• Title/Summary/Keyword: atomic ratio

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Microstructure of ZrC Coatings of TRISO Coated Particles by Codeposition of Free Carbon and Control of Stoichiometry (유리탄소의 동시증착에 의한 TRISO 피복입자의 ZrC 코팅층 미세구조와 화학양론비 제어)

  • Ko, Myung-Jin;Kim, Daejong;Park, Ji Yeon;Cho, Moon Sung;Kim, Weon-Ju
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.446-450
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    • 2013
  • TRISO coated particles with a ZrC barrier layer were fabricated by a fluidized-bed chemical vapor deposition (FBCVD) method for a use in a very high temperature gas-cooled reactor (VHTR). The ZrC layer was deposited by the reaction between $ZrCl_4$ and $CH_4$ gases at $1500^{\circ}C$ in an $Ar+H_2$ mixture gas. The amount of free carbon codeposited with in ZrC was changed by controlling the dilution gas ratio. Near-stoichiometric ZrC phase was also deposited when an impeller was employed to a $ZrCl_4$ vaporizer which effectively inhibited the agglomeration of $ZrCl_4$ powders during the deposition process. A near-stoichiometric ZrC coating layer had smooth surface while ZrC containing the free carbon had rough surface with tumulose structure. Surface roughness of ZrC increased further as the amount of free carbon increased.

PAALD 방법을 이용한 TaN 박막의 구리확산방지막 특성

  • 부성은;정우철;배남진;권용범;박세종;이정희
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2002.11a
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    • pp.14-19
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    • 2002
  • In this study, as Cu diffusion barrier, tantalum nitrides were successfully deposited on Si(100) substrate and SiO2 by plasma assisted atomic layer deposition(PAALD) and thermal ALD, using pentakis (ethylmethlyamino) tantalum (PEMAT) and $NH_3$ as precursors. The TaN films were deposited on $250^{\circ}$C by both method. The growth rates of TaN films were $0.8{\AA}$/cycle for PAALD and $0.75{\AA}$/cycle for thermal ALD. TaN films by PAALD showed good surface morphology and excellent step coverage for the trench with an aspect ratio of h/w - $1.8 : 0.12 \mu\textrm{m}$ but TaN films by thermal ALD showed bad step coverage for the same trench. The density for PAALD TaN was $11g/\textrm{cm}^3$ and one for thermal ALD TaN was $8.3g/\textrm{cm}^3$. TaN films had 3 atomic % carbon impurity and 4 atomic % oxygen impurity for PAALD and 12 atomic % carbon impurity and 9 atomic % oxygen impurity for thermal ALD. The barrier failure for Cu(200nm)/TaN(l0nm)/$SiO_2(85nm)$/Si structure was shown at temperature above $700^{\circ}$C by XRD, Cu etch pit analysis.

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A CORRELATION FOR SINGLE PHASE TURBULENT MIXING IN SQUARE ROD ARRAYS UNDER HIGHLY TURBULENT CONDITIONS

  • Jeong, Hae-Yong;Ha, Kwi-Seok;Kwon, Young-Min;Chang, Won-Pyo;Lee, Yong-Bum
    • Nuclear Engineering and Technology
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    • v.38 no.8
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    • pp.809-818
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    • 2006
  • The existing experimental data related to the turbulent mixing factor in rod arrays is examined and a new definition of the turbulent mixing factor is introduced to take into account the turbulent mixing of fluids with various Prandtl numbers. The new definition of the mixing factor is based on the eddy diffusivity of energy. With this definition of the mixing factor, it was found that the geometrical parameter, ${\delta}_{ij}/D_h$ correlates the turbulent mixing data better than Sid, which has been used frequently in existing correlations. Based on the experimental data for a highly turbulent condition in square rod arrays, a correlation describing turbulent mixing dependent on the parameter ${\delta}_{ij}/D_h$ has been developed. The correlation is insensitive to the Re number and it takes into account the effect of the turbulent Prandtl number. The proposed correlation predicts a reasonable mixing even at a lower S/d ratio.

