• Korean Chemical Engineering Research
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• v.49 no.4
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• pp.485-490
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• 2011

Tetrafluoromethane($CF_4$) has been used as etching and chamber cleaning gases for semiconductor manufacturing processes. These gases need to be removed efficiently because of their strong absorption of infrared radiation and long atmospheric lifetime which causes the global warming effect. We have developed a waterjet gliding arc plasma system in which plasma is combined with waterjet and investigated optimum operating conditions for efficient $CF_4$ destruction through enlarging discharge region and producing large amount of OH radicals. The operating conditions are waterjet flow rate, initial $CF_4$ concentration, total gas flow rate, specific energy input. Through the parametric studies, the highest $CF_4$ destruction of 97% was achieved at 2.2% $CF_4$, 7.2 kJ/L SEI, 9 L/min total gas flow rate and 25.5 mL/min waterjet flow rate.

• Journal of Climate Change Research
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• v.7 no.4
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• pp.433-442
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• 2016

In this study, we examine future changes in surface radiation associated with cloud amount and aerosol emission over East Asia. Data in this study is HadGEM2-CC (Hadley Centre Global Environmental Model version 2, Carbon Cycle) simulations of the Representative Concentration Pathways (RCPs) 2.6/4.5/8.5. Results show that temperature and precipitation increase with rising of the atmosphere $CO_2$. At the end of $21^{st}$ century (2070~2099) relative to the end of $20^{st}$ century (1981~2005), changes in temperature and precipitation rate are expected to increase by $+1.85^{\circ}C/+6.6%$ for RCP2.6, $+3.09^{\circ}C/+8.5%$ for RCP4.5, $+5.49^{\circ}C/10%$ for RCP8.5. The warming results from increasing Net Down Surface Long Wave Radiation Flux (LW) and Net Down Surface Short Wave Radiation Flux (SW) as well. SW change increases mainly from reduced total Aerosol Optical Depth (AOD) and low-level cloud amount. LW change is associated with increasing of atmospheric $CO_2$ and total cloud amount, since increasing cloud amounts are related to absorb LW radiation and remit the energy toward the surface. The enhancement of precipitation is attributed by increasing of high-level cloud amount. Such climate conditions are favorable for vegetation growth and extension. Expansion of C3 grass and shrub is distinct over East Asia, inducing large latent heat flux increment.

• Applied Chemistry for Engineering
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• v.22 no.1
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• pp.31-36
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• 2011

Tetrafluoromethane ($CF_4$) has been used as the plasma etching and chemical vapor deposition (CVD) gas for semiconductor manufacturing processes. However, the gas need to be removed efficiently because of their strong absorption of infrared radiation and the long atmospheric lifetime which cause global warming effects. A waterjet gliding arc plasma system in which plasma is combined with the waterjet was developed to effectively produce OH radicals, resulting in efficient destruction of $CF_4$ gas. Design factors such as electrode shape, electrode angle, gas nozzle diameter, electrode gap, and electrode length were investigated. The highest $CF_4$ destruction of 93.4% was achieved at Arc 1 electrode shape, $20^{\circ}$ electrode angle, 3 mm gas nozzle diameter, 3 mm electrode gap and 120 mm electrode length.

• Proceedings of the Korean Society of Crop Science Conference
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• 2022.10a
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• pp.145-145
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• 2022

South Korea greenhouse gas emissions have increased year by year, resulting in a total emission of 727.6 million tons of CO₂ eq in 2018, a 2.5% increase compared to 2017. Among them, the agricultural sector emitted 21.2 million tons of CO₂ eq., accounting for 2.9% of the total. Among the greenhouse gases emitted from the agricultural sector, a particularly problematic is methane gas emitted from rice paddies. Methane is one of the important greenhouse gases with a global warming potential (GWP) that is about 21 times higher than that of carbon dioxide due to its high infrared absorption capacity despite its relatively short remaining atmospheric period. Since the pattern of methane generation varies depending on the rice variety and ecological type, research related to this is necessary for accurate emission calculation and development of reduction technology. Accordingly, a study was conducted to find out the changes in greenhouse gas emission according to rice varieties and ecology types. As for the rice eco-type cultivar, early maturing cultivar (Haedamssal) and medium-late rice cultivar (Saeilmi) were used. Haedamssal was transplanted on May 25 and June 25, and Saeilmi was transplanted on June 10 and June 25. The amount of methane generated according to the growing day showed a tendency to increase as the planting period was earlier. The difference between varieties was that Haedamssal showed higher methane production than Saeilmi. The total CH₄ flux in the saeilmi was 18.7 kg·h^-1(Jun 10 transplanting), 12.4 kg·h^-1(Jun 25 transplanting) during rice cultivation. Lower methane emission was observed in Saeilmi than in Haedam rice. In addition, the earlier the planting period, the higher the methane emission. This study is the result of the first year of research, and it is planned to investigate the amount of greenhouse gas emission between double cropping and single cropping using wheat cultivation after harvest for each ecological type.

