• Title/Summary/Keyword: atomic ratio

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DETERMINATION OF BURNUP AND PU/U RATIO OF PWR SPENT FUELS BY GAMMA-RAY SPECTROMETRY

  • Park, Kwang-June;Ju, June-Sik;Kim, Jung-Suk;Shin, Hee-Sung;Chun, Yong-Bum;Kim, Ho-Dong
    • Nuclear Engineering and Technology
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    • v.41 no.10
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    • pp.1307-1314
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    • 2009
  • The isotope ratio of $^{134}Cs/^{137}Cs$ in a spent PWR fuel sample was obtained with a newly developed gamma/neutron combined measuring system at KAERI. Burnup and Pu/U ratio of the spent fuel sample were determined by using the measured isotope ratio and the burnup-isotope ratio correlation equations calculated from the ORIGEN-ARP computer code. The results were compared and evaluated with the chemically determined burnup and Pu/U ratio. As a result of the comparative evaluation, the nondestructively determined burnup and Pu/U ratio values showed a good agreement with the chemically obtained results to within a 4.5% and 0.8% difference, respectively.

Theoretical Calculation and Experimental Verification of the Hf/Al Concentration Ratio in Nano-mixed $Hf_xAl_yO_z$ Films Prepared by Atomic Layer Deposition

  • Kil, Deok-Sin;Yeom, Seung-Jin;Hong, Kwon;Roh, Jae-Sung;Sohn, Hyun-Cheol;Kim, Jin-Woong;Park, Sung-Wook
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.5 no.2
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    • pp.120-126
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    • 2005
  • We have proposed a characteristic method to estimate real composition when multi component oxide films are deposited by ALD. Final atomic concentration ratio was theoretically calculated from the film densities and growth rates for $HfO_2$ and $Al_2O_3$ using ALD processed HfxAhOz mms.W e have transformed initial source feeding ratio during deposition to fins] atomic ratio in $Hf_xAl_yO_z$ films through thickness factors ($R_{HFO_2}$ ami $R_{Al_2O_3}$) ami concentration factor(C) defined in our experiments. Initial source feeding ratio could be transformed into the thickness ratio by each thickness factor. Final atomic ratio was calculated from thickness ratio by concentration factor. It has been successfully confirmed that the predicted atomic ratio was in good agreement with the actual measured value by ICP-MS analysis.

Effect of C/Ti Atomic Ratio of TiCx Raw Powder on the Properties of Ti-Mo-W-TiC Sintered Hard Alloy

  • Nakahara, Kenji;Sakaguchi, Shigeya
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.109-110
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    • 2006
  • We have studied the effect of C/Ti atomic ratio of TiCx (x=0.5, 0.75 and 1.0) raw powder on the properties of the Ti-Mo-WTiC sintered hard alloy. The decrease of C/Ti atomic ratio accelerated the densification in the sintering process. The hardness was remarkably improved up to 1350HV with decreasing the C/Ti atomic ratio because of increase of TiCx phase volume content and its fine dispersion. From the results of electro-chemical tests in acid and 3% NaCl solutions, it was obvious that every alloy had excellent corrosion resistance, which meant about 200 times better than that of WC-Co cemented carbide.

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Effects of Transition Temperature and Atomic Ratio on Glass Formation Tendency in the PbO-B$_2$O$_3$-TiO$_2$-BaO System (PbO-B$_2$O$_3$-TiO$_2$-BaO계의 유리화에 대한 전이온도 및 성분 원소비의 영향)

  • 이선우;심광보;오근호
    • Journal of the Korean Ceramic Society
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    • v.35 no.12
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    • pp.1274-1279
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    • 1998
  • The glass forming ability of the PbO-B2O3-TiO3-BaO system was investigated in relation to transitieon tem-peratures and the atomic ratio between constituents. Glass forming tendency was improved as the tem-peratures and the atomic ratio between constituents. Glass forming tendency was improved as the tem-perature differences between liquidus temperature and crystallization(or glass transition) temperature de-creased and the temperature difference between crystallization and glass transition temperature increases. The atomic ratio could be used as a criterion to deign glass systems. The interposition of B and Ba atoms between Pb and Ti atoms was one of important factors in glass formation.

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Ball-milling Effect on the Sinterability of the $UO_2$ ex-AUC Powder (AUC 공정으로 변환된 $UO_2$ 분말의 소결성에 미치는 Ball-milling효과)

  • Kim, H.S.;Park, C.H.;Park, C.J.;Choi, C.B.;Jung, S.H.;Suk, H.C.
    • Nuclear Engineering and Technology
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    • v.26 no.2
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    • pp.190-196
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    • 1994
  • In order to investigate the ball-milling effect on the property changes of UO$_2$ ex-AUC powder, the sinterability of ball -milled powder was studied in terms of the ball -milling time. Spherical shape was found to be kept for ball-milled UO$_2$ powder and the particle size showed a bimodal distribution, which seems to have a higher packing ratio compared with those having monomodal gaussian distribution. The increase of sintered density of the ball -milled UO$_2$ powder is assumed to be mainly affected by the packing ratio, which increase with longer ball -milling time. It is confirmed that the sinterability of UO$_2$ ex-AUC powder is improved by the ball-milling process.

