• Title/Summary/Keyword: atomic ratio

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Comparison of the Cylindrical Geometry and the Planar Geometry for the Near-Field Radionuclides Transport Model (방사성 폐기물 처분장내 충전물질에서의 핵종 이동 모델의 원주좌표계와 평면좌표계에서 결과 비교)

  • Kang, Chul-Hyung;Han, Kyong-Won;Park, Hun-Hwee
    • Nuclear Engineering and Technology
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    • v.23 no.1
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    • pp.41-48
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    • 1991
  • Many of the analyses of the transient radionuclide migration are approximated by an one-dimensional geometry and/or planar geometry. To validate these approximations, one should prove that these are reasonable and proper approximations. In this paper, the approximation which was in the study of the transport through backfill into a fissure is tried to validate. In that analysis, a cylindrical geometry was approximated by a planar geometry. The numerical illustrations show that the planar approximation agrees very well with the result of the cylindrical geometry for a ratio of the backfill outer radius to the waste form radius closed to unity. Even for a larger ratio of the two radii, the numerical difference is relatively small. Also the planar approximation which was used in the analysis gives conservative estimates.

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Characteristics of Vanadium Oxide Grown by Atomic Layer Deposition for Hole Carrier Selective Contacts Si Solar Cells (실리콘 전하선택접합 태양전지 적용을 위한 원자층 증착법으로 증착된 VOx 박막의 특성)

  • Park, Jihye;Chang, Hyo Sik
    • Korean Journal of Materials Research
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    • v.30 no.12
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    • pp.660-665
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    • 2020
  • Silicon heterojunction solar cells can achieve high conversion efficiency with a simple structure. In this study, we investigate the passivation characteristics of VOx thin films as a hole-selective contact layer using ALD (atomic layer deposition). Passivation characteristics improve with iVoc (implied open-circuit voltage) of 662 mV and minority carrier lifetime of 73.9 µs after post-deposition annealing (PDA) at 100 ℃. The improved values are mainly attributed to a decrease in carbon during the VOx thin film process after PDA. However, once it is annealed at temperatures above 250 ℃ the properties are rapidly degraded. X-ray photoelectron spectroscopy is used to analyze the chemical states of the VOx thin film. As the annealing temperature increases, it shows more formation of SiOx at the interface increases. The ratio of V5+ to V4+, which is the oxidation states of vanadium oxide thin films, are 6:4 for both as-deposition and annealing at 100 ℃, and 5:5 for annealing at 300 ℃. The lower the carbon content of the ALD VOx film and the higher the V5+ ratio, the better the passivation characteristics.

Optimization of a Radio-frequency Atomic Magnetometer Toward Very Low Frequency Signal Reception

  • Lee, Hyun Joon;Yu, Ye Jin;Kim, Jang-Yeol;Lee, Jaewoo;Moon, Han Seb;Cho, In-Kui
    • Current Optics and Photonics
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    • v.5 no.3
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    • pp.213-219
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    • 2021
  • We describe a single-channel rubidium (Rb) radio-frequency atomic magnetometer (RFAM) as a receiver that takes magnetic signal resonating with Zeeman splitting of the ground state of Rb. We optimize the performance of the RFAM by recording the response signal and signal-to-noise ratio (SNR) in various parameters and obtain a noise level of 159 $fT{\sqrt{Hz}}$ around 30 kHz. When a resonant radiofrequency magnetic field with a peak amplitude of 8.0 nT is applied, the bandwidth and signal-to-noise ratio are about 650 Hz and 88 dB, respectively. It is a good agreement that RFAM using alkali atoms is suitable for receiving signals in the very low frequency (VLF) carrier band, ranging from 3 kHz to 30 kHz. This study shows the new capabilities of the RFAM in communications applications based on magnetic signals with the VLF carrier band. Such communication can be expected to expand the communication space by overcoming obstacles through the high magnetic sensitive RFAM.

The measurement of oxygen and metal ratio of simulated spent fuels by wet and dry chemical analysis (습식 및 건식법에 의한 모의 사용후핵연료의 O/M비 측정)

  • Choi, Ke Chon;Lee, Chang Heon;Kim, Won Ho
    • Analytical Science and Technology
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    • v.16 no.2
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    • pp.117-124
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    • 2003
  • Oxygen to metal ratio has been measured by wet and dry chemical analysis to study the properties of sintered $UO_2$ pellets and $U_3O_8$ in the lithium reduction process of spent pressurized water reactor fuels. Uranium dioxide pellets simulated for the spent PWR fuels with burnup values of 20,000~60,000 MWd/MtU were prepared by mixing $UO_2$ powder and oxides of fission product elements, pelleting the powder mixture and sintering it at $1,700^{\circ}C$ under a hydrogen atmosphere. For wet chemical analysis, the simulated spent fuels were dissolved with mixed acid (10 M HCl : 8 M $HNO_3$, 2.5 : 1, v/v) using acid digestion bomb technique. The total amount of uranium and fission products added in the simulated spent fuels were measured using inductively coupled plasma atomic emission spectrometry. Weight change of the simulated fuel during its oxydation was measured by thermogravimetry and then the O/M ratio result was compared to that obtained by wet chemical analysis. Influence of $Mo_{0.4}-Ru_{0.4}-Rh_{0.1}-Pd_{0.1}$, quaternary alloy, on the determination of O/M ratio was investigated.

