• Title/Summary/Keyword: and water purification

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A Prediction Model for Removal of Non-point Source Pollutant Considering Clogging Effect of Sand Filter Layers for Rainwater Recycling (빗물 재활용을 위한 모래 정화층의 폐색특성을 고려한 비점오염원 제거 예측 모델 연구)

  • Ahn, Jaeyoon;Lee, Dongseop;Han, Shinin;Jung, Youngwook;Choi, Hangseok
    • Journal of the Korean Geotechnical Society
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    • v.30 no.6
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    • pp.23-39
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    • 2014
  • An artificial rainwater reservoir installed in urban areas for recycling rainwater is an eco-friendly facility for reducing storm water effluence. However, in order to recycle the rainwater directly, the artificial rainwater reservoir requires an auxiliary system that can remove non-point source pollutants included in the initial rainfall of urban area. Therefore, the conventional soil filtration technology is adopted to capture non-point source pollutants in an economical and efficient way in the purification system of artificial rainwater reservoirs. In order to satisfy such a demand, clogging characteristics of the sand filter layers with different grain-size distributions were studied with real non-point source pollutants. For this, a series of lab-scale chamber tests were conducted to make a prediction model for removal of non-point source pollutants, based on the clogging theory. The laboratory chamber experiments were carried out by permeating two types of artificially contaminated water through five different types of sand filter layers with different grain-size distributions. The two artificial contaminated waters were made by fine marine-clay particles and real non-point source pollutants collected from motorcar roads of Seoul, Korea. In the laboratory chamber experiments, the concentrations of the artificial contaminated water were measured in terms of TSS (Total Suspended Solids) and COD (Chemical Oxygen Demand) and compared with each other to evaluate the performance of sand filter layers. In addition, the accumulated weight of pollutant particles clogged in the sand filter layers was estimated. This paper suggests a prediction model for removal of non-point source pollutants with theoretical consideration of the physical characteristics such as the grain-size distribution and composition, and change in the hydraulic conductivity and porosity of sand filter layers. The lumped parameter ${\theta}$ related with the clogging property was estimated by comparing the accumulated weight of pollutant particles obtained from the laboratory chamber experiments and calculated from the prediction model based on the clogging theory. It is found that the lumped parameter ${\theta}$ has a significant influence on the amount of the pollutant particles clogged in the pores of sand filter layers. In conclusion, according to the clogging prediction model, a double-sand-filter layer consisting of two separate layers: the upper sand-filter layer with the effective particle size of 1.49 mm and the lower sand-filter layer with the effective particle size of 0.93 mm, is proposed as the optimum system for removing non-point source pollutants in the field-sized artificial rainwater reservoir.

Distribution of Biota and Removal Efficiency of Organic Matter in Natural Wetland (농촌배수처리용 습지의 생물상 및 유기물 제거율)

  • Kim, Bum-Chul;Jeon, Man-Sik;Jung, Geun;Jung, Yeon-Sook;Hwang, Gil-Soon
    • Korean Journal of Environmental Biology
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    • v.17 no.4
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    • pp.407-414
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    • 1999
  • Distribution of biota and removal efficiency of organic matter in natural wetland systems were examined from June to October 1998. The aquatic macrophyte communities were consisted of 13 families and 22 species. The composition of occurrence species were as follows: Phragmites communis Trinius are 35%, Persicaria thunbergii Nakai are 19%, Typha angustifolia L. are 17%, Bidens tripartita L. are 16%, Echinochloa crus-galli (L.) Beauv. are 12% and others are l%. The fauna collected from 5 sites consisted of total 6 classes of macroinvertebrates. The composition of occurrence classes were as follows: Insecta are 76%, O1igochaeta are 19%, Gastrapoda are 4% and others are 1%. These included 18 families, 7 orders of Insects. The larve and mosquito and midges were found in wetlands. Preventive strategies are needed for the suppression of mosquito at the stage of wetland planning and design. In wetland, removal efficiency of dissolved organic carbon is low because of primary production and the background level of DOC in the wetland discharge seems to be 5 mgC/1, but those of BOD was ca. 50%. Wetlands receiving water of low concentration can not work as purification field.

