• Bulletin of the Korean Chemical Society
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• 제34권7호
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• pp.2044-2050
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• 2013

A series of poly(glycerol-succinic acid) dithiocarbamate and 1,3,4-thiadiazole dendrimers, which have potential as anti-wear oil additives, were synthesized. Their anti-wear properties in three different oils (100N, DB-51, and soybean) were evaluated using a four-ball wear tester. The results indicated that thiocarbamate dendrimers have moderate anti-wear properties in DB-51 oil, and 1,3,4-thiadiazole dendrimers exhibited good anti-wear properties in 100N and DB-51 oils. However, dithiocarbamate and 1,3,4-thiadiazole dendrimers were not effective anti-wear additives in soybean oil.

• 공업화학
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• 제27권5호
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• pp.521-526
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• 2016

알킬그룹과 에스터, 싸이오에스터, 아미드 등의 결합을 가지는 다양한 싸이아다이아졸과 다이싸이오카바메이트 유도체를 분자설계하고 합성하였다. 이들의 내마모제로써 사용 가능성 연구를 위하여 DB-51, 대두유, 100 N에 대한 용해도와 내마모 특성을 분자 구조 및 극성 비교에 따라 고찰하였다. 윤활기유에 대한 용해도는 다이싸이오카바메이트 유도체가 싸이아다이아졸 유도체 보다 좋았다. 싸이아다이아졸 유도체가 다이싸이오카바메이트 유도체 보다는 내마모 특성이 더 우수하였으며, 특히 알킬 그룹이 올레일 그룹일 때 가장 뛰어난 성능을 보여주었다.

• Tribology and Lubricants
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• 제25권3호
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• pp.192-196
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• 2009

This paper presents the hardness and wear characteristic of bronze metals, which are manufactured by a sintering process with a high pressuring technology. A bronze metal with a high hardness and anti-wear properties is usually used for a high pressure cylinder and a pin-bush bearing. The new bronze metal in which is manufactured for this experimental study shows very high hardness of 192${\sim}$220 Hv compared with that of a conventional bronze metal of 120${\sim}$140 Hv. The high hardness of new bronze metals is strongly related to the radical reduction of wear volumes and an improved surface roughness of operated worn surfaces. As explained by previous many research works, the improved hardness of nonferrous metals may increase a load-carrying capacity and anti-wear properties of tribological components.

• 한국자동차공학회논문집
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• 제9권3호
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• pp.51-59
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• 2001

A diesel engine oil formulated in KRICT and a commercial diesel engine oil (API CG-4) were tested by car and their Kinematic Viscosity, TAN, TBN, metal content, additive depletion, anti-wear property and IR analysis were analyzed. From the research, both of the tested oils had almost the same properties f3r the change of TAN and TBN, but the change of Kinematic Viscosity of formulated oil was slightly higher than that of commercial oil. The iron content in the commercial oil increased rapidly from 7000 km while that of the formulated oil was still low. These results were confirmed by the anti-wear test with a 4-ball wear test machine for the each samples. Also, for the commercial oil, the depletion factor of the Zn-DTP which was added as an anti-wear property did not change any more after 7000 km. But, that of the formulated oil changed continuously to 8000 km, which means that the ability to prevent wear of the sliding pairs exists for the formulated oil. From the analysis results of oil properties obtained by field test, it was found that the commercial oil could be used only within 7000 km, but the formulated oil could be used more than 8000 km without severe wear of the sliding parts in the diesel engine.

• 한국윤활학회:학술대회논문집
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• 한국윤활학회 2004년도 학술대회지
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• pp.111-116
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• 2004

Li-complex and urea type greases (each 10 species) which were furnished by Chang-Am LS, analyzed anti-wear performance into fretting wear tester & four-bail wear tester. from the results of fretting wear test, the wear volume of Li-complex greases are $4.6\~8.9mg\;and\;8.3\~14.4mg$ with the test of urea greases. The anti-wear performance for 4-ball wear test of greases produced results around 0.5mm at the value of WSD. The grease life performance were evaluated by SKF-ROF Grease Tester and wheel bearing life tester. From the results of SKF-ROF tester, the life performance evaluated by whole working time produced results $50\~300hr$ with the Li-complex greases and 100-1000hr with the urea greases. That is to say, in spite of severe condition at the higher of $10^{\circ}C$ reaction temp, the life performance with Urea type greases are much superior to Li-complex type greases. Prior to wheel bearing life tester, the grease selected performance evaluation(=anti-wear test) are tested by wheel bearing tester. In this results, we can confirm results those are similar with SKF-ROF tester. In this study, we can draw two major conclusions, one is that Li-complex greases are superior to urea greases with anti-wear properties and the other is that urea greases are much superior to Li-complex greases with life performance.

