• Analytical Science and Technology
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• v.21 no.6
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• pp.518-525
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• 2008

Mandipropamid is a new mandelamide-type fungicide to control foliar Oomycete pathogens in some vegetables. An analytical method was developed to determine mandipropamid residues in agricultural commodities using high-performance liquid chromatography (HPLC) and liquid chromatography/mass spectrometry (LC/MS). Mandipropamid was extracted with methanol from grape, tomato, green pepper, Chinese cabbage and potato samples. The extract was diluted with saturated sodium chloride solution and distilled water, and dichloromethane partition was followed to recover the mandipropamid from the aqueous phase. Florisil column chromatography was employed to further remove interfering co-extractives prior to HPLC analysis. Reverse-phased HPLC was successfully applied to determine mandipropamid in sample extracts with the detection at its ${\lambda}_{max}$ (223 nm). Overall recoveries of mandipropamid from fortified samples averaged $99.8{\pm}1.7$ (n=6), $89.3{\pm}5.3$ (n=6), $98.7{\pm}2.2$ (n=6), $99.7{\pm}6.8$ (n=6) and $91.1{\pm}3.1$ (n=6) for grape, tomato, green pepper, Chinese cabbage and potato, respectively. Limit of quantification of the method was 0.02~0.04 mg/kg for all samples. A LC/mass spectrometry with selected-ion monitoring was also provided to confirm the suspected residue. The proposed method was reproducible and sensitive enough to determine the terminal residue of mandipropamid in agricultural commodities.

• Nuclear Engineering and Technology
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• v.16 no.2
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• pp.70-79
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• 1984

With the help of the nuclear computational system for a large LMFBR (KAERI-26 group cross section library/1DX/2DB), the reactivity coefficients for the diagrid expansion and the pad expansion at the beginning of cycle of the equilibrium core of SUPER-PHENIX I are calculated and reviewed. the core is described using R-Z geometry model, and a two-dimensional multigroup diffusion theory is used. For reference cases, reactivity calculations for radial and axial uniform expansion are performed, and also calculated are reactivity variations due to changes in material density and core volume. The reactivity coefficient for the diagrid expansion is calculated to be -0.553pcm/mil. The temperature coefficient corresponding to the above value is -1.0766pcm/$^{\circ}C$ and is well in accord with the French datum of -1.09pcm/$^{\circ}C$ within 1.2% difference. With the use of 4he calculational method for the diagrid expansion effect, reactivity calculations for the pad expansion bringing about nonuniform expansion are performed, which show that the calculational method is very useful in the analysis of the pad expansion effect. The reactivity coefficients for the pad expansion are calculated to be -0.2743 pcm/mil and -0.2786pcm1mi1 for the averaged expansion model and for the integrated pancake model, respectively. Under the assumption of the free expanding core the temperature reactivity coefficients for each model are obtained to be -0.5766pcm/$^{\circ}C$ and -0.5858pcm/$^{\circ}C$, both of which agree with the French datum of -0.574pcm/$^{\circ}C$ within 2% difference.

• Korean Journal of Agricultural and Forest Meteorology
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• v.19 no.3
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• pp.110-119
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• 2017

The agroclimatic indices are produced by statistical analysis based on primary climate data (e.g., temperature, precipitation, and solar irradiance) or driving agronomic models. This study was carried out to evaluate how selection of daily temperature for a climate normal (1983-2012) affected the precision of the agroclimatic indices. As a first step, averaged daily 0600 and 1500 LST temperature for a climate normal were produced by geospatial schemes based on topo-climatology ($365days{\times}1$ set, EST normal year). For comparison, 30 years daily temperature data were generated by applying the same process ($365days{\times}30sets$), and calculated mean of daily temperature (OBS normal year). The flowering date of apple 'Fuji' cultivar, the last frost date, and the risk of late frost were estimated based on EST normal year data and compared with the results from OBS normal year. The results on flowering date showed 2.9 days of error on average. The last frost date was of 11.4 days of error on average, which was relatively large. Additionally, the risk of the late frost was determined by the difference between the flowering and the last frost date. When it was determined based on the temperature of EST normal year, Akyang was classified as a risk area because the results showed that the last frost date would be the same or later than the flowering date in the 12.5% of area. However, the temperature of OBS normal year indicated that the area did not have the risk of a late frost. The results of this study implied that it would be necessary to reduce the error by replacing the EST method with the OBS method in the future.