Ultrasonic Examination of Thick Austenitic Stainless Steel Welds and Factors Influence the Sensitivity

  • Palaniappan, M.;Subbaratnam, R.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.23 no.4
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    • pp.372-379
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    • 2003
  • The problems encountered by ultrasonic testing of austenitic stainless steel weld joints are discussed in the paper. Due to low thermal conductivity and the occurrence of single phase between the melting point and the room temperature, coarse and oriented grains are formed in such weld metals more in thick sections. This leads to higher scattering at the grain boundaries and low signal to noise ratio, and extensive beam skewing. Experimental results to understand these problem are explained.

A Brief Review on the Design Factors of Steam Generator U-Tube Assembly for CANDU Type Nuclear Power Plant

  • Park, Nam-Il;Park, June-Soo
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05d
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    • pp.321-326
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    • 1996
  • During the plant operation, steam generator U-tube assembly will potentially be subject to adverse environmental conditions which can cause damages to them. This report addresses the major design factors of CANDU type steam generator which are intended to minimize the potential tube damages. Such factors include U-tube material, high circulation ratio, tube-to-tubesheet joint, tube support design. Also a few suggestions are presented for the design and performance improvement of CANDU type steam generators.

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Reduction of Leakage current Generated by Degradation in Organic Thin Film Transistors using Pattern on Pentacene Surface by Atomic Force Microscope

  • Hwang, Hyun-Doo;Kim, Hyun-Suck;Kim, Chang-Ho;Kim, Jae-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.560-562
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    • 2009
  • In this paper, we proposed a simple method of decreasing the off current generated by degradation for improve the electrical characteristics such as mobility and on/off current ratio by making the line patterns on the pentacene surface between the electrodes using atomic force microscope (AFM) lithography.

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Force Reflecting and Compliant Control for Heavy-Duty Power Manipulators (고하증 원격조작기의 힘반영 유연성 제어)

  • Ahn, Sung-Ho;Yoon, Ji-Sup;Lee, Sang-Jeong
    • Proceedings of the KIEE Conference
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    • 2000.07d
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    • pp.2907-2909
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    • 2000
  • This paper proposes a force reflecting and compliant control scheme for the heavy-duty power manipulators with high ratio gear reducers at its joints. From the experimental results. it can be seen that the proposed scheme has an excellent compliant force control performance.

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Studies on the Determination of Rifampicin by Atomic Absorption Spectrophotometry (원자흡광광도법에 의한 리팜피신의 정량에 관한 연구)

  • 이왕규;김박광;유병기
    • YAKHAK HOEJI
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    • v.29 no.4
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    • pp.220-222
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    • 1985
  • Rifampicin reacts with cupric ion to produce rifampicin-Cu(II) chelate (2:1) at pH 6.5, which can be extracted with methylisobutylketone (MIBK). Therefore, rifampicin can be quantitatively, determined by measuring the quantity of Cu(II) in the organic phase by atomic absorption spectrophotometry. Because higher absorbance ratio was obtained in pH 6.0~7.0, buffer solution at pH 6.5 was used in this measurement. Linear relationship was found between absorbance and concentration in the range of 1.0~4.0${\times}10^{-4}M$. This method might be applicable to the determination of rifampicin in the preparations.

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Preparation of Iron Oxide-mixed ZnO films by Ultrasonic Spray Pyrolysis (초음파분무법을 이용한 산화철이 혼합된 ZnO막의 제조)

  • Choi Mu-Hee;Ma Tae-Young
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.1
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    • pp.58-63
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    • 2006
  • In this Paper, ZnO films mixed with iron oxide were prepared by an ultrasonic spray pyrolysis method. The chemical composition and structural properties as a function of the Fe atomic ratio in the deposition solution were studied. Zinc acetate and ferrous chloride were used as precursors of Zn and Fe, respectively. Fe atomic ratio to Zn varied from 0.15 to 10.0. Substrate temperature was fixed at $250^{\circ}C$. The crystallographic properties and surface morphologies of the films were studied by X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. Electron probe X-ray microanalysis (EPMA) and X-ray photoelectron spectroscopy (XPS) were carried out to analyse the chemical composition and state of Zn and Fe atoms.