• Title/Summary/Keyword: apparent power

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Aqueous Polymerization of Acrylamide Initiated by Periodic Acid and Its Kinetics

  • Cho, Myung-Rae;Han, Yang-Kyoo;Kim, Bum-Sung
    • Macromolecular Research
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    • v.8 no.4
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    • pp.147-152
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    • 2000
  • The activity of periodic acid as an initiator for the polymerization of acrylamide in aqueous medium was investigated. The rate of polymerization was found to be proportional to the monomer concentration to the 1.5th power in the range of 1.41-5.64 mol/L. The reaction order to the periodic acid concentration was 0.49, which indicated a bimolecular mechanism for the termination reaction in the range of 0.5-4.0$\times$10$\^$-2/ mol/L. Propagation rate increased with raising the temperature according to an Arrhenius expression resulting in the exhibition of an apparent activation energy of 87.8 kJ/mol in the temperature range of 60-80$\^{C}$. The addition of hydroquinone as a radical scavenger stopped the polymerization of acrylamide initiated by periodic acid. These results support that the polymerization proceeds via a radical chain mechanism .

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THERMALLY INDUCED PHASE SEPARATION IN TERNARY POLYMER SOLUTION

  • Jung, Bum-Suk;Kang, Yong-Soo;Jones, Richard-A.L.
    • Proceedings of the Membrane Society of Korea Conference
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    • 1999.07a
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    • pp.79-82
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    • 1999
  • Using Small Angle Light Scattering (SALS), the effect of quench depth on the kinetics of phase separation for ternary solution blends was investigated. The system was composed of two polymers (polystyrene and polybutadiene) and a solvent (toluene). The analyses of the early stage of phase separation were based of the Cahn-Hilliard theory [1,5]. Apparent diffusion coefficients and the fastest mode of fluctuations were evaluated, when quench depth of the system were varied near the critical composition of polymer. In the late stage of phase separation, the domain growth showed a power law with the 1/3 exponent, i.e. $q_m(t)~t^{-1/3}$. For comparison between real images and scattering profiles with time, the image of phase domains with time were obtained by using Laser Confocal Scanning Microscopy (LSCM).

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Stabilization of Low-Temperature Metastable Phase of $ZrO_2$ (저온 준안정상 $ZrO_2$의 안정화)

  • 오영제;정형진;이희수
    • Journal of the Korean Ceramic Society
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    • v.27 no.5
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    • pp.613-618
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    • 1990
  • The pure and 6mol% MgO-doped ZrO2 powders were prepared by hot petroleum drying method. The power characterization of homogeneous fine powder was indentified by the method of thermal analysis, BET and electron microscope. The transformation, content of t-ZrO2, crystallite size and apparent strain were measured by X-ray diffraction technique. The prepared powders were transformed in order of amorphouslongrightarrowmetastable cubic ZrO2longrightarrowmetastable tetragonal ZrO2longrightarrowstable monoclinic ZrO2 by a adequate heat treatment. The stabilization of metastable phase can be discussed in terms of energetial concept ; the difference of surface energy and internal strain in particle.

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Removal Method for a Deposit at Sewerage with Polymer Additives (폴리머를 이용한 하수관로에서의 퇴적물 제거 기법)

  • Jeon, Chan-Yeal;Oh, Yool-Kwon;Hwang, Se-Joon
    • Journal of the Korean Society of Safety
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    • v.17 no.4
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    • pp.153-159
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    • 2002
  • This experimental study is aimed to increasing the velocity in the sewerage and also development of easy removal method for a corrosion and sand in the flow pipe. And the result by the increasing the out flow per unit time, diameter of sewerage pipe is becoming small size, cut down the construction fee and the same time reducing the tubulent flow pattern in the flow pipe. As a result of detected experimental velocity signal from the probe in the test wall surface, reducing the pump power and increasing the out flow unit time. Apparent water velocity decreases as the value of void ratio increases depends on the varies center of pipe.

Design and Fabrication of a Partial Discharge Analyzer (부분방전 분석장치의 설계 및 제작)

  • Song, Jae-Yong;Moon, Seung-Bo;Cha, Myung-Soo;Kil, Gyung-Suk
    • Proceedings of the KIEE Conference
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    • 2006.07c
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    • pp.1517-1518
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    • 2006
  • This paper describes the design and fabrication of a partial discharge(PD) analyzer to evaluate insulation performance for low-voltage electrical and electronic devices. The analyzer consists of an adjustable AC power supply, a coupling network, an amplifier, a shielding encloser, a sample-hold (S/H) circuit and a data acquisition (DAQ) board. The analyzer holds the height of PD pulse for $10{\mu}s$ by the S/H circuit, and this makes possible to measure PD pulses having fast rise and short duration by a low speed analog-to-digital (A/D) converter. The data are transmitted to the personal computer through the DAQ board, and the designed analysis program calculate apparent charges, discharge inception and extinction voltages.

