• Korean Journal of Fisheries and Aquatic Sciences
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• v.28 no.3
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• pp.263-269
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• 1995

To determine the autochthonous COD caused by the production of phytoplankton, three different methods were used simultaneously utilizing several environmental factors and applied to the Nakdong Estuary. From the estimation of the tropic state index, tropic level in the Nakdong Estuary was found to be in excess of eutrophication level at all area studied. The percentage of autochthonous COD in total COD was largest in summer and in station No. 6 $(43.5\%)$. Using of the relationship between COD and salinity was not appropriate tov the evaluation of the autochthonous COD due to discrepancy with other tesulfs evaluated. However, the evaluations of autochthonous COD obtained from the $\DeltaCOO$ and the relationship between COD and chl.a were found to be proper methods, resulting in a relative error less than $20\%$ for all of the area investigated.

• Journal of Environmental Science International
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• v.16 no.8
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• pp.959-971
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• 2007

The three-dimensional eco-hydrodynamic model was applied to estimate the autochthonous COD caused by production of phytoplankton in Jinhae Bay. A residual current was simulated, using a hydrodynamic model, to have a sightly complicated pattern in the inner part of the bay, ranging from 0.001 to 5 cm/s. In the outer part of the bay, the simulated current flowed out to the south sea with a southward flow at a maximum of 25 cm/s. The results of the ecological model simulation of COD levels showed high concentrations, exceeding 4 mg/L, in the inner bay of Masan, an area of wastewater discharge, and lower levels, approaching less than 1 mg/L, closer to the outer part of the bay. The simulation results of Autochthonous COD by two methods using ecological modeling, showed high ratio over 70% of total COD. Therefore, it is more important to consider nutrients than organic matters in the region for control COD standard.

• Journal of Environmental Science International
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• v.10 no.2
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• pp.119-127
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• 2001

The Keum river is one of the important river in Korea and has a drainage area of 9,873$\textrm{km}^2$. The Keum river is deepening pollution state due to development of the lower city and construction of a industrial complex. The water quality of the Keum river come to eutrophication state and belong to III grade of water quality standard. The concentration BOD in river is affected by the organic loading from a tributary and the algae biomass that largely happen to under eutrophication state. In the eutrophic water mass such as the Keum river, the autochthonous BOD was very important part for making a decision of water quality management, because it was accounted for majority of the total BOD. The purpose of this study was to survey the chatacteristics of water quality in summer and to estimate reaction coefficient. Also, we studied to correlationship between chlorophyll a and BOD(COD) for estimation of the autochthonous BOD. The correlationship between chlorophyll a and BOD(COD) were obtained through the culture experiment of phytoplankton in the laboratory. The results of this study may be summarized as follows ; The characteristics of water quality in summer were belong to III~IV grade of water quality standard as BOD and nutritive condition is very high. The BOD, ammonia nitrogen and phosphate loadings in Miho stream which inflowing untreated sewage from Chungju city was occupied with 64.07%, 26.36%, 46.08%, respectively. Maximum nutrient uptake (Vmax) was 0.4400$\mu$M/hr as substrate of ammonia nitrogen, 0.1652$\mu$M/hr as substrate of phosphate. Maximum specific growth rate ($\mu$max) was 1.2525$hr^{-1}$ as substrate of ammonia nitrogen, 1.5177$hr^{-1}$ as substrate of phosphate. The correlation coefficient between chlorophyll a and BOD by the culture experiment were found to be 0.911~0.935 and 0.942~0.947 in the case adding nutrient and no adding nutrient, respectively. The correlation coefficient between chlorophyll a and COD through the culture experiment were found to be 0.918~0.977 and 0.880~0.931 in the case adding nutrient and no adding nutrient, respectively. The autochthonous BOD(COD) was estimated to the relationship between BOD(COD) and chlorophyll a. The regression equation were found to be autochthonous BOD=(0.045~0.073)${\times}chlorophyll$ a and autochthonous $COD=(0.137~0.182){\times}chlorophyll$ a.