• Korean Journal of Applied Biomechanics
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• v.18 no.2
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• pp.115-124
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• 2008

The purpose of this study was to examine the effects of customized foot orthotics on lower extremity muscle activity and fatigue during march in combat boots. Four volunteers with normal foot and five volunteers with excessive pronation foot among soldiers on service were fitted with foot orthotics. The electromyography signal from activity of low extremity muscles were collected with surface electromyography device during walking on the treadmill. The walk on the treadmill was performed with a speed of 4.5 km/h. The experiment design for reseach wes composed two experimentation. The first experiment was to examine the muscle activity of lower extremity between normal foot and excessive pronator foot during march. The second experiment was to examine the muscle activity of lower extremity between wearing orthotics and no wearing orthotics. These data were analyzed by the averaged integral EMG and the mean power frequency. The analyzed results were compared by independent T-test method and paired T-test method of SPSS(windows version 12.0). The result of the study were the muscle activity on pronator foot tend to increase during march but a statistically significant increase in muscle fatigue of vastus lateralis and fibularis longus. A statistically significant decrease in muscle activity of anterior tibialis and fibularis longus and fatigue occurred using the customized foot orthotics in volunteers with excessive pronation foot compared to volunteers with normal foot. Clinically, the application of orthotics for the soldiers with excessive pronation foot appears to delay muscle fatigue and prevent from variable foot injuries. This may contribute to enhancing fighting efficiency.

• The Journal of Engineering Geology
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• v.23 no.4
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• pp.375-380
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• 2013

The concept of safe yield places an emphasis on balancing groundwater withdrawal with groundwater recharge but ignores naturally occurring groundwater discharge. Because streams and their alluvial aquifers are closely linked in terms of water supply and water quality, to be properly understood and managed they must be considered together. Therefore, some districts in Kansas have reevaluated their safe-yield policies to account for natural groundwater discharge and stream-aquifer interactions by amending their safe-yield regulations to include a portion of baseflow as the minimum desirable streamflow (MDS). This study proposes a modified safe-yield policy in which the drought flow is chosen as the MDS. Baseflow separation was conducted from streamflow hydrograph and the results are presented as a flow-duration curve. The exploitable groundwater can be determined by subtracting MDS from the cumulative baseflow. This method was tested in the Musimcheon watershed, which was validated for streamflow using the SWAT-K model. The annually averaged exploitable groundwater in the whole watershed was estimated to be 86 mm. The exploitable groundwater amounts were also estimated for each subwatershed in the Musimcheon watershed.

• Toxicological Research
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• v.29 no.2
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• pp.121-127
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• 2013

Nanotoxicological research has shown toxicity of nanomaterials to be inversely related to particle size. However, the contribution of agglomeration to the toxicity of nanomaterials has not been sufficiently studied, although it is known that agglomeration is associated with increased nanomaterial size. In this study, we prepared aerosols of nano-sized carbon black by 2 different ways to verify the effects of agglomeration on the toxicity and deposition of nano-sized carbon black. The 2 methods of preparation included the carbon black dispersion method that facilitated clustering without sonication and the carbon black dispersion method involving sonication to achieve scattering and deagglomeration. Male Sprague-Dawley rats were exposed to carbon black aerosols 6 hr a day for 3 days or for 2 weeks. The median mass aerodynamic diameter of carbon black aerosols averaged $2.08{\mu}m$ (for aerosol prepared without sonication; group N) and $1.79{\mu}m$ (for aerosol prepared without sonication; group S). The average concentration of carbon black during the exposure period for group N and group S was $13.08{\pm}3.18mg/m^3$ and $13.67{\pm}3.54mg/m^3$, respectively, in the 3-day experiment. The average concentration during the 2-week experiment was $9.83{\pm}3.42mg/m^3$ and $9.08{\pm}4.49mg/m^3$ for group N and group S, respectively. The amount of carbon black deposition in the lungs was significantly higher in group S than in group N in both 3-day and 2-week experiments. The number of total cells, macrophages and polymorphonuclear leukocytes in the bronchoalveolar lavage (BAL) fluid, and the number of total white blood cells and neutrophils in the blood in the 2-week experiment were significantly higher in group S than in normal control. However, differences were not found in the inflammatory cytokine levels (IL-$1{\beta}$, TNF-${\alpha}$, IL-6, etc.) and protein indicators of cell damage (albumin and lactate dehydrogenase) in the BAL fluid of both group N and group S as compared to the normal control. In conclusion, carbon black aerosol generated by sonication possesses smaller nanoparticles that are deposited to a greater extent in the lungs than is aerosol formulated without sonication. Additionally, rats were narrowly more affected when exposed to carbon black aerosol generated by sonication as compared to that produced without sonication.