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INFLUENCE OF SIGNAL-TO-NOISE RATIO ON EDDY CURRENT SIGNALS OF CRACKS IN STEAM GENERATOR TUBES

  • Hur, Do Haeng;Choi, Myung Sik;Shim, Hee-Sang;Lee, Deok Hyun;Yoo, One
    • Nuclear Engineering and Technology
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    • v.46 no.6
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    • pp.883-888
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    • 2014
  • This work presents the influence of noise originating from the tube itself on the detectability and sizing accuracy for laboratory-induced outer diameter axial cracks in nuclear steam generator tubes. The variations of signal amplitude and phase angle of the same cracks were analyzed when increasing the signal-to-noise ratio of the tube itself from 9 to 18. It was experimentally verified that the detectability for small cracks was enhanced by increasing the signal-to-noise ratio. The phase angle also rotated to a value representing the actual position and depth of a crack when increasing the signal-to-noise ratio.

Determination of Boron Isotopic Ratio by Using an Alpha Track Technique

  • Park, Yong-Joon;Pyo, Hyung-Yeal;Song, Kyu-Seok;Song, Byoung-Chul;Jee, Kwang-Yong;Kim, Won-Ho
    • Bulletin of the Korean Chemical Society
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    • v.27 no.10
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    • pp.1609-1612
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    • 2006
  • The determination of the boron isotopic ratio in solutions was achieved by means of a solid state track detector by using an alpha track. The neutron flux was optimized by using a Cd-foil to find the optimum conditions for counting the number of alpha tracks on the selected solid detector caused by the (n, $\alpha$) nuclear reaction of boron. The home-made multi-dot detector plate was utilized in this study to increase the reproducibility of the measurement by uniformly drying the boron solution within the marked circle area on the detector plate. The experimental results of this study verified that the $^{11}B/^{10}B $ isotopic ratio can be measured by observing the number of alpha tracks for different concentrated standard solutions with various isotopic compositions. This technique was applied to the determination of $^{10}B$ enrichment factor in a biological sample for a boron neutron capture therapy.

Microstructure and Mechanical Properties of TiC-Co/Al Composites Prepared by Reaction-Bonded Sintering (반응결합 소결에 의한 TiC-Co/Al 복합체의 미세구조 및 기계적 특성)

  • 한인섭;남기웅;정윤중
    • Journal of the Korean Ceramic Society
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    • v.32 no.2
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    • pp.257-269
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    • 1995
  • The TiC-Co/Al reaction-sintered products were prepared by the infiltration of various Co/Al metal mixture into the preform, and their microstructure, phases, and mechanical properties were investigated. With increasing the atomic ratio of Co/Al, tiC grain shape was changed from spherical to platelet particles, and the grain size increased. The crystalline phases found in the liquid matrix formed by the infiltration of Co/Al metal mixture were determined to be Al5Co2 and AlCo by EDS and XRD, and the two crystalline phases were located dominantly between TiC grains, when the Co/Al atomic ratio was lower than an unity. There was a tendency that the density, bending strength and fracture toughness increase with Co/Al atomic ratio until the infiltrated metal was 100% Co. The maximum value was achieved by the composition containing 100% Co infiltrated metal. The Vickers hardness decreased as Co/Al atomic ratio increased.

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Microstructure and Mechanical Properties of Reaction-Bonded Sintering TiC-Based Composite Prepared by Ni-Ti Metal Infiltration (Ni/Ti 금속침투에 의한 반응결합소결 TiC계 복합체의 미세구조 및 기계적 특성)

  • 한인섭;우상국;김홍수;양준환;정윤중
    • Journal of the Korean Ceramic Society
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    • v.33 no.9
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    • pp.995-1002
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    • 1996
  • The TiC-(Ni/Ti) composites were prepared by reaction bonding between TiC preforms and the melted mixture of Ni/Ti metal the atomic ratio of which were the ranges of 0.3 to 3. And their microstructures phase composi-tions and mechanical properties were investigated. During reaction bonding Ni/Ti metal mixture had a good wettability an permeability with TiC preforms and pore-free and fully dense sintered bodies were fabricated. TiC particle shape changed from spherical to angular platelet-like and grain size was grown with Ni/Ti atomic ratio increasing from 0.3 to 1. whereas grain growth of TiC particle was restrained and its shape changed gain from angular platelet-like to spherical when Ni/Ti atomic ratio was more than 2. Maximum bending strength and fracture toughness were obtained at the Ni/Ti atomic ratio being 1 their values were 582 MPa and 11.1 MPa.m1/2 respectively.

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