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A new approach to determine batch size for the batch method in the Monte Carlo Eigenvalue calculation

  • Lee, Jae Yong;Kim, Do Hyun;Yim, Che Wook;Kim, Jae Chang;Kim, Jong Kyung
    • Nuclear Engineering and Technology
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    • v.51 no.4
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    • pp.954-962
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    • 2019
  • It is well known that the variance of tally is biased in a Monte Carlo calculation based on the power iteration method. Several studies have been conducted to estimate the real variance. Among them, the batch method, which was proposed by Gelbard and Prael, has been utilized actively in many Monte Carlo codes because the method is straightforward, and it is easy to implement the method in the codes. However, there is a problem when utilizing the batch method because the estimated variance varies depending on batch size. Often, the appropriate batch size is not realized before the completion of several Monte Carlo calculations. This study recognizes this shortcoming and addresses it by permitting selection of an appropriate batch size.

Characteristics of Noise Emission from Wind Turbine According to Methods of Power Regulation (파워 조절 방법에 따른 풍력 터빈의 방사 소음 특성)

  • Cheong, Cheol-Ung;Cheung, Wan-Sup;Shin, Su-Hyun;Chun, Se-Jong;Choi, Yong-Moon;Jung, Sung-Soo
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.16 no.8 s.113
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    • pp.864-871
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    • 2006
  • In the development of electricity generating wind turbines for wind farm application, only two types have survived as the methods of power regulation; stall regulation and full span pitch control. The main purpose of this paper is to experimentally identify the characteristics of noise emission of wind turbines according to the power regulation types. The sound measurement procedures of IEC 61400-11 are applied to field test and evaluation of noise emission from each of 1.5 MW and 660 kW wind turbines (WT) utilizing the stall regulation and the pitch control for the power regulation, respectively. Apparent sound power level, wind speed dependence, third-octave band levels and tonality are evaluated for both of WTs. It is observed that equivalent continuous sound pressure levels (ECSPL) of the stall control type of WT continue to increase with increasing wind speed whereas those of the pitch control type of WT show less correlation with wind speed. These observed characteristics are believed to be due to the different airflow patterns around the blade between the stall regulation and the pitch control types of WT; the airflow on the suction side of blade in the stall types of WT are separated at the high wind speed. It is also found that the 1.5 MW WT using the stall control emits lower sound power than 660 kW one using the pitch control at wind speeds below 8m/s, whereas sound power of the former becomes higher than that of the latter in the wind speed over 8m/s. This wind-speed dependence of sound power leads to the very different noise omission characteristics of WTs depending on the seasons because the average wind speed in summer is lower than 8m/s whereas that in summer is higher. Based on these experimental observations, it is proposed that, in view of environmental noise regulation, the developer of wind farm should give enough considerations to the choice of power regulation of their WTG based on the weather conditions of potential wind farm locations.

Rheological Properties of Pear Juice Concentrates (배주스 농축액의 리올로지 특성)

  • Choi, Hee-Don;Kim, Kyung-Tack;Hong, Hee-Do;Lee, Boo-Yong;Kim, Sung-Su
    • Korean Journal of Food Science and Technology
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    • v.27 no.6
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    • pp.845-851
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    • 1995
  • To improve the utilization of pear in its processing, the cloudy and clear juice concentrates were prepared and their rheological properties were investigated in the range of temperatures($5{\sim}60^{\circ}C$) and concentrations($15{\sim}60^{\circ}Brix$). Pear juice concentrates showed flow behavior close to Newtonian fluids. Their flow behavior was also explained by applying Power law model and Herschel-Bulkley model. Flow behavior index did not have good correlation with concentration, but decreased with the increase of temperature, showing pseudoplastic properties. Consistency index increased with the increase of concentration and with the decrease of temperature. The effect of temperature and concentration on the apparent viscosity at 1500 1/s shear rate was examined by applying Arrhenius equation. The activation energy for flow of the cloudy and clear pear juice concentrates increased from $1.5140{\times}10^4\;to\;3.4141{\times}10^4\;J/kg{\cdot}mol$, and from $1.4762{\times}10^4\;to\;3.4963{\times}10^4\;J/kg{\cdot}mol$ with the increase of concentration, respectively. The influence of temperature on the apparent viscosity was more pronounced at higher concentration. And the concentration-dependent constant A decreased from $0.0789\;to\;0.0484^{\circ}Brix^{-1}$, and from $0.0786\;to\;0.0476^{\circ}Brix^1$ with the increase of temperature, respectively.