• Journal of Environmental Impact Assessment
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• v.27 no.5
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• pp.405-416
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• 2018

In this research, the distribution of Platinum Group Elements (PGEs) at roadside dust in Daejeon, Korea was examined using an ICP-MS (Inductively Coupled Plasma-Mass Spectrometry) technique. For the quality assurance of the determination, method validation based on its accuracy and precision was conducted using SRM (Standard Reference Material). It was found that the relative errors of Pt, Pd, and Rh against each SRM value were -0.7%, -10.0%, and -20.4%, respectively, while relative standard deviations for three elements were less than 10%. The concentrations of Pt, Pd and Rh in roadside dust averaged as $17.4{\pm}9.2{\mu}g/kg$, $283.6{\pm}20.5{\mu}g/kg$, and $7.3{\pm}2.8{\mu}g/kg$, respectively. The concentrations of Pt and Rh have significantly higher distribution patterns in the dust at roadside and underground parking lot than those in soil of the background or other urban area. The correlation analysis between concentrations of PGEs in roadside dust indicates that the distribution of Pt and Rh concentration were strongly affected by automobile sources.

• Journal of the Korean Arthroscopy Society
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• v.4 no.1
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• pp.54-60
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• 2000

Purpose : The purpose of this study was to evaluate the gutter pathologies and the clinical results of arthroscopic treatment for ankle gutter syndrome. Materials and Methods : Seventy six patients(77 ankles) who had lesions in the ankle gutter were treated by arthroscopy. The gutter pathology could be divided into 3 categories; hypertrophic scar tissue, loose bodies and bone spurs. Fifty two patients were evaluated subjectively and functionally with authors' criteria. The follow-up period averaged 44 months(range, 2.9 year-8.5 year). Results : The incidence of the gutter lesion was $21\%$(77 ankles) among 366 ankles undergoing arthroscopy. The most common pathology was hypertrophic scar tissue. In 31 ankles$(40\%)$, the lesions were found only in gutter, and 46 ankles$(60\%)$ were associated with pathologies in other areas. All of parameters for subjective and functional evaluation were improved with statistical significance(p<0.001). Seventeen patients$(33\%)$ could returned to competitive or contact sports activity with same level of premorbid period. Conclusion : Ankle gutter is an important site of pathologies which cause chronic ankle pain, and should be explored in ankle arthroscopy. The ankle arthroscopy is a very effective treatment method fur the removal of pathologies in ankle gutter syndrome.

• Journal of the Korean Association of Geographic Information Studies
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• v.5 no.2
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• pp.25-33
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• 2002

We were trying to understand indirectly the range of the discharge from the Nakdong with the dispersion of suspended solid(SS) related to the amount of discharge from river in this study. The range of dispersion of SS from the Nakdong was estimated using satellite remote sensing and numerical modeling. The stream field with two dimensional and numerical model using the condition of integrated depth was calculated. According to the results, the streamline flowed from Busan to the Jinhae Bay and Geojae Island. at the flood. The situation at the ebb was totally changed. The streamline flowed out Busan from the Bay. The velocity in offshore was faster than one at coastal water of the Nackdong. Residual current which was averaged during 12hours dominantly appeared the dominant direction from the southwestern part of the Nackdong to the northeastern part of it. The eastward current appeared at the eastern coast of Gaduck Is. Base on the results of the velocity field, the quantifying of the dispersion of SS was estimated by the method of numerical tracer related to the Lagrangian method. The significant range of the dispersion of the SS from the Nackdong was from the eastern coast of Gaduck Is, to the coastal areas of Busan, Korea. The estimated range of the dispersion of the SS using the SeaWiFS and Landsat satellite data was similar to the estimated results using the numerical model.

• Journal of IKEEE
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• v.17 no.4
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• pp.505-510
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• 2013

In this paper, a method of estimating hand and elbow movements using electrocorticogram (ECoG) signals is proposed. Using multiple channels, surface electromyogram (EMG) signals and ECoG signals were obtained from patients simultaneously. The estimated movements were those to close and then open the hand and those to bend the elbow inward. The patients were encouraged to perform the movements in accordance with their free will instead of after being induced by external stimuli. Surface EMG signals were used to find movement time points, and ECoG signals were used to estimate the movements. To extract the characteristics of the individual movements, the ECoG signals were divided into a total of six bands (the entire band and the ${\delta}$, ${\Theta}$, ${\alpha}$, ${\beta}$, and ${\gamma}$ bands) to obtain the information entropy, and the maximum likelihood estimation method was used to estimate the movements. The results of the experiment showed the performance averaged 74% when the ECoG of the gamma band was used, which was higher than that when other bands were used, and higher estimation success rates were shown in the gamma band than in other bands. The time of the movements was divided into three time sections based on movement time points, and the "before" section, which included the readiness potential, was compared with the "onset" section. In the "before" section and the "onset" section, estimation success rates were 66% and 65%, respectively, and thus it was determined that the readiness potential could be used.