• Title/Summary/Keyword: amphibole

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Geochemical Studies of BIF in Wugang, North China Craton: Implication for the Genesis (북중국 우강 지역에 분포하는 호상철광상의 성인에 대한 지구화학적 연구)

  • Moon, Inkyeong;Lee, Insung;Yang, Xiaoyong
    • Economic and Environmental Geology
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    • v.52 no.3
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    • pp.213-221
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    • 2019
  • The Wugang banded iron formation (BIF) is located within the Taihua complex at the southern margin of the North China Craton (NCC). In this study, we analyzed major elements and rare-earth elements in iron ores from the Wugang BIF, to study the type of BIFs and their formation mechanism in combination with previously-published data from the literature. We found that the iron ores from the Wugang BIF display two types of banding textures, which can be described as weak banding or no banding. The samples are composed of coarse-grained magnetite, quartz, pyroxene, and amphibole. Based on our geochemical results, mixing of a hydrothermal fluid with sea water led to the precipitation of the Wugang BIF, and there is evidence of crustal contamination. These results, combined with previous literature data, almost all of the iron ores lack Ce anomalies, though some samples show negative Ce anomalies. Our results indicate that the Wugang BIF was formed in a dominantly reducing environment, although the surfaces were relatively oxidized. Geochemical evidence suggests that the Wugang BIF iron ores were formed in a near-shore continental-shelf environment or in a back-arc basin. The BIF is known as interbedded with migmatite, amphibole gneiss, minor quartz and marble, which indicating lack of volcanic materials input. This study, combined with previous results on geochemical interpretation of related wall rock of Wugang BIF, demonstrated that Wugang BIF belongs to Superior-type BIF.

Investigation on Potential Value for Maritime Cultural Heritage, Historical and Petrographic Characteristics of the Seosan Black Submerged Rocks (Geomenyeo) in Korea (서산 검은여의 역사적 및 암석기재적 특징과 해양유산적 잠재가치 검토)

  • Park, Jun Hyoung;Lee, Chan Hee
    • Journal of Conservation Science
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    • v.35 no.2
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    • pp.131-144
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    • 2019
  • The Seosan Geomenyeo(black submerged rocks), once located at the Cheonsuman bay of Buseokmyeon in Seosan, Korea, is a reef rock now exposed on the land surface. The Geomenyeo can also be found in the ancient geographic maps around the area. The local geographic names, like Buseok and Buseoksa temple are derived from the Geomenyeo. It is composed of ultramafic rocks complex and intrusive felsic igneous rocks. These rocks show diverse facies with various petrographic characteristics caused by geological processes such as intrusion and alteration. Ultramafic rocks complex can be roughly categorized as coarse grained ultramafic rocks and medium grained mafic rocks. Both cases are composed of pyroxene and amphibole, showing the general rock facies of pyroxenite, diabase and lamprophyre. Felsic igneous rocks includes pinkish medium grained granite, porphyritic amphibole granite and aplite with varied mineral compositions. The Geomenyeo is the only ultramafic rocks complex in the Cheonsuman Bay; moreover, it has a distinctive geological and scenic value, as well as a symbolic property. In order to preserve the Geomenyeo, it is necessary to investigate and promote it as a designated heritage site through academic studies, and compensate for the convenience and protection facilities. Additionally, the Geomenyeo should be evaluated as a maritime heritage site, due to the unique local culture as it succeeds the recognition of forefathers which regarded it as a local scenic site with significance.

Mg-skarn Minerals from Magnetite Deposits of the Janggun Mine, Korea (장군광산(將軍鑛山)의 자철석광상(磁鐵石鑛床)에서 산출(産出)되는 Mg-스카른광물(鑛物))

  • Lee, Chan Hee;Song, Suckhwan;Lee, Hyun Koo
    • Economic and Environmental Geology
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    • v.29 no.1
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    • pp.11-21
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    • 1996
  • The first Mg-skarn minerals are found from magnetite ore deposits of the Janggun mine, Korea. The skarn minerals are composed of mostly chondrodite, olivine, chlorite, serpentine, phlogophite, talc, apatite, magnesite, dolomite, siderite and trace amount of clinopyroxene, amphibole, garnet, wollastonite associated with magnetite, pyrrhotite and pyrite. The skarn zone is developed in the magnetite deposits at the contact of the Mg-rich Janggun Limestone Formation and the Chunyang granite. The chondrodites are columnar and radial shapes and some of them show twins. The chemical compositions of twinning-type chondrodites have high FeO (4.63 to 5.6 wt%), MnO (0.26 to 0.46 wt%) and low MgO (55.02 to 56.18 wt%) relative to the radial-type chondrodites. Twinning in chondrodite has been formed in close relation to substitution between Mg and Fe + Mn in humite solid solution. Temperature, $-logfo_2$ and $X_{CO2}$ during the skarn stage of magnetite deposits from the Janggun mine range from 395 to $430^{\circ}C$, from 30.5 to 31.2 atm and from 0.06 to 0.09, respectively.

