• Bulletin of the Korean Chemical Society
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• 제18권7호
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• pp.749-754
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• 1997

Rate constants have been measured spectrophotometrically for the reactions of alkali metal ethoxides (EtOM) with S-p-nitrophenyl 2-thiofuroate (1b) and 2-thiophenethiocarboxylate (2b) in absolute ethanol at 25.0±0.1 ℃. 1b is observed to be more reactive than 2b toward all the EtOM studied. The reactivity of EtOM is in the order EtOK > EtONa > EtO- > EtOLi for both substrates, indicating that K+ and Na+ behave as a catalyst while Li+ acts as an inhibitor in the present system. Equilibrium association constants of alkali metal ions with the transition state (KaTS) have been calculated from the known equilibrium association constants of alkali metal ion with ethoxide ion (Ka) and the rate constants for the reactions of EtOM with 1b and 2b. The catalytic effect (KaTS/Ka) is larger for the reaction of 1b than 2b, and decreases with decreasing the size of the alkali metal ions. Formation of 5-membered chelation at the transition state appears to be responsible for the catalytic effect.

• 한국수자원학회:학술대회논문집
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• 한국수자원학회 2005년도 학술발표회 논문집
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• pp.1053-1057
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• 2005

The occurrence probability (OP) distributions of tide levels using harmonic constants of six tidal gauging stations in Korean coastal zone were estimated and analysed in detail. OP analysis using harmonic constants data of Incheon(Youldo), Mokpo, Yeosu, Pusan, Pohang and Sokcho was carried out and compared with the OP using hourly tidal elevation data which were served through the Internet Homepage by the National Ocean Research Institute. The tidal elevation data were divided by the AHHW (ALLW) value referenced to MSL in order to compare the OP patterns in a relative scale. The OP of the tidal elevation calculated using 38 harmonic tidal constituents relatively well agreed with those of hourly observed tidal elevation data. However, the OP results using four harmonic tidal constituents overestimate the occurrence probability at the peak points and underestimate at the tail-regions of the OP. Especially, the OP patterns of the Sokcho and Pohang tidal gauging stations on the East Sea show totally different patterns and the estimation method using four harmonic constants should be modified and application should be strictly limited on the East Sea areas. The OP patterns are considerably well generated in case of the OP generation using the additional two or three dominant tidal constituents,

• 한국결정성장학회:학술대회논문집
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• 한국결정성장학회 1997년도 Proceedings of the 12th KACG Technical Meeting and the 4th Korea-Japan EMGS (Electronic Materials Growth Symposium)
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• pp.145-145
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• 1997

Recent progress of electric technology requires new piezoelectric crystals having superior properties such as zero temperature coefficients and large electromechanical coupling factors. We have developed a series of new leading chandidates, La$_3$Ga5SiO14(langasite, LGS), La3Nb0.5Ga5.5O14(LNG), La3Ta0.5O14(LTG), to satisfy those requirements. High quality LGS, LNG and LTG single crystals, with dimensions of 2 inches in diameter, were successfully grown by the Czochralski method at a pulling rate of 1mm/h. Since no variation of chemical composition was observed when whole melt in a crucible was crystallized, congruency of these compositions was confirmed. Physical constants such as elastic constants, dielectric constants and piezoelectric constants were measured. Filters and oscillators made of grown LGS, LNG and LTG single crystals showed superior properties such as three times wider passband than that of quartz, low insertion loss and easy processing, Langasite family crystals were shown to be superior materials to other known materials such as quartz, LiTaO$_3$, $\alpha$-AlPO$_4$ and Li$_2$B$_4$O7.

• Archives of Pharmacal Research
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• 제19권4호
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• pp.269-274
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• 1996

The binding interactions between human serum albumin (HSA) and the edible food dyes amaranth, tartrazine and sunset yellow have been studied. Intrinsic association constants and the free energy changes associated with dye-protein binding at physiological pH for amaranth and tartrazine, and at two different pH values for sunset yellow have been calculated from ultrafiltration data. The temperature dependence $(20-40^{\circ}C)$ of the intrinsic association constants at pH 7.4 for amaranth-HSA and tartrazine-HSA mixtures have been measured, from which a plot of the van't Hoff isochore exhibits a marked change in slope around $30^{\circ}C$ indicating a possible change in protein conformation. The number of dye binding sites on HSA is reported for all the above conditions. HSA-ligand binding enthalpies have been used in conjunction with the N-B transitional binding enthalpy for HSA, to calculate the enthalpy for the N-B transition when ligands are bound with the protein.

