized. The solution behaviors of the complexes indicate that the formation of the octahedral complexes are significantly promoted by the protonation of the uncoordinated tertiary amines. The proportion of the octahedral complexes depends on the type of acid, and increases in the order of HBr < HNO3 < HCl.

• Tribology and Lubricants
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• v.21 no.1
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• pp.8-15
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• 2005

In this study a general Galerkin FE lubrication analysis method is utilized to analyze the complex lubrication performance of a spiral groove seal, which is being designed and developed for a high-speed flying object application operating at a high-speed of over 50,000 rpm. As at the equilibrium seal clearance the axial stiffness of the seal is predicted to have almost such a constant high value of $1.04\times10^8\;N/m$ regardless of a rotating speed, the seal is expected to maintain a stable thickness of lubrication film under a certain external excitation acting. Also, as even at an ultra high-speed of 80,000 rpm the axial damping of the seal is shown to have a rotatively high value of 5,775 N-s/m, the dynamic stability of the seal system at the axial degree of freedom is assured well enough.

• Structural Engineering and Mechanics
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• v.57 no.4
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• pp.733-762
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• 2016

Based on a reduced displacement field, a layer-wise (LW) formulation is developed for analysis of thick shell panels which is subjected to axial tension. Employing the principle of minimum total potential energy, the local governing equations of thick panel which is subjected to axial extension are obtained. An analytical method is developed for solution of the governing equations for various edge conditions. The governing equations are solved for free and simply supported edge conditions. The interlaminar stresses in the panel are investigated by means of Hooke's law and also by means of integration of the equilibrium equations of elasticity. Dependency of the result upon the number of numerical layers in the layerwise theory (LWT) is studied. The accuracy of the numerical results is validated by comparison with the results of the finite element method and with other available results in the open literature and good agreement is seen between the results. Numerical results are then presented for the distribution of interlaminar normal and shear stresses within the symmetric and un-symmetric cross-ply thick panels with free and simply supported boundaries. The effects of the geometrical parameters such as radius to thickness and width to thickness ratio are investigated on the distribution of the interlaminar stresses in thick panels.

• Steel and Composite Structures
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• v.17 no.3
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• pp.287-303
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• 2014

8 steel reinforced concrete (SRC) columns with the encased steel ratio of 13.12% and 15.04% respectively were tested under the test axial load ratio of 0.33-0.80 and the low-frequency cyclic lateral loading. The cross sectional area of composite columns was $500mm{\times}500mm$. The mechanical properties, failure modes and deformabilities were studied. All the specimens produced flexure failure subject to combined axial force, bending moment and shear. Force-displacement hysteretic curves, strain curves of encased steels and rebars were obtained. The interaction behavior of encased steel and concrete were verified. The hysteretic curves of columns were plump in shapes. Hysteresis loops were almost coincident under the same levels of lateral loading, and bearing capacities did not change much, which indicated that the columns had good energy-dissipation performance and seismic capacity. Based on the equilibrium equation, the suggested practical calculation method could accurately predict the flexural strength of SRC columns with cross-shaped section encased steel. The obtained M-N curves of SRC columns can be used as references for further studies.

• Steel and Composite Structures
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• v.20 no.3
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• pp.571-597
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• 2016

A new unified design formula for calculating the composite compressive strength of the axially loaded circular concrete filled double steel tubular (CFDST) short and slender columns is presented in this paper. The formula is obtained from the analytic solution by using the limit equilibrium theory, the cylinder theory and the "Unified theory" under axial compression. Furthermore, the stability factor of CFDST slender columns is derived on the basis of the Perry-Robertson formula. This paper also reports the results of experiments and finite element analysis carried out on concrete filled double steel tubular columns, where the tested specimens include short and slender columns with different steel ratio and yield strength of inner tube; a new constitutive model for the concrete confined by both the outer and inner steel tube is proposed and incorporated in the finite element model developed. The comparisons among the finite element results, experimental results, and theoretical predictions show a good agreement in predicting the behavior and strength of the concrete filled steel tubular (CFST) columns with or without inner steel tubes. An important characteristic of the new formulas is that they provide a unified formulation for both the plain CFST and CFDST columns relating to the compressive strength or the stability bearing capacity and a set of design parameters.

• Journal of the Korean Chemical Society
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• v.35 no.5
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• pp.512-519
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• 1991

The axial ligations of nitrogenous bases (pyridine, imidazole, 1-methylimidazole and 2,6-lutidine) to Zn(II)-, Cu(II)-, and Ni(II)-tetrakis(o-chlorophenyl)porphyrin(o-ClTPP), and -tetraphenylporphyrin (TPP) were investigated in organic solvents $(CH_2Cl_2,\;C_6H_6,\;CH_3NO_2,\;(CH_3)_2CO,\;CHCl_3,\;DMF\;and\;DMSO)$ and at 0.01M of ionic strength. The equilibrium constants for the ligation reactions of methalloporphyrins were determined using spectrophotometric method at 15∼35${\circ}C$. In case of M(II)-TPP the equilibrium constants K were considerably larger than those of M(II)-(o-Cl)TPP, depending on steric effect of the porphyrin. The linear relationships between logK of the axial ligation and $pK_a$ of nitrogenous base were shown in M(II)-TPP, but not in M(II)-(o-Cl)TPP. The stabilities of MTPP(L) were controlled by the reation enthalpy and entropy, while those of M(o-Cl)TPP almost by the reaction entropy. The coordinating power of solvent to the methalloporphyrin were also studied in $CHCl_3,\;(CH_3)_2CO$, DMF and DMSO. From those results the solvent effects on the equilibrium constants were discussed.

