• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.06a
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• pp.418-418
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• 2009

Vertically aligned arrays of multi-walled carbon nanotube (MWCNT) on layered Si substrates have been synthesized by water-assisted thermal chemical vapor deposition (CVD). We studied changes in growth by parameters of growth temperature, growth time, rates of gas and annealing time of catalyst. Also, We grew CNTs by adding a little amount of water vapor to enhance the growth of CNTs. $H_2$, Ar, and $C_2H_2$ were used as carrier gas and feedstock, respectively. Before growth, Fe served as catalyst, underneath which AI were coated as an underlayer and a diffusion barrier, respectively, on the Si substrate. The water vapor had a greater effect on the growth of CNTs on a smaller thickness of catalyst. When the water vapor was introduced, the growth of CNTs was enhanced than without water. CNTs grew 1.29 mm for 10 min long by adding the water vapor, while CNTs were 0.73 mm long without water vapor for the same period of time. CNTs grew up to 1.97 mm for 30 min prior to growth termination under adding water vapor. As-grown CNTs were characterized by using scanning electron microscopy (SEM), high resolution transmission electron microscopy (HRTEM), and Raman spectroscopy.

• Ocean and Polar Research
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• v.38 no.4
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• pp.339-345
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• 2016

Stable water vapor isotopes have been utilized as a tracer for studying atmospheric global circulations, climate change and paleoclimate with ice cores. Recently, since laser spectroscopy has been available, water vapor isotopes can be measured more precisely and continuously. Studies of water vapor isotopes have been conducted over the world, but it is the early stage in south Korea. For vapor isotopes study, a cryogenic sampling device for water vapor isotopes has been developed. The cryogenic sampling device consists of the dewar bottle, filled with extremely low temperature material and impinger connected with a vacuum pump. Impinger stays put in the dewar bottle to change the water vapor which passes through the inside of impinger into the solid phase as ice. The fact that water vapor has not sampled completely leads to isotopic fractionation in the impinger. To minimize the isotopic fractionation during sampling water vapor, we have tested the method using a serial connection with two sets of impinger device in the laboratory. We trapped 98.02% of water vapor in the first trap and the isotopic difference of the trapped water vapor between two impinger were about 20‰ and 6‰ for hydrogen and oxygen, respectively. Considering the amount of water vapor trapped in each impinger, the isotopic differences for hydrogen and oxygen were 0.33‰ and 0.06‰, respectively, which is significantly smaller than the precision of isotopic measurements. This work can conclude that there is no significant fractionation during water vapor trapping.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.148.2-148.2
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• 2013

We prepared hydrophobic PDMS-coated porous silica as pre-concentration adsorbent for chemical warfare agents (CWAs). Since CWAs can be harmful to human even with a small amount, detecting low-concentration CWAs has been attracting attention in defense development. Porous silica is one of the promising candidates for CWAs pre-concentration adsorbent since it is thermally stable and its surface area is sufficiently high. A drawback of silica is that adsorption of CWAs can be significantly reduced due to competitive adsorption with water molecule in air since silica is quite hydrophilic. In order to solve this problem, hydrophobic polydimethylsiloxane (PDMS) thin film was deposited on silica. Adsorption and desorption of chemical warfare agent (CWA) simulants (Dimethylmethylphosphonate, DMMP and Dipropylene Glycol Methyl Ether, DPGEM) on bare and PDMS-coated silica were studied using temperature programed desorption (TPD) with and without co-exposing of water vapor. Without exposure of water vapor, desorbed amount of DMMP from PDMS-coated silica was twice larger than that from bare silica. When the samples were exposed to DMMP and water vapor at the same time, no DMMP was desorbed from bare silica due to competitive adsorption with water. On the other hand, desorbed DMMP was detected from PDMS-coated silica with reduced amount compared to that from the sample without water vapor exposure. Adsorption and desorption of DPGME with and without water vapor exposing was also investigated. In case of bare silica, all the adsorbed DPGME was decomposed during the heating process whereas molecular DPGME was observed on PDMS-coated silica. In summary, we showed that hydrophobic PDMS-coating can enhance the adsorption selectivity toward DMMP under humid condition and PDMS-coating also can have positive effect on molecular desorption of DPGME. Therefore we propose PDMS-coated silica could be an adequate adsorbent for CWAs pre-concentration under practical condition.

