• Title/Summary/Keyword: approximation model

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Fluorescence Quenching of Bis-msb by Carbon Tetrachloride in Different Solvents

  • Thipperudrappa, J.;Biradar, D.S.;Lagare, M.T.;Hanagodimath, S.M.;Inamdar, S.R.;Kadadevaramath, J.S.
    • Journal of Photoscience
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    • v.11 no.1
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    • pp.11-17
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    • 2004
  • Fluorescence quenching of l,4-bis [2-(2-methylphenyl) ethenyl]-benzene (Bis-MSB) by carbon tetrachloride in five different solvents namely hexane, cyclohexane, toluene, benzene and dioxane has been carried out at room temperature with a view to understand the quenching mechanisms. The Stern-Volmer plot has been found to be non-linear with a positive deviation for all the solvents studied. In order to interpret these results we have invoked the Ground state complex and Sphere of action static quenching models. Using these models various rate parameters have been determined. The magnitudes of these parameters imply that sphere of action static quenching model agrees well with the experimental results. Hence the positive deviation in the Stem-Volmer plots is attributed to the static and dynamic quenching. Further, with the use of Finite Sink approximation model, it was possible to check whether these bimolecular reactions as diffusion limited and to estimate independently distance parameter R' and mutual diffusion coefficient D. Finally an effort has been made to correlate the values of R'and D with the values of the encounter distance R and the mutual diffusion coefficient D determined using the Edwardis empirical relation and Stokes-Einstein relation.

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Rule-Based Fuzzy-Neural Networks Using the Identification Algorithm of the GA Hybrid Scheme

  • Park, Ho-Sung;Oh, Sung-Kwun
    • International Journal of Control, Automation, and Systems
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    • v.1 no.1
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    • pp.101-110
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    • 2003
  • This paper introduces an identification method for nonlinear models in the form of rule-based Fuzzy-Neural Networks (FNN). In this study, the development of the rule-based fuzzy neural networks focuses on the technologies of Computational Intelligence (CI), namely fuzzy sets, neural networks, and genetic algorithms. The FNN modeling and identification environment realizes parameter identification through synergistic usage of clustering techniques, genetic optimization and a complex search method. We use a HCM (Hard C-Means) clustering algorithm to determine initial apexes of the membership functions of the information granules used in this fuzzy model. The parameters such as apexes of membership functions, learning rates, and momentum coefficients are then adjusted using the identification algorithm of a GA hybrid scheme. The proposed GA hybrid scheme effectively combines the GA with the improved com-plex method to guarantee both global optimization and local convergence. An aggregate objective function (performance index) with a weighting factor is introduced to achieve a sound balance between approximation and generalization of the model. According to the selection and adjustment of the weighting factor of this objective function, we reveal how to design a model having sound approximation and generalization abilities. The proposed model is experimented with using several time series data (gas furnace, sewage treatment process, and NOx emission process data from gas turbine power plants).

The Evaluation of Long-Term Generation Portfolio Considering Uncertainty (불확실성을 고려한 장기 전원 포트폴리오의 평가)

  • Chung, Jae-Woo;Min, Dai-Ki
    • Journal of the Korean Operations Research and Management Science Society
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    • v.37 no.3
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    • pp.135-150
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    • 2012
  • This paper presents a portfolio model for a long-term power generation mix problem. The proposed portfolio model evaluates generation mix by considering the tradeoffs between the expected cost for power generation and its variability. Unlike conventional portfolio models measuring variance, we introduce Conditional Value-at-Risk (CVaR) in designing the variability with aims to considering events that are enormously expensive but are rare such as nuclear power plant accidents. Further, we consider uncertainties associated with future electricity demand, fuel prices and their correlations, and capital costs for power plant investments. To obtain an objective generation by each energy source, we employ the sample average approximation method that approximates the stochastic objective function by taking the average of large sample values so that provides asymptotic convergence of optimal solutions. In addition, the method includes Monte Carlo simulation techniques in generating random samples from multivariate distributions. Applications of the proposed model and method are demonstrated through a case study of an electricity industry with nuclear, coal, oil (OCGT), and LNG (CCGT) in South Korea.

A Study on the Equivalent Model of an External Electrode Fluorescent Lamp Based on Equivalent Resistance and Capacitance Variation

  • Cho, Kyu-Min;Oh, Won-Sik;Moon, Gun-Woo;Park, Mun-Soo;Lee, Sang-Gil
    • Journal of Power Electronics
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    • v.7 no.1
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    • pp.38-43
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    • 2007
  • An External Electrode Fluorescent Lamp (EEFL) has longer lifespan, higher power efficiency and higher luminance than a Cold Cathode Fluorescent Lamp (CCFL). Moreover, it is easy to drive them in parallel. Therefore, the EEFL is expected to quickly replace the CCFL in LCD backlight systems. However, the EEFL has more complex characteristics than the CCFL with a resistive component, because it has both a resistive component by plasma and a capacitive component by external electrode. In this paper, values of resistance and capacitance are measured at several power levels and at several operating frequencies. They are expressed by a numeral formula based on a linear approximation that represents the equivalent resistance and capacitance as a function of power. Then we made block diagram of the equivalent circuit model using numerical expressions. Simulation waveforms and experimental results are presented to verify the feasibility of the equivalent model.

