• Title/Summary/Keyword: anorthosite

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Occurence of Ilmenite on the Ti-bearing Ore Bodies in Bukcheon, Hadong Area (하동군 북천면 지역 함티타늄광체 내 티탄철석의 산출특성)

  • Kwak, Ji Young;Choi, Jin Beom
    • Journal of the Mineralogical Society of Korea
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    • v.27 no.4
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    • pp.197-205
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    • 2014
  • Study area (Jikjeon-ri) is located in south end of the Hadong anorthositic rocks. And along the south-western boundary, diorite intruded the Hadong anorthosite. Ilmenite ore bodies are extended in both anorthosite and diorite. And their occurrence in the diorite are not studied yet. While no particular textures are found in the ilmenite within the anorthosite, the ilmenite within the diorite shows characteristic exsolution texture, that is, ilmenite phases are separated into rutile and Fe-oxide and the ilmenite and Fe-oxide. MnO composition in ilmenite ratios are 2.14~3.74wt%, it has higher composition in diorite than that in anorthosite. The plagioclase composition display andesine ($An_{28.7-42.9}$) in the diorite and labradorite ($An_{57.1-72.8}$) in the anorthosite in composition. The exsolution of ilmenite has been developed during the cooling of partly melted ilmenite into rutile and Fe-oxides which is related to the intrusion of the diorite.

Dissolution Behavior of Plagioclase in HCl and KOH Solutions (염산과 수산화칼슘 수용액과의 반응에 의한 사장석의 용해 거동)

  • 현성필;김수진
    • Journal of the Mineralogical Society of Korea
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    • v.9 no.2
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    • pp.71-81
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    • 1996
  • Dissolution experiments were conducted to understand chemical nature of weathering of anorthosite from the Hadong area. Anorthosite and plagioclase from it were reacted with HCl or KOH solutions under various conditions concerning such as grain size, initial pH of solutions, and shaking Average composition of plagioclase used in the experiment was Na0.32Ca0.71Al1.71Si2.28O8.Under acidic conditions, solution pH increases rapidly in the initial stage and then gradually to reach palteau. Shaking agitates the reaction rate in the initial stage but does not affect after the system reached steady state. Ca and si concentrations show rapid increase and then gradual increase. Al concentration increases rapidly in the early stage and then decreases. Later decrease was interpreted as the precipitation of an Al-bearing material. Different dissolution rates of different constituents of plagioclase together the with precipitation of al-bearing material might be responsible for the non-stoichiometric dissolution of plagioclase.X-ray diffraction analyses on anorthosite before and after dissolution experiment show dissolution rates differ with different lattice planes of plagioclase. It suggests the crystallographic control on dissolution reaction. X-ray photoelectron spectroscopic result shows that the average composition of plagioclase surface reacted with HCL of initial pH 1.97 for 2000 hours is Na0.20Ca0.26Al1.7Si2.3O8. It means that Na- and Ca-depleted H-feldspar is developed without Al-depleted layer on the surface of plagioclase by reaction with HCl and that dissolution reaction takes place sparsely on the surface of plagioclase. Al and Si are dissolved preferentially over Ca from anorthosite powder in KHO solution. Reaction of acid-reacted anorthosite with KOH solution shows the same Si dissolution behavior as in the fresh anorthosite. This indicates that the Al-depleted and Si-enriched layer does not build up on the acid-reacted surface.