• Journal of the Korean Society for Marine Environment & Energy
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• v.15 no.1
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• pp.38-46
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• 2012

This study carried out current status, characteristics, and problems of coastal environment management on semi-enclosed Masan Bay in Korea and suggests cost-effective and eco-friendly water quality management policy. The pollutants from terrestrial sources into the Bay have apparently environmental pollution problems, such as eutrophication, red tide, and hypoxia. The carrying capacity of the Bay is estimated by hydrodynamic model and ecosystem model, material circulation including bivalve in ecosystem is analyzed by the growth model of bivalve. The resulting reduction in the input load was found to be 50~90%, which is unrealistic. When the efficiency of water quality improvement through bivalve farming was assessed based on the autochthonous COD, 30.7% of the total COD was allochthonous COD and 69.3% was autochthonous COD. The overall autochthonous COD reduction rate by bivalve aquaculture farm was found to be about 6.7%. This study indicate that bivalve farming is about 31% less expensive than advanced treatment facilities that remove both nitrogen and phosphorous.

• Journal of Environmental Science International
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• v.14 no.9
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• pp.835-842
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• 2005

The three-dimensional eco-hydrodynamic model was applied to estimate the physical process in terms of COD (chemical oxygen demand) and net supply(or decomposition) rate of COD in Kamak Bay to find proper management plan for oxygen demanding organic matters. The estimation results of the physical process in terms of COD showed that transportation of COD is dominant in surface level while accumulation of COD is dominant in bottom level. In the case of surface level, the net supply rate of COD was 0 -0.50 mg/m2/day. The net decomposition rate of COD was 0 -0.04 mg/m2/day in middle level(3 -6m) and 0.05 -0.1 5 mg/m2/day in bottom level(6m -bottom). These results indicates that the biological decomposition and physical accumulation of COD are occurred predominantly at the northern part of bottom level. Therefore, it is important to consider both allochthonous and autochthonous oxygen demanding organic matters in the region.

• Journal of Environmental Science International
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• v.16 no.12
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• pp.1369-1382
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• 2007

To find proper water quality management strategy for oxygen consumption organic matters in Jinhae bay, the physical process and net supply/decomposition in terms of COD was estimated by three-dimensional eco-hydrodynamic modeling. The estimation results of physical process in terms of COD showed that transportation of COD was dominant in loading area from land to sea, while accumulation of COD was dominant in $middle{\sim}bottom$ level. In case of surface level, the net supply rate of COD was $0{\sim}60\;mg/m^2/day$. The net decomposition rate of COD was $0{\sim}-0.05\;mg/m^2/day$($-5{\sim}-10$ m, in depth) to 2 level, and $-0.05{\sim}-0.20\;mg/m^2/day(10m{\sim})$ to bottom level. These results indicate that the biological decomposition and physical accumulation of COD are occurred for the most part of Jinhae Bay bottom. The variation of net supply or net decomposition rate of COD as reducing land based input loading is also remarkable. Therefore, it is important to consider both allochthonous and autochthonous oxygen demanding organic matters to improve the water quality of Jinhae Bay.

• Journal of the Korean Society of Marine Environment & Safety
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• v.24 no.6
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• pp.735-749
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• 2018

In this study, one studied the principal factors and water-quality components that determine the concentration of chemical oxygen demand (COD) in seawater in estuaries, such as the Han, Geum, Youngsan, Seomjin, and Nakdong rivers in Korea. The principal factors determining the concentration of COD in seawater indicated by the principal component analysis were salinity, exogenous origin and autochthonous resources based on chlorophyll-a. Moreover, organic matter in the submarine sediment layer also had a secondary effect. Regression slope assessed the contribution of water-quality components to determine the concentration of COD in the estuary. One found that the effect of salinity on the overall survey was significant. Moreover, the effect of chlorophyll-a was also appeared in April and August. In each estuary, the most significant contribution factor was chlorophyll-a in the Nakdong River and salinity in the Han and Yongsan rivers. The contribution of salinity and chlorophyll-a were found to be the largest in the Geum River. The salinity and chlorophyll-a in the Seomjin River showed a low contribution.

• Journal of the Korean Society of Marine Environment & Safety
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• v.5 no.2
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• pp.57-65
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• 1999

The in situ observations and the seawater analyses were conducted at all seasons from July 1996 to April 1999 for the purpose of describing the characteristics of seasonal variations of water quality in Mokpo harbour, Korea. Vertical stratification started to be formed in water column in spring, developed in summer and disappeared in fall. In summer, vertical density distribution of water column was found to be in stable structure with lower temperature and higher salinity of bottom water, and the vertical mixing of water between surface and bottom layers was restricted. In winter, however, surface water was found to be similar to bottom water in temperature and salinity, and water column was in unstable structure and in well-mixed condition between surface and bottom waters. The saturation percentage of dissolved oxygen(DO) in bottom water of inner part of Mokpo harbour at all seasons was shown to be decreased to the third grade or under the third grade of Korean standards of seawater quality. In particular, dissolved oxygen was oversaturated in surface water and undersaturated in bottom water in summer, due to stratification and organic pollution. The difference of DO concentration between surface and bottom waters was found to be greater in spring and summer than in fall and winter, due to stratification and photosynthesis of phytoplankton. The concentrations of chemical oxygen demand(COD) over the entire waters of Mokpo harbour were found to fluctuate from below the third grade to the first grade of Korean standards through all seasons and COD concentrations of same seasons were shown to be different year after year. In particular, in view of COD, the annual average seawater quality of Mokpo harbour was evaluated to be in third grade of Korean standards, due to organic pollution. The average COD of surface water was greater than that of bottom water in spring and summer, due to the autochthonous COD caused by production of phytoplankton in surface waters, while the average COD of surface water was similar to that of bottom water in fall and winter, due to the vertical mixing of water between surface and bottom layers.

• Journal of the Korean Society of Marine Environment & Safety
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• v.16 no.1
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• pp.1-9
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• 2010

Numerical study on coastal water quality management was conducted to examine the response of summer water quality to the flow into the sea of land based pollution load in Ulsan Bay, Korea The abatement of pollution load. from point sources of land was estimated on the basis of Korean coastal water quality standard using an ecosystem model. The results of the ecological model simulation showed that COD values in the inner part of the bay were greater than 280mg/L, and exceeded the grade III limit of Korean coastal water quality standard 30% of all land based pollution loads or organic and inorganic material loads from point sources should be cut down to keep the COD levels below 2mg/L. As environmental carrying capacity was estimated to be 7,193kgCOD/day to keep the COD levels below 2mg/L in Ulsan Bay, 3,083kgCOD/day of land based organic loads should be reduced. The phytoplankton blooms have occurred in the Teahwa river mouth or estuary repetitively, so it is important to control land based nutrients loads for removal of autochthonous organic loads around Ulsan Bay.

• Journal of Microbiology and Biotechnology
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• v.24 no.7
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• pp.987-997
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• 2014

The mature landfill leachate, which is characterized by a high concentration of ammonia nitrogen ($NH_3$-N) and humic acid (HA), poses a challenge to biotreatment methods, due to the constituent toxicity and low biodegradable fraction of the organics. In this study, we applied bioaugmentation technology in landfill leachate degradation by introducing a domesticated $NH_3$-N and HA resistant bacteria strain, which was identified as Bacillus cereus (abbreviated as B. cereus Jlu) and Enterococcus casseliflavus (abbreviated as E. casseliflavus Jlu), respectively. The isolated strains exhibited excellent tolerant ability for $NH_3$-N and HA and they could also greatly improved the COD (chemical oxygen demand), $NH_3$-N and HA removal rate, and efficiency of bioaugmentation degradation of landfill leachate. Only 3 days was required for the domesticated bacteria to remove about 70.0% COD, compared with 9 days' degradation for the undomesticated (autochthonous) bacteria to obtain a similar removal rate. An orthogonal array was then used to further improve the COD and $NH_3$-N removal rate. Under the optimum condition, the COD removal rate in leachate by using E. casseliflavus Jlu and B. cereus Jlu increased to 86.0% and 90.0%, respectively after, 2 days of degradation. The simultaneous removal of $NH_3$-N and HA with more than 50% and 40% removal rate in leachate by employing the sole screened strain was first observed.