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Occurrences of Asbestos within Gapyeong Serpentinite Mines and Characteristics of Host Rocks (가평 사문암 광산의 석면 산출의 산상과 모암의 특성)

  • Song, Suckhwan;Kang, Joongu
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.26 no.3
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    • pp.253-266
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    • 2016
  • Objectives: This study is for characteristics of asbestos occurrence (NOA, naturally occurring asbestos) from the Gapyeong area and its host rocks, serpentinites. Methods: Representative samples are collected from the serpentinite bodies, following degrees of hydrothermal alteration and metamorphism, after about 2 year field trips. Mineralogical, morphological and optical characteristics of the asbestos and host rocks are confirmed by PLM, XRD EPMA and SEM results. Results: The serpentinites are dunites and harzburgites, and host asbestos, including chrysotile, tremolite and actinolite. The asbestos chrysotiles are found as veins ranging from several millimeters to several centimeters in thickness, while asbestos-tremolite and -actinolite occur along cracks and fractures ranging up to ten centimeters in thickness. The chryostiles occur mainly as cross and slip fibers, while the amphibole asbestos is found as vein, slip and oblique fibers. More tremolitic grains are colorless and commonly show elongated or fiber shapes, whereas the magnesio hornblende grains mainly show light green and occur as subhedral to euhedral diamond grains. Conclusions: Overall characteristics of serpentinites from the Gapyeong area are similar to worldwide orogenic-related Alpine type ultramafic rocks serpentinized and serpentinites in South Chungcheong-do Province, Korea, and occurrences of asbestos are similar to those of the ultramafic bodies in South Chungcheong-do Province.

Characteristics of Hydrothermal Chlorite and Its Interstratification with 7-${\AA}$ Phase in Rhyodacitic Tuff, Western Pusan, Korea (열수변질기원 녹니석과 이에 수반된 혼합층상 광물의 특징)

  • 추창오;김수진
    • Journal of the Mineralogical Society of Korea
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    • v.13 no.4
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    • pp.196-204
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    • 2000
  • We present characteristics of hydrothermal chlorite and its interstratification with 7-$\AA$ mineral phase that occur in the propylitic alteration zone of the Bobae sericite deposit formed in rhyodacitic tuff. Chlorite is found as disseminated fine-grained aggregate or replacement materials of precursor minerals such as Fe-oxides and amphibole. Based on X-ray diffraction(XRD), all chlorites belong to IIb polytype and the (060) reflections averaging $1.53~1.54\AA$ indicate a trioctahedral structure. Chemical compositions of chlorite show that the Fe/(Fe+Mg) values are mostly in the range of 0.44~0.53, and cation deficiencies in octahedral sites range from 0.06 to 0.37. Under scanning electron microscope(SEM) chlorite occurs as well-crystallized aggregates and is subparallely stacked in interstices or between grain boundaries of associated minerals. transmission electron microscopic(TEM) images reveal that chlorite shows regular layers with $14-\AA$ spacings, locally interstratified with $7-\AA$ or $21-\AA$ periodicities. The $21- \AA$ periodicity corresponds to the sum of the $d_{001}$ values of chlorite and $7-\AA$ phase. The chlorite packet coexisting with 7-$\AA$ layers displays abundant defects such as edge dislocations and layer terminations. Selected-area electron diffraction(SAED) indicates that chlorite and $7-\AA$ phase are randomly interstratified in the mixed-layer areas. We propose a lateral change of layers for the polymorphic transition of $7-\AA$ phase to chlorite.e.