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Estimation of Geochemical Evolution Path of Groundwaters from Crystalline Rock by Reaction Path Modeling (반응경로 모델링을 이용한 결정질암 지하수의 지구화학적 진화경로 예측)

  • 성규열;박명언;고용권;김천수
    • Economic and Environmental Geology
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    • v.35 no.1
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    • pp.13-23
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    • 2002
  • The chemical compositions of groundwaters from the granite areas mainly belong to Ca-HC0$_{3}$ and Na-HC0$_{3}$type, and some of these belong to Ca-(CI+S0$_{4}$) and Na-(CI+S0$_{4}$) type. Spring waters and groundwaters from anorthosite areas belong to Ca-HC03 and Na-HC03 type, respectively. The result of reaction path modeling shows that the chemical compositions of aqueous solution reacted with granite evolve from initial Ca-CI type, via CaHC0$_{3}$ type, to Na-HC0$_{3}$ type. The result of rain water-anorthosite interaction is similar to evolution path of granite reaction and both of these results agree well with the field data. In the reaction path modeling of rain watergranite/anorthosite reaction, as a reaction is progressing, the activity of hydrogen ion decreases (pH increases). The concentrations of cations are controlled by the dissolution of rock-forming minerals and precipitation and re-dissolution of secondary minerals according to the pH. The continuous addition of granite causes the formation of secondary minerals in the following sequence; gibbsite plus hematite, Mn-oxide, kaolinite, silica, chlorite, muscovite (a proxy for illite here), calcite, laumontite, prehnite, and finally analcime. In the anorthosite reaction, the order of precipitation of secondary minerals is the same as with granite reaction except that there is no silica precipitation and paragonite precipitates instead of analcime. The silica and kaolinite are predominant minerals in the granite and anorthosite reactions, respectively. Total quantities of secondary minerals in the anorthosite reaction are more abundant than those in the granite reaction.

Formation of Mixed-layered Chlorite/Vermiculite and Halloysite from Clinochlore by Weathering in Anorthosite in the Sancheong District (산청지역 회장암내 단사녹니석의 풍화에 의한 녹니석/버미큘라이트 혼합층 광물 및 할로이사이트의 생성)

  • Jeong, Gi Young;Kim, Soo Jin
    • Journal of the Mineralogical Society of Korea
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    • v.6 no.2
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    • pp.145-155
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    • 1993
  • Mineralogical, textural, and chemical changes of chlorite by weathering in anorthosite in the Sancheong district were stucdied using X-ray diffraction, scanning electron microscopy, and electron microprobe analysis. Chlorite in anorthosite corresponds to ferroan clinochlore with IIb structural type. It weatheres firstly to regularly mixed-layered chlorite/vermiculite(C/V) and then, to halloysite without the intermediate stage of vermiculite. Clinochlore packet cleaves and transforms to several thin packets of C/V, which subsequently change to halloysite developint fan-sharped structures by large volume increase. Direct halloysitization of C/V is attributed to the rapid weathering of anorthosite.

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A potential displacement marker of the Honam Shear Zone: Gaya anorthosite (호남 전단대의 잠재적 변위 지시자: 가야 지역 회장암체)

  • 권성택;사공희
    • The Journal of the Petrological Society of Korea
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    • v.12 no.4
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    • pp.207-209
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    • 2003
  • The Honam Shear Zone, an important feature in the Phanerozoic geologic history of Korea, has attracted much attention due to its potential tectonic significance. However, little has been known about the displacement amount of the shear zone. Here, we propose a possible displacement marker for the shear zone. The geographic position and peculiar lithology of the Sancheong and Gaya anorthosite bodies in the south-central part of Korea suggest a NE-trending dextral strike slip shear zone that has a displacement of ca. 50 km. This hypothetical shear zone is considered as a part of the Honam Shear Zone since the former has the same trend and shear sense as the latter.

