• Title/Summary/Keyword: and resonance

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Irradiation Induced Defects in a Si-doped GaN Single Crystal by Neutron Irradiation

  • Park, Il-Woo
    • Journal of the Korean Magnetic Resonance Society
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    • v.12 no.2
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    • pp.74-80
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    • 2008
  • The local structure of defects in undoped, Si-doped, and neutron irradiated free standing GaN bulk crystals, grown by hydride vapor phase epitaxy, has been investigated by employing electron magnetic resonance(EMR), Raman scattering and cathodoluminescence. The GaN samples were irradiated to a dose of $2{\times}10^{17}$ neutrons in an atomic reactor at Korea Atomic Energy Research Institute. There was no appreciable change in the Raman spectra for undoped GaN samples before and after neutron irradiation. However, a forbidden transition, $A_1$(TO) mode, appeared for a neutron irradiated Si-doped GaN crystal. Cathodoluminescence spectrum for the neutron irradiated Si-doped GaN crystal became much broader or was much more broadened than that for the unirradiated one. The observed EMR center with the g value of 1.952 in a neutron irradiated Si-doped GaN may be assigned to a Si-related complex donor.

Quantification of Methanol Concentration in the Polymer Electrolyte Membrane of Direct Methanol Fuel Cell by Solid-state NMR

  • Kim, Seong-Soo;Paik, Youn-Kee;Kim, Sun-Ha;Han, Oc-Hee
    • Journal of the Korean Magnetic Resonance Society
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    • v.12 no.2
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    • pp.96-102
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    • 2008
  • Direct quantification of methanol in polymer electrolyte membrane (PEM) by solid-state nuclear magnetic resonance (NMR) spectroscopy was studied and the methanol concentrations in PEM produced by crossover and diffusion were compared. The error range of the quantification was not smaller than ${\pm}15%$ and the amount of the methanol crossed over in our direct methanol fuel cells (DMFCs) was less than the methanol diffused to PEM. The methanol concentration in the PEM of the DMFC operated at different current densities were equivalent.

Study on nuclear magnetic resonance of superionic conductor NH4HSeO4 in rotating frame

  • Choi, Jae Hun;Lim, Ae Ran
    • Journal of the Korean Magnetic Resonance Society
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    • v.18 no.1
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    • pp.41-46
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    • 2014
  • In order to obtain information on the structural geometry of $NH_4HSeO_4$ near the phase transition temperature, the spectrum and spin-lattice relaxation time in the rotating frame $T_{1{\rho}}$ for the ammonium and hydrogen-bond protons were investigated through $^1H$ MAS NMR. $T_{1{\rho}}$ for the hydrogen-bond protons abruptly decreased at high temperature and it is associated with the change in the structural geometry in $O-H{\cdots}O$ bonds. This mobility of the hydrogen-bond protons may be the main reason for the high conductivity.

$^{13}C$ Solid State NMR Study on the Dynamics of the Poly(vinyl butylal) with Various Water Contents

  • Hyun Namgoong;Kim, Jong-Soo;Han, Oc-Hee
    • Journal of the Korean Magnetic Resonance Society
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    • v.6 no.1
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    • pp.1-11
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    • 2002
  • Physical properties of PVB [Poly(vinyl butyral)] polymer are strongly correlated with water contents in the polymer. Thus dynamics of PVB containing 10~50(w/w) % of water were studied by $^{13}$ C CP/MAS/DD over the temperature range 293K -348K. From the Peak area, line width, chemical shift, and relaxation times ( $T_{1}$ $T_{1p}$) measured at 9.4 T, it was deduced that water facilitates molecular dynamics of the PVB molecules overall including conformational exchange of the racemic and meso butyaldehyde rings in the PVB. However, the influence of water was not linear to the amount of water in the PVB samples. It is suggested that water up to 30 w/w % of the sample is closely bound to the PVB polymer and water relatively free from the PVB polymer starts to appear when water is added more than 30 w/w %.%.

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An Experimental Study that depend on the Resonance Tube Length for a Thermoacoustic Refrigerator of 1/4 wave (1/4파장 열음향 냉동기의 공명관 길이 의존 특성 연구)

  • Song, Kyu-Joe;Park, Jong-Ho;Koh, Deuk-Yong;Park, Seong-Je
    • Proceedings of the KSME Conference
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    • 2001.11b
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    • pp.229-234
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    • 2001
  • The thermoacoustic refrigerator bas not only considerable possibility but also commercial usability, because it bas high reliability, lower vibration, no moving part, and can easily be constructed. In this study, the resonance characteristics of the thermoacoustic refrigerator were investigated for better performance, varying length of the resonance tube to 400mm, 500mm, 600mm, 700mm. In order to determine the optimum resonance tube length and the frequency, the $\lambda/4$ thermoacoustic engine and the similar apparatus of Wheatly type refrigerator were constructed. It was used air as a coolant. in the fifth harmonic, it was taken the highest ${\Delta}t$ that was $56.3^{\circ}C$ at 626Hz in 400mm tube with 40mm stack.

