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A Study on the Formation of Nitrate in Atmosphere(II) (환경 대기중에서 Nitrate의 생성에 관한 연구(II))

  • 천만영;이영재;김희강
    • Journal of Korean Society for Atmospheric Environment
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    • v.9 no.3
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    • pp.216-221
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    • 1993
  • This study was carried out to determine the concentration of gaseous nitrate$(HNO_3)$ particulate nitrate$(NO_3^-)$ and conversion rate of NOx to nitrate in atmosphere in Seoul from Oct 1991 to July 1992. The average concentration of gaseous nitrate in daytime(09:00 - 17:00) was 9.93, 3.37, 7.40 and 10.40$\mug/m^3$ and, in highttime was 6.21, 7.31, 4.79 and 3.86$\mug/m^3$ respectively. The concentratin of $HNO_3$ was greater in summer and daytime than winter and nighttime. But the concentration of $NO_3^-$ was greater in winter and nighttime than in summer and daytime. The average conversion rate of NOx to $HNO_3$(Fn) indaytime was 13.18, 3.78, 9.13 and 23.13% and, in nighttime was 3.06, 1.37, 1.70 and 8.72% during fall, winter, spring and summer respectively. But the average conversion rate of NOx to $NO_3^-$(Fn') in daytime was 5.79, 5.77, 2.63 and 3.90% and in nighttime was 5.95, 6.51, 3.25 and 4.84% respectively. The average conversion rate of NOx to total nitrate $(HNO_3 + NO_3^-)$(Fn') was 12.72, 7.81, 7.82 and 18.40% respectively. The average conversion rate of NOx to $HNO_3$(Fn) was greater than $NO_3^-$(Fn') about 1.6 times.

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Behaviors of Rubber Particles, Lead and Zinc in Atmospheric Particulate Classified by Particle Size Range (대기 부유분진중의 고무성분 및 납과 아연의 입도별 거동)

  • 이용근;원정호;김경섭;황규자
    • Journal of Korean Society for Atmospheric Environment
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    • v.2 no.2
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    • pp.60-65
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    • 1986
  • Atmospheric particulates were collected at a site near the front gate of the Yonsei University using nine stages Andersen air sampler and the distribution of seasonal particle size was investigated. Rubber, Pb and Zn contents of the collected particulates in each stage were determined. Particle size distribution of atmospheric particulate, which was made by concentration distribution curve method, was usually divided into two groups, course (particles larger than 1 - 2 $\mu m in diameter$) and fine (particles smaller than 1 - 2 \mu m in diameter$) groups, regardless of sampling period. More than 80 percent of the total rubber contents in atmospheric particulates were larger than $5 \mu m$ in diameter, meaning that most of rubber particles were originated from tire tread. After benzene extraction for 4 hrs, the extracts were analyzed by Curie-point pyrolysis gas chromatography for rubber content. Pb and Zn contents were determined by atomic absorption spectroscopy. The annual average concentration of rubber particles was $4.2 \mu g/m^3$, which corresponded to 2.2% of the annual average total suspended particulates. Average concentration of styrene brtadiene rubber was about five times that of natural rubber. Annual average concentrations of Pb and Zn were $1.2 \mu g/m^3 and 0.4 \mu g/m^3$ respectively, which corresponded to about 0.7% and 0.2% of the annual average total suspended particulates.

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Analysis of Respiratory and Cardiovascular Diseases according to PM Concentration in the Incheon Area (인천시 자치구별 미세먼지 농도에 따른 호흡기 및 심혈관계 외래환자 수 상관분석)

  • Lee, Seungwoon;Jung, Seungkwon
    • Journal of Environmental Health Sciences
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    • v.46 no.3
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    • pp.276-284
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    • 2020
  • Objectives: This study was conducted to identify the effects of PM10 and PM2.5 on hospital visits in the Incheon area over the period of 2016-2018. Methods: We applied correlation analysis and Poisson regression to perform the analysis using cardiovascular disease and respiratory disease data from the National Health Insurance Service and the daily average PM10 and PM2.5 from the Korea Environment Corporation adjusting for time lag. Results: When the daily average PM10 concentration increased by 10 ㎍/㎥, the number of cardiovascular disease patients were 1.002 times higher (95% CI [Confidence Interval]; 1.000-1004) in Ganghwa County. As the daily average PM2.5 concentration increased by 10 ㎍/㎥, the number of cardiovascular disease patients were 1.012 times higher (95% CI; 1.008-1.016) in Ganghwa County. As the daily average PM10 concentration increased by 10 ㎍/㎥, the respiratory disease patients were 1.003 times (95% CI; 1.002-1.004) higher in Gyeyang and Michuhol Counties. As the PM2.5 concentration increased by 10 ㎍/㎥, the respiratory disease patients were 1.003 times higher (95% CI; 1.002-1.005) in Bupyeong County. Conclusions: In some parts of the Incheon area there was a correlation between the number of patients with respiratory and cardiovascular conditions and the concentration of PM10 and PM2.5.

