• Title/Summary/Keyword: and resonance

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The Magnetic Properties and Quantum Effects of Molecular Nanomagnets (분자 자성체의 자기 특성과 양자역학적 효과)

  • Jang, Zee-Hoon
    • Journal of the Korean Magnetics Society
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    • v.14 no.2
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    • pp.83-88
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    • 2004
  • Magnetism of molecular nanomagnet, which attracted a lot of academic attention after the discovery of the macroscopic quantum tunneling of magnetism, is reviewed. Molecular nanomagnet is metal-organic material in which magnetic ions are regularly located in the organic skeleton. Also, the interaction between the molecules is very small and those molecules form macroscopic molecular crystal in which molecules are residing at the element points in the crystal. Molecular nanomagnets show a lot of interesting features, especially, equivalence of macroscopic magnetic properties and molecular magnetic properties. In this paper, research results on molecular nanomagnet with microscopic tool like NMR are reviewed mainly. The new method to observe the quantum tunneling of magnetization discovered in Mnl2-ac with NMR is shown and the research results on the microscopic aspects of the macroscopic quantum tunneling of magnetization using the new method are shown. Also, the physical aspect of the level crossing effect which has been reported originally with NMR in molecular nanomagnet is reviewed with experiment results. The research results on the molecular nanomagnets will reveal the important information about the limit of the miniaturization of magnetic memory units and give us the basic scientific knowledge which is needed for the application for the quantum computation. Moreover, academically, many quantum mechanical theories which have not been checked the validity can be checked with experiments.

Evaluation of Cardiac Ejection Fraction using Cardiac MRI (Cardiac MRI를 이용한 심박출계수의 평가)

  • Eun, Sung-Jong;Kook, Jin-Sun
    • Journal of the Korean Society of Radiology
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    • v.5 no.5
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    • pp.289-294
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    • 2011
  • The aim of this study is to evaluate the differences of ejection fraction of left ventricle through the quantitative analysis of diastolic and systolic volumes according to slices selected using cardiac MR imaging. A total of 12 volunteers (7 normal, 1 myocardium bridge, and 4 arrhythmia) underwent cardiac MRI on a MR scanner(Magnetom Trio, Siemens, Germany). Ejection fractions for quantitative analysis were calculated at single slice of center of left ventricle, 3, 5, and 6-7 slices extending from the center of left ventricle. Average values were analyzed for evaluating differences of ejection fraction according to the number of slices selected. Mean value of normal person of ejection fraction were 67.14% at single slice of center of left ventricle, 66.24% at 3 slices, 65.63% at 5 slices, and 65.29% at 6-7 slices. While ejection fraction obtained from a patient with 61.74% at single slice of center of left ventricle, 60.92% at 3 slices, 60.89% at 5 slices, and 61.89% at 6-7 slices. There was no significant differences by the number of slices selected. This study demonstrates that ejection fraction obtained from single slice of center of left ventricle may represent a optimum parameter for cardiac function, instead of the value calculated on the variable slices selected.

Copper(II) Binding Mechanisms with Water Soluble Organic Fractions Extracted from Sewage Sludge Amended Soils (구리(II) 이온과 Sewage Sludge를 시용(施用)한 토양(土壤)에서 추출(抽出)한 수용성유기물(水溶性有機物)과의 착화합물(錯化合物) 형성방법(形成方法))

