• 한국화재소방학회논문지
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• 제30권1호
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• pp.24-30
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• 2016

자연발화 특성은 가연성물질의 취급 및 화재예방을 위한 중요한 인자이다. 본 연구는 ASTM D2155식 발화온도 측정장치를 사용하여 Ethylene Glycol과 물을 혼합한 시료의 자연발화 특성을 고찰하였다. Ethylene Glycol 100%는 시료량 $75{\mu}l{\sim}160{\mu}l$의 범위에서 $434^{\circ}C$로 나타났다. 물을 첨가하여 Ethylene Glycol 80%와 물 20%를 혼합한 시료는 시료량 $100{\mu}l{\sim}125{\mu}l$의 범위에서 $434^{\circ}C$로 나타났고, Ethylene Glycol 60%와 물 40%를 혼합한 시료에서 시료량 $120{\mu}l{\sim}160{\mu}l$의 범위에서 $437^{\circ}C$로 나타났다. 또한 순간발화온도는 시료량 $125{\mu}l$에서 각각 $579^{\circ}C$, $595^{\circ}C$ 및 $611^{\circ}C$를 구하였으며, 물의 비율이 증가할수록 자연발화온도와 순간발화온도는 증가되는 것으로 나타났다.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 1995년도 제5회 학술강연회논문집
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• pp.139-144
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• 1995

The main purpose of igniter is sure ignition of main propellant at desired ignition delay times. Since ignition mechanism of solid rocket propellant involves so many complicated physical and chemical phenomena, it is almost impossible to predict ignition behavior with pure analytical means. In this study, one dimensional and unsteady ignition transient phenomena in solid rocket was analyzed by finite volume method. In analysis, assumption was made that ignition occurs when propellant surface temperature reaches to it's auto-ignition temperature.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2010년도 제34회 춘계학술대회논문집
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• pp.202-205
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• 2010

이 연구에서는 아산화질소의 촉매 분해를 이용한 하이브리드 로켓의 자연 점화에 관한 연구를 수행하였다. 하이브리드 로켓은 촉매 점화기, 고체연료, 연소기, 노즐로 구성하였다. 아산화질소를 분해하기 위해 Ru 촉매를 $Al_2O_3$ 지지체에 함침법을 이용하여 담지하였고, 제조된 촉매의 반응온도에 따른 아산화질소 분해율을 측정하였다. 촉매 점화기의 작동조건에 따른 온도변화를 측정하였고, 하이브리드 로켓의 자연 점화에 대한 가능성을 확인하였다.

• 한국자동차공학회논문집
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• 제14권5호
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• pp.25-31
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• 2006

Controlled Auto Ignition(CAI) combustion has great potential in achieving significant increase in engine efficiency, while simultaneously reducing exhaust emissions. The process itself involves the auto ignition and subsequent simultaneous combustion of a premixed charge. In this study, NVO(Negative Valve Overlap) system was applied to a CAI engine in order to use residual gas. The fuel was injected directly to the cylinder under the high temperature condition resulting from heating the intake port to initiate CAI combustion. This paper introduced the valve timing strategy and experimental set-up. From this study, the effect of engine speed and valve timing on CAI combustion and exhaust emissions was clarified. In addition, stratified charge method was used to extend CAI operating region.

• 대한기계학회논문집B
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• 제30권5호
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• pp.457-464
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• 2006

Controlled auto ignition (CAI) combustion, also known as HCCI (homogeneous charge compression ignition), offers the potential to simultaneously improve fuel economy and reduce emission. CAI-combustion was achieved in a single cylinder gasoline DI engine, with a cylinder running in a CAI mode. Standard components were used the camshafts which had been modified in order to restrict the gas exchange process. The effects of air-fuel ratio, residual EGR rate and injection timing such as early injection and late injection on the attainable CAI combustion region were investigated. The effect that injection timings on factor such as start of combustion, combustion duration and heat release rate was also investigated. From results early injection caused the mixture to ignite earlier and burn more quickly due to the exothermic reaction during the recompression and gave rise to good mixing of the fuel-air.

• 대한기계학회논문집B
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• 제31권6호
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• pp.514-521
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• 2007

This study focused on the effects of the $CO_2$ gas concentration in fresh charge and induction air temperature on the combustion characteristics of homogeneous charge compression ignition with dimethyl ether (DME) fuel, which was injected at the intake port. Because of adding $CO_2$ in fresh charge, start of auto-ignition was retarded and bum duration became longer. Indicated combustion efficiency and exhaust gas emission were found to be worse due to the incomplete combustion. Partial burn was observed at the high concentration of $CO_2$ in fresh charge with low temperature of induction air. However, indicated thermal efficiency was improved due to increased expansion work by late ignition and prolonged bum duration. Start of auto-ignition timing was advanced with negligible change of burn duration, as induction air temperature increased. Burn duration was mainly affected by oxygen mole concentration in induction mixture. Bum duration was increased, as oxygen mole concentration was decreased.

• 대한기계학회논문집B
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• 제41권11호
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• pp.749-757
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• 2017

본 연구는 대체연료 개발 및 국제환경규제에 대응하기 위하여, 노말데케인과 에탄올 혼합연료의 조성 및 온도 변화가 자착화 특성에 미치는 영향을 수치적으로 해석하였다. 해석용 프로그램으로는 CHEMKIN-PRO를 사용하였고, 반응모델은 LLNL모델을 이용하였다. 수치해석 결과를 통해 저온 연소 반응이 일어나는 1000K 이하에서는 에탄올의 몰 비율이 증가함에 따라 점화지연 시간이 증가하는 현상을 확인하였다. 에탄올의 높은 옥탄가로 인해 에탄올의 높은 비율은 점화를 일으키는 OH라디칼의 농도 증가를 지연시키기 때문이다. 배기가스 재순환을 적용하기 위해 혼합연료에 산소농도를 변화하여 수치해석을 하였다. 산소농도가 감소함에 따라 전체 점화지연시간은 증가하게 되고, 이는 질소가스가 연소실 내에 열부하로 작용하기 때문이다.

• 한국자동차공학회논문집
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• 제16권2호
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• pp.143-149
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• 2008

The present study is mainly motivated to investigate the vaporization, auto-ignition and spray combustion processes in DI diesel engine using DME and n-heptane. In order to realistically simulate the dimethyl ether (DME) spray dynamics and vaporization characteristics in high-pressure and high-temperature environment, the high-pressure vaporization model has been utilized. The interaction between chemistry and turbulence is treated by employing the Representative Interaction Flamelet (RIF) model. The detailed chemistry of 336 elementary steps and 78 chemical species is used for the DME/air reaction. Based on numerical results, the detailed discussion has been made for the distinctly different combustion characteristics of DME diesel engine in term of vaporization, ignition delay, pollutant formation, and heat release rate.

• 한국연소학회:학술대회논문집
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• 한국연소학회 1998년도 제17회 KOSCI SYMPOSIUM 논문집
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• pp.59-67
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• 1998

The aim of this study is to investigate advantages that the catalytically supported combustor can have. For this purpose, the catalytic combustor was prepared which consisted of the catalyst bed and the thermal combustor at the downstream of the catalyst bed. The catalyst bed consisted of two-stage. Pd catalyst was installed in the first stage of the catalyst bed, and Pt catalyst was placed in the second stage. Results showed that the catalytically supported combustion had some advantages. One was that auto-ignition occurred in the thermal combustor. This can give merit that an igniter is not necessary to start flame ignition. Other was that the catalytically supported combustion was stable for lean mixture. When combustion of lean mixture was not supported by surface reaction it became unstable so that big combustion noise was created. Therefore, it is desirable to support flame by catalytic surface reaction to obtain the stable combustion of lean mixture.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2013년도 제46회 KOSCO SYMPOSIUM 초록집
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• pp.33-35
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• 2013

The present work is an experimental investigation on potential operating range using directly injected gasoline fuel in a single-cylinder compression ignition (CI) engine. The objectives of present study were to apply auto-ignited combustion to gasoline fuel and to evaluate potential operating range. In order to auto-ignite gasoline fuel in CI engine, the fuel direct-injection system and the intake air system were modified that a flow rate and temperature of intake air were regulated. The heat-release rate (HRR), net indicated mean effective pressure (IMEP), start of combustion (SOC), and combustion duration were derived from in-cylinder pressure data in a test engine, which has 373.33cc displacement volume and 17.8 compression ratio. The exhaust emission characteristics were obtained emission gas analyzer and smoke meter on the exhaust line system.