• Title/Summary/Keyword: anodic polarization test

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Anodic Polarization Characteristics in Ti-20%Zr(-5%Cr) Alloys for Dental Castings (치과주조용 Ti-20%Zr(-5%Cr)합금의 양극분극특성)

  • Jung, Jong-Hyun;Han, Sok-Yoon
    • Journal of Technologic Dentistry
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    • v.26 no.1
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    • pp.41-48
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    • 2004
  • Ti-20%Zr(-5%Cr) alloys not containing harmful Al and V were newly designed in order to reveal their possibility for dental casting and melted in an arc melting and casting furnace under Ar atmosphere. The corrosion resistance was studied by anodic polarization test. From the observation of anodic polarization behavior, it was found that the corrosion resistance was markedly increased by the addition of Cr. The corrosion resistance of Ti-20%Zr-5%Cr alloy was superior to that in Ti-6%Al-4%V alloy but almost similar to that in CP Ti using in market place today.

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Cryogenic fracture behaviors and polarization characteristics according to sensitizing heat treatment on structural material of the nuclear fusion reactor (핵 융합로 구조재료의 예민화 열처리에 따른 극저온 파괴거동 및 분극특성)

  • Kwon, Il-Hyun;Chung, Se-Hi
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.22 no.2
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    • pp.311-320
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    • 1998
  • The cryogenic fracture behaviors of austenitic stainless steel HN2 developed for nuclear fusion reactor were evaluated quantitatively by using the small punch(SP) test. The electrochemical polarization test was applied to study thermal aging degradation of HN2 steel. The X-ray diffraction(XRD) analysis was conducted to detect carbides and nitrides precipitated on the grain boundary of the heat treated HN2 steel. The mechanical properties of the HN2 steel significantly decreased with increasing time and temperature of heat treatment or with decreasing testing temperature. The integrated charge(Q) obtained from electrochemical polarization test showed a good correlation with the SP energy(ESP) obtained by means of SP tests. From the results observed in the x-ray diffraction and anodic polarization curve, it was known that the material the grain boundary. Combining SP test and electrochemical polarization test, it could be useful tools to non-destructively evaluate the cryogenic fracture behaviors and the aging degradation for cryogenic structural material.

Characteristics on Corrosion Resistance of Medium High Carbon Low Alloy Steels using Plasma Nitriding Process (플라즈마 질화처리한 중, 고탄소저합금강의 내식성에 관한 연구)

  • 이병찬
    • Journal of Advanced Marine Engineering and Technology
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    • v.22 no.5
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    • pp.702-711
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    • 1998
  • The characteristics of corrosion resistance for the surface of medium high carbon steels and low alloy steels utilizing as manufacturing the machinery structures and machining tools and treating by plasma/ion nitriding process have been studied in terms of electrochemical polarization behav-iors including corrosion potential(Ecorr) anodic polarization trends and polarization resistance(Rp) The seven base materials showed a clear passivation behavior for the polarization tests in the ASTM standard solution 1N ${H_2){SO_4}$ Although the treated surface by plasma nitriding for the seven test materials showed a significant increase in hardness the treatment gave a detri-mental effect in corrosion resistance. The various characteristics including corrosion potential polarization curves microstructures corrosion current polarization resistance among non-treat-ed nitriding and/or soft-nitriding treated specimens have been investigated and some of the mechanisms discussed.

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The Study on the Corrosion Characteristics of Al-Alloy Shell for Cooler (알루미늄합금 원통냉각기의 부식 특성에 관한 연구)

  • 임우조;김성진;윤병두
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.39 no.2
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    • pp.152-157
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    • 2003
  • Most Recently, with rapid development in marine industries such as marine structures and ship, there occurs much interest in the study of corrosion characteristics which play an important role in design of cooling water system like heat-exchanger. Especially, as operating environment of fresh cooling water system in vessels is acidified, this system is seriously corroded. In this study, to study on the corrosion characteristics of Al-alloy shell for cooler, the electrochemical polarization test of materials for the marine fresh water cooler such as Al-alloy, Cu and naval brass was carried out in fresh water. And thus the polarization resistance and anodic polarization behavior of Al-alloy, Cu and naval brass are investigated. Also, galvanic corrosion characteristics of Al-alloy coupled with Cu and naval brass is considered. The main results obtained are as follows ; (1) The current density of corrosion is high in order of Al-alloy > naval brass > Cu (2) As anodic potential increases, the corrosion resistance of naval brass is better than that of Cu. (3) The galvanic corrosion of Al-alloy coupled with Cu and naval brass is activated than corrosion of Al-alloy.

