• Title/Summary/Keyword: atomic ratio

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Effects of Gamma Ray Irradiation on the Struvite Crystallization of Livestock Wastewater (축산폐수를 이용한 스트러바이트 합성에 감마선 조사가 미치는 영향)

  • Yoo, Byeong-Hak;Jo, Seong-Hui;Lee, Myun-Joo;Kim, Tak-Hyun
    • Journal of Radiation Industry
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    • v.4 no.4
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    • pp.313-317
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    • 2010
  • The struvite crystallization was applied to remove $NH_4{^+}$ in livestock wastewater. The ammonium ions can be very toxic to the aquatic creatures. In this experiments, the livestock wastewater from Gongju livestock wastewater treatment plant was used. The behaviors of various parameters such as pH, mole ratio of $Mg^{2+}$ : $NH_4{^+}$ : $PO{_4}^{3-}$ and reaction temperature for struvite crystallization of livestock wastewater and the effect of gamma ray irradiation were evaluated. As results, for the pH variation, the $NH_4{^+}$ removal efficiency showed the highest, 88%, at pH 9~9.25. The removal efficiency of $NH_4{^+}$, $Mg^{2+}$ and $PO{_4}^{3-}$ was showed highest when same molar ratio of $Mg^{2+}$ and $PO{_4}^{3-}$ were applied. The $NH_4{^+}$ removal efficiency showed 82% at $7^{\circ}C$, and 90% at $30^{\circ}C$ with temperature. When the wastewater was irradiated with 20 kGy of gamma ray, $NH_4{^+}$ was removed as much as 83%.

Detection Characteristics of Gamma-Irradiated Korean Medicinal Herbs by Using PSL, TL, and ESR (PSL, TL 및 ESR 분석에 의한 감마선 조사 한약재의 검지 특성)

  • Yang, Hee-Sun;Park, Yong-Dae;Jin, Chang-Hyun;Choi, Dae-Seong;Chung, Hyung-Wook;Byun, Myung-Woo;Jeong, Il-Yun
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.37 no.11
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    • pp.1529-1533
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    • 2008
  • The detection characteristics of gamma-irradiated ($0{\sim}10.0\;kGy$) medicinal herbs (Platycodon grandiflorum, Acanthopanax chiisanensis) were investigated by photostimulated luminescence (PSL), thermoluminescence (TL), and electron spin resonance (ESR). The results of the PSL, a first screening method in comparison with the TL, showed photon counts greater than 5,000 counts/60 s (positive) in the irradiated samples, while the non-irradiated samples yielded photon counts less than 700 counts/60 s (negative). The TL was also applied for the detection method of irradiated medicinal herbs and showed that the non-irradiated sample revealed a glow curve with a low intensity, while the irradiated samples showed a higher intensity. These results were normalized by re-irradiating the mineral grains with a irradiation dose of 1.0 kGy, and a second glow curve was recorded. The ratio of the intensity of the first glow curve ($TL_1$) to that after the normalization dose ($TL_2$) was determined and compared with the recommended threshold values. TL ratio ($TL_1/TL_2$) was below 0.007 for the non-irradiated sample and higher than 0.1 for all irradiated samples (above 1.0 kGy). ESR spectroscopy revealed specific signals (6.065 mT) derived from free radicals in cellulose containing irradiated medicinal herbs. The P. grandiflorum showed clearer signals than A. chiisanensis. From the results of our studies, the PSL, TL, and ESR determinations were found to be suitable for the detection of irradiated medicinal herbs such as P. grandiflorum and A. chiisanensis.

