• Title/Summary/Keyword: anti-wear properties

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Synthesis of Poly(glycerol-succinic acid)-dithiocarbamate and Poly(glycerol-succinic acid)-1,3,4-thiadiazole Dendrimers and Their Use as Anti-Wear Oil Additives

  • Kim, Yeong-Joon;Hoang, Quoc-Viet;Kim, Sung-Ki;Cho, Chang-Yong;Kim, Jeongkwon;Chung, Keun-Woo;Kim, Young-Wun
    • Bulletin of the Korean Chemical Society
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    • v.34 no.7
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    • pp.2044-2050
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    • 2013
  • A series of poly(glycerol-succinic acid) dithiocarbamate and 1,3,4-thiadiazole dendrimers, which have potential as anti-wear oil additives, were synthesized. Their anti-wear properties in three different oils (100N, DB-51, and soybean) were evaluated using a four-ball wear tester. The results indicated that thiocarbamate dendrimers have moderate anti-wear properties in DB-51 oil, and 1,3,4-thiadiazole dendrimers exhibited good anti-wear properties in 100N and DB-51 oils. However, dithiocarbamate and 1,3,4-thiadiazole dendrimers were not effective anti-wear additives in soybean oil.

Anti-wear Properties of Thiadiazole and Dithiocarbamate Derivatives (Thiadiazole과 Dithiocarbamate 유도체의 내마모 특성)

  • Kim, Sung-Ki;Hoang, Quoc-Viet;Lee, Ju-Yeon;Kim, Yeong-Joon;Chung, Keun-Woo;Kim, Young-Wun
    • Applied Chemistry for Engineering
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    • v.27 no.5
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    • pp.521-526
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    • 2016
  • Some thiadiazole and dithiocarbamate derivatives were desinged and synthesized in order to study the potential use as anti- wear additives. Their anti-wear properties in three different base oils (DB-51, soybean, and 100 N) were evaluated using a four-ball wear tester (ASTM D4172). The solubilities of dithiocarbamate derivatives in the base oils were better than those of thiadiazole derivatives. The compounds containing oleoyl group rather than nonanoyl group gave good anti-wear properties. The solubilities and anti-wear properties were explained by the polarity of the compounds.

Experimental Study on the Hardness and Wear Characteristics of Bronze Metals (청동소재의 경도 및 마멸특성에 관한 실험적 연구)

  • Kim, Chung-Kyun;Kim, Kyung-Sup
    • Tribology and Lubricants
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    • v.25 no.3
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    • pp.192-196
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    • 2009
  • This paper presents the hardness and wear characteristic of bronze metals, which are manufactured by a sintering process with a high pressuring technology. A bronze metal with a high hardness and anti-wear properties is usually used for a high pressure cylinder and a pin-bush bearing. The new bronze metal in which is manufactured for this experimental study shows very high hardness of 192${\sim}$220 Hv compared with that of a conventional bronze metal of 120${\sim}$140 Hv. The high hardness of new bronze metals is strongly related to the radical reduction of wear volumes and an improved surface roughness of operated worn surfaces. As explained by previous many research works, the improved hardness of nonferrous metals may increase a load-carrying capacity and anti-wear properties of tribological components.

The Study on Field Test of the New Formulated and Commercial Diesel Engine Oils (제조 디젤엔진 오일과 상업용 디젤엔진 오일의 실차시험 연구)

  • 김영운;정근우;강석춘
    • Transactions of the Korean Society of Automotive Engineers
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    • v.9 no.3
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    • pp.51-59
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    • 2001
  • A diesel engine oil formulated in KRICT and a commercial diesel engine oil (API CG-4) were tested by car and their Kinematic Viscosity, TAN, TBN, metal content, additive depletion, anti-wear property and IR analysis were analyzed. From the research, both of the tested oils had almost the same properties f3r the change of TAN and TBN, but the change of Kinematic Viscosity of formulated oil was slightly higher than that of commercial oil. The iron content in the commercial oil increased rapidly from 7000 km while that of the formulated oil was still low. These results were confirmed by the anti-wear test with a 4-ball wear test machine for the each samples. Also, for the commercial oil, the depletion factor of the Zn-DTP which was added as an anti-wear property did not change any more after 7000 km. But, that of the formulated oil changed continuously to 8000 km, which means that the ability to prevent wear of the sliding pairs exists for the formulated oil. From the analysis results of oil properties obtained by field test, it was found that the commercial oil could be used only within 7000 km, but the formulated oil could be used more than 8000 km without severe wear of the sliding parts in the diesel engine.