An Evaluation of Degraded Damage for Superaustenitic Stainless Steel by Electrochemical Polarization Technique (전기화학기법에 의한 슈퍼 오스테나이트 스테인리스강의 열화손상 평가)

  • Kwon, Il-Hyun;Lee, Song-In;Baek, Seung-Se;Lee, Jong-Gi;Iino, Y.;Yu, Hyo-Sun
    • Proceedings of the KSME Conference
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    • 2001.11a
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    • pp.143-148
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    • 2001
  • This research was undertaken to clarify effects of thermal aging on electrochemical and mechanical properties of superaustenitic stainless steel. The steel was artificially aged at $300{\sim}650^{\circ}C$ for $240{\sim}10,000hrs$. and investigated at $-196{\sim}650^{\circ}C$ using small punch(SP) test. Also, the change in electrochemical properties caused by effects of thermal aging was investigated using electrochemical anodic polarization test in a KOH electrolyte. Carbides and ${\eta}-phase(Fe_2Mo)$ precipitated in the grain bounderies seem to deteriorate the mechanical properties by decreasing cohesive strength in the grain bounderies and promote the current density observed in electrochemical polarization curves. The electrochemical and mechanical properties of superaustenitic stainless steel was drastically decreased in the specimen aged at $650^{\circ}C$.

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The Study on the Behavior of Polarization curve of Reinforcement with Oxidation Layer (산화피막이 있는 철근의 분극곡선의 거동에 대한 연구)

  • 한정섭
    • Journal of Ocean Engineering and Technology
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    • v.14 no.1
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    • pp.60-66
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    • 2000
  • In order to study for corrosion behavior of reinforcing steel with oxidation layer. Experiments were done with various NaCl concentrations and with immersion time in simulated concrete pore solution(SPS) the characteristics of corrosion behavior were measured by polarization resistance method and cyclic potentiodynamic method. reinforcements were coated by epoxy except corrosion without oxidation layer and it also showed two anodic-nose. by the result of potention dynamic test the potential curve shift to low with time and anodic-nose was appeared with 3% NaCl solution after 15 days. By result of cyclic Potentiodynamic test the type of corrosion was different accoding to concentration.

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Degradation Damage Evaluation of High Temperature Structural Components by Electrochemical Anodic Polarization Test (전기화학적 양극분극시험에 의한 고온 설비부재의 열화손상 평가)

  • Yu, Ho-Seon;Song, Mun-Sang;Song, Gi-Uk;Ryu, Dae-Yeong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.6 s.177
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    • pp.1398-1407
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    • 2000
  • The structural steels of power plant show the decrease of mechanical properties due to degradation such as temper embrittlement, creep damage and softening during long-term operation at high temper ature. The typical causes of material degradation damage are the creation and coarsening of carbides(M23C6, M6C) and the segregation of impurities(P, Sb and Sn) to grain boundary. It is also well known that material degradation induces the cleavage fracture and increases the ductile-brittle transition temperature of steels. So, it is very important to evaluate degradation damage to secure the reliable and efficient service condition and to prevent brittle failure in service. However, it would not be appropriate to sample a large test piece from in-service components. Therefore, it is necessary to develop a couple of new approaches to the non-destructive estimation technique which may be applicable to assessing the material degradation of the components with not to influence their essential strength. The purpose of this study is to propose and establish a new electrochemical technique for non-destructive evaluation of material degradation damage for Cr-Mo steels which is widely used in the high temperature structural components. And the electrochemical anodic polarization test results are compared with those of semi-nondestructive SP test.