Formation Process and Its Mechanism of the Sancheong Anorthosite Complex, Korea (산청 회장암복합체의 형성과정과 그 메커니즘)

  • Kang, Ji-Hoon;Lee, Deok-Seon
    • Economic and Environmental Geology
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    • v.48 no.6
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    • pp.431-449
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    • 2015
  • The study area is located in the western part of the Precambrian stock type of Sancheong anorthosite complex, the Jirisan province of the Yeongnam massif, in the southern part of the Korean Peninsula. We perform a detailed field geological investigation on the Sancheong anorthosite complex, and report the characteristics of lithofacies, occurrences, foliations, and research formation process and its mechanism of the Sancheong anorthosite complex. The Sancheong anorthosite complex is classified into massive and foliation types of Sancheong anorthosite (SA), Fe-Ti ore body (FTO), and mafic granulite (MG). Foliations are developed in the Sancheong anorthosite complex except the massif type of SA. The foliation type of SA, FTO, MG foliations are magmatic foliations which were formed in a not fully congealed state of SA from a result of the flow of FTO and MG melts and the kinematic interaction of SA blocks, and were continuously produced in the comagmatic differentiation. The Sancheong anorthosite complex is formed as the following sequence: the massive type of SA (a primary fractional crystallization of parental magmas under high pressure)${\rightarrow}$ the foliation type of SA [a secondary fractional crystallization of the plagioclase-rich crystal mushes (anorthositic magmas) primarily differentiated from parental magmas under low pressure]${\rightarrow}$the FTO (an injection by filter pressing of the residual mafic magmas in the last differentiation stage of anorthositic magmas into the not fully congealed SA)${\rightarrow}$the MG (a solidification of the finally residual mafic magmas). It indicates that the massive and foliation types of SA, the FTO, and the MG were not formed from the intrusion and differentiation of magmas which were different from each other in genesis and age but from the multiple fractionation and polybaric crystallization of the coeval and cogenetic magma.

Geometric and Kinematic Characteristics of Fracture System in the Sancheong Anorthosite Complex, Korea (산청 회장암복합체 내 발달하는 단열계의 기하학적·운동학적 특성)

  • Lee, Deok-Seon;Kang, Ji-Hoon
    • The Journal of the Petrological Society of Korea
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    • v.25 no.4
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    • pp.389-400
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    • 2016
  • The study area, which is located in the southeastern part of the Jirisan province of the Yeongnam massif, Korea, consists mainly of the Precambrian Sancheong anorthosite complex and the Jirisan metamorphic rock complex, the Mesozoic granitoids which intruded them. Several fracture sets with various geometric indicators, which determine their relative timing and shear sense, are well observed in the Sancheong anorthosite complex. The aim of this study is to determine the development sequence of extension fractures, the movement sense and development sequence of shear fractures in the Sancheong anorthosite complex on the basis of detailed analysis of their geometric indicators. This study suggests fracture system of the Sancheong anorthosite complex was formed at least through five different fracturing events, named as Dn to Post-Dn+3 phases. (1) Dn phase: extension fracturing event of NNW trend. The fracture set experienced the reactivations of dextral ${\rightarrow}$ sinistral shearing with the change of stress field afterward. (2) Dn+1 phase: extension fracturing event of (N)NE trend. The fracture set experienced the reactivations of sinistral ${\rightarrow}$ sinistral ${\rightarrow}$ dextral. (3) Dn+2 phase: extension fracturing event of NW trend. The fracture set experienced the activated of dextral shearing. (4) Dn+3 phase: extension fracturing event of N-S trend. (5) Post-Dn+3 phase: extension fracturing event of (E)NE trend. Dn deformation formed during the early Songnim orogeny. Dn+1 deformation formed during the late Songnim orogeny. Dn+2 deformation formed during the Daebo orogeny. Dn+3 deformation formed during the Bulguksa orogeny.

Morphology of Halloysite Particles and Aggregates in the Weathering of Anorthosite (회장암 풍화과정에서 생성되는 할로이사이트 입자 및 집합체의 형태)

  • 정기영;김영호
    • Journal of the Mineralogical Society of Korea
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    • v.9 no.2
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    • pp.64-70
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    • 1996
  • Early weathering products of anorthosite were investigated by using scanning electron microscopy in order to trace the development of halloysite particles and aggregates. Tiny short tubes or spheres precipitate on the plagioclase surface in the initial stage of weathering and form the compact globular aggregates. With continued growth, several globules are coalesced into wrinkled halloysite aggregates, and short tubes or spheres in globules grow into long tubes forming sheaf-like aggregates. Particle shape of halloysite varies with changing supersaturation degree of weathering solution, and determines the morphology of halloysite aggregates.