• International Journal of Air-Conditioning and Refrigeration
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• v.7
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• pp.69-78
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• 1999

Effects of a non-absorbable gas on the absorption process in a vertical tube absorber has been investigated numerically. The water vapor mixed with air is absorbed into LiBr/water solution film. The flow is assumed to be laminar and fully developed in both liquid and gas phases. The diffusion and energy equations were solved in both phases to give the temperature and concentrations, from which heat and mass fluxes were determined. The local absorption rate has been shown to decrease as the mass fraction of air in the water vapor increases. The vapor pressure of water at the liquid-vapor is interface reduced significantly since the non-absorbable gas accumulates near the interface. The effects of non-absorbable gases on absorption rate become larger as the mass flow rate of the vapor decreases. For a small amount of non-absorbable gases, the total absorption rate of water vapor increases as the mass flow rate of the vapor decreases. The total absorption rate increases as the mass flow rate of the vapor increases for large concentrations of non-absorbable gases at the inlet of an absorber.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.10 no.4
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• pp.456-465
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• 1998

Effect of a non-absorbable gas on the absorption process in a vertical tube absorber was investigated numerically. The water vapor mined with air as the non-absorbable gas is absorbed into LiBr/water solution film. The flow is assumed to be laminar and fully developed in both liquid and gas phases. The diffusion and energy equations were solved in both phases to give the temperature and concentrations, from which heat and mass fluxes were determined. It was shown that the local absorption rate decreases as the mass fraction of air in water vapor increases. The vapor pressure of water at the liquid-vapor interface reduces significantly since the non-absorbable gas is accumulated near the interface. The effect of non-absorbable gases on absorption rate becomes larger as the mass flow rate of the vapor decreases. For small amount of non-absorbable gases the total absorption rate of water vapor increases as the mass flow rate of the vapor decreases. Total absorption rate increases as the mass flow rate of the vapor increases for large concentration of non-absorbables at the inlet of an absorber.

• Proceedings of the KSME Conference
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• 2002.08a
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• pp.397-400
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• 2002

Vapor explosion is one of the most important problems encountered in severe accident management of nuclear power plants. In spite of many efforts, a lot of questions still remain. So, KAERI launched a real experimental program called TROI using $UO_{2}$ and $ZrO_{2}$ to investigate the vapor explosion. Besides TROI tests, a small-scale experiment with molten-tin/water system was performed to quantify the characteristics of vapor explosion and to understand the phenomenology of vapor explosion. A vapor explosion was observed while the amount of air bubble and water temperature were systematically varied The mass and temperature of tin are $50\;g\;and\;150^{\circ}C$, respectively. Water temperature is set to $24^{\circ}C\;and\;50^{\circ}C$. The void fraction of air bubble ranges from $0\;to\;10\;{\%}$. The strength of vapor explosion was measured using dynamic pressure sensors attached in reactor tube wall. as a function of void fraction. In addition, a high speed video filming up to 1,000 flame/sec was taken in order to visually investigate the behavior of the vapor explosion .

• Journal of the Korean Society of Clothing and Textiles
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• v.17 no.4
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• pp.577-586
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• 1993

Pesticide protective clothing has not been frequently worn due to its lack of thermal comfort. It is important to develop fabrics which can allow the wearer to work in comfort. One of the possible way to achieve the goal is to produce fabrics with a water- and oil-repellent finish which would resist pesticide penetration but maintain some breathability. The purpose of this study were to evaluate the pesticide barrier properties of untreated and water- and oil-repellent finished nonwoven fabrics. Three types of nonwoven fabrics(Tyvek, Sontara and Kimlon) were used as test specimens. By pad-dry-cure method, each of the specimen was treated with fluorocarbon. The pesticide barrier properties (amount of pesticide penetration and residue) were measured by the gas chromatography. The performance properties of untreated and treated specimens were evaluated with respects to water pepellency(KS K 0590), oil repellency(AATCC 118), water resistance(KS K 0591, AATCC 42), water vapor transmission (KS A 1013) and air permeability(KS K 0570). The results of this study were as follows : 1) The untreated Sontara showed much more amount of pesticide penetration than untreated Tyvek and Kimlon, while the treated Sontara showed little amount of pesticide penetration. 2) After laundering, the amount of pesticide residue in the untreated and treated Sontara was less than that in Tyvek and in Kimlon. 3) Water- and oil-repellent finish improved water repellency, oil repellency, and water resistance of specimens. 4) The untreated Sontara and Kimlon showed higher water vapor transmission and air permeability than untreated Tyvek. Water vapor transmission and air permeability of treated specimen decreased compared to those of untreated.