  • Lim, Hyung-Sik;Volk, V.V.;Baham, John
    • Korean Journal of Soil Science and Fertilizer
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    • v.19 no.4
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    • pp.307-314
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    • 1986
  • Cu(II) binding mechanisms with water soluble organic fractions (WSOF) extracted from an agricultural soil (W), a soil treated with sludge for 6 years ($WS_6$), a sludge-soil mixture incubated for one week ($WS_1$), and sewage sludge (SS) were studied by electron spin resonance (ESR) spectroscopy and potentiometric titrations. Cu(II)-WSOF complexes produced $g_{11}$ values which were larger than $g_{\perp}$ values, indicating that the coordination of Cu(II) complex was an elongated octahedron. At liquid $N_2$ temperature (77K), the Cu(II)-W complex showed an anisotropic ESR spectrum while the Cu(II)-SS complex showed an isotropic spectrum. These spectral results suggest that the oxygen donor ligands of W may form relatively strong bonds with $Cu^{2+}$ due to extensive chelation while ligands of SS may form little or no chelate bonds with $Cu^{2+}$. The ESR spectra of Cu(II)-SS complex also suggest that each of four in-plane ligands (e.g., $COO^-$, $H_2O$, $Cl^-$, etc.) may act independently as monodentate ligands. Oxygen donor ligands such as aromatic carboxyl groups were probably the major Cu(II) binding sites in W. Sulfonate, aliphatic carboxyl group, and N-containing ligands were probably the major binding sites in SS at pH 5. The Cu(II) complexation with N-containing groups increased as sludge was added to the soil. Much higher (6x) pyridine concentrations were required to displace W from Cu(II)-W complex as compared to the Cu(II)-SS complex.

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A Study on the Model Test for Estimating Dynamic Vertical Load Added to Shallow Foundation for Machine (진동기 얕은기초에 추가되는 동적 연직하중 산정을 위한 모형실험 방안 연구)

  • Ha, Ik-Soo;Yoo, Mintaek
    • Journal of the Korean Geotechnical Society
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    • v.36 no.11
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    • pp.157-165
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    • 2020
  • At present, there are no clearly stated criteria or theories in calculating additional vertical dynamic loads that occur at the machine foundation due to vibration and reflecting them in the design at home and abroad. According to the domestic standard, although it is not a serious vibration condition, the additional dynamic load due to vibration is considered up to 100% of the static load. This is an extremely conservative design. The purpose of this study is to propose a model test method for evaluating the quantitative magnitude of additional dynamic loads that are generated at certain static loads due to vertical mechanical vibrations. As preliminary basic tests for the model tests, the test for evaluating the effects of reflective wave that may occur within a limited size soil box and the test for estimating the natural frequency of the devised model soil-foundation system were carried out. From the analysis of results for basic tests, a method to minimize the influence of the reflected wave was prepared, and the effect of the resonance of the model system was minimized during the model tests. After the basic tests, the main model tests were conducted. Through the proposed main test, the quantitative magnitude of additional dynamic loads caused by machine vibration on a shallow foundation for machine on medium dense sand foundations were evaluated. From the results of the model test, the feasibility of design applied at home and abroad was reviewed.

Isolation of N-Iauroyl Tyrosine Antibiotic in E. coli Carrying N-acyl Amino Acid Synthase Gene from Environmental DNA in Korean Soils (한국 토양 환경유래의 N-acyl amino acid synthase 유전자에 의한 대장균 내 항생제 N-lauroyl tyrosine 생산)

  • Yeo, Yun-Soo;Lim, Yoon-Ho;Kim, Jeong-Bong;Yang, Jung-Mo;Lee, Chang-Muk;Kim, Soo-Jin;Park, Min-Seon;Koo, Bon-Sung;Yoon, Sang-Hong
    • Applied Biological Chemistry
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    • v.50 no.4
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    • pp.262-267
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    • 2007
  • To access the natural product antibiotics produced by uncultured microorganisms, six cosmid libraries of DNA extracted directly from soil samples (environmental DNA, eDNA) were constructed and screened for the production of antibacterial active molecules. Of the approximately 60,000 clones screened, one antibacterial clone (YS92B) was detected. Ethyl acetate extracts of clone YS92B showed antibacterial activity against various pathogenic bacteria (Listeria monocytogenes, Bacillus subtilis, Pseudomonas syringae, Xanthomonas campestris pv. oryzae, Staphylococcus epidemis). Active constituents from cultures of YS92B were isolated and purified using a bioassay-guided fractionation against B. subtilis through a series of procedures (ethyl acetate extraction, Sephadex LH20 column chromatography, High Performance Liquid Chromatography). NMR (Nuclear Magnetic Resonance) spectral analysis of a major antibacterial active YS92B-VII indicated that it is a lauric acid linked to tyrosine. This report describes the characterization of antibacterially active long chain N-acyl derivatives of tyrosine that are produced by eDNA clones hosted in Escherichia coli from Korean soils.

