• Title/Summary/Keyword: antimony

Search Result 229, Processing Time 0.028 seconds

Piezoelectric characteristics of PZ-PT-PMS ceramics according to calcination temperature of PMS (PMS 하소온도애 따른 PZ-PT-PMS 계 세라믹 압전특성)

  • Lee, D.J.;Jeong, S.H.;Kim, H.H.;Park, S.K.;Lim, K.J.
    • Proceedings of the KIEE Conference
    • /
    • 1997.07d
    • /
    • pp.1510-1512
    • /
    • 1997
  • Piezoelectric characteristics of lead zirconate(PZ)-lead titanate(PT)-lead manganese antimony(PMS) ceramics with the various changes of calcination temperature in PMS were prepared. The range of their sintering temperature was from $1100^{\circ}C$ to $1250^{\circ}C$. The electro-mechanical properties of PZ-PT-PMS ceramics such as piezoelectric constant, electro-mechanical coupling coefficient, and mechanical quality factor are measured as a function of the calcination temperature of PMS. As increasing the calcination temperature of PMS mechanical quality factor is increased.

  • PDF

Thermoelectric Properties of CoSb3-yTey Prepared by Encapsulated Induction Melting (밀폐유도용해로 제조한 CoSb3-yTey의 열전특성)

  • Kim, Mi-Jung;Shim, Woo-Seop;Ur, Soon-Chul;Kim, Il-Ho
    • Korean Journal of Materials Research
    • /
    • v.16 no.7
    • /
    • pp.412-415
    • /
    • 2006
  • Te-doped $CoSb_3$ was prepared by the encapsulated induction melting, and its doping effects on the thermoelectric properties were investigated. Single phase ${\delta}-CoSb_3$ was successfully obtained by the subsequent annealing at 773 K for 24 hrs. Tellurium atoms acted as electron donors by substituting antimony atoms. Thermoelectric properties were remarkably improved by the appropriate doping. Dimensionless figure of merit was obtained to be 0.83 at 700K for the $CoSb_{2.8}Te_{0.2}$ specimen.

Study on the Thermal Degradation of Poly(n-bulyl methacrylate) (Poly(n-butyl methacrylate)의 열분해에 관한 연구)

  • Kwak, Ki-Chul;Seul, Soo-Duk;Sohn, Jin-Eon
    • Elastomers and Composites
    • /
    • v.23 no.3
    • /
    • pp.213-222
    • /
    • 1988
  • The thermal decomposition of poly(n-butyl methacrylate)(Pn-BMA) was studied using a dynamic and isothermal thermogravimetry in nitrogen gas with 50ml/min at several heating rates from 1 to $20^{\circ}C/min$, and at several heating temperature from 320 to $370^{\circ}C$. The mathematical techniques used for calculation of activation energy were Kissinger, Anderson, Chatterjee-Conrad, Friedman, Fuoss, Ozawa and isolthermal method. The range of activation energies obtained using the several techniques was between 43 and 51Kcal/mol except Chatterjee-Conrad and this range agreed with each other very well. The thermal degradation of Pn-BMA was considered to be carried out by main chain scission.

  • PDF

Effect of Antimony Sesquioxide on the Dielectric Property of Rutile $(TiO_2)$ ($TiO_2$ 의 유전성에 미치는 $Sb_2O_3$ 영향)

  • 윤기현;김창수;강영환
    • Journal of the Korean Ceramic Society
    • /
    • v.17 no.2
    • /
    • pp.75-79
    • /
    • 1980
  • The effect of the additive on the dielectric property of $TiO_2$ containing 0-2.5wt %. $Sb_2O_3$ was investigated as a function of frequency from $5{\times}10^4$ to $6.3{\times}10^7$ cps and temperature from 25 to 375$^{\circ}C$. The dielectric constant increased with increasing $Sb_2O_3$ concentration from 0.25 to 0.5wt.% It is due to space charge polarization caused by increasing anion vacanices. The dielectric constant decreased for further increase in $Sb_2O_3$ concentration. It can be explained by increasing grain size effect rather than space charge polarization.

  • PDF

Preparation of thin films with light transmission conductive by electrospinning (Electrospinning을 통한 광투과 전도성 박막의 제조)

  • Lee, Kui-Young;Kim, Han-Seong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2008.06a
    • /
    • pp.383-384
    • /
    • 2008
  • $SnO_2$ oxides are considerable interest for the development of transparent electrode, thin film resistor and gas sensors. Electrospinning is a class of nanofiber forming processes by which electrostatic forces are employed to control the production of nanofibers. In this study, antimony doped tin oxide thin films were prepared by electrospinning process. Effects of ATO doping concentration and applied voltage on electrical and light transmission properties were investigated.