• Atmosphere
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• v.26 no.1
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• pp.19-33
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• 2016

Water vapor in the atmosphere is an important element that generates various meteorological phenomena and modifies a hydrological cycle. In general, the Yeongdong region has a lot of snow compared to the other regions in winter due to the complex topography and an adjacent East Sea. However, the phase change from water vapor to ice cloud and further snowfall has little been examined in detail. Therefore, in this study, we investigated phase change of liquid water in terms of a quantitative budget as well as time lag of water vapor conversion to snowfall in the ESSAY (Experiment on Snow Storms At Yeongdong) campaign that had been carried out from 2012 to 2015. First, we classified 3 distinctive synoptic patterns such as Low Crossing, Low Passing, and Stagnation. In general, the amount of water vapor of Low Crossing is highest, and Low Passing, Stagnation in order. The snowfall intensity of Stagnation is highest, whereas that of Low Crossing is the lowest, when a sharp increase in water vapor and accordingly a following increase in precipitation are shown with the remarkable time lag. Interestingly, the conversion rate of water vapor to snowfall seems to be higher (about 10%) in case of the Stagnation type in comparison with the other types at Bukgangneung, which appears to be attributable to significant cooling caused by cold surge in the lower atmosphere. Although the snowfall is generally preceded by an increase in water vapor, its amount converted into the snowfall is also controlled by the atmosphere condition such as temperature, super-saturation, etc. These results would be a fundamental resource for an improvement of snowfall forecast in the Yeongdong region and the successful experiment of weather modification in the near future.

• Economic and Environmental Geology
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• v.46 no.4
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• pp.339-344
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• 2013

Water vapor isotopes can be excellent tools for understanding complex mechanisms in the water cycle and atmospheric hydrological cycle and they can be applied to various fields of paleoclimatology, atmospheric science, hydrogeology, oceanography, and ecohydrology. Thus, studies of global or local transport of water vapor may be able to provide a very useful clue to better understand the movements of water and energy in the atmosphere, hydrosphere and biosphere. In this study, the isotopic compositions of water vapor have been observed for moisture transport during the passage of Typhoon Bolaven at Korea Polar Research Institute (KOPRI), Incheon, in the western part of Korea, from August 27 to August 29, 2012. In the clear sky, the isotopic compositions of water vapor at KOPRI exhibited relatively higher isotopic ratios, which were near isotopic equilibrium with sea surface water (${\delta}^{18}O$=-14‰). On the other hand, a largely depleted isotopic ratios in surface water vapor were observed in association with the passage of Typhoon Bolaven (approximately 10‰ depleted compared to the clear sky). The fact that the isotopic minima in water vapor are encountered during the onset period of the Typhoon Bolaven with increases of relative humidity, which is consistent with, so called, "the amount effect".

• Journal of Astronomy and Space Sciences
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• v.27 no.3
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• pp.231-238
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• 2010

We analyzed global positioning system (GPS)-derived precipitable water vapor (PWV) trends of the Korea Astronomy and Space Science Institute 5 stations (Seoul, Daejeon, Mokpo, Milyang, Sokcho) where Korea Meteorological Administration meteorological data can be obtained at the same place. In the least squares analysis, the GPS PWV time series showed consistent positive trends (0.11 mm/year) over South Korea from 2000 to 2009. The annual increase of GPS PWV was comparable with the 0.17 mm/year and 0.02 mm/year from the National Center for Atmospheric Research Earth Observing Laboratory and Atmospheric InfraRed Sounder, respectively. For seasonal analysis, the increasing tendency was found by 0.05 mm/year, 0.16 mm/year, 0.04 mm/year in spring (March-May), summer (June-August) and winter (December-February), respectively. However, a negative trend (-0.14 mm/year) was seen in autumn (September-November). We examined the relationship between GPS PWV and temperature which is the one of the climatic elements. Two elements trends increased during the same period and the correlation coefficient was about 0.8. Also, we found the temperature rise has increased more GPS PWV and observed a stronger positive trend in summer than in winter. This is characterized by hot humid summer and cold dry winter of Korea climate and depending on the amount of water vapor the air contains at a certain temperature. In addition, it is assumed that GPS PWV positive trend is caused by increasing amount of saturated water vapor due to temperature rise in the Korean Peninsula. In the future, we plan to verify GPS PWV effectiveness as a tool to monitor changes in precipitable water through cause analysis of seasonal trends and indepth/long-term comparative analysis between GPS PWV and other climatic elements.