• Analytical Science and Technology
• /
• v.21 no.1
• /
• pp.9-13
• /
• 2008

We have collected a batch of leaf samples at several main crossroads in Daejeon and a background site to obtain distribution of $CO_2$ (greenhouse gas) due to fossil fuel combustion. The leaf samples were treated with AAA method and ${\Delta}^{14}C$ values of them were measured using AMS. ${\Delta}^{14}C$ values of downtown sites were found to be lower by 27-102 ‰ than that of the background site, and the ratio of $CO_2$ originated from fossil fuel combustion in the atmosphere of Daejeon could be calculated from the differences of ${\Delta}^{14}C$ values. The average ${\Delta}^{14}C$ of the background site, around Kyeryong mountain, was measured to be $35{\pm}8$ ‰, and this value is lower than 66.3 ‰, which have been known as the backgdound values in USA.

• Journal of Korean Institute of Industrial Engineers
• /
• v.14 no.2
• /
• pp.115-129
• /
• 1988

This paper discusses an analytical method to derive the efficiency and the average storage level of an unreliable two-machine, two-stage automatic transfer line with interstage buffer storage. Extensive numerical experiments and simulations are also conducted to see the behavior of the system under the wide range of parameter values as well as various distributions.

• Journal of Environmental Health Sciences
• /
• v.35 no.5
• /
• pp.402-410
• /
• 2009

This study was carried out to examine the optimal analytical method for determination of urinary toxic arsenic (inorganic arsenic and its metabolites) by HG-AAS (hydride generation-atomic absorption spectrometry). In the analysis of SRMs (standard reference materials), method E (addition of 0.4% L-cysteine to pre-reductant and use 0.04M HCl as carrier acid) showed the most accurate results compared with the reference values. In the analysis of 30 urinary samples, analytical results were significantly different depend on the component of pre-reductant and the concentration of carrier acid. When the concentration of carrier acid was higher, the analytical result was lower. The recovery rates of MMA (monomethylarsonic acid) and DMA (dimethylarsenic acid) were varied by the concentration of pre-treatment acid and carrier acid and hydride generation reagents. When the concentration of carrier acid was 1.62 M (5% HCl), the recovery rates of DMA was 1%. The recovery rates of MMA and DMA in method E (=V) were 102% and 100%, respectively. The results of this study suggest that the component and concentration of pre-reductant and carrier acid must be carefully adjusted in the analysis of urinary arsenic, and method E is recommendable as the most precise analytical method for determination of urinary toxic arsenic.

• Analytical Science and Technology
• /
• v.13 no.2
• /
• pp.179-188
• /
• 2000

Trace elements in air samples artificially loaded on filters with urban dust and the bulk material of urban dust as an environmental sample were determined non-destructively using instrumental neutron activation analysis. Standard reference material (Urban Dust, SRM 1648) of the National Institute of Standard and Technology was used for the analytical quality control. The relative error for 37 elements was less than 15% and the standard deviation was less than 10%. 29 elements in the urban dust and 21 elements in the loaded filter sample were determined respectively. To evaluate the proficiency and reliability of the measurement, data intercomparison was performed and 39 analytical laboratories participated in the analysis using different analytical methods; neutron activation analysis, particle induced X-ray emission analysis, X-ray fluorescence analysis and atomic absorption spectrometry. Z-scores were calculated using the standard deviation of the laboratorie's mean as target standard deviation, and a good result was obtained that the values fall between -1 and +1 except some elements.

• Advances in materials Research
• /
• v.8 no.3
• /
• pp.197-217
• /
• 2019

In this study, the interfacial stresses in RC beams strengthened by externally bonded prestressed GFRP laminate are evaluated using an analytical approach, based on the equilibrium equations and boundary conditions. A comparison of the interfacial stresses obtained from the present analytical model and other existing models is undertaken. Otherwise, a parametric study is conducted to investigate the effects of geometrical and material properties on the variation of interfacial stresses in damaged RC beams strengthened by externally bonded prestressed GFRP laminate. The results obtained indicate that the damage degree has little effect on the maximum shear stress, with a variation less than 5% between the damaged and undamaged RC beams. However, the results also reveal that the prestressing level has a significant effect on the interfacial stresses; hence the damaged RC beam strengthened with an initial prestressing force of 100 kN gives 110% higher maximum shear stress than the damaged RC beam strengthened with an initial prestressing force of 50 kN. The values of shear stress obtained by the analytical approach are approximately equal to 44% of those obtained from the numerical solution, while the interfacial normal stresses predicted by the numerical study are approximately 26% higher than those calculated by the analytical solution.