• Journal of the Korean Geotechnical Society
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• v.39 no.11
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• pp.63-70
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• 2023

Underground carbon dioxide (CO₂) storage emerges as a pivotal strategy for mitigating atmospheric CO₂ emissions and addressing global warming concerns. This study investigates techniques to optimize storage efficiency in aquifers, which stand out for their superior capacity compared to other geological layers. The focus is on the application of nonionic and anionic surfactants to enhance CO₂ storage efficiency within confined spaces. A specialized micromodel facilitating fluid flow observation was employed for the evaluation. Experimental results revealed a noteworthy minimum 40% increase in storage efficiency at the lowest injection rate when utilizing nonionic and anionic surfactants, in comparison to pure water injection. Interestingly, no significant variations in storage efficiency were observed based on the ionicity and concentration of the surfactants under investigation. These findings have implications for guiding the selection and concentration determination of surfactants in future underground CO₂ storage endeavors.

• Journal of the Microelectronics and Packaging Society
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• v.30 no.4
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• pp.17-31
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• 2023

Amidst escalating global warming fueled by indiscriminate fossil fuel consumption, concerted efforts are underway worldwide to mitigate atmospheric carbon dioxide (CO₂) levels. Electrochemical CO₂ reduction technology is recognized as a promising and environmentally friendly approach to convert CO₂ into valuable hydrocarbon compounds, deemed essential for achieving carbon neutrality. Copper, among the various materials used as CO₂ reduction electrodes, is known as the sole metal capable of generating C₂₊ compounds. However, low conversion efficiency and selectivity have hindered its widespread commercialization. This review highlights diverse research endeavors to address these challenges. It explores various studies focused on utilizing copper-based electrodes for CO₂ reduction, offering insights into potential solutions for advancing this crucial technology.

• Journal of The Korean Society of Agricultural Engineers
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• v.66 no.3
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• pp.25-37
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• 2024

Global warming-induced drought inflicts significant socio-economic and environmental damage. In Korea, the persistent drought in the southern region since 2022 has severely affected water supplies, agriculture, forests, and ecosystems due to uneven precipitation distribution. To effectively prepare for and mitigate such impacts, it is imperative to develop proactive measures supported by early monitoring systems. In this study, we analyzed the spatiotemporal changes of multiple evapotranspiration-based drought indices, focusing on the flash drought event in the southern region in 2022. The indices included the Evaporative Demand Drought Index (EDDI), Standardized Precipitation Evapotranspiration Index (SPEI) considering precipitation and temperature, and the Evaporative Stress Index (ESI) based on satellite images. The Standardized Precipitation Index (SPI) and SPEI indices utilized temperature and precipitation data from meteorological observation stations, while the ESI index was based on satellite image data provided by the MODIS sensor on the Terra satellite. Additionally, we utilized the Evaporative Demand Drought Index (EDDI) provided by the North Oceanic and Atmospheric Administration (NOAA) as a supplementary index to ESI, enabling us to perform more effective drought monitoring. We compared the degree and extent of drought in the southern region through four drought indices, and analyzed the causes and effects of drought from various perspectives. Findings indicate that the ESI is more sensitive in detecting the timing and scope of drought, aligning closely with observed drought trends.