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Ore Mineralization of The Hadong Fe-Ti-bearing Ore Bodies in the Hadong-Sancheong Anorthosite Complexes (하동-산청 회장암체 내 부존하는 하동 함 철-티탄 광체의 광화작용)

  • Lee, In-Gyeong;Jun, Youngshik;Choi, Sang-Hoon
    • Economic and Environmental Geology
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    • v.50 no.1
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    • pp.35-44
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    • 2017
  • The Hadong-Sancheong Proterozoic anorthosite complex occurs in the southwestern region of the Ryongnam massif. The geology of the area mainly consists of metamorphic rocks of the Jirisan metamorphic complex as basement rocks, charnockite, and the Hadong-Sancheong anorthosite, which are intruded by the Mesozoic igneous rocks. Hadong-Sancheong anorthosite complex is divided into the Sancheong anorthosite and the Hadong anorthosite which occur at north-southern and south area of the Jurassic syenite, respectively. The Hadong Fe-Ti-bearing dike-like ore bodies developed intermittently in the Hadong anorthosite with north-south direction and extend about 14 km. The Hadong Fe-Ti-bearing ore bodies consist mainly of magnetite and ilmenite with rutile, titanite, and minor amounts of sulfides(pyrrhotite, pyrite, chalcopyrite and sphalerite). The Hadong Fe-Ti-bearing ore bodies show a paragenetic sequence of magnetite-ilmenite ${\rightarrow}$ magnetite-ilmenite-pyrrhotite ${\rightarrow}$ ilmenite-pyrrhotite-rutile-titanite(and/or pyrite) ${\rightarrow}$ sulfides. Equilibrium thermodynamic interpretation of the mineral paragenesis and assemblages indicate that early Fe-Ti-bearing ore mineralization in the ore bodies occurs at about $700^{\circ}C$ which corresponds to oxygen fugacity of about $10^{-11.8}{\sim}10^{-17.2}$ atm with the decrease tendency of sulfur fugacity to about $10^0$ atm as equilibrium of $Fe_3O_4-FeS$. The change of ore mineral assemblages from Fe-Ti-bearing minerals to sulfides in late ore mineralization of the ore bodies indicates that oxygen fugacity would have slightly decreased to ${\geq}10^{-20.2}$ atm and increased sulfur fugacity to ${\geq}10^0$ atm.

Petrological Study on the Intermediate-basic Plutonic Rocks in the Southwestern Part of the Korean Peninsula (한반도 서남부에 분포하는 중성-염기성 심성암류에 대한 암석학적 연구)

  • Kim, Yong-Jun;Park, Jae-Bong;Park, Byung-Kyu
    • Journal of the Korean earth science society
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    • v.27 no.5
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    • pp.528-538
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    • 2006
  • Main aspect of this study is to clarify the petrochemistry and petrogenesis of intermediated-basic plutons located in the southwestern part of the Korean peninsula. These Intermediated-basic plutons consist of Pre-Cambrian anorthosite-gabbro, Triassic hornblende gabbro (Jirisan area), Jurassic diorite-syente (Jirisan and north area) and Cretaceous gabbro-diorite (south area). The Massif type anorthosite has multi intrusions, where each one intruded by gabbroic rocks, composed of gabbro, norite, troctolite and leucogabbro. In the variation diagram of the major-minor composition, AMF and Pl-Px-Ol diagrams, we suggest that intermediated-basic plutons in the southwestern part of the Korea show a trend consistent to Daly's value and calc-alkaline rock series. Accoding to REE (La/Yb)cw and Eu/Sm, these plutons are enriched with LREE than HREE, and emplaced by the tectonic setting in continent and/or continental margin.