• 한국과학교육학회지
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• 제31권6호
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• pp.848-863
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• 2011

본 연구는 기본물리상수의 교육적 활용 실태를 탐색하기 위하여 문헌연구를 통해 기본물리상수를 구성하는 구성요소로 수치, 크기, 단위, 차원, 탄생배경 및 측정실험, 물리적 의미를 제안하고, 각각의 측면에서 고등학교 물리 교과서의 내용을 분석하였다. 나아가 계층적 분석과정(Analytic Hierarchy Process, AHP)을 통해 각각의 기본물리상수 별로 강조되는 구성요소의 상대적 중요도를 결정하였다. 이를 바탕으로 기본물리상수에 대한 고등학교 물리교사들의 인식수준을 알아보기 위해 검사도구를 개발하여 서울, 경기, 인천 소재 고등학교 물리교사 124명을 대상으로 기본물리상수에 대한 인식 수준과 교수-학습에의 적용에 대한 인식을 설문조사하였다. 또한, 설문 내용에 대한 심층적인 이해와 구체적인 교수 전략을 알아보기 위하여 교사 6명과의 면담을 시행하였다. 면담 결과 교사들의 기본물리상수에 대한 인식과 구체적인 교육적 활용 실태를 알 수 있었다.

• 분석과학
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• 제9권4호
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• pp.411-415
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• 1996

The new potentially heptadentate $N_7$ ligand 1, 15-bis(2-pyridyl)-2, 5, 8, 11, 14-pentaazapentadecane(pytetren) has been synthesized and characterized by EA, IR, NMR, and mass spectrometry. Its proton association constants (log $K{_H}^n$) and stability constants(log $K_{ML}$) for $Co^{2+}$, $Ni^{2+}$, $Cu^{2+}$, and $Zn^{2+}$ ions were determined at 298.1K and ionic strength=0.100M($KNO_3$) by potentiometry: log $K{_H}^1=9.36$, log $K{_H}^2=9.12$, log $K{_H}^3=8.09$, log $K{_H}^4=6.62$, log $K{_H}^5=4.02$, log $K{_H}^6=2.54$: log $K_{ML}(CO^{2+})=22.67$, log $K_{ML}(Ni^{2+})=26.25$. log $K_{ML}(Cu^{2+})=28.46$, log $K_{ML}(Zn^{2+})=19.90$.

• 대한치과교정학회지
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• 제11권1호
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• pp.31-34
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• 1981

A study of a sample of 81 Korean adolescents was taken to determine the degree of correlation between mandibular anterior teeth size and the size of the canines and premolars. The correlation between the total mesiodistal width of the mandibular permanent incisors and that of maxillary or mandibular canine and first and second premolars was found to be 0.53 and 0.58, respectively. Further , regression constants were determined in an attempt to estimate the buccal segments from the mandibular incisors.

• 물과 미래
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• 제18권2호
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• pp.175-185
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• 1985

본 연구는 유출해석을 위하여 저유함수모델의 상수와 유역의 수문인자 및 지형인자와의 관계를 명백히 할 수 있는 방법에 대하여 고찰하였다. 연구대상유역은 우리나라의 중요수계에 속하는 한강 금강 낙동강 영산강 유역의 8개소유역을 택하였다. 최적상수의 탐색은 수학적 최적치 탐색방법의 하나인 SDFP 법을 사용하였으며 적합성 검정에는 $\chi$2-기준을 적용하였다. 저유함수법과 kinematic wave 이론에 의하여 저유상수와 지대시간을 구하는 공식을 인도하였으며 kinematic wave 모델의 가정치와 저유함수 모델의 최적상수를 기준으로 하여 검토하였다. 주요한 결과를 요약하면 다음과 같다. 1) 저유함수법과 kinematic wave 모델의 상수 사이에는 서로 공통된 관계가 있다. 따라서 이 두 모델의 관계로부터 ⑬식을 얻었다. 2) 위에서 구한 공식을 간단히 하여 산지유역에서 실제적으로 적용될 수 있는 새로운 공식을 제안하였다. 3) 여기에서 제안된 방정식의 적합성을 검정하기 위하여 산지유역의 몇 개 지점에 몇 개의 홍수자료를 적용하여 이 방정식으로 구한 상수를 갖이고 저유함수법에 의하여 유출해석을 하여 제안식의 타당성을 확인하였다.

• Bulletin of the Korean Chemical Society
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• 제11권4호
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• pp.347-350
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• 1990

The association between psoralens and some micelles is measured by the fluorescence quenching of psoralens by methylviologen $(MV^{2+})$ and bromide ion in some ionic micellar solutions. The association constants were estimated to be ca. $10^4$ for all the psoralens studied even though they show different hydrophobicity.

• 한국수자원학회:학술대회논문집
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• 한국수자원학회 2006년도 학술발표회 논문집
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• pp.360-364
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• 2006

The physical characteristics of suspended solid in urban watersheds are estimated and are described the accumulation processes on the urban surface. And build up the accumulation model which has two parameters and three constants. Two parameters are $p_0\;and\;p_{max'}$, and three constants are landuse, clean and traffic constant. Suggested model is applied three industry watershed which has variable area. And simulated results are compared with observed data. The model estimates the real phenomenon and the results are pretty good. The simulated accumulation mass are 1.20, 0.96 and $2.88g/m^2$. The differences of simulation and observation data are about 30%.