Numerical Study on Flow Patterns in a Stirred Tank with Impeller Types (혼합탱크 내의 임펠라 형태에 따른 유동 특성에 관한 수치해석)

  • Song, Gil-Sub;Oh, Sueg-Young;Oh, Jeong-Jin
    • The KSFM Journal of Fluid Machinery
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    • v.5 no.2 s.15
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    • pp.29-35
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    • 2002
  • The present study is concerned with the flow patterns induced by various impellers in a rectangular tank. Impellers are FBT (Flat blade turbine), PBT (Pitched blade turbine), Shroud turbine, Rushton turbine, and Helical ribbon turbine types. The solutions of flows in moving reference frames require the use of 'moving' cell zone. The moving zone approaches are based on MRF (Multiple reference frame), which is a steady-state approximation and sliding method, which is an unsteady-state approximation. Numerical results using two moving zone approaches we compared with experiments by Ranade & Joshi, which have done extensive LDA measurements of the flow generated by a standard six-bladed Rushton turbine in a cylindrical baffled vessel. In this paper, we simulated the flow patterns with above-mentioned moving zone approaches and impellers. Turbulence model used is RNG $k-{\epsilon}$ model. Sliding-mesh method is more effective than MRF for simulating the rectangular tank with inlet and outlet. RNG $k-{\epsilon}$ model strongly underestimates the velocity of experimental data and velocity by Chen & Kim's model, but it seems to be correctly predicted in overall distribution.

Comparison of PCGM and Parabolic Approximation Numerical Models for an Elliptic Shoal (타원형천퇴에 대한 PCGM과 포물형근사식 수치모형비교)

  • 서승남;연영진
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.6 no.3
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    • pp.216-225
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    • 1994
  • By use of laboratory experiment data set for an elliptic shoal by Berkhoff et al. (1982), both accuracy and Performance tests of numerical results between PCGM (Preconditioned Conjugate Gradient Method) and PA(Parabolic Approximation) are compared. Although both results show good agreement with the experimental data the PA model gives better reproduction of the relatively high amplitudes in the section 4-5 downwave of the shoal, in comparison with the PCGM. The PA model has been proved to be a useful tool for predicting wave transformationsin large shallow water region, but it can be applied only to the case of negligible reflection. On the other hand, there is a need to improve the computational efficiency of the PCGM model which is a finite difference scheme directly derived from the mild slope equation and can handle reflection. By taking the results of th PA model as an input data of the PCGM, the CPU time can be reduced by about 40%.

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The emotional evaluation of color pattern based on information fusion (정보융합 기법을 이용한 칼라 패턴의 감성 평가)

  • 김성환;엄경배;이준환
    • Proceedings of the Korean Institute of Intelligent Systems Conference
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    • 2000.11a
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    • pp.23-27
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    • 2000
  • In this paper, we propose an emotional evaluation model based on information fusion. This model can transform the physical features of a color pattern to the emotional features. Our proposed model consists of the fuzzy logic system and neural network model. The evaluation values produced by them were fused. The model shows comparable performances to the neural network and fuzzy logic system for the approximation of the nonlinear transforms. We believe the evaluated results of a color pattern can be used to the emotion-based color image retrievals.

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Empirical Bayes Estimate for Mixed Model with Time Effect

  • Kim, Yong-Chul
    • Communications for Statistical Applications and Methods
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    • v.9 no.2
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    • pp.515-520
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    • 2002
  • In general, we use the hierarchical Poisson-gamma model for the Poisson data in generalized linear model. Time effect will be emphasized for the analysis of the observed data to be collected annually for the time period. An extended model with time effect for estimating the effect is proposed. In particularly, we discuss the Quasi likelihood function which is used to numerical approximation for the likelihood function of the parameter.

A Study on the Approximation analytical Model of PECVD Topography simulator considering the effect of the presheath (플라즈마 증착 형상 모의 실험기의 앞덮개 효과를 고려한 근사 해석적 모델에 관한 연구)

  • Lee, Kang-Whan;Son, Myung-Sik;Hwang, Ho-Jung
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.36D no.1
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    • pp.90-99
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    • 1999
  • In this work, we consider the effect of the presheath on the ion angular distribution. The recent shows the ion-neutral collision in the presheath and the calculated energy flux with the ion angular distribution at the presheath edge in plasma reactor. We also propose a new approximation analytical model for the ion angular distribution and the energy flux distribution with ion temperature. The ion passing the presheath region, Shows a ion scattering effect without ion-neutral collisions. This because the kinetic energy by the ambipolar diffusion field is changed by the gas collision,. Using the proposed approximation analytical model, we show the simulated results of a deposit profile on variable trench shape.

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