• Title/Summary/Keyword: anion size

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A Study on Combined Processes of Sliding Arc Plasma and Corona Dielectric Barrier Discharge for Improve the Efficiency Treatment of Harmful Substance (슬라이딩아크 방전과 코로나 방전의 복합공정을 통한 유해물질 처리효율 개선에 관한 연구)

  • Kwon, Woo-Taeg;Lee, Woo-Sik
    • Fire Science and Engineering
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    • v.28 no.6
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    • pp.108-113
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    • 2014
  • The combined process of Sliding Arc Plasma and corona dielectric barrier discharge process (CDBD) was used to efficiently improve harmful substance, which convert into OH radicals which have strong oxidation potential, and so have deodorization and sterilizing effects, by generating specific radicals and anion and then reacting with the moisture contained in harmful substance. As a result of experiment, even if the size of SAP reactor is reduced from 80 A to 50 A, there is no much change and therefore it is judged the size of reactor may be minimized. And it was confirmed that after the anion and ozone generated from CDBD rector react with harmful substance, a anion was reduced from 510,000 ppb to 470 ppb and ozone from 98 ppb to 22 ppb. It was also judged the stability and durability of plasma producer are excellent. Accordingly, it is considered the harmful substances which exist in indoor air quality will be efficiently improved and removed by using further plasma combined process through this study.

Characterization of Size distribution of Anion Species in Atmospheric Aerosols (대기에어로졸중 음이온성분에 대한 입경분포의 변화특성)

  • 최금찬;박정호;임경택
    • Journal of Korean Society for Atmospheric Environment
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    • v.10 no.2
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    • pp.124-129
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    • 1994
  • Aerosol size distribution was determined using Anderson sampler for the anions( sulfate nitrate and chloride ) and TSP. Ionic species concentration and size distribution have been investigated in the daytime and nightime individually. Size classified samples were extracted with distilled water and analyzed for C $l^{[-10]}$ , N $O_3$$^{[-10]}$ and S $O_4$$^{2-}$, by ion chromatography. The size distribution of these ions and TSP was analyzed to investigate the seasonal and diurnal variation of concentrations as follows: (1)Size distribution of TSP showed bi- modal type in the daytime, but indicated tri-mode distribution in the nightime without any seasonal variation. (2)Sulfate concentrations were higher in fine- mode both in the daytime and nightime but fraction of sulfate was higher in coarse-mode during the Yellow Sand Period. (3)Nitrate and Chloride ions are dominant in fine-mode in winter while dominant in coarse-mode in the summer.

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The Effect of Stream Anion and River-Bed Materialson Aquatic Insects (계류수의 음이온과 하상재료가 수서곤충에 미치는 영향)

  • Seo, Mun Won;Chun, Kun-Woo
    • Journal of Forest and Environmental Science
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    • v.15 no.1
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    • pp.89-97
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    • 1999
  • This study was carried out to obtain basic data on the kinds of aquatic insects and their living conditions in the mountain stream. The investigation was done in Bongmyung stream. Experimental Forest, Kangwon National University on aquatic insects, anions and river-bed materials. The results are as follows. 1. At every plot surveyed, diversity index, richness index and evenness index of aquatic insects appeared higher at upper stream than at lower stream in erosion control dam. 2. Anion concentrations were almost the same in plots A, B, C, D and E, but plot F at the lower stream showed 1.5 to 89 times higher concentration than the others. 3. In river-bed materials analysed, particle diameter was bigger at the upper stream than at the lower stream. At the down stream of erosion control dam showed high pebble composition ratio. 4. The number of aquatic insects showed the negative relation with the anion concentration and the positive one with the size of river-bed materials. Especially, they were affected much by the distribution chart of boulder.

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Application of Polymer Brush to Enzyme-Multilayered Porous Hollow-Fiber Membrane

  • Kawakita Hidetaka;Uezu Kazuya;Tsuneda Satoshi;Saito Kyoichi;Tamada Masao;Sugo Takanobu
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.11a
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    • pp.142-145
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    • 2004
  • Anion-exchange porous hollow-fiber membranes with a thickness of about 1.2 mm and a pore size of about $0.30{\mu}m$ were used as a supporting matrix to immobilize cycloisomaltooligosaccharide glucanotransferase (CITase). CITase was immobilized to the membrane via anion-exchange adsorption and by subsequent enzymatic cross-linking with transglutaminase, the amount of which ranged from 3 to 110 mg per g of the membrane. The degree of enzyme multilayer binding was equivalent to 0.3 to 9.8. Dextran, as the substrate, was converted into seven- to nine-glucose-membered cycloisomaltooligosaccharides (CI-7, -8, and -9) at a maxi mum yield of $28\%$ in weight at a space velocity of 10 per hour during the permeation of $2.0(w/w)\%$ dextran solution across the CITase-immobilized porous hollow-fiber membrane.