• Journal of Ginseng Research
• /
• v.37 no.4
• /
• pp.475-482
• /
• 2013

The main active components of Panax ginseng are ginsenosides. Ginsenoside Rb1 and Rg1 are accepted as marker substances for quality control worldwide. The analytical methods currently used to detect these two compounds unfairly penalize steamed and dried (red) P. ginseng preparations, because it has a lower content of those ginsenosides than white ginseng. To manufacture red ginseng products from fresh ginseng, the ginseng roots are exposed to high temperatures for many hours. This heating process converts the naturally occurring ginsenoside Rb1 and Rg1 into artifact ginsenosides such as ginsenoside Rg3, Rg5, Rh1, and Rh2, among others. This study highlights the absurdity of the current analytical practice by investigating the time-dependent changes in the crude saponin and the major natural and artifact ginsenosides contents during simmering. The results lead us to recommend (20S)- and (20R)-ginsenoside Rg3 as new reference materials to complement the current P. ginseng preparation reference materials ginsenoside Rb1 and Rg1. An attempt has also been made to establish validated qualitative and quantitative analytical procedures for these four compounds that meet International Conference of Harmonization (ICH) guidelines for specificity, linearity, range, accuracy, precision, detection limit, quantitation limit, robustness and system suitability. Based on these results, we suggest a validated analytical procedure which conforms to ICH guidelines and equally values the contents of ginsenosides in white and red ginseng preparations.

• Structural Engineering and Mechanics
• /
• v.77 no.5
• /
• pp.601-612
• /
• 2021

To study the vibration characteristics of a high-speed railway continuous girder bridge-track coupling system (HSRCBT), a coupling vibration analysis model of an m-span continuous girder bridge-subgrade-track system with n-span approach bridge was established. The model was based on the energy and its variational method, where both the interlaminar slip and shear deformation effects were considered. In addition, the free vibration equations and natural boundary conditions of the HSRCBT were derived. Further, according to the coordination principle of deformation and mechanics, an analytical method for calculating the natural vibration frequencies of the HSRCBT was obtained. Three typical bridge-subgrade-track coupling systems of high-speed railway were taken and the results of finite element analysis were compared to those of the analytical method. The errors between the simulation results and calculated values of the analytical method were less than 3%, thus verifying the analytical method proposed in this paper. Finally, the analytical method was used to investigate the influence of the number of the approach bridge spans and the interlaminar stiffness on the natural vibration characteristics of the HSRCBT based on the degree of sensitivity. The results suggest the approach bridges have a critical number of spans and in general, the precision requirements of the analysis could be met by using 6-span approach bridges. The interlaminar vertical compressive stiffness has very little influence on the low-order natural vibration frequency of HSRCBT, but does have a significant influence on higher-order natural vibration frequency. As the interlaminar vertical compressive stiffness increases, the degree of sensitivity to interlaminar stiffness of each of the HSRCBT natural vibration characteristics decrease and gradually approach zero.

• Structural Engineering and Mechanics
• /
• v.73 no.2
• /
• pp.109-121
• /
• 2020

This study aims to estimate crack location and crack length in damaged beam structures using transfer matrix formulations, which are based on analytical solutions of governing equations of motion. A single variable shear deformation theory (SVSDT) that considers parabolic shear stress distribution along beam cross-section is used, as well as, Timoshenko beam theory (TBT). The cracks are modelled using massless rotational springs that divide beams into segments. In the forward problem, natural frequencies of intact and cracked beam models are calculated for different crack length and location combinations. In the inverse approach, which is the main concern of this paper, the natural frequency values obtained from experimental studies, finite element simulations and analytical solutions are used for crack identification via plots of rotational spring flexibilities against crack location. The estimated crack length and crack location values are tabulated with actual data. Three different beam models that have free-free, fixed-free and simple-simple boundary conditions are considered in the numerical analyses.

• Journal of Environmental Health Sciences
• /
• v.37 no.1
• /
• pp.57-63
• /
• 2011

Crocidolite quality control (QC) sampling created by the wet generation method has been validated by validation tests such as the accuracy, precision, and storage tests. For this study we designed and developed a manufacturing apparatus and standard operating procedure for making these QC samples. The most important step in the procedure of making QC samples was the stage eliminating static electricity in asbestos fibers. This static electricity hampers the fibers clog functioning. In accuracy and precision tests by phase contrast microscopy analysis, the difference between the reference values and the studied values was at maximum 17.8%. This satisfies the AIHA proficiency analytical test criteria for asbestos. We could confirm the nearly even distribution of crocidolite fibers on the membrane filter. Also, there was no loss of fibers in the storage test after the one month.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.13 no.2
• /
• pp.229-235
• /
• 1993

This paper examines the conventional methods to estimate the uplift capacity of the piles in sands and points out the limitations of each methods. And the modified method to estimate the uplift capacity more correctly is proposed. The comparisons between each theoretical values and the reported experimental results show that Meyerhof method tends to underestimate the uplift capacity for dense sands, but to overestimate for medium and loose sands. Of the analytical methods, Chattopadhyay and Pise method is most agreeable to the experimental data. But the difference between the measured values and the analytical ones is significant. This difference can be reduced by the modification of the failure surface proposed by Chattopadyay and Pise.