• Journal of Climate Change Research
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• v.34 no.16
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• pp.6841-6853
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• 2021

The leading modes of the North Pacific jet (NPJ) variability include intensity changes and meridional shifts in jet position on low-frequency time scales. These leading modes of NPJ variability are closely associated with weather and climate conditions spanning from Asia to the United States. In this study, we investigated changes in the NPJ's role as a conduit for U.S. surface air temperature (SAT) anomalies during the boreal winter across the late 1990s. We found that the leading mode of NPJ variability changed from the NPJ intensity changes to meridional shifts in NPJ position across the late 1990s. It leads to the change in the role of the NPJ as a conduit for U.S. SAT anomalies. Before the late 1990s, the variability of NPJ intensity significantly impacted western U.S. SAT anomalies related to the anomalous surface cyclonic circulation over the North Pacific. After the late 1990s, however, the variability of the NPJ's meridional shift significantly influenced the eastern U.S. SAT anomalies in association with the anomalous surface cyclonic circulation over the northern North Pacific. Further analysis and model experiments revealed that the western to central North Pacific Ocean has been warming since the late 1990s and modulates atmospheric baroclinicity. This phenomenon mainly leads to a northward NPJ shift and implies that the eddy-driven mechanism on the NPJ's formation, which acts to enhance the meridional variability of NPJ position, becomes dominant. We conclude that this northward shift of NPJ could have contributed to enhancing the NPJ's meridional shift variability, significantly influencing the eastern U.S. SAT anomalies since the late 1990s.

• Journal of the Korean earth science society
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• v.36 no.2
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• pp.139-157
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• 2015

We investigated the relative errors of satellite-observed Surface Skin Temperature (SST) data caused by sea ice in the northern hemispheric ocean ($30-90^{\circ}N$) during April 16-24, 2003-2014 by intercomparing MODerate Resolution Imaging Spectroradiometer (MODIS) Ice Surface Temperature (IST) data with two types of Atmospheric Infrared Sounder (AIRS) SST data including one with the AIRS/Advanced Microwave Sounding Unit-A (AMSU) and the other with 'AIRS only'. The MODIS temperatures, compared to the AIRS/AMSU, were systematically up to ~1.6 K high near the sea ice boundaries but up to ~2 K low in the sea ice regions. The main reason of the difference of skin temperatures is that the MODIS algorithm used infrared channels for the sea ice detection (i.e., surface classification), while microwave channels were additionally utilized in the AIRS/AMSU. The 'AIRS only' algorithm has been developed from NASA's Goddard Space Flight Center (NASA/GSFC) to prepare for the degradation of AMSU-A by revising part of the AIRS/AMSU algorithm. The SST of 'AIRS only' compared to AIRS/AMSU showed a bias of 0.13 K with RMSE of 0.55 K over the $30-90^{\circ}N$ region. The difference between AIRS/AMSU and 'AIRS only' was larger over the sea ice boundary than in other regions because the 'AIRS only' algorithm utilized the GCM temperature product (NOAA Global Forecast System) over seasonally-varying frozen oceans instead of the AMSU microwave data. Three kinds of the skin temperatures consistently showed significant warming trends ($0.23-0.28Kyr^{-1}$) in the latitude band of $70-80^{\circ}N$. The systematic disagreement among the skin temperatures could affect the discrepancies of their trends in the same direction of either warming or cooling.

• Journal of the Korean earth science society
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• v.26 no.1
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• pp.93-105
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• 2005

Climatological characteristics in the variation of soil temperatures in Korea were investigated using Korea Meterological Administration's observation data. And the impacts of soil moisture on the variation of soil temperature were examined using observed precipitation data. The climatological averages of soil temperatures are ranged from 14.4 to $15.0^{\circ}C$ regardless of depths. And they showed an latitudinal gradient with a warm temperature at the southern region and 'U' shape as in the air temperature with a high value along the coastal region. The relatively higher heat capacity and low conductivity of soil compared to those of the air resulted in the significant delay of the maximum and minimum date with depth. As a results, soil acts as a heat source during winter while a heat sink during summer. Global warming and urban heat island have increased the soil temperatures with an average rate $0.3\~0.5^{\circ}C/10-year$ as in the air temperature during last 30 years $(1973\~2002)$. However, the warming rate is maximized during spring contrary to the winter in the air temperature. The temporal variation of soil temperatures is strongly affected by that of soil moisture through an modification of the heat capacity and heat convection. In general, the increased soil moisture clearly decreased the temporal variations and increased the deep layer soil temperatures during cold season.