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Analysis of Angiotensin I Converting Enzyme Inhibitory Activity of Oligosacchride Extracted from Capsosiphon fulvescens (매생이 유래 올리고당의 추출 분리 및 Angiotensin I Converting Enzyme 저해능 분석)

  • Kim, Hyun-Woo;Lee, Jung-Heon
    • KSBB Journal
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    • v.28 no.2
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    • pp.131-136
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    • 2013
  • The hydrolysates prepared with various enzyme digestion of Capsosiphon fulvescens were used to measure the inhibitory effects against angiotensin I converting enzyme (ACE). The commercially available enzymes such as Celluclast, Viscozyme, Lysing enzyme, Flavourzyme, Alcalase and Pectinex were used to digest C. fulvescens and produce hydrolysates. The maximum ACE inhibitory activity was observed using Alcalase hydrolysis (72.9%). The optimal conditions of Alcalase extraction were pH 8.0 and extraction time for 12 hr. The hydrolysates were fractionated using preparative-LC and anion-exchange chromatography on DEAE-cellulose and the fraction B and B-2 were isolated. The ACE inhibitory activity of fraction B-2 by anion-exchange chromatography was 82.6%. The molecular weight of fraction B-2 estimated using size exclusion chromatography was about 1 kDa. The monosaccharide composition of the fraction B-2 was determined to be mannose (1.1%), glucuronic acid (1.3%), galactose (1.3%) and glucose (96.3%).

Retention of sulfate and chloride ions in commercially available tubular membranes

  • Qadir, Danial;Mukhtar, Hilmi;Keong, Lau Kok
    • Membrane and Water Treatment
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    • v.8 no.4
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    • pp.369-380
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    • 2017
  • Performance evaluation of four commercially available tubular membranes (AFC 80, AFC 30, PU 608, ES 404) was accomplished in self-assembled membrane testing unit. Effects of varying transmembrane pressure, feed concentration and anion type were investigated. Aqueous solutions of salts such as calcium chloride, calcium sulfate, tin chloride and tin sulfate were prepared for this study. It was noted that the investigated parameters e.g., pressure and concentration had significant effects on membrane's performance. Nevertheless, anion type effectively played its role in the rejection of salts since salt having SO4-2 anions had a better rejection than the salts containing Cl-1. It is observed that rejection was dominated by Donnon exclusion for strongly charged nanofiltration membranes whereas for weakly charged ultrafiltration membranes, size exclusion was the key mechanism to reject the ions.

Concentration and Size Distribution of Atmospheric Particulate Matters, Chloride, Nitrate, and Sulfate Salts in Urban Air (都市大氣중 浮遊粒子狀物質, 鹽化物, 窒酸鹽 및 黃酸鹽의 濃度와 粒經分布)

  • Sohn, Dong-Hun;Heo, Moon-Young
    • Journal of Korean Society for Atmospheric Environment
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    • v.2 no.3
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    • pp.27-33
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    • 1986
  • Atmospheric particulate matter (A. P. M.) was collected and size-fractionated by an Andersen high-volume air sampler over 15 month period from Jan. 1985 to Feb. 1986 in Seoul. The concentration of chloride, nitrate and sulfate were extracted in an ultrasonic bath and were analyzed by ion chromatography. The annual arithmetical mean of A. P. M. was 128.54 $\mug/m^3$. The concentration of anions were 2.88 $\mug/m^3$ for chloride, 3.86$\mug/m^3$ for nitrate, and 25.44$\mug/m^3$ for sulfate. The content of A. P. M. was lowest in the particle size range 1.1 $\sim 3.3\mum$ and increased as the particle size increased or decreased. And the anions exhibited a seasonal variation in the isize distribution. The contents of anions were higher in winter than summer. Ther ratio of fine particles to the total particles defined by F/T for chloride, nitrate and sulfate. The F\ulcornerT of these anion generally decrease with increasing air temperature. This tendency was prevalent in the chloride and nitrate.