• 열처리공학회지
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• 제16권6호
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• pp.335-340
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• 2003

To improve properties of wear resistance and anti-corrosion of the trivalent chromium platings, oxinitrocarbunsing and steam oxidation were conducted. Armophous trivalent Cr platings could be transformed to chromium carbides of high hardness, that showed low friction and wear rate. Even though micro-cracks were within as platings, superior anti-corrosion property was obtained by these treatments due to healing of cracks at the interface between the trivalent chromium platings and substrate.

• 한국산학기술학회논문지
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• 제8권4호
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• pp.697-702
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• 2007

마찰 마모에 대한 트라이볼로지 특성은 표면 재질에 대하여 중대한 영향을 끼친다. 더욱이 자동차의 가혹한 운전조건하에서의 엔진오일의 경우 내스커핑성과 시져는 트라이볼로지 특성에 상당히 중요하다. 본 연구에서는 펠렉스 마찰 마모시험기를 이용 첨가제들을 자동차 엔진오일에 널리 쓰이는 윤활기유에 첨가하여 트라이볼로지 특성을 연구하였다. 연구결과 다음과 같은 결론을 얻었다. 엔진오일에 표면거칠기의 특성을 가진 인산염(Phosphate)을 첨가하면 낮은 온도에서 우수하고, ZnDTP와 Ca-phenate를 첨가했을 때 높은 하중에서 내마모성, 극압성이 월등히 뛰어나며, ZnDTP와 P를 첨가했을 때는 높은 온도에서도 안정적으로 온도특성 또한 우수하였다.

• 한국윤활학회:학술대회논문집
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• 한국윤활학회 2002년도 proceedings of the second asia international conference on tribology
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• pp.175-176
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• 2002

Our study is to search for tribological properties of diamond-like carbon (DLC) films as known as anti- wear hard thin film on various polymers. This report deals with the deposition of DLC films on various polymer substrates in vacuum by magnetron radio frequency (RF) sputtering method with using argon plasma and graphite, titanium target. The properties of friction and wear are measured using a ball-on-disk wear -testing machine. The properties of friction and wear have been remarkably improved by DLC coating. Moreover the composition of DLC films has been analyzed by using auger electron spectroscopy(AES). The wear rate of titanium-containing DLC film is lower than that of no-metal-containing DLC film.

• Corrosion Science and Technology
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• 제7권2호
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• pp.92-98
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• 2008

This paper describes the experiments of the corrosion and the sliding tests of the nickel-based alloys for the gate valve seating materials used at high pressure and temperature. The general corrosion rates and IGC susceptibility are tested in pressurized water at 533 K and 575 K and in Strauss test solution. The sliding tests have been done in pressurized water at 293 k, 473 K and 573 k. The alloys containing above 10% chromium may have the anti-corrosion properties that could be applied to the valve seats for the power plants. The good sliding performance and the good pressure tightness are obtained when the disc specimens that have hardness 500 to 600 Hv combined with the seat specimens that have hardness 250 to 410 Hv containing about 40 percent of iron. The large size gate valves sliding tests have certified the test results. The anti-wear properties of the seat alloy and the anti-IGC susceptibility of the disc alloy could be improved by the addition of silicon and niobium, respectively.

• 한국공작기계학회논문집
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• 제15권5호
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• pp.91-96
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• 2006

The friction and wear properties of ceramics are very important in the applications to engineering ceramic parts such as seal rings, pump parts, automobile meter parts, and so on. In this study, the effects of each other purity on the mechanical and tribological properties of purity zirconia ceramics were investigated. Also in order to determine the effects of sliding distance, sliding speed, contact load, friction coefficient, the amount of worn out material at a certain time, and the prepared composites were measured. Crystalline phases and microstructure were examined with XRD and SEM. The results show that we obtained the good properties of friction coefficient and wear resistance at the purity 99.5% of zirconia. than this of the purity 95% were great at the wear amount of worn out material.