• Structural Engineering and Mechanics
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• v.58 no.3
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• pp.515-532
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• 2016

The elastoplastic response of functionally graded material (FGM) beams resting on a nonlinear elastic foundation to an eccentric axial load is investigated by using the finite element method. The FGM is assumed to be formed from ceramic and metal phases with their volume fraction vary in the thickness direction by a power-law function. A bilinear elastoplastic behavior is assumed for the metallic phase, and the effective elastoplastic properties of the FGM are evaluated by Tamura-Tomota-Ozawa (TTO) model. Based on the classical beam theory, a nonlinear finite beam element taking the shift in the neutral axis position into account is formulated and employed in the investigation. An incremental-iterative procedure in combination with the arc-length control method is employed in computing the equilibrium paths of the beams. The validation of the formulated element is confirmed by comparing the equilibrium paths obtained by using the present element and the one available in the literature. The numerical results show that the elastoplastic post-buckling of the FGM beams is unstable, and the post-buckling strength is higher for the beams associated with a higher ceramic content. Different from homogeneous beams, yielding in the FGM beam occurs in the layer near the ceramic layer before in the layer near metal surface. A parametric study is carried out to highlight the effect of the material distribution, foundation support and eccentric ratio on the elastoplastic response of the beams.

• Steel and Composite Structures
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• v.8 no.1
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• pp.1-18
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• 2008

Observations from experiments and real fire indicate that restrained steel beams have better fire-resistant capability than isolated beams. Due to the effects of restraints, a steel beam in fire condition can undergo very large deflections and the run away damage may be avoided. In addition, axial forces will be induced with temperature increasing and play an important role on the behaviour of the restrained beam. The factors influencing the behavior of a restrained beam subjected to fire include the stiffness of axial and rotational restraints, the load type on the beam and the distribution of temperature in the cross-section of the beam, etc. In this paper, a simplified model is proposed to analyze the performance of restrained steel beams in fire condition. Based on an assumption of the deflection curve of the beam, the axial force, together with the strain and stress distributions in the beam, can be determined. By integrating the stress, the combined moment and force in the cross-section of the beam can be obtained. Then, through substituting the moment and axial force into the equilibrium equation, the behavior of the restrained beam in fire condition can be worked out. Furthermore, for the safety evaluation and repair after a fire, the behaviour of restrained beams during cooling should be understood. For a restrained beam experiencing very high temperatures, the strength of the steel will recover when temperature decreases, but the contraction force, which is produced by thermal contraction, will aggravate the tensile stresses in the beam. In this paper, the behaviour of the restrained beam in cooling phase is analyzed, and the effect of the contraction force is discussed.

• Earthquakes and Structures
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• v.11 no.4
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• pp.723-740
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• 2016

Reinforced concrete corbels are generally used to transfer loads within a structural system, such as buildings, bridges, and facilities in general. They commonly present low aspect ratio, requiring an accurate model for shear strength prediction in order to promote flexural behavior. The model described here, originally developed for walls, was adapted for corbels. The model is based on a reinforced concrete panel, described by constitutive laws for concrete and steel and applied in a fixed direction. Equilibrium in the orthogonal direction to the shearing force allows for the estimation of the shear stress versus strain response. The original model yielded conservative results with important scatter, thus various modifications were implemented in order to improve strength predictions: 1) recalibration of the strut (crack) direction, capturing the absence of transverse reinforcement and axial load in most corbels, 2) inclusion of main (boundary) reinforcement in the equilibrium equation, capturing its participation in the mechanism, and 3) decrease in aspect ratio by considering the width of the loading plate in the formulation. To analyze the behavior of the theoretical model, a database of 109 specimens available in the literature was collected. The model yielded an average model-to-test shear strength ratio of 0.98 and a coefficient of variation of 0.16, showing also that most test variables are well captured with the model, and providing better results than the original model. The model strength prediction is compared with other models in the literature, resulting in one of the most accurate estimates.

• Transactions of the Korean Society of Pressure Vessels and Piping
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• v.7 no.3
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• pp.1-7
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• 2011

The analysis shows that the vibration is one of the main reasons of turbine failure. Especially, the problems caused by vibration occur right after retrofit of the turbine-generator and restarting the turbine. Through the case study of high vibration caused by after the turbine trip and restart, turbine vibration was identified to be influenced by startup condition. Turbine startup at high casing temperature right after unscheduled turbine trip cause radial expansion in rotor by contraction in axial direction, while casing continues to contract by steam flowing into casing. Consequently, gap between rotor and casing decrease until to metal contact to cause high vibration. Through the case study of high vibration of turbine-generator system after generator retrofit, it was identified that generator replacement could cause high vibration in turbine-generator system if the influence of generator replacement on entire system was not considered properly. To prevent startup delay caused by high vibration, it is important to keep the gaps at the design standard and start the turbine after thermal equilibrium.