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Bioequivalence of Enteric-coated Omeprazole Products (오메프라졸 장용성제제에 대한 생물학적 동등성 평가)

  • Kim, Chong-Kook;Jeong, Eun-Ju;Lee, Eun-Jin;Shin, Hee-Jong;Lee, Won-Keun
    • Journal of Pharmaceutical Investigation
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    • v.23 no.1
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    • pp.41-49
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    • 1993
  • The bioequivalence of two omeprazole enteric-coated products was evaluated in 16 normal male volunteers (age 26-32 yr, body weight 57-75 kg) following single oral administration. Test product was enteric-coated KD-182 tablet (Chong Kun Dang Corp., Korea) and reference product was $Rosec^{\circledR}$ capsule containing enteric-coated pellets of omeprazole (Yuhan Corp., Korea). Both products contain 20 mg of omeprazole. One tablet or capsule of the test or the reference product was administered to the volunteers, respectively, by randomized two period cross-over study ($2\;{\times}\;2$ Latin square method). Average drug concetrations at each sampling time and pharmacokinetic parameters calculated were not significantly different between two products(p>0.05); the area under the concentrationtime curve to last sampling time (8 hr) $(AUC_{0-8hr})$ $(1946.5{\pm}675.3\;vs\;2018.3{\pm}761.6\;ng{\cdot}hr/ml)$, AUC from time zero to infinite $(AUC_{o-\infty})$ $(2288.6{\pm}1212.8\;vs\;2264.9{\pm}1001.3\;ng{\cdot}hr/ml)$, maximum plasma concentration $(C_{max})$ $(772.5{\pm}283.3\;vs\;925.8{\pm}187.7\;ng/ml)$, time to maximum plasma concentration $(T_{max})$ $(2.38{\pm}1.06\;vs\;2.34{\pm}1.09\;hr)$, apparent elimination rate constant $(k_{\ell})$ $(0.5339{\pm}0.2687\;vs\;0.5769 {\pm}0.2184\;hr^{-I})$, apparent absorption rate constant $(k_a)$ $(1.1536{\pm}0.5278\;vs\;0.9739{\pm}0.9507 hr^{-1})$ and mean residence time (MRT) $(3.13{\pm}0.73\;vs \;3.41{\pm}1.04\;hr)$. The differences of mean $(AUC_{0-8hr})$, $C_{max}$, $T_{max}$ and MRT between the two products (3.69, 19.83, 1.32 and 8.99%, respectively) were less than 20%. The power $(1-{\beta})$ and treatment difference $(\triangle)$ for $AUC_{o-8hr}$ $C_{max}$ and MRT were more than 0.8 and less than 0.2, respectively. Although the power for $T_{max}$ was under 0.8, $T_{max}$ of the two products was not significantly different each other(p>0.05). These results suggest that the bioavailability of KD-182 tablet is not significantly different from that of $Rosec^{\circledR}$ capsule. Therefore, two products are bioequivalent based on the current results.

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Rheological Characteristics and Viscosity Prediction Models of Tomato Ketchup Suspensions (토마토케찹 현탁액의 리올로지 특성과 점성예측모델)

  • Ha, Sung-Kwon;Choi, Yong-Hee
    • Korean Journal of Food Science and Technology
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    • v.20 no.6
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    • pp.812-819
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    • 1988
  • Rheological properties of rehydrated suspensions of freeze dried tomato ketchup were measured by Brabender Viscotron at the temperature range of $30-90^{\circ}C$, at the concentration of 15-50%, and at the shear rate of $0-250sec^{-1}$. At the shear rate of $0-210sec^{-1}$, tomato ketchup was found to be a thixotropic food product. The values of flow behavior index, consistency index and yield stress at the shear rate of $0-210sec^{-1}$, at the temperature of $30^{\circ}C$ and at the concentration of 33% , were 0.2131, 22.5047 $Pa\;sec^{-n}$, and 8.544 Pa, respectively. It was found that the apparent viscosity model for temperature was expressed by Andrade model and the model for concentration was expressed by Power model, and the model for both temperature and concentration was described by exponential and power models. The activation energies at the concentrations of 15, 20, 30, 33, 40, and 50% were 3.973, 4.985. 5.078, 5.226, 5.357, and 7.655 $kcal/g{\cdot}mole$, respectively.

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