Housing Analysis for Ocean Radiation Detection (해양 방사선 탐지를 위한 하우징 분석)

  • Park, Gang-teak;Kim, Jong-Yeol;Jung, Hyun-kyu;Lee, Nam-ho;Hwang, Young-gwan
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2017.10a
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    • pp.714-715
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    • 2017
  • Much of the interest in ocean radiation detection has been heightened as a lot of radioactivity has leaked to the ocean due to the accident at the Fukushima nuclear power plant in Japan. In the study, MCNP simulation for radiation detection in the ocean was performed. Unlike in the air, the marine environment must ensure the stability of the sensor from water depth, temperature, pressure, and salinity. In the marine environment, too much radiation is shielded. Therefore, it is an object to select a housing with a low radiation shielding ratio.

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Investigation into Tritium Behaviour in Chinese cabbage and Rice after a Short-term Exposure of HTO (HTO 피폭후 배추와 벼에서 삼중수소 거동)

  • Kim, Sang-Bog;Lee, Myung-Ho;Choi, Gun-Sik;Choi, Young-Mo;Lee, Chang-Woo
    • Journal of Radiation Protection and Research
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    • v.23 no.2
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    • pp.75-82
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    • 1998
  • Tritium concentration in the atmosphere during HTO exposure was different between two experiments due to different velocity of HTO evaporation. Assimilation rate of the rice plant was considered to be higher than that of Chinese cabbage The uptake of atmospheric HTO into tissue free water tritium(TFWT) was higher in rice plants than in Chinese cabbage. However, organically bound tritium(OBT) concentration is relatively higher in Chinese cabbage than in rice. The specific activity ratio(SAR) increased slowly after HTO exposure and decreased gradually with time. The behaviour of HTO in the soil was affected by the environmental conditions.

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Microstructural Properties of the Insoluble Residue in a Simulated Spent Fuel

  • Kim, J.S.;Song, B.C.;Jee, K.Y.;Kim, J.G.;Chun, K.S.
    • Nuclear Engineering and Technology
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    • v.30 no.2
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    • pp.99-111
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    • 1998
  • Chemical composition of the insoluble residue in a simulated spent PWR fuel(SIMRJEL) were studied. SIMFUELS were prepared by adding calculated amount of FP(fission product) elements with a burnup of 3.6% FIMA(fission per initial metal atom) to uranium in nitrate solution, evaporating the mixed solution to dryness, calcining at 90$0^{\circ}C$ in a stream of 4% H$_2$ + 96% He, and heating the pellet at 140$0^{\circ}C$ under high and low oxygen potentials. Insoluble residue was obtained from the dissolution of the SIMFUEL with HNO$_3$(1 : 1). The chemical composition of the SIMFUELs and the insoluble residues was determined by EPMA(electron probe microanalysis), XPS(X-ray photoelectron spectroscopy) and by XRD (X-ray diffraction) measurements. All of the insoluble residues suspended and precipitated were composed mainly of Mo, Ru with a small amount of Zr, Rh, Pd and Cd. The amount of insoluble residue(<1 wt.%) and a Mo/Ru ratio decreased with increasing oxygen potential. Formation of the zirconium molybdate precipitate, ZrMo$_2$O$_{7}$(OH)$_2$($H_2O$)$_2$, was observed in the residues. The possible role of Mo on the phase formation was discussed in regard to oxygen potential.l.

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Design and dynamic simulation of a molten salt THS coupled to SFR

  • Areai Nuerlan;Jin Wang;Jun Yang;Zhongxiao Guo;Yizhe Liu
    • Nuclear Engineering and Technology
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    • v.56 no.4
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    • pp.1135-1144
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    • 2024
  • With the increasing ratio of renewables in the grid, a low-carbon and stable base load source that also is capable of load tracking is in demand. Sodium cooled fast reactors (SFRs) coupled to thermal heat storage system (THS) is a strong candidate for the need. This research focuses on the designing and performance validation of a two-tank THS based on molten salt to integrate with a 280 MWth sodium cooled fast reactor. Designing of the THS includes the vital component, sodium-to-salt heat exchanger which is a technology gap that needs to be filled, and designing and parameter selection of the tanks and related pumps. Modeling of the designed THS is conducted followed by the description of operation strategies and control logics of the THS. Finally, the dynamic simulation of the designed THS is conducted based on Fortran. Results show, the proposed power system meets the need of the design requirements to store heat for 18 h during a day and provide 500 MWth for peak demand for the rest of the day.