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Spectral Characteristics of Hydrothermal Alteration in Zuru, NW Nigeria

  • Aisabokhae, Joseph;Tampul, Hamman
    • Korean Journal of Remote Sensing
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    • v.35 no.4
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    • pp.535-544
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    • 2019
  • This study demonstrated the ability of a Landsat-8 OLI multispectral data to identify and delineate hydrothermal alteration zones around auriferous prospects within the crystalline basement, North-western Nigeria. Remote sensing techniques have been widely used in lithological, structural discrimination and alteration rock delineation, and in general geological studies. Several artisanal mining activities for gold deposit occur in the surrounding areas within the basement complex and the search for new possible mineralized zones have heightened in recent times. Systematic Landsat-8 OLI data processing methods such as colour composite, band ratio and minimum noise fraction were used in this study. Colour composite of band 4, 3 and 2 was displayed in Red-Green-Blue colour image to distinguish lithologies. Band ratio ${\frac{4}{2}}$ image displayed in red was used to highlight ferric-ion bearing minerals(hematite, goethite, jarosite) associated with hydrothermal alteration, band ratio ${\frac{5}{6}}$ image displayed in green was used to highlight ferrous-ion bearing minerals such as olivine, amphibole and pyroxenes, while ratio ${\frac{6}{7}}$ image displayed in blue was used to highlight clay minerals, micas, talc-carbonates, etc. Band rationing helped to reduce the topographic illumination effect within images. The result of this study showed the distribution of the lithological units and the hydrothermal alteration zone which can be further prospected for mineral reserves.

The Mineralogy and Geochemistry of the Uppermost Sediments of the Lake Hovsgol, North Mongolia : It's Implication to the Paleoenvironmental Changes

  • Tumurhuu, D.;Narantsetseg, Ts.;Ouynchimeg, Ts.
    • The Korean Journal of Quaternary Research
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    • v.18 no.2 s.23
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    • pp.3-3
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    • 2004
  • One short core with length of 146cm(HB-107, at coordinates of $N51^{\circ}$11'37.5";$E100^{\circ}$24'45.6", from 229m water depth was subject of the present study. The sub-samples of the core were analyzed for the water contents (WC%), biogenic silica, identification of the main phases, grain size distribution, geochemistry and some physical properties of sediment(Wet density and Magnetic susceptibility) with aims of recording palaeo-environmental changes in Northem Mongolia. The evaluation of the geochemical and mineralogical proxies on palaeo-climated and palaeo-environmental changes are based on comparison to the behvior of biogenic silica through core, as later one had been showed itself, as good indicator of the climate and environmental fluctuation. Age model of the investigating core based on previously C 14 dated core HB105 taken from the central part of the Hobsgol Lake and the result had been published elsewhere. The core consists of two litological varieties : upper diatomaceous silt, lower clay. According to the age model the upper diatomaceous silt formed during the Holocene, lower caly-during the late Pleistocene glacial period. The geochemistry and phase identification analysis on the core samples are resulted in determining main minerals that form the bottom sediments and their geochemistry. The main include quartz, felspar, muscovite, clinochlore, amphibole and carbonate phase(dolomite and calcite). Through the core not only occur the relative quantitative changes of the main phases, but also happen that the carbonate phase completely disappear in diatomaceous silt. This is believed to be related to the lake water salinity changes, which occurred during the trassition period from Pleistocene glacial-to the Holocene interglacial. These abrupt changes of the mineralogy have been clearly traced in geochemistry of sediments, specially in calcium concentration, which is high in lower clay and low in upper diatomaceous silt. That means, geochemistry and mineralogy of the bottom sediments can be used as proxy data on palaeo-climate and palaeo-environmental changes.

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Serpentinization of the Ultramafic Rock in the Yesan-Gongju-Cheongyang Area, Korea (충남 예산-공주-청양지역의 초염기성암의 사문암화 작용)

  • 김건영;김수진
    • Journal of the Mineralogical Society of Korea
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    • v.10 no.2
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    • pp.126-138
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    • 1997
  • Serpentinite of the Yesan-Gongju-Cheongyang area has been formed by serpentinization of ultramafic rocks. The ultramafic rock might be composed mainly of oilvine with minor pyroxene and amphibole. Olivine has a considerably restricted chemical compositional ranging from Fo90 to Fo93. Fresh serpentinite containing large amount of oilvine is usually massive in occurrence and dark green to black in color. Serpentine minerals occur not only as major mineral of serpentinite, but also as remnants in the talc ore which was formed from serpentinite. XRD study indicates that antigorie is the most abundant serpentine mineral of the serpentinite. Serpentinite consisting of antigorite usually shows non-pseudomorphic texture, whereas that consisting of lizardite shows pseudomorphic texture. Antigorite is found along the margins or fractures of olivine grains resulting in the formation of network of magnetite which was formed at the time of serpentinization. Lizardite, subordinate constituent mineral of serpentinite, frequently shows pseudomorphic mesh-texture after olivine. The chemical differences between antigorite and lizardite/chrysotile are small, so both minerals are not easily discernible with the electron microprobe. Antigorite occuers as elongate blades, flakes, or plates forming interpenetrating texture to obliterate previous textures. SEM study also shows that most serpentine minerals occur in platy or tabular form rather than in asbestiform. Fractures formed after main serpentinization are observed within the pseudomorphic central olivine grain. Careful observation of the serpentine pseudomorphs gives a great deal of data on the pre-serpentinization nature of the serpentine pseudomorphs gives a great deal of data on the pre-serpentinization nature of the ultramafic rocks. It is inferred that the serpentinization took place after the emplacement of ultramafic body into the relatively wet environment ceased and the cooling intrusive body crossed into the stability field of serpentine. It is inferred that the final pervasive serpentinization took place over a long time, by hydrothermal water supplied through the fracture system produced during emplacement of ultramafic rock.