Effect of Water Pollution on the Irrigation Water (하천수질오염이 농업용수에 미치는 영향)

  • 나규환;이장훈;김치년
    • Environmental Analysis Health and Toxicology
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    • v.6 no.3_4
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    • pp.155-161
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    • 1991
  • The water quality in Wonju stream, Seom river in Kangwon province and Bokha, Shindun stream in Kyeonggi province was investigated between the season of irrigation on July, 1990 and of non-irrigation on September in 1989. The results of water quality obtained from this study were as follows; As for water quality of the Wonju stream and the Seom river, the concentration of COD, T-N, SS and Cu, and for the Bokha, Shindun stream, the concentration of T-N, SS and Cu were exceeded standard levels of quality guideline of agricultural water use in the season of irrigation. However, in the water quality of Wonju and Bokha stream, the concentration of T-N , SS and Cu, and in the Seom river, the concentration of T-N, SS, Cu and Zn were exceeded standard levels of agricultural water quality in the season of non-irrigation. And the average water quality of the 4 streams were not suitable for agricultural water use. The comparison of the annual average water quality of the 4 streams for pH, DO, T-N and SS were in statistics significantly different with p values less than 0.01. When the average water quality between the season of irrigation and non-irrigation in each stream was compared, DO and COD in the Wonju stream, COD in the Seom river, pH, DO, T-N, SS and Cu in the Shindun stream showed a significant difference with p<0.01. The average in the sediment were; COD, 5.65∼26.53 ppm; Cu, 0.26∼0.49 ppm and Zn 0.95∼2.97 ppm. The concentration of three contaminants were markedly higher than the water quality. And the concentration of COD, Zn in the sediment showed a significant difference with p<0.01, and Cu showed a considerably significant difference with p<0.05.

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Speciation of THMs, HAAs (THMs, HAAs의 종분포)

  • Kim, Jin-Keun
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.11
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    • pp.1135-1140
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    • 2006
  • Concentration and speciation of trihalomethanes(THMs) and haloacetic acids(HAAs) that can be created during chlorine disinfection as disinfection by-products(DBPs) in Korean water treatment plants(WTPs) were investigated. 4 WTPs that adopted conventional water treatment processes were chosen for investigation and each represented a typical WTP on the Han, Keum, Sumjin and Nakdong Rivers. The average concentration of THMs was 26.9 ppb, and the maximum and minimum concentrations were 47.6 ppb and 11.0 ppb respectively, while the average concentration of HAAs was 25.4 ppb, and the maximum and minimum concentrations were 57.1 ppb and 9.7 ppb respectively. DBPs concentration was lower in the winter than the summer. The major species of THMs was chloroform and its average percentage was 77%, and the second highest was bromodichloromethane(20%), while the concentration of bromoform was below detection limits. The sum of dichloroacetic acid(DCAA) and trichloroacetic acid(TCAA) was 97% of $HAA_5 $ on average base. But its percentage was 90% in the Han River WTP, especially it was the lowest during the winter. On the other hand, the concentration of DCAA was higher than TCAA except during the summer.

Studies on the Contamination Degree of Effluent from the Sewage Purification System and Septic Tank (오수정화시설 및 정화조 방류수의 수질오염도에 관한 연구)

  • 어수미;이홍근
    • Journal of Environmental Health Sciences
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    • v.17 no.2
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    • pp.35-40
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    • 1991
  • This study was performed to investigate the contamination degree of effluent from the sewage purification system and septic tank. The 711 samples, were collected from the large size tank located in Seoul from Mar. to June 1991. The results were as follows 1. The pH values of effluent were largely neutral of 6.96 in sewage and 7.43 in septic tank. 2. The average concentration of BOD was 48.18 mg/l in sewage and 127.0 rng/l in septic tank. 3. The average concentration of SS was 40.8mg/l in sewage and 90.5rng/l in septic tank. 4. In the analysis of nutrient salts, the average concentration of NH$_{3}$-N was 31.62mg/l in sewage and 88.79 mg/l in septic tank. 5. In the analysis of correlation among items, BOD, SS, NH$_{3}$-N and PO$_{4}$-P were higly correlated beween items. 6. As a results of above analysis, it is considered as desirable evaluation method of effluent not through the only item but through the integrated items.

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A Study on the Relation of Urban Heat Island and Air Pollution in Seoul Area (서울지역의 도시열섬현상과 대기오염도의 관계에 관한 연구)

  • 장영기;김정욱
    • Journal of Korean Society for Atmospheric Environment
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    • v.7 no.1
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    • pp.49-53
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    • 1991
  • Relations of urban heat island and air pollution are analyzed by using $SO_2$ concentration data (winter season in 1985) from 10 sites of Seoul area and differences of wind speed and air temperature in urban and rural area. Urban heat island is developed when daily mean wind speed at urban site is lower than 1.5m/sec or in the interval of 3.0 $\sim$ 3.5m/sec. When differences between urban and rural air temperature is greater than the overall average of those differences, $SO_2$ concentrations of those above-average differences are 1.3 $\sim$ 1.8 times higher than those of below-average differences. The trends are shown obviously at north-eastern area of Seoul (Gilum Dong, Ssangmun Dong, Myeonmog Dong). When intensity of Urban Heat Island is weak, $SO_2$ concentration was reduced in propotion to a rise of wind speed. But $SO_2$ concentration is on the partial increase in spite of a rise of wind speed when intensity of urban heat island is strong.