Design and Performance Evaluation of Two-Layered Microwave Absorbers(Dielectric/Magnetic) for Wide Oblique Incidence Angles Used for ITS (ITS용 2층형 전파 흡수체(유전체/자성체) 설계 및 경사 입사 흡수 특성 해석)

  • Kim, Jae-Woong;Kim, Sung-Soo
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.18 no.11
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    • pp.1217-1223
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    • 2007
  • Advanced microwave absorbers for wide oblique incidence angles are required in many applications including wireless communication or vehicle identification in ITS(Intelligent Transport System) where 5.8 GHz DSRC(Dedicated Short Range Communication) system is applied. In this study, two-layered microwave absorber(with a laminate structure of dielectric/magnetic composites) has been designed for the achievement of low reflection coefficient over wide incidence angles at 5.8 GHz. Iron flake particles are used as the filler in the absorbing layer, and the magnetic composite sheet exhibits high magnetic loss due to ferromagnetic resonance in gigahertz frequencies. The surface layer of low dielectric constant containing small amount of carbon black is used as the impedance transformer. On the basis of transmission line theory, the reflection loss has been calculated for the two-layer structure with variation of incident angles for both TE(Transverse Electric) and TM(Transverse Magnetic) polarizations. At the optimum thickness of the composite layers, a low value of reflection loss(less than -10 dB) has been predicted for wide incidence angles up to $55^{\circ}$ which is in good agreement with the measured value determined by free-space measurement.

Field Map Estimation for Effective Fat Quantification at High Field MRI (고자장 자기공명영상에서 효율적인 지방 정량화를 위한 필드 맵 측정 기술)

  • Eun, Sung-Jong;Whangbo, Taeg-Keun
    • The Journal of the Korea Contents Association
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    • v.14 no.11
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    • pp.558-574
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    • 2014
  • The number of fatty liver patients is sharply growing due to the rapid increase in the incidence of metabolic syndrome, which can lead to diseases such as abdominal obesity, hypertension, diabetes, and hyperlipidemia. Early diagnosis requires examinations using magnetic resonance imaging (MRI), wherein quantitative analyses are implemented through a professional water-fat separation method in many cases, as the intensity values of the areas of interest and non-interest are considerably similar or the same. However, such separation method generates inaccurate results in high magnetic fields, where the inhomogeneity of the fields increases. To overcome the limits of such conventional fat quantification methods, this paper proposes a field map estimation method that is effective in high magnetic fields. This method generates field maps through echo images that are obtained using the existing IDEAL sequences, and considers the wrapping degree of the field maps. Then clustering is performed to separate calibration areas, the least square fits based on the region growing method schema of the separated calibration areas, and the histograms are adjusted to separate the water from the fats. In experiment results, our proposed method had a superior fat detection rate of an average of 86.4%, compared to the ideal method with an average of 61.5% and Yu's method with an average of 62.6%. In addition, it was confirmed that the proposed method had a more accurate water detection rate of 98.4% on the average than the 88.6% average of the fat saturation method.