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Geochemical Characteristics of the Mineral Water in Taegu Area. (대구지역에 분포하는 약수의 지구화학적 특성)

  • 김종근;이재영
    • Journal of Environmental Health Sciences
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    • v.23 no.3
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    • pp.56-65
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    • 1997
  • Chemical analysis, statistical analysis and geochemical study were carried out to investigate the influence of the geology on the chemical characferistics of the mineral water in Taegu area. A simple comparision between the chemical components of the mineral water and their bedrocks indicates that the bedrock types in the catchmerit area control the chemical characteristics of the surface water. However more objective evidences for the mineral water-bedrock relationship come from the statistical analyses(cluster analysis and factor analysis). The results of the statistical analyses suggest that the bedrock type factor explains the data variation seven times as much as pollution does, which evidently indicates that the bedrock in the study area mainly control the mineral water chemistries. The results of comparision of the statistical analyses results with the mineral weathering reactions and mineral stability diagrams can be summarized as follows: 1. Plagioclase weathering to kaolinite provides SiO$_2$ , Ca$^{2+}$ and Na$^+$, and muscovite weathering to kaolinite provides K$^+$, and amphibole and mica minerals weathering to kaolinite provides F to the mineral water. Most of Ca$^{2+}$ and Mg$^{2+}$ in the mineral water are the products of carbonate mineral dissolution. SO$_4^{2-}$ may be the byproduct of sulfide oxidation. 2. The weatering of silicate mineral produces Ca-rich smectite and kaolinite, but Ca-rich smectite is unstable and will be transformed to more stable kaolinite because of the continuous dilution of the mineral water by precipitation. By Hashimoto's Mineral Balance Index, S-10 and S-12 mineral spring water were evaluated tasty and healthy water, S-9 and S-11 mineral spring water were evaluated tasty water and S-7, S-8 and S-13 mineral spring water were evaluated healthy water.

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Characteristics of Analytical Errors Shown in the Korean Quality Control Program on Bulk Asbestos Analyses (고형물 석면분석에 대한 국내 정도관리 프로그램에서 나타난 분석 오류의 특성)

  • Kwon, Jiwoon;Chung, Eun-Kyo;Lee, In Seop;Kang, Seong-Kyu;Kim, Hyunwook
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.21 no.4
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    • pp.222-226
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    • 2011
  • This study was conducted to identify the characteristics of analytical errors shown in the Korean quality control program on bulk asbestos analyses using polarized light microscopy (PLM). 179 participating laboratories were required to analyze 4 samples respectively and asked to classify each test sample as asbestos-containing (positive) or non-asbestos-containing (negative). For positive samples, participants were also asked to identify the type and semiquantitate the contents of asbestos present. The test results showed 21 (4%) false negative errors among 562 samples, 9 (6%) false positive errors among 154 samples and 53 (9%) asbestos identification errors among 562 samples. Most of false negative and positive errors were observed in a few types of samples. Higher frequencies of asbestos identification errors were shown in samples containing two or more types of asbestos and samples containing anthophyllite, tremolite or actinolite asbestos. For semiquantitative analyses, the ratios of mean to nominal weight contents were 2.1 for chrysotile and 2.9 for amphiboles. A tendency of over-estimation was observed in semiquantitative analyses using the visual estimation technique and higher in case of analyzing samples containing amphiboles than chrysotile. Coefficients of variation (CVs) of semiquantitative analytical results were 0.44~0.83 and 0.5~1.14 for samples containing chrysotile and amphibole asbestos, respectively.