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A Combination of the Frozen Raindrop Collection Method and a High-performance Capillary Electrophoresis Technique for the Size-resolved Raindrops Study

  • Ma, Chang-Jin
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.E1
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    • pp.27-34
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    • 2006
  • Although the importance of size-resolved raindrops study has been known, it has not been popularized up to the present. In the present study, an attempt was made to generalize the size-resolved raindrops study by a combination of the frozen raindrop collection method and a commercially available high-performance capillary electrophoresis (HPCE). Samplings were carried out at Kyoto, Japan in October 2002. The inorganic ions (chloride, nitrate, sulphate, calcium, ammonium, sodium, magnesium, potassium) in size classified raindrop samples were successfully analyzed by HPCE with good repeatability. To assure the accuracy and precision of HPCE data, t-test was conducted with paired analytical data, which were experimentally constructed by analyzing standard solutions with HPCE and IC, respectively. T-test showed that there is no notable difference between the concentrations determined by the two analytical methods. Every ionic concentration in both cation and anion was found to be strong raindrop size dependence. Though there was slight increase of sodium and sulphate concentrations between 0.85 mm and 1.15 mm raindrop radius, it showed a strong decrease for every ionic component with increasing droplet radius. The combination of the frozen raindrop collection method and a commercially available HPCE can meet the need of size-resolved raindrops study.

The Properties of Porous and Non Porous Aminated Polystyrene Divinylbenzene Anion Exchanger (아민화된 다공성 및 비다공성 폴리스티렌 디비닐벤젠 음이온교환체의 성질)

  • Dong Won Kim;Jae Jick Oh;Tae Won Min
    • Journal of the Korean Chemical Society
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    • v.29 no.3
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    • pp.233-238
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    • 1985
  • The non-porous and porous polystyrene divinylbenzene copolymers were prepared by the suspension polymerization method. The non-porous aminated polystyrene divinylbenzene, N-APSTDVB and the porous aminated polystyrene divinylbenzene, P-APSTDVB of 50∼100mesh size weakly basic anion exchanger were synthesized by chloromethylation followed by amination with methylamine. The functional groups of these synthesized anion exchangers were confirmed by their infrared spectra. The maximum capacity of these exchangers was 4.86meq/g. Pore volume and pore spectra were determined with a mercury porosimeter. The pore volume of P-PSTDVB increased with increasing X$_{diluent}$ at 30% of divinylbenzene. However, the pore volume of P-PSTDVB increased with increasing volume percent of divinylbenzene at constant mole fraction of diluent, X$_{diluent}$ of 0.5. The pore volume of synthesized copolymer and anion exchanger at 8% divinylbenzene and 0.5X$_{heptane}$ decreased as follows; P-PSTDVB 〉P-APSTDVB 〉N-PSTDVB. This result was attributed to the possibility that the pore volume were reduced by amination reactions. The distribution coefficients of boric acid on the N-APSTDVB anion exchanger in various concentrations of alcohol water solutions showed that as alcohol concentration increased, the distribution coefficients values decreased due to the reduced concentration of H$_2$BO$_3^-$.

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Anion Effects on Crystal Structures of CdII Complexes Containing 2,2'-Bipyridine: Photoluminescence and Catalytic Reactivity

  • Park, Hyun-Min;Hwang, In-Hong;Bae, Jeong-Mi;Jo, Young-Dan;Kim, Cheal;Kim, Ha-Yeong;Kim, Young-Mee;Kim, Sung-Jin
    • Bulletin of the Korean Chemical Society
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    • v.33 no.5
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    • pp.1517-1522
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    • 2012
  • Anion effects on structures of $Cd^{II}$ complexes containing 2,2'-bipyridine (2,2'-bpy) ligands have been studied, and compared with $Zn^{II}$-(2,2'-bpy) complexes. For each anion, different structures have been obtained in both $Zn^{II}$-(2,2'-bpy) and $Cd^{II}$-(2,2'-bpy). Polymeric structures of $Cd^{II}$-2,2'-bpy complexes can be produced by hydrogen bonding interactions as shown in $Zn^{II}$-2,2'-bpy complexes. In addition, the bigger size of a $Cd^{II}$ ion gives higher coordination numbers forming variety of structures, and it makes that chlorides can act as bridging ligands to form a one-dimensional structure. The compound $\mathbf{5}$ catalyzed efficiently the transesterification of a variety of esters with methanol, while the rest of the compounds have displayed very slow conversions. In addition, the emission bands of complexes $\mathbf{1}$, $\mathbf{2}$, $\mathbf{4}$, and $\mathbf{6}$ are blue-shifted compared to the corresponding ligand 2,2'-bpy, whereas $\mathbf{3}$ and $\mathbf{5}$ showed the similar emission observed for the ligand.