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Verification of Antibacterial Activities of Oriental Herbal Medicine Extracts (한약재 추출물의 항균활성 검증)

  • Lee, Chang-Eun;Jo, Jung-Kwon;Kim, Jae-Deok;Lee, Dong-Geun;Kim, Won-Seok;Lee, Sang-Hyeon
    • Journal of Life Science
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    • v.27 no.6
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    • pp.611-616
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    • 2017
  • The antibacterial activities of nine oriental herbal medicine extracts were measured against seven kinds of bacteria known to cause food poisoning and disease. The extracts were prepared with distilled water using an autoclave ($121^{\circ}C$ for 30 min). The extraction yields of nine oriental herbal medicines were in the rage of 0.5%-33.4%. The antibacterial activities were evaluated using the paper-disc method. Extracts of Hwangryeon, Jiyu, and Ohbaeja showed antibacterial activities while the others did not. Extracts of Coptis japonica, Hwangryeon, and Sanguisorba officinalis, Jiyu showed antibacterial activities only against Clostridium perfringens and Listeria monocytogenes. Extracts of Rhus javanica, Ohbaeja showed the strongest antibacterial activities against all the bacteria tested. The minimum inhibitory concentration (MIC) and minimum bactericidal concentration (MBC) of R. javanica extracts were in the range of 2.4~20 mg/ml for the bacteria tested. In conclusion, the extract of R. javanica showed superior antibacterial activities against the seven bacterial strains tested. The MIC and MBC values for each bacterium were represented as strain names (MIC, MBC), which were Bacillus cereus (11.2, 20), Clostridium perfringens (2.4, 4.7), Escherichia coli (9.1, 9.1), Listeria monocytogenes (11.1, 20), Salmonella typhi (4.7, 9.1), Staphylococcus aureus (2.4, 4.7), and Vibrio parahaemolyticus (2.4, 5.3). Further purification and study of this antibacterial material would be helpful for developing antibiotics or promoting synergistic effects with known antibiotics, producing antibacterial material for lengthening the shelf-life of food, and so on.

Effects of Anodic Voltages of Photcatalytic TiO2 and Doping in H2SO4 Solutions on the Photocatalytic Activity (광촉매 TiO2의 황산용액에서의 양극산화전압과 도핑이 광촉매 활성에 미치는 영향)

  • Lee, Seung-Hyun;Oh, Han-Jun;Chi, Choong-Soo
    • Korean Journal of Materials Research
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    • v.22 no.8
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    • pp.439-444
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    • 2012
  • To compare the photocatalytic performances of titania for purification of waste water according to applied voltages and doping, $TiO_2$ films were prepared in a 1.0 M $H_2SO_4$ solution containing $NH_4F$ at different anodic voltages. Chemical bonding states of F-N-codoped $TiO_2$ were analyzed using surface X-ray photoelectron spectroscopy (XPS). The photocatalytic activity of the co-doped $TiO_2$ films was analyzed by the degradation of aniline blue solution. Nanotubes were formed with thicknesses of 200-300 nm for the films anodized at 30 V, but porous morphology was generated with pores of 1-2 ${\mu}m$ for the $TiO_2$ anodized at 180 V. The phenomenon of spark discharge was initiated at about 98 V due to the breakdown of the oxide films in both solutions. XPS analysis revealed the spectra of F1s at 684.3 eV and N1s at 399.8 eV for the $TiO_2$ anodized in the $H_2SO_4-NH_4F$ solution at 180 V, suggesting the incorporation of F and N species during anodization. Dye removal rates for the pure $TiO_2$ anodized at 30 V and 180 V were found to be 14.0% and 38.9%, respectively, in the photocatalytic degradation test of the aniline blue solution for 200 min irradiation; the rates for the F-N-codoped $TiO_2$ anodized at 30 V and 180 V were found to be 21.2% and 65.6%, respectively. From the results of diffuse reflectance absorption spectroscopy (DRS), it was found that the absorption edge of the F-N-codoped $TiO_2$ films shifted toward the visible light region up to 412 nm, indicating that the photocatalytic activity of $TiO_2$ is improved by appropriate doping of F and N by the addition of $NH_4F$.

Alchemical Transformation Process revealed in Sand Play (모래놀이에 나타난 연금술적 변환과정)

  • Dukkyu Kim
    • Sim-seong Yeon-gu
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    • v.39 no.1
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    • pp.61-91
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    • 2024
  • Alchemy is the process of producing worthless substances into the best substances through chemical opus(work). On the surface, many of the alchemist's experiments can be depicted as work on transforming substances, but in reality, the alchemist's result is a product of the Unconscious. This study aims to explain the three phases of alchemy, Nigredo, Albedo, and Rubedo, through Michael Mayer's alchemical text, Atalanta Fugiens, and understand the transformation process by utilizing images that appeared from clients' sand play therapy. This study first described why alchemy, as the foundation for the psychology of the Unconscious, is important in sand play that deals with images. Next, Nigredo (blackening), the first phase of the alchemical process, is briefly described, and how the contents of Nigredo, such as chaos, dissolution, separation, division, corruption, death, and calcination, appear in sand play therapy. Next, the second phase, albedo (whitening), is described, and how the images of water and fire, which are representative images of albedo in the form of purification, sublimation, distillation, separation, descension, and coagulation, are revealed in sand play. Lastly, the phase of rubedo (reddening) in alchemy is described, and how the form of union (mandala or central image) in rubedo, which appears in the form of conjunction and rebirth, is revealed in sand play. The symbols revealed in alchemy are very valuable in amplifying the images that appeared in sand play therapy or dream analysis. In particular, the procedures found in alchemical opus are helpful in understanding the transformation process of personality.