  • PDF

Multi-Electron Donor Organic Molecules Containing Hydroquinone Methyl-Ether as Redox Active Units

  • Khandelwal, Manish;Hwang, In-Chul;Nair, Prakash Chandran R.;Lee, Jung-Woo
    • Bulletin of the Korean Chemical Society
    • /
    • v.33 no.4
    • /
    • pp.1190-1198
    • /
    • 2012
  • Three hydroquinone dimethyl ether derivatives have been synthesized and characterized by X-ray diffraction. The electron donating properties were evaluated by using UV-vis spectroscopy, cyclic voltammetry and by ESR spectroscopy. The microcrystalline cation-radical salts of the three donor molecules were also isolated by using antimony pentachloride, a single electron Lewis acid oxidant.

Fabrication and Characteristics of High-performance Doped-$SnO_2$ Thin Films for Explosive Gas Sensor

  • Chwa, Sang-Ok;Park, Hee-Chan;Kim, Kwang-Ho
    • The Korean Journal of Ceramics
    • /
    • v.2 no.2
    • /
    • pp.83-88
    • /
    • 1996
  • Long term stability, sensitization in air, and gas sensing behaviors of tin oxide films were investigated with doping of antimony and palladium. The tin oxide films were prepared on a Corning glass by reactive rf sputtering method and tested for detection of hydrogen gas. Sb-doping improved a long-term stability in the base resistance of $SnO_2$ film sensor. A small amount of Pd doping caused the optimum sensor operating temperature to reduce and also enhanced the gas sensitivity, compared with the undoped $SnO_2$ film. Gas sensitivity depended largely on the film thickness. The important sensitization reactions for sensor operating were $(O_{2ads})+e^-\;{\rightarrow}\;2(O_{ads})^-$ on the surface of $SnO_2$ film at elevated temperature in air and a followed reaction of hydrogen atoms with $(O_{ads})^-$ ions.

  • PDF

Experimental fabrication and analysis of thermoelectric devices (복합재료에 의한 열전변환 냉각소자의 개발에 관한 연구)

  • 성만영;송대식;배원일
    • Electrical & Electronic Materials
    • /
    • v.9 no.1
    • /
    • pp.67-75
    • /
    • 1996
  • This paper has presented the characteristics of thermoelectric devices and the plots of thermoelectric cooling and heating as a function of currents for different temperatures. The maximum cooling and heating(.DELTA.T) for (BiSb)$\_$2/Te$\_$3/ and Bi$\_$2/(TeSe)$\_$3/ as a function of currents is about 75.deg. C, A solderable ceramic insulated thermoelectric module. Each module contains 31 thermoelectric devices. Thermoelectric material is a quaternary alloy of bismuth, tellurium, selenium, and antimony with small amounts of suitable dopants, carefully processed to produce an oriented polycrystalline ingot with superior anisotropic thermoelectric properties. Metallized ceramic plates afford maximum electrical insulation and thermal conduction. Operating temperature range is from -156.deg. C to +104.deg. C. The amount of Peltier cooling is directly proportional to the current through the sample, and the temperature gradient at the thermoelectric materials junctions will depend on the system geometry.

  • PDF

Characteristics of ATO Thin Films Prepared by Sol-Gel Process (졸겔법으로 제조된 ATO 박막의 특성 연구)

  • 구창영;이동근;이희영
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2000.11a
    • /
    • pp.192-195
    • /
    • 2000
  • Antimony doped tin oxyde thin films have been deposited by sol-gel method using non-alkoxide precursor SnCl$_2$$.$2H$_2$O as host and SbC1$_3$ as dopant material. Using spin coating method, thin films of thickness up to 200nm have been uniformly deposited on Corning 1737F non-alkali glass substrates. Effect of Sb doping concentration and heat treatment on electrical and optical properties was investigated. Heat treatment was performed at the temperature from 350$^{\circ}C$ to 650$^{\circ}C$ in flowing O$_2$. The resulting ATO films showed widely changing electrical resistivity and optical transmittance values in the visible spectrum depending on the composition and firing condition.

  • PDF

ATO Thin Films Prepared by Reactive lout Beam Sputtering (반응성 이온빔 스퍼터링법에 의해 제조된 ATO박막)

  • 구창영;김경중;김광호;이희영
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2000.07a
    • /
    • pp.361-364
    • /
    • 2000
  • Antimony doped tin oxide (ATO) thin films were deposited at room temperature by reactive ion-beam sputter deposition (IBSD) technique in oxidizing atmosphere utilizing Sb and Sn metal targets. Effect of Sb doping concentration, film thickness and heat treatment on electrical and optical properties was investigated. The thickness of as-deposited films was controlled approximately to 1500 $\AA$ or 2000$\AA$, and Sb concentration to 10.8 and 14.9 wt%, as determined by SEM and XPS analyses. Heat treatment was performed at the temperature from 40$0^{\circ}C$ to 80$0^{\circ}C$ in flowing $O_2$or forming gas. The resulting ATO films showed widely changing electrical resistivity and optical transmittance values in the visible spectrum depending on the composition, thickness and firing condition.

  • PDF