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Anti-wear performance and life evaluation of wheel bearing type greases

  • Kim Jung-Young;Chung Keun-Wo;Kim Young-Wun;Jo Won-Oh
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2004.11a
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    • pp.111-116
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    • 2004
  • Li-complex and urea type greases (each 10 species) which were furnished by Chang-Am LS, analyzed anti-wear performance into fretting wear tester & four-bail wear tester. from the results of fretting wear test, the wear volume of Li-complex greases are $4.6\~8.9mg\;and\;8.3\~14.4mg$ with the test of urea greases. The anti-wear performance for 4-ball wear test of greases produced results around 0.5mm at the value of WSD. The grease life performance were evaluated by SKF-ROF Grease Tester and wheel bearing life tester. From the results of SKF-ROF tester, the life performance evaluated by whole working time produced results $50\~300hr$ with the Li-complex greases and 100-1000hr with the urea greases. That is to say, in spite of severe condition at the higher of $10^{\circ}C$ reaction temp, the life performance with Urea type greases are much superior to Li-complex type greases. Prior to wheel bearing life tester, the grease selected performance evaluation(=anti-wear test) are tested by wheel bearing tester. In this results, we can confirm results those are similar with SKF-ROF tester. In this study, we can draw two major conclusions, one is that Li-complex greases are superior to urea greases with anti-wear properties and the other is that urea greases are much superior to Li-complex greases with life performance.

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Improvement of the Wear Resistance and Anti-Corrosion of the Trivalent Cr Platings Using Heat Treatments (열처리를 통한 3가 크롬도금층의 마모 및 부식특성 개선)

  • Nam, K.S.;Park, Y.M.;Rha, J.J.;Kwon, S.C.
    • Journal of the Korean Society for Heat Treatment
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    • v.16 no.6
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    • pp.335-340
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    • 2003
  • To improve properties of wear resistance and anti-corrosion of the trivalent chromium platings, oxinitrocarbunsing and steam oxidation were conducted. Armophous trivalent Cr platings could be transformed to chromium carbides of high hardness, that showed low friction and wear rate. Even though micro-cracks were within as platings, superior anti-corrosion property was obtained by these treatments due to healing of cracks at the interface between the trivalent chromium platings and substrate.

Tribological Characteristics with Concentration ZnDTP Additives in Automotive Engine (자동차 엔진의 ZnDTP 첨가제 농도에 따른 트라이볼로지 특성)

  • Oh, Seong-Mo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.8 no.4
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    • pp.697-702
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    • 2007
  • The lubricational characteristics about friction and wear has an important effect on the material quality of surface. Therefore, in the case of automobile engine oil which is used under severe running condition, or therefore, the seizure and anti-scuffing is very important. We have studied the lubricational characteristics of auto engine oil with additives using Falex wear test machine. We have obtained the studied result is as fellows. In order to more improved the surface roughness characteristics adding the P(phosphate) as additives is excellent at a low temperature. Adding the ZnDTP and Ca-phenate is excellent on the anti-wear and extreme pressure properties at the high load. Moreover, when the ZnDTP and P are added, the temperature properties is excellent because the stability is maintained in a high temperature.

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Tribological properties of DLC films on polymers

  • Hashizume, T.;Miyake, S.;Watanabe, S.;Sato, M.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.175-176
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    • 2002
  • Our study is to search for tribological properties of diamond-like carbon (DLC) films as known as anti- wear hard thin film on various polymers. This report deals with the deposition of DLC films on various polymer substrates in vacuum by magnetron radio frequency (RF) sputtering method with using argon plasma and graphite, titanium target. The properties of friction and wear are measured using a ball-on-disk wear -testing machine. The properties of friction and wear have been remarkably improved by DLC coating. Moreover the composition of DLC films has been analyzed by using auger electron spectroscopy(AES). The wear rate of titanium-containing DLC film is lower than that of no-metal-containing DLC film.

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Corrosion and Sliding Properties of the Nickel-Based Alloys for the Valve Seats Application

  • Honda, Tadashi
    • Corrosion Science and Technology
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    • v.7 no.2
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    • pp.92-98
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    • 2008
  • This paper describes the experiments of the corrosion and the sliding tests of the nickel-based alloys for the gate valve seating materials used at high pressure and temperature. The general corrosion rates and IGC susceptibility are tested in pressurized water at 533 K and 575 K and in Strauss test solution. The sliding tests have been done in pressurized water at 293 k, 473 K and 573 k. The alloys containing above 10% chromium may have the anti-corrosion properties that could be applied to the valve seats for the power plants. The good sliding performance and the good pressure tightness are obtained when the disc specimens that have hardness 500 to 600 Hv combined with the seat specimens that have hardness 250 to 410 Hv containing about 40 percent of iron. The large size gate valves sliding tests have certified the test results. The anti-wear properties of the seat alloy and the anti-IGC susceptibility of the disc alloy could be improved by the addition of silicon and niobium, respectively.

Tribological Characteristics with Purity Zirconia of Compression Ring Materials in Piston (피스톤 압축 링 재료의 지르코니아 순도에 따른 트라이볼로지 특성)

  • Oh, Seong-Mo
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.15 no.5
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    • pp.91-96
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    • 2006
  • The friction and wear properties of ceramics are very important in the applications to engineering ceramic parts such as seal rings, pump parts, automobile meter parts, and so on. In this study, the effects of each other purity on the mechanical and tribological properties of purity zirconia ceramics were investigated. Also in order to determine the effects of sliding distance, sliding speed, contact load, friction coefficient, the amount of worn out material at a certain time, and the prepared composites were measured. Crystalline phases and microstructure were examined with XRD and SEM. The results show that we obtained the good properties of friction coefficient and wear resistance at the purity 99.5% of zirconia. than this of the purity 95% were great at the wear amount of worn out material.