Purification of Complement System-Activating Polysaccharide from Hot Water Extract of Young Stems of Cinnamomum cassia Blume (계지(桂枝) 열수추출물로부터 보체계 활성화 다당의 정제)

  • Kweon, Mee-Hyang;An, Hyun-Jung;Shin, Kwang-Soon;Na, Gyeong-Su;Sung, Ha-Chin;Yang, Han-Chul
    • Korean Journal of Food Science and Technology
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    • v.29 no.1
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    • pp.1-8
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    • 1997
  • A complement system-activating (anti-complementary) polysaccharide was purified from the hot water extract of young stems of Cinnamomum cassia Blume. Crude polysaccharide fraction (CC-1) was prepared from the hot water extract of the young stems followed by methanol-reflux, precipitation with ethanol, dialysis, and lyophilization. The anti-complementary activity of CC-1 was decreased greatly by periodate oxidation, but was not changed by pronase digestion. These suggest that carbohydrate moiety may be related to the activation of complement system. According to its ionic strength CC-1 was fractionated first using cetavlon to give 4 fractions, CC-2, 3, 4 and 5. Among them CC-2 fraction was found to retain the highest activity and yield. CC-2 was separated to an unabsorbed neutral sugar portion (CC-2-I) and seven absorbed acidic sugar fractions $(CC-2-II{\rightarrow}CC-2-VIII)$ on DEAE-Toyopearl 650C (Cl-). CC-2-III showing higher anti-complementary activity and yield than those of other fractions, was further purified on the gel permeation of Sephadex G-100 and Sepharose CL-6B to CC-2-IIIa-3. CC-2-IIIa-3 was determined to have a homogeneity hy GPC (Sepharose CL-6B) and HPLC. Gel chromatography using standard dextrans gave a value of $2.4{\times}10^5$ for the molecular weight. The purified polysaccharide, CC-2-IIIa-3 consisted of arabinose, xylose, glucose, galactose, galacturonic acid and glucuronic acid in a molar ratio of 5.56 : 3.77 : 1.87 : 1.00 : 5.12 : 3.13 and contained no nitrogen.

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An Evaluation of Environmental-Control Function on Forest Using GIS (GIS를 활용한 산림녹지의 환경조절적 기능 평가)

  • Lee, Woo-Sung;Jung, Sung-Gwan
    • Journal of the Korean Association of Geographic Information Studies
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    • v.14 no.4
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    • pp.102-115
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    • 2011
  • The purpose of this study is to establish the evaluation model through the systematic process of selecting the indicators and to evaluate the environmental-control function on forest using GIS in Deagu for the sustainable forest planning. The 35 indicators as basic items were selected by literature review and those were squeezed into the 29 indicators through expert brainstorming. Also, the 8 indicators to evaluate environmental-control function were selected by the first survey and the 5 final indicators such as carbon sink, temperature decrease, wind formation, water circulation, air purification were determined by MCB analysis using the second survey. The evaluation model was established through the weight of each indicator by AHP analysis using the third survey. According to the result of evaluating the environmental-control function on forest, the functions around the top area of Mt. Ap, Mt. Biseul, Mt. Palgong had more than 66 scores. On the other hand, the functions around Mt. Waryong and forest of Chilgok in Buk-gu had less than 40 scores. It is necessary to improve the function through the sustainable restoration and management in case of forest that the environmental-control function was lower. Furthermore, these results will be able to be utilized as basic data in order to establish the preservation area and control development area at the urban, environmental, and forest planning.