Precipitation of Rare Earth Chlorides in a LiC-KCl Eutectic Molten Salt (LiCl-KCl 공융염 내에서 희토류염화물들의 침전)

  • Cho, Yung-Zun;Yang, Hee-Chul;Eun, Hee-Chul;Kim, Eung-Ho;Kim, In-Tae
    • Applied Chemistry for Engineering
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    • v.18 no.4
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    • pp.361-365
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    • 2007
  • The precipitation reaction of some rare earth chlorides ($Ce/Nd/GdCl_3$) in a LiCl-KCl molten salt has been carried out by reaction with oxygen. Identification of rare earth precipitates by reaction with oxygen and effects of oxygen sparging time (max. 420 min) and molten salt temperature ($450{\sim}750^{\circ}C$) on conversion were investigated. In this study, regardless of the oxygen sparging time and the molten salt temperature, oxychlorides (REOCl) for $NdCl_3$ and $GdCl_3$, and an oxide ($REO_2$) for $CeCl_3$ are formed as a precipitate, which are identical with the estimation results of Gibbs free energy of reaction (${\Delta}G_r$). The conversion of rare-earth chlorides into insoluble precipitates was described by using a conversion ratio. The conversion ratio increased exponentially with the oxygen sparging time and finally showed asymptotic value, over 0.999 at $750^{\circ}C$ of the molten salt temperature and over 300 min of sparging time conditions. The conversion ratios were increased with the molten salt temperature. In case of $CeCl_3$, when the sparging time exceed 60 min, the values of the conversion ratio were nearly constant over 0.999 in all experimental temperature conditions.

Investigation of Spacer Grid Thermal Mixing Performance Based on Hydraulic Tests

  • Yang, Sun-Kyu;Min, Kyung-Ho;Chung, Moon-Ki
    • Proceedings of the Korean Nuclear Society Conference
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    • 1995.10a
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    • pp.377-382
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    • 1995
  • An evaluation method of spacer grid thermal mixing performance in rod bundles is suggested based on hydraulic tests in a single phase flow. Heat transfer correlation was derived by the analogy between momentum and heat transfer. Three of major factors, such as blockage ratio of spacer grid, convective flow swirling, and turbulent intensity, were found to be significantly influential to the spacer grid thermal mixing performance. Local heat transfer near spacer grid was predicted for the hydraulic test of 6 ${\times}$ 6 rod bundles with neighboring different spacer grids.

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An Experimental Investigation of Side-Orifice Effects on Pressure Drop for Single-Phase Flow

  • Seo, Kyong-Won;Chun, Moon-Hyun;Nam, Ho-Yun;Park, Seok-Ki;Lee, Yong-Bum
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.11a
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    • pp.295-300
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    • 1996
  • To investigate the effects of the side-orifice on the pressure drop for single-phase flow, a series of experiments have been carried out with 16 different downstream test sections with various combinations of side-orifice shapes, different numbers of side-orifices, and different arrangements of the side-orifice using water as a working fluid. From the measurements of the pressure drop and the flow rate, the pressure loss coefficient of the side-orifice(s) has been evaluated. Based on the total number of 529 present data, an empirical correlation for the pressure loss coefficient has been developed in terms of Reynolds number and geometric parameters, such as area ratio, equivalent diameter, leading edge, and average width of side-orifice.

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Improvement of delayed hydride cracking assessment of PWR spent fuel during dry storage

  • Hong, Jong-Dae;Yang, Yong-Sik;Kook, Donghak
    • Nuclear Engineering and Technology
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    • v.52 no.3
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    • pp.614-620
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    • 2020
  • In a previous study, delayed hydride cracking (DHC) assessment of pressurized water reactor (PWR) spent fuel during dry storage using the threshold stress intensity factor (KIH) was performed. However, there were a few limitations in the analysis of the cladding properties, such as oxide thickness and mechanical properties. In this study, those models were modified to include test data for irradiated materials, and the cladding creep model was introduced to improve the reliability of the DHC assessment. In this study, DHC susceptibility of PWR spent fuel during dry storage depending on the axial elevation was evaluated with the improved assessment methodology. In addition, the sensitivity of affecting parameters such as fuel burnup, hydride thickness, and crack aspect ratio are presented.