Role of Anxiety in Concealed Information Test : an fMRI study (숨긴정보검사에서 불안의 역할 : fMRI 연구)

  • Eum, Yeong-Ji;Eom, Jin-Sup;Park, Kwang-Bai;Sohn, Jin-Hun
    • Science of Emotion and Sensibility
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    • v.14 no.2
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    • pp.227-234
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    • 2011
  • The purpose of present study was to examine brain functions associated with intention to conceal information. Kubo & Nittono(2009) and Verschuere et al.(2009) studied the intention to conceal information using P300 amplitude. On the basis of these two studies, present study attempted to identify brain area while participants were performing concealed information test. 19 healthy college students participated in fMRI-based concealed information test. Participants' name were used as concealed information. The test was performed in two conditions. In the intention condition, participants were instructed to try leaving their names undetected by suppressing their brain response to it. In the no intention condition, participants performed the test without intention to conceal. The fMRI results showed that the right anterior cingulated cortex (Rt. ACC), and left orbito-frontal cortex (Lt. OFC) activations were greater in the deceptive condition than the truth condition. These finding confirmed that ACC is area a deception-specific process as shown in the previous fMRI study. The OFC activation was also observed in the deceptive condition. The OFC is an area known as associated with emotional response such as anxiety, fear, and guilty. The anxiety induced while participants were intended to conceal information might be related to the OFC activation.

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The Study of Surface Plasmonic Bands Using Block Copolymer Nanopatterns (블록공중합체 나노패턴을 이용한 표면 플라즈몬 연구)

  • Yoo, Seung Min
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.11
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    • pp.88-93
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    • 2017
  • It is important to develop a simple method oftuning localized surface plasmon resonance(LSPR) properties, due to their numerous applications. In addition, the careful examination of the shape, size and combination of metal nanoparticles is useful for understanding the relation between the LSPR properties and metal nanostructures. This article describes the dependence of theLSPR properties on the arrays of metal nanoparticles obtained from a block copolymer(BCP) micellar thin film. Firstly, two different Au nanostructures, having a dot and ring shape, were fabricated using conventional block copolymer micelle lithography. Then, Ag was plated on the Au nanostructures through the silver mirror reaction technique to obtain Au/Ag bimetallic nanostructures. During the production of these metallic nanostructures, the processing factors, such as the pre-treatment by ethanol, silver mirror reaction time and removal or not of the BCP, were varied. Once the Au nanoparticles were synthesized, Ag was properly plated on the Au, providing two distinguishable characteristic plasmonic bands at around 525nm for Au and around 420nm for Ag, as confirmed bythe UV-vis measurements. However, when a small amount of Au seed nanoparticles, which accelerate the Ag plating speed,was formed by usinga block copolymer with a relatively highmolecular weight, all of the Au surfaces were fully covered by Ag during the silver mirror reaction, showing only the characteristic peak for Ag at around 420nm. The Ag plating technique on Au nanoparticles pre-synthesized from a block copolymer is useful to study the LSPR properties carefully.

Complete Rupture of the Origins of Rectus Femoris Occurred During Relay Race - A Case Report - (릴레이 경주 중에 발생한 대퇴직근 기시부의 완전 파열 - 증례보고 -)

  • Jeon, Seung-Ju;Jeon, Ho-Seung;Moon, Chan-Sam;Noh, Haeng-Kee;Ha, Seung-Joo
    • Journal of Korean Orthopaedic Sports Medicine
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    • v.7 no.2
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    • pp.151-155
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    • 2008
  • During sports activity, rectus femoris muscle can be commonly injured as the quadriceps contracts forcefully to extend the knee and flex the hip, and rectus femoris muscle has a high percentage of type II muscle fibers which enable it to produce rapid forceful activity and the muscle is the only biarticular muscle of the quadriceps. Avulsion fractures by the traction of rectus femoris from the anterior inferior iliac spine in children are often reported. Rarely, complete rupture of proximal musculotendinous junction of rectus femoris muscle in adult may occurs by chronic repetitive stimulation and may mimic soft tissue neoplasm in the case of no history of antecedent trauma. However, there has been no report of acute complete rupture of origins of the rectus femoris muscle during relay race till now. So, we report a case of acute complete rupture of origins of the rectus femoris muscle occurred during relay race in middle-aged man, diagnosed by magnetic resonance image and treated by surgical repair with review of current literature.

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