Purification and Characteriztion of an Antifungal Antibiotic from Bacillus megaterium KL 39, a Biocontrol Agent of Red-Papper Phytophtora Blight Disease. (고추역병균 Phytophthora capsici를 방제하는 길항균주 Bacillus megaterium KL39의 선발과 길항물질)

  • 정희경;김상달
    • Microbiology and Biotechnology Letters
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    • v.31 no.3
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    • pp.235-241
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    • 2003
  • For the biological control of Phytophthora blight of red-pepper caused by Phytophthora capsici, an antibiotic-producing plant growth promoting rhizobacteria (PGPR) Bacillus sp. KL 39 was selected from a local soil of Kyongbuk, Korea. The strain KL 39 was identified as Bacillus megaterium by various cultural, biochemical test and API and Microlog system. B. megaterium KL 39 could produce the highest antifungal antibiotic after 40 h of incubation under the optimal medium which was 0.4% fructose, 0.3% yeast extract, and 5 mM KCl at 30 C with initial pH 8.0. The antifungal antibiotic KL 39 was purified by Diaion HP-20 column, silica gel column, Sephadex LH-20 column, and HPLC. Its RF value was confirmed 0.32 by thin-layer chromatography with Ethanol:Ammonia:Water = 8:1:1. The crude antibiotic KL39 was active against a broad range of plant pathogenic fungi, Rhizoctonia solani, Pyricularia oryzae, Monilinia fructicola, Botrytis cinenea, Alteranria kikuchiana, Fusarium oxysporum and Fusarium solani. The purified antifungal antibiotic KL39 had a powerful biocontrol activity against red-pepper phytophthora blight disease with in vivo pot test as well as the strain B. megaterium KL 39.

Synthesizing Behavior of Calcium Chloroaluminate with using MSWI Fly Ash in the Different Sintering Conditions (생활폐기물(生活廢棄物) 소각(燒却) 비산(飛散)재의 소성(燒成) 조건(條件)에 따른 Calcium Chloroaluminate 합성(合成) 거동(擧動)에 관한 연구(硏究))

  • Yoo, Kwang-Suk;Lee, Seong-Ho;Hwang, Sun-Ho;Ahn, Ji-Whan
    • Resources Recycling
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    • v.19 no.5
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    • pp.68-74
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    • 2010
  • The aim of this study is to investigate the behaviors of synthesis of Calcium Chloroaluminte($11CaO{\cdot}7Al_2O_3{\cdot}CaCl_2$) under the melting temperature of municipal solid waste incineration fly ash(MSWI fly ash); $900^{\circ}C-1300^{\circ}C$ of sintering temperature. A sludge generated from a water purification plant (SW) was also used to fill up $Al_2O_3$ source, which might be deficient in MSWI fly ash. MF and SW were mixed at mixing ratio of 10 to 7, which is the mole ratio of CaO to $Al_2O_3$ of calcium Chloroaluminte. Mixed samples were sintered in the opened sintering reactor and the closed sintering reactor, respectively. The results showed that calcium chloroaluminte was formed at $1,000^{\circ}C$ in both reactors, but the temperature of decomposition of calcium chloroaluminte depended upon sintering reactor type; an opened sintering reactor and a closed sintering reactor, owing to the vaporization velocity of Cl.

Development of Analytical Method for Fipronil Residues in Agricultural Commodities Using GC-ECD/MS (GC-ECD/MS를 이용한 농산물 중 Fipronil의 잔류 분석법 개발)

  • Ahn, Kyung-Geun;Kim, Gyeong-Ha;Kim, Gi-Ppeum;Hwang, Young-Sun;Kang, In-Kyu;Lee, Young Deuk;Choung, Myoung-Gun
    • Korean Journal of Environmental Agriculture
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    • v.34 no.4
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    • pp.309-317
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    • 2015
  • BACKGROUND: An analytical method was developed using GC-ECD/MS to precisely determine the residue of fipronil, a phenylpyrazole insecticide used to control a wide range of foliar and soil-borne pests.METHOD AND RESULTS: Fipronil residue was extracted with acetone from representative samples of five raw products which comprised hulled rice, soybean, Kimchi cabbage, green pepper, and apple. The extract was diluted with saline water, and fipronil was partitioned into n-hexane/dichloromethane (20/80, v/v) to remove polar co-extractives in the aqueous phase. Florisil column chromatography was additionally employed for final purification of the extract. Fipronil was separated and quantitated by GC-ECD using a DB-17 capillary column. Accuracy of the proposed method was validated by the recovery from crop samples fortified with fipronil at 3 levels per crop in each triplication.CONCLUSION: Mean recoveries ranged from 86.6% to 106.0% in five representative agricultural commodities. The coefficients of variation were less than 10%. Limit of quantitation of fipronil was 0.004 mg/kg as verified by the recovery experiment. A confirmatory technique using GC/MS with selected-ion monitoring was also provided to clearly identify the suspected residue. Therefore, this analytical method was reproducible and sensitive enough to determine the residue of fipronil in agricultural commodities.