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Ferromagnetic Resonance Observation of Martensitic Phase Transformation in Ni-Mn-Ga Ferromagnetic Shape Memory Films

  • Dubowik, J.;Kudryavtsev, Y.V.;Lee, Y.P
    • Journal of Magnetics
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    • v.9 no.2
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    • pp.37-39
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    • 2004
  • Polycrystalline Ni-Mn-Ga films have been deposited onto mica substrates held at 720 K by flash-evaporation method. At room temperature the films have a tetragonal structure with a = b = 0.598 and c = 0.576 nm typical for bulk $Ni_2MnGa$ below a martensitic transformation. Temperature measurements of ferromagnetic resonance reveal a martensitic phase transformation at 310 K. The transformation brings about a substantial decrease in the effective magnetization and a drastic increase in the ferromagnetic resonance linewidth due to a strong increase in the magnetic anisotropy in the martensitic phase.

Vibration Analyses and Design of Resonance Avoidance of the Unmanned Helicopter Master (무인 헬리콥터 마스터의 진동해석 및 공진회피 설계)

  • Lee, Seong-Chul;Son, In-Soo;Hur, Kwan-Do
    • Journal of the Korean Society for Precision Engineering
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    • v.28 no.8
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    • pp.951-958
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    • 2011
  • In this paper, the purpose is to investigate the vibration characteristics and the design of resonance avoidance of the unmanned helicopter master. Based on the Euler-Bernoulli beam theory for helicopter master, the equation of motion is derived by using extended Hamilton's principle. It was studied about the natural frequency of helicopter master as the design variances(tip mass, length and diameter of master). Also, it was compared the theoretical results for natural frequency with the results of FE analysis. The results of this study showed the vibration characteristics of helicopter master for the design of resonance avoidance.

The Integrated Surface Plasmon Resonance Sensor using Polymer Optical Waveguide (폴리머 광도파로를 이용한 집적형 표면 플라즈몬 공명 센서)

  • Oh, Geum-Yoon;Kim, Doo-Gun;Kim, Hong-Seung;Lee, Tae-Kyeong;Choi, Young-Wan
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.61 no.3
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    • pp.433-436
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    • 2012
  • We propose a novel micro surface plasmon resonance (SPR) sensor system based on polymer materials. The proposed SPR system consists of the incident medium with polymer waveguide and the gold thin film for sensing area. Using a polymer optical waveguide instead of a prism in SPR sensing system offers miniaturization, low cost, and potable sensing capability. The whole device performance was analyzed using the finite-difference time domain method. The optimum gold thickness in the attenuated total reflection mirror of polymer waveguide is around 50 nm and the resonance angle to generate surface plasmon wave is 68 degrees.

Operation Characteristic of Transless type Grid-connected Inverter using Multi-level Switching circuit (멀티레벨 스위칭 회로를 이용한 트렌스리스형 계통 연계 인버터의 동작 특성)

  • Kim, Ju-Yong;No, Kwae-Hyeop;Jung, Tae-Uk
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.916-917
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    • 2008
  • In this paper, Switching damage of switches that is used to proposed power conversion system is reduced by soft switching way. dissipation by part resonance and my resonance stress for resonance of resonance circuit are decreased. Is acted by conversion system high effectiveness. Have following characteristic. Design snubber circuit that is used by switch protection in existent hard work rate Topology by resonant circuit for sogt switching, circuit structure was simple and control system is easy. Also, Can generate free output voltage by multi level Tuesday of output that use individuation Power Cell's Phase Shift PWM, and Low-end switching frequency the harmonic is few.

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Pulsed Electron Paramagnetic Resonance Application on the Photoinduced Charge Separation of Alkylphenothiazine Derivatives in Molecular Assemblies

  • Kang, Young-Soo;Park, Chan-Young
    • Journal of the Korean Magnetic Resonance Society
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    • v.4 no.2
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    • pp.82-90
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    • 2000
  • Photoinduced charge separation of alkylphenothiazines in molecular assemblies such as positively, negatively and neutrally charged micelle interface results in the paramagnetic phenothiazine cation radical. This was studied as a model system for the light energy conversion into chemical energy. The photoproduced phenothaizne cation radical was identified and its amount was quantized with electron spin resonance (ESR). The microenvironment of photoproduced cation radical was studied with pulsed-ESR. Such a charge separation is enhanced by the optimization of various structural factors of the molecular assemblies. The structural factors of molecular assemblies have focused on the interface charge, interface structure with different headgroups and interfacial perturbation by disolving interface active organic additives.

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