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Characteristics of Concentration and Load of Nitrogen and Phosphorous in Paddy Field Areas (광역논에서의 질소 .인의 농도와 오염부하량 특성)

  • 김진수
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.41 no.4
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    • pp.47-56
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    • 1999
  • The concentration and load of T-N and T-P in paddy field areas in Chongwon, Chungbuk , Korea , were investigated during the irrigation period. The concentration of T-N and T-P in ponded water in paddies is higher than that in the irrigation, drainage and percolation waters. For T-N, the average concentration indrainage water was higher than that in irrigation water until end of Jung, But lower thereafter. The average T-N concentration in irrigation water was 2.3 ∼3.2mg/l and therefore the agricultural water quality standard at on-farm level for T-N should be established realistically . The expontial L(load)-Q(discharge) equations have higher coefficients of determination than the linear L-Q equations . Especially, the exponential L-Q equation of T_N showed a coefficient of determinatino of over 0.9 for irrigation water.

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Streamflow Quality in a Forest Land (산지 계류수의 수질 특성(지역환경 \circled1))

  • 김선종;김진수;오광영;김재수;류득현
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2000.10a
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    • pp.531-535
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    • 2000
  • This study was carried out to investigate water quality of streamflow in a forest land. We measured discharges and the concentration of streamflow for T-N, T-P, COD, cations(Na$\^$+/, K$\^$+/, Ca$\^$2+/, Mg$\^$2+/), and anions(CI$\^$-/, SO$\_$4/$\^$2-/). The average concentration of pollutants were extremely low, such as 0.4mg/$\ell$ for T-N, 0.02 mg/$\ell$ for T-P and 2.68mg/$\ell$for COD. The concentration of cations have a tendency to decrease with increasing discharge, while the concentration of SO$\_$4/$\^$2-/) increase with increasing discharge. It was found that the average concentration of Ca$\^$2+/ was highest and that of K$\^$+/ was lowest among cations.

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Distribution of Heavy metals in Soil at Iksan 2nd Industrial Complex Area (익산 제 2공단 토양의 중금속 함량 분포 조사)

  • Kim, Seong-Jo;Baek, Seung-Hwa;Moon, Kwang-Hyun;Jang, Kwang-Ho;Kim, Su-Jin;Lee, Seung-Hyeon
    • Korean Journal of Environmental Agriculture
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    • v.18 no.3
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    • pp.250-258
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    • 1999
  • The purpose of this study was to compare heavy metal concentrations in uncontaminated soil with those in soil influenced by industrial activities, and to investigate the relationship between change of heavy metal content and the kind of industry at the Iksan 2nd Industrial Complex that has started since 1995. Soils sampled in 0-3 cm and 3-6 cm soil depth, respectively were analized for content of Cd, Cu, Ni, Pb and Zn. The content of Cd in soil layer of 0 to 3 cm was 0.07-4.37ppm range, average concentration was 0.516ppm and 3-6 cm was 0.07-8.52ppm range, average concentration was 0.380ppm. Area of the chemicals, dyes and metal products manufacturing were higher than the other manufacturing area in Industrial Complex. The content of Cu in soil layer of 0 to 3 cm was 0.61-42.62ppm range, average concentration was 11.087ppm and 3-6 cm was 0.16-35.45ppm range, average concentration was 7.578ppm. Area of the metal products manufacturing were higher than the other manufacturing area in Industrial Complex. The content of Ni in soil layer of 0 to 3 cm was 0.19-15.93ppm range, average concentration was 5.525ppm and 3-6 cm was 0.39-15.59ppm range, average concentration was 5.310ppm. Area of the metal and chemical products manufacturing were higher than the other manufacturing area in Industrial Complex. The content of Pb in soil layer of 0 to 3 cm was 3.10-55.75ppm range, average concentration was 23.543ppm and 3-6 cm was 3.35-46.55ppm range, average concentration was 19.198ppm. Area of the chemicals and metal products manufacturing were higher than the other manufacturing area in Industrial Complex. The content of Zn in soil layer of 0 to 3 cm was 26.50-943.00ppm range, average concentration was 158.329ppm and 3-6 cm was 35.45-882.45ppm range, average concentration was 127.914ppm. Area of the chemicals and metal products manufacturing were higher than the other manufacturing area in Industrial Complex. As the result, this study was to compare Cd, Cu, Ni, Pb, Zn average concentration in uncontaminated soil of world with those in soil, that Cu, Ni were uncontaminated concentration level, Cd was somewhat higher compare with the concentration level of world, Pb and Zn were very higher. Soil contaminated degree of Iksan 2nd Industrial Complex was known a difference by type of industrial activities(chemical, dyes and metal of products)

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