Measurements of In-phantom Neutron Flux Distribution at the HANARO BNCT Facility

  • Kim Myong Seop;Park Sang Jun;Jun Byung Jin
    • Nuclear Engineering and Technology
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    • v.36 no.3
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    • pp.203-209
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    • 2004
  • In-phantom neutron flux distribution is measured at the HANARO BNCT irradiation facility. The measurements are performed with Au foil and wires. The thermal neutron flux and Cd ratio obtained at the HANARO BNCT facility are $1.19{\times}10^9\;n/cm^{2}s$ and 152, respectively, at 24 MW reactor power. The measured in-phantom neutron flux has a maximum value at a depth of 3 mm in the phantom and then decreases rapidly. The maximum flux is about $25\%$ larger than that of the phantom surface, and the measured value at a depth of 22 mm in the phantom is about a half of the maximum value. In addition, the neutron beam is limited well within the aperture of the neutron collimator. The two-dimensional in-phantom neutron flux distribution is determined. Significant neutron irradiation is observed within 20 mm from the phantom surface. The measured neutron flux distribution can be utilized in irradiation planning for a patient.

PREDICTION OF A MUTUAL SEPARATION OF ACTINIDE AND RARE EARTH GROUPS IN A MULTISTAGE REDUCTIVE EXTRACTION SYSTEM

  • Yoo, Jae-Hyung;Lee, Han-Soo;Kim, Eung-Ho
    • Nuclear Engineering and Technology
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    • v.39 no.5
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    • pp.663-672
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    • 2007
  • The mutual separation behavior of actinides and rare earths in a countercurrent multistage reductive extraction system was predicted by computer calculation. The distribution information for actinides and rare earths in the reductive extraction systems of LiCl-KCl/Cd and LiCl-KCl/Bi was collected from literature and then it was used for the calculation of a multistage extraction. The results of the concentration profiles throughout the extraction cascade, recovery yields of various metal solutes, and separation factors between the actinides and rare earths were calculated. The effects of the major process parameters, such as reducing agent content in the metal phase, number of stages, and salt/metal flow ratio, etc., on the extraction behavior were also examined.

Development of a Teleoperated Manipulator System for Remote Handling of Spent Fuel Bundles

  • Ahn Sung Ho;Jin Jae Hyun;Yoon Ji Sup
    • Nuclear Engineering and Technology
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    • v.35 no.3
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    • pp.214-225
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    • 2003
  • A teleoperated manipulator system has been developed for remote handling of the spent fuel bundles. A heavy-duty power manipulator with high reduction ratio joints is used for the slave manipulator in the developed system since the handling tasks of the spent fuel bundles need power. Also, the universal type master manipulator, which has force reflecting capability, is used for precise remote manipulation. The power manipulators so frequently occur the control input saturation that the precise control performances are not achieved due to the windup phenomenon. An advanced bilateral control scheme compensating for the saturation is applied to the teleoperated manipulator system. The validity of the developed system is verified by the grid cutting and fuel transportation tasks from the mockup spent fuel bundle.

Force Reflecting Position Control for 2 Axes Heavy-Duty Power Manipulators (2축 고하중 조작기의 힘반영 위치제어)

  • Ahn, Sung-Ho;Park, Byung-Suk;Yoon, Ji-Sup;Koh, Youn-Se;Lee, Sang-Jeong
    • Proceedings of the KIEE Conference
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    • 2000.07d
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    • pp.2910-2912
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    • 2000
  • Since the heavy-duty power manipulator has high ratio gear reducers at its joints, its dynamic characteristics are much slower than that of the master manipulator and it is likely to encounter the saturation in the input magnitude when it is used as the slave manipulator in telemanipulator systems. This paper proposes a force reflecting position control scheme for 2 axes heavy-duty power manipulator which compensates control input saturation. A series of experiments is shown to give an excellent tracking performance regardless of saturation.

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