Effect for Alloy Addition(Ta, Zr, Sn) on Mechanical Properties and Corrosion Resistance of cp-Ti for Dental Implants (인공치근용 cp-Ti에 첨가원소(Ta, Zr, Sn)가 기계적 특성 및 내식성에 미치는 영향)

  • Park, H.B.
    • Journal of Technologic Dentistry
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    • v.21 no.1
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    • pp.43-53
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    • 1999
  • The mechannical properties and corrosion resistance of alloy added commercially pure titanium for dental implants have been investigated. Ti, To-65Zr, Ti-10.1Ta and Ti-17Sn alloys were melthed in arc furnace and the corrosion resistance of Ti alloys was evaluated by anodic polarization test. The microstructure and mechanical properties of Ti alloy were analysed by optical micrograph. hardness tester and instron. In isothermal test, Ti-10.1Ta and Ti-17Sn alloys exhibited the best oxidation resistance below $1100^{\circ}C$. Ti65Zr, Ti-10.1Ta and Ti-17Sn alloys showed better rockwell hardness compared with commercially pure. Ti As the result of the anodic polarization test in 5%HCl, it 5%HCl, it was known knows that Ti-65Zr, alloy showed a rapid decrease in current density at higher potenial in comparision with other Ti alloys.

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An Nondestructive Evaluation of Degraded Damage for Superaustenitic Stainless Steel (슈퍼 오스테나이트 스테인리스강의 열화손상에 대한 비파괴적 평가)

  • Kwon, Il-Hyun;Baek, Seung-Se;Iino, Y.;Yu, Hyo-Sun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.7
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    • pp.1332-1339
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    • 2002
  • This research was undertaken to clarify effects of thermal aging on electrochemical and mechanical properties of superaustenitic stainless steel and to detect the material degradation nondestructively. The steel was artificially aged at $300{\sim}650^{\circ}C$ for $240{\sim}10,000h$ and the mechanical properties were investigated at $-196{\sim}650^{\circ}C$ using small punch(SP) test. Also, the change in electrochemical properties caused by effects of thermal aging on superaustenitic stainless steel was investigated using electrochemical anodic polarization test in a KOH electrolyte. Carbides and ${\eta}-phase(Fe_2Mo)$ precipitated in the grain boundaries seem to deteriorate the mechanical properties by decreasing cohesive strength in the grain boundaries and to promote the current density observed in electrochemical polarization curves, The electrochemical and mechanical properties of superaustenitic stainless steel decreased significantly in the specimen aged at $650^{\circ}C$ corresponding to the sensitization temperature for conventional austenitic stainless steels.

Study on the Cavitation Damage of Cupronickel(70/30) Tube for Gas Absorption Refrigeration Machine

  • Lim, Uh-Joh;Jeong, Ki-Cheol;Yun, Byoung-Du
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.2
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    • pp.332-337
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    • 2004
  • The use of gas absorption refrigeration machine has considerably increased because of the shortage of the electric power in the summer and the regulation of freon refrigerant. Gas absorption refrigeration machine consists of a condenser, a heat exchanger. supplying pipes, a radiator etc, This system is likely to be corroded by acid. dissolved oxygen and gases, Cavitation erosion-corrosion by flow velocity of cooling water may happen in absorption refrigeration machine. In these cases. erosion and corrosion occur simultaneously. Then, it makes a serious damage with synergy effect. Therefore, this paper was studied on the cavitation damage of cupronickel(70/30) tube for gas absorption refrigeration machine, In the $30^{\circ}C$ tap water, linear polarization test and anodic polarization test were carried out for copper(C1220T-OL) and cupronickel(70/30) tube. Also, cavitation erosion-corrosion behavior of cupronickel (70/30) tube was considered, The main results are as following: (1) In the linear test, the corrosion current density of cupronickel(70/30) is higher than that of copper. (2) The erosion-corrosion rate of cupronickel(70/30) displayed later tendency than that of copper by vibratory cavitation in cooling water. (3) In cooling water, the progress mechanism of erosion-corrosion rate of copper and cupronickel(70/30) follows a pattern of incubation, acceleration, attenuation and a steady state period.