Structural and Magnetic Properties of Co2MnSi Heusler Alloy Films

  • Lim, W.C.;Okamura S.;Tezuka N.;Inomata K.;Bae, J.Y.;Kim, H.J.;Kim, T.W.;Lee, T.D.
    • Journal of Magnetics
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    • v.11 no.1
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    • pp.8-11
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    • 2006
  • Recently half-metallic full-Heusler alloy films have attracted significant interests for spintronics devices. As these alloys have been known to have a high spin polarization, very large TMR ratio is expected in magnetic tunnel junctions. Among these alloys, $Co_2MnSi$ full-Heusler alloy with a high spin polarization and a high Curie temperature is considered a good candidate as an electrode material for spintronic devices. In this study, the magnetic and structural properties of $Co_2MnSi$ Heusler alloy films were investigated. TMR characteristics of magnetic tunnel junctions with a $Co_2MnSi/SiO_2/CoFe$ structure were studied. A maximum MR ratio of 39% with $SiO_2$ substrates and 27% with MgO(100) substrates were obtained. The lower MR ratio than expectation is considered due to off-stoichiometry and atomic disorder of $Co_2MnSi$ electrode together with oxidation of the electrode layer.

Thin Film Encapsulation with Organic-Inorganic Nano Laminate using Molecular Layer Deposition and Atomic Layer Deposition

  • Yun, Gwan-Hyeok;Jo, Bo-Ram;Bang, Ji-Hong;Seong, Myeong-Mo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.270-270
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    • 2016
  • We fabricated an organic-inorganic nano laminated encapsulation layer using molecular layer deposition (MLD) combined with atomic layer deposition (ALD). The $Al_2O_3$ inorganic layers as an effective single encapsulation layer were deposited at 80 degree C using ALD with alternating surface-saturation reactions of TMA and $H_2O$. A self-assembled organic layers (SAOLs) were fabricated at the same temperature using MLD. MLD and ALD deposition process were performed in the same reaction chamber. The prepared SAOL-$Al_2O_3$ organic-inorganic nano laminate films exhibited good mechanical stability and excellent encapsulation property. The measurement of water vapor transmission rate (WVTR) was performed with Ca test. We controlled thickness-ratio of organic and inorganic layer, and specific ratio showed a lowest WVTR value. Also this encapsulation layer contained very few pin-holes or defects which were linked in whole area by defect test. To apply into real OLEDs panels, we controlled a film stress from tensile to compressive and flexibility defined as an elastic modulus with organic-inorganic ratio. It has shown that OLEDs panel encapsulated with nano laminate layer exhibits better properties than single layer encapsulated in acceleration conditions. These results indicate that the organic-inorganic nano laminate thin films have high potential for flexible display applications.

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The Observation of Fatigue Striations for Aluminum Alloy by Atomic Force Microscope(AFM) (원자력 현미경(AFM)에 의한 알루미늄 합금의 피로 스트라이에이션 관찰)

  • Choe, Seong-Jong;Gwon, Jae-Do
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.4 s.175
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    • pp.955-962
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    • 2000
  • Scanning Probe Microscope (SPM) such as Scanning Tunneling Microscope (STM) and Atomic Force Microscope (AFM) was shown to be the powerful tool for nano-scale characterization of a fracture surface . AFM was used to study cross sectional profiles and dimensions of fatigue striations in 2017-T351 aluminum alloy. Their widths (SW) and heights (SH) were measured from the cross sectional profiles of three-dimension AFM images. The following results that will be helpful to understand the fatigue crack growth mechanism were obtained. (1) Coincidence of the crack growth rate with the striation width was found down to the growth rate of 10-5 mm/cycle. (2) The relation of SH=0.085(SW)1.2 was obtained. (3) The ratio of the striation height to its width SH/SW did not depend on the stress intensity factor range K and the stress ratio R. (4) Not only the SW but also the SH changed linearly with the crack tip opening displacement (CTOD) when plotted in log-log scale. From these results, the applicability of the AFM to nano-fractography is discussed.