• Title/Summary/Keyword: auto ignition temperatures

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The Measurement and Investigation of Combustible Properties for n-Hexane (노말헥산의 연소특성치의 측정 및 고찰)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.26 no.2
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    • pp.36-41
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    • 2011
  • For the safe handling of n-hexane, the explosion limit at $25^{\circ}C$, the temperature dependence of the explosion limits and the lower flash point were investigated. And AITs(auto-ignition temperatures) by ignition delay time for n-hexane were experimented. By using the literatures data, the lower and upper explosion limits of n-hexane recommended 1.0 Vol% and 8.0 Vol%, respectively. In this study, the lower flash points of n-hexane recommended $-23^{\circ}C$. This study measured relationship between the AITs and the ignition delay times by using ASTM E659-78 apparatus for n-hexane, and the experimental AIT of n-hexane was $240^{\circ}C$. The new equations for predicting the temperature dependence of the explosion limits of n-hexane is proposed. The values calculated by the proposed equations were a good agreement with the literature data.

The Investigation of Compatibility of Combustible Characteristics for n-Tridecane (노말트리데칸의 연소특성치의 적정성 고찰)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.27 no.3
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    • pp.83-88
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    • 2012
  • For the safe handling of n-tridecane, the lower flash points and AITs(auto-ignition temperatures) by ignition delay time were experimented. Also lower explosion limits by the lower flash points were calculated. The lower flash points of n-tridecane by using closed-cup tester were experimented $92^{\circ}C$ and $96^{\circ}C$. The lower flash points and fire point of n-tridecane by using open cup tester were experimented 100 oC and 103 oC, respectively. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 apparatus for n-tridecane. The experimental AIT of n-tridecane was 223 oC. The calculated lower explosion limit by using measured lower flash point 92 oC for n-tridecane was 0.6 Vol.%.

The Measurement of Combustible Properties of Acetic Anhydride for the Compatibility of MSDS (MSDS 적정성을 위한 아세틱안하이드리드의 연소특성치 측정)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.29 no.4
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    • pp.85-90
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    • 2014
  • For the safe handling of acetic anhydride, this study was investigated the explosion limits of acetic anhydride in the reference data. And the lower flash points, upper flash points, and AITs(auto-ignition temperatures) by ignition delay time were experimented. The lower and upper explosion limits of acetic anhydride by the investigation of the literatures recommended 2.9 Vol% and 10.3 Vol.%, respectively. The lower flash point of acetic anhydride by using Setaflash closed-cup tester was experimented $49^{\circ}C$. The lower flash point acetic anhydride by using Tag and Cleveland open cup tester were experimented $55^{\circ}C$and $62^{\circ}C$, respectively. Also, this study measured relationship between the AITs and the ignition delay times by using ASTM E659 tester for acetic anhydride. The experimental AIT of acetic anhydride was $350^{\circ}C$.

Measurement and Prediction of Fire and Explosion Properties of 3-Hexanone (3-헥사논의 화재 및 폭발 특성치의 측정 및 예측)

  • Ha, Dong-Myeong
    • Journal of the Korean Institute of Gas
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    • v.17 no.6
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    • pp.33-38
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    • 2013
  • For the safe handling of 3-hexanone(ethyl propyl ketone), this study was investigated the explosion limits of 3-hexanone in the reference data. The flash points and AITs(auto-ignition temperatures) by ignition delay time were experimented. The lower flash points of 3-hexanone by using closed-cup tester were experimented at $18^{\circ}C$. The lower flash points of 3-hexanone by using open cup tester were experimented in $27^{\circ}C{\sim}32^{\circ}C$. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 tester for 3-hexanone. The experimental AIT of 3-hexanone was at $425^{\circ}C$. The lower explosion limit( LEL) by the measured lower flash point of 3-hexanone was calculated as 1.21 Vol%.

Combustion and Exhaust Emission Characteristics by the Change of Intake Air Temperature in a Single Cylinder Diesel Engine (단기통 디젤엔진에서 흡기온도변화에 따른 연소 및 배기특성)

  • Shin, Dalho;Park, Suhan
    • Transactions of the Korean Society of Automotive Engineers
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    • v.25 no.3
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    • pp.336-343
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    • 2017
  • Intake air conditions, such as air temperature, pressure, and humidity, are very important parameters that influence engine performance including combustion and emissions characteristics. The purpose of this study is to investigate the effects of intake air temperature on combustion and exhaust emissions characteristics in a single cylinder diesel engine. In this experiment, an air cooler and a heater were installed on the intake air line and a gas flow controller was installed to maintain the flow rate. It was found that intake air temperature induced the evaporation characteristics of the fuel, and it affects the maximum in-cylinder pressure, IMEP(indicated mean effective pressure), and fuel consumption. As the temperature of intake air decreases, the fuel evaporation characteristics deteriorate even as the fuel temperature has reached the auto-ignition temperature, so that ignition delay is prolonged and the maximum pressure of cylinder is also reduced. Based on the increase in intake air temperature, nitrogen oxides(NOx) increased. In addition, the carbon monoxide(CO) and unburned hydrocarbons(UHC) increased due to incomplete fuel combustion at low intake air temperatures.

The Evaluation of Hazard by Measurement of Combustible Characteristics of n-Tetradecane (노말테트라데칸의 연소특성치 측정에 의한 위험성 평가)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.27 no.5
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    • pp.70-76
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    • 2012
  • For the safe handling of n-tetradecane, the lower flash points and the upper flash point, fire point, AITs (auto-ignition temperatures) by ignition delay time were experimented. Also lower and upper explosion limits by using measured the lower and upper flash points for n-tetradecane were calculated. The lower flash points of n-tetradecane by using closed-cup tester were measured $104^{\circ}C$ and $112^{\circ}C$. The lower flash points and fire point of n-tetradecane by using open cup tester were measured $113^{\circ}C$ and $115^{\circ}C$, respectively. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 apparatus for n-tetradecane. The experimental AIT of n-tridecane was $207^{\circ}C$. The calculated lower and upper explosion limit by using measured lower $104^{\circ}C$ and upper flash point $140^{\circ}C$ for n-tetradecane were 0.63 Vol.% and 3.18 Vol%.

The Measurement of Combustible Properties of Cyclopentanol (사이클로펜탄올의 연소특성치의 측정)

  • Ha, Dong-Myeong
    • Journal of the Korean Institute of Gas
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    • v.18 no.2
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    • pp.35-40
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    • 2014
  • For the safe handling of cyclopentanol, this study was investigated the explosion limits of cyclopentanol in the reference data. The flash points and AITs(auto-ignition temperatures) by ignition delay time were experimented. The lower flash point of cyclopentanol by using closed-cup cyclopentanol was experimented at $49^{\circ}C$. The lower flash points of cyclopentanol by using open cup tester was experimented at $59^{\circ}C$. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 tester for cyclopentanol. The experimental AIT of cyclopentanol was at $363 ^{\circ}C$.

The Measurement of Fire and Explosion Properties of n-Pentadecane (노말펜타데칸의 화재 및 폭발 특성치의 측정)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.28 no.4
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    • pp.53-57
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    • 2013
  • For the safe handling of n-pentadecane, the lower flash points and the upper flash point, fire point, AITs(auto-ignition temperatures) by ignition delay time were experimented. Also lower and upper explosion limits by using measured the lower and upper flash points for n-pentadecane were calculated. The lower flash points of n-pentadecane by using closed-cup tester were measured $118^{\circ}C$ and $122^{\circ}C$. The lower flash points and fire point of n-pentadecane by using open cup tester were measured $126^{\circ}C$ and $127^{\circ}C$, respectively. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 apparatus for n-pentadecane. The experimental AIT of n-pentadecane was $195^{\circ}C$. The calculated lower and upper explosion limit by using measured lower $118^{\circ}C$ and upper flash point $174^{\circ}C$ for n-pentadecane were 0.54 Vol.% and 6.40 Vol.%.

DME and Diesel HCCI Combustion Characteristics (DME와 Diesel의 HCCI 연소특성 비교)

  • Lee, Joo-Kwang;Kook, Sang-Hoon;Park, Cheol-Woong;Bae, Choong-Sik
    • 한국연소학회:학술대회논문집
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    • 2003.12a
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    • pp.231-236
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    • 2003
  • HCCI(Homogeneous Charge Compression Ignition) combustion is an advanced combustion process explained as a homogeneously premixed charge of a fuel where air is admitted into the cylinder and compression ignited. It has possibility to reduce NOx by spontaneous auto-ignition at multiple points that allows very lean combustion resulting in low combustion temperatures. Particulate matters (PM) could be also reduced by the homogeneous combustion and no fuel-rich zones. Injection timing is extremely advanced to achieve homogeneous charge where a diesel fuel could not be vaporized sufficiently due to low pressure and low temperature condition. Also the over-penetration could be a severe problem. The small injection angle and multi-hole injectors were applied to solve these problems. Dimethyl ether (DME) as an altenative fuel was also applied to relive the bad vaporization problem associated with early injection of diesel fuel. Neat DME has a very high cetane rating and high vapor pressure. Contained oxygen reduces soot during the combustion. Experimental result shows DME can be easily operated in an HCCI engine. PM shows almost zero value and NOx is reduced more than 90% compared to direct-injection diesel engine operating mode but problem of early ignition needs more investigation.

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The Measurement and Investigation of Fire and Explosion Characteristics of Cyclohexanone (사이클로헥사논의 화재 및 폭발 특성치의 측정 및 고찰)

  • Ha, Dong-Myeong
    • Fire Science and Engineering
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    • v.25 no.4
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    • pp.28-34
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    • 2011
  • For the safe handling of cyclohexanone, the explosion limits at $25^{\circ}C$ were investigated. The lower flash points and AITs (auto-ignition temperatures) by ignition time delay for cyclohexanone were experimented. By using the literatures data, the lower and upper explosion limits of cyclohexanone recommended 1.1 Vol.% ($100^{\circ}C$) and 9.4 Vol.%, respectively. The lower flash points of cyclohexanone were experimented $42{\sim}43^{\circ}C$ by using closed-cup tester and $49{\sim}51^{\circ}C$ by using open cup tester. This study measured relationship between the AITs and the ignition delay times by using ASTM E659-78 apparatus for cyclohexanone and the experimental AIT of cyclohexanone was $415^{\circ}C$.