• Title/Summary/Keyword: auto-oxidation

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A stydy on the whitening substrate of natural products

  • Park, S. S.;Kim, W. H.;K. H. Kong;S. H. Cho;S. J. Jang
    • Proceedings of the SCSK Conference
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    • 2003.09a
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    • pp.499-500
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    • 2003
  • To investigate the potency of some natural extracts as skin whitening agents, in this study, 25 natural plants were prepared from natural sources including medicinal plants, such as Angelica dahurica using methylene dichloride, ethyl acetate, n-butyl alcohol, and water as the extraction and/or the partitioning solvents. These natural extracts were subsequently subjected to in-vitro DOPA auto-oxidation test in the media containing human or mushroom tyrosinase as the oxidation promoting enzymes. Most of the extracts showed relatively higher enzyme inhibition(omitted)

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The Storage Property of Squid Viscera by Supercritical Carbon Dioxide Extraction

  • Lee, Min-Kyung;Yoo, Hong-Suk;Pack, Hyun-Duk;Chun, Byung-Soo
    • Journal of Marine Bioscience and Biotechnology
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    • v.2 no.1
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    • pp.55-59
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    • 2007
  • The oil and concentrated protein powder from squid viscera was extracted and recovered by a semi-batch supercritical carbon dioxide ($SCO_2$) extraction system and the degree of oxidation in the extracted oil was measured in order to compare with extracted oils using organic solvents. The degree of storage in treated squid viscera by $SCO_2$ extraction was measured in order to compare with untreated squid viscera. As results obtained, it was found that the auto-oxidation of the oils using $SCO_2$ extraction occurred very slowly compared to the oils by organic solvent extraction. And the treated squid viscera by $SCO_2$ extraction was reached the point of initial rottenness slowly than untreated squid viscera.

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EFFECTS OF SPLIT INJECTION AND OXYGEN-ENRICHED AIR ON SOOT EMISSIONS IN A DIESEL ENGINE

  • Nguyen, Khai;Sung, Nak-Won;Lee, Sang-Su
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.2965-2970
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    • 2008
  • Effects of split injection and oxygen-enriched air on soot emissions in a DI diesel engine were studied by the KIVA-3V code. When split injection is applied, the second injection of fuel into a cylinder results in two separate stoichiometric zones which increases soot oxidation. As a result, soot emissions are decreased with split injection. When oxygen-enriched air is applied together with split injection, higher concentration of oxygen helps secondary combustion which results in a higher temperature in the cylinder. The increased temperature promotes growth reaction of acetylene with soot but doesn't improve the acetylene formation during the second injection of fuel. As more acetylene is consumed in the growth reaction of acetylene, the net acetylene mass in the cylinder is decreased, which leads to a decrease of soot formation. With an increase of soot oxidation caused by split injection, the soot emissions are decreased significantly. However, to avoid excessive NOx emissions with increased oxygen concentration, the level of oxygen concentration should be lower than 22% in volume.

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Lubricating performance of vegetable oils as environmentally friendly fluids

  • Mimura, K.;Mitsumune, S.;Minami, I.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.341-342
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    • 2002
  • Although vegetable oils provide good lubricity, they still need optimization by certain additive technology for practical applications. ZDTP improve antiwear properties of vegetable oils. However the additive performance depends on quality of the base Oil. Antioxidants were applied to prevent the auto-oxidation of vegetable oils. Good synergistic effect of anti-wear and antioxidant additives was confirmed.

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Case Study of Application of $SuperMAK^{R}$Submersed Hollow fiber Membrane) ($SuperMAK^{R}$(침지형분리막)을 적용한 오ㆍ폐수시설의 개 보수 사례)

  • 박헌휘;최영근;서창희;조재청;김수룡
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05b
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    • pp.123-123
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    • 2004
  • 일반적인 활성슬러지 공정은 MLSS 1,500 - 3,000 mg/L 정도인데 MBR 공정은 보통 8,000 mg/L 이상의 농도로 운전할 수 있어, 높은 유기물 제거와 질산화 효율을 증가시킬 수 있다. 따라서 기존의 포기조 용량을 줄일 수 있으며 미생물의 자산화(Auto-Oxidation)가 증가하여 슬러지 발생량(Sludge Production)은 줄어들게 된다.(중략)

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THE STUDY ON TISSUE CULTURED WILD MOUNTAIN GINSENG(Panax Ginseng C.A. Meyer) ADVENTITIOUS ROOTS EXTRACT AS A COSMETIC INGREDIENT

  • Jung, Eun-Joo;Park, Jong-Wan;Kim, Joong-Hoi;Paek, Kee-Yoeup
    • Proceedings of the SCSK Conference
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    • 2003.09a
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    • pp.611-616
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    • 2003
  • Korean ginseng(Panax Ginseng C.A. Meyer) known as a oriental miracle drug is an important medicinal plant. Ginseng has been used for geriatric, tonic, stomachic, and aphrodisiac treatments for thousands years. Also, it is an antibiotic and has therapeutic properties against stress and cancer. Ginseng is widely distributed all over the world. Among them, Korean mountain ginseng has the most valuable effect on pharmaceuticals. The roots of mountain ginseng contained several kinds of ginsenosides that have many active functions for the human body. However, the study of mountain ginseng has a limit because the mountain ginseng is very expensive and rare. So, we artificially cultured mountain ginseng adventitious roots using the bioreactor culture system. We induced callus from original mountain ginseng, directly dug up in mountain and aged about one hundred ten years. Separated adventitious roots were precultured in 500ml conical flasks and then, transferred in 20L bioreactors. The adventitious roots of mountain ginseng were harvested after culturing for 40days, dried and then, extracted with several solvents. In this study, we investigated the whitening effect, anti-wrinkle effect and the safety of tissue cultured adventitious roots extract of mountain ginseng in order to identify the merit as a cosmetic ingredient. Particularly, extract of mountain ginseng adventitious roots showed whitening and anti-wrinkle effects. The inhibitory effect of this extract on the melanogenesis was examined using B-16 melanoma cell. When B-16 melanoma cells were cultured with adventitious root extract, there was a dramatically decrease in melanin contents of 8-16 melanoma cell. And we identified this extract inhibited Dopa auto-oxidation significantly. Also, when transformed mouse fibroblast L929 cells were treated with this extract, there was a significant increase in collagen synthesis. The results show significant inhibited melanization and wrinkle without inhibiting cell viability.

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Effects of heat and gamma radiation on the degradation behaviour of fluoroelastomer in a simulated severe accident environment

  • Inyoung Song ;Taehyun Lee ;Kyungha Ryu ;Yong Jin Kim ;Myung Sung Kim ;Jong Won Park;Ji Hyun Kim
    • Nuclear Engineering and Technology
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    • v.54 no.12
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    • pp.4514-4521
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    • 2022
  • In this study, the effects of heat and radiation on the degradation behaviour of fluoroelastomer under simulated normal operation and a severe accident environment were investigated using sequential testing of gamma irradiation and thermal degradation. Tensile properties and Shore A hardness were measured, and thermogravimetric analysis was used to evaluate the degradation behaviour of fluoroelastomer. Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy were used to characterize the structural changes of the fluoroelastomer. Heat and radiation generated in nuclear power plant break and deform the chemical bonds, and fluoroelastomer exposed to these environments have decreased C-H and functional groups that contain oxygen and double bonds such as C-O, C=O and C=C were generated. These functional groups were formed by auto oxidation by reacting free radicals generated from the cleaved bond with oxygen in the atmosphere. In this auto oxidation reaction, crosslinks were generated where bonded to each other, and the mobility of molecules was decreased, and as a result, the fluoroelastomer was hardened. This hardening behaviour occurred more significantly in the severe accident environment than in the normal operation condition, and it was found that thermal stability decreased with the generation of unstable structures by crosslinking.

Effectiveness of the Sensor using Lead Dioxide Electrodes for the Electrochemical Oxygen Demand (전기화학적 산소요구량 측정용 이산화납 전극 센서의 유효성)

  • Kim, Hong-Won;Chung, Nam-Yong
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.21 no.4
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    • pp.575-581
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    • 2012
  • The electrochemical oxygen demand (ECOD) is an additional sum parameter, which has not yet found the attention it deserves. It is defined as the oxygen equivalent of the charge consumed during an electrochemical oxidation of the solution. Only one company has yet developed an instrument to determine the ECOD. This instrument uses $PbO_2$-electrodes for the oxidation and has been successfully implemented in an automatic on-line monitor. A general problem of the ECOD determination is the high overpotential of electrochemical oxidations of most organic compounds at conventional electrodes. Here we present a new approach for the ECOD determination, which is based on the use of a solid composite electrodes with highly efficient electro-catalysts for the oxidation of a broad spectrum of different organic compounds. Lead dioxide as an anode material has found commercial application in processes such as the manufacture of sodium per chlorate and chromium regeneration where adsorbed hydroxyl radicals from the electro-oxidation of water are believed to serve as the oxidizing agent. The ECOD sensors based on the Au/$PbO_2$ electrode were operated at an optimized applied potential, +1.6 V vs. Ag/AgCl/sat. KCl, in 0.01 M $Na_2SO_4$ solution, and reduced the effect of interference ($Cl^-$ and $Fe^{2-}$) and an expended lifetime (more than 6 months). The ECOD sensors were installed in on-line auto-analyzers, and used to analyze real samples.

Numerical Design of Auto-Catalyst Substrate for Improved Conversion Performance Using Radially Variable Cell Density (변환효율 향상을 위한 횡방향 가변 셀밀도법을 사용한 자동차용 촉매변환기의 수치적 설계)

  • Jeong, Su-Jin;Kim, U-Seung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.12
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    • pp.1596-1607
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    • 2000
  • The optimal design of auto-catalyst needs a good compromise between the pressure drop and flow uniformity in the substrate. One of the effective methods to achieve this goal is to use the concept of radially variable cell density. But this method has not been examined its usefulness in terms of chemical behavior and conversion performance. In this work, two-dimensional performance prediction of catalyst coupled with turbulent reacting flow simulation has been used to evaluated the benefits of this method n the flow uniformity and conversion efficiency. The results showed that two cell combination of 93cpsc and 62 cpsc was the most effective for improved pressure drop and conversion efficiency due to balanced space velocity and efficient usage of geometric surface area of channels. It was also found that large temperature difference between the bricks in case that the edge of the frontal face of brick has too much lower cell density(less than 67% of cell density of the center of the brick). This study has also demonstrated that the present computational results show the better prediction accuracy in terms of CO, HC and NO conversion efficiencies compared to those of conventional 1-D adiabatic model by comparison with experimental results.

The Environmental Degradability of Starch-Polyethylene Composite Film (전분-폴리에틸렌 복합필름의 환경분해성)

  • Kim, Young-Gi;Park, Young-Hoon;Im, Seung-Soon
    • Applied Chemistry for Engineering
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    • v.4 no.1
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    • pp.178-187
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    • 1993
  • Degradation of the starch-polyethylene composite film by an activated sludge treatment and a soil burial test was examined. The treated films had deformed structures which were resulted from the removal of starch during the treatments. The added auto-oxidant caused the degradation of the polyethylene matrices and the crosslinking reactions after the oxidation of polyethylene chains as well. As a result of soil burial test, the degradation reaction of the composite film containing corn oil as an auto-oxidant was, however, prevalent : number- and weight-average molecular weight of polyethylene